MBEZI BEACH HIGH SCHOOL

FORM SIX TERMINAL ASSESSMENT

CODE: 132/2 CHEMISTRY 2
(For both school and private candidates)
TIME: 3:00 HRS November 2023
INSTRUCTIONS
1. This paper consists of six (06) questions.
2. Answer only five (05) questions.
3. Each question carries twenty (20) marks.
4. Mathematical tables and non-programmable calculators may be used.
5. Cellular phones and any unauthorized materials are not allowed in the examination room.
6. Write your examination number on every page of your answer booklet(s)
7. For calculations you may use the following constants
• Universal gas constant, R=8.314JK-mol- or 0.0821K-atm mol-K-dm3
• Velocity of light, C=3.0 ×108m/s
• Standard temperature=273K
• GMV=22.3dm3
• 1Faraday = 96500C
• Standard pressure=760mmHg = 1.0 ×105N/M2 = 1 atm
QUESTION QUESTION FOR EXAMINER’S USE ONLY
NUMBER ATTEMPTED
PUT A TICK(V) MARKS EXAMINER’S
SIGNATURE
1
2
3
4
5
6
TOTAL
MARKS
CHECKER’S INITIALS

Page 1 of 4
 01. (a) (i) What does the term disprotonation means?
(ii) The reaction between dichromate (vi) Ions and chloride Ions in Acidic solution
yield chlorine and chromium (iii) Ions as shown in the following unbalanced
equation:
Cr2O7(aq) + Cl-(aq) → Cr3+(aq) + Cl2(
g)
Derive the balanced Half – reaction equations and overall Net Equation for this
redox reaction.
(b)A Form five student was trying to balance the equation then he noticed that single
equation tends to loose and gain an electron simultaneously. State which of the
following equation potray such behavior.
(i) CH4(g) + 2O2(g) → CO2(g) + 2H2O(g)
(ii) Zn(s) + 2HCl(aq) → ZnCl2(aq) + H2(g)
(iii) Cr2O72-(aq) + 2OH- (aq) → 2CrO4 + H2O(l)
(iv) O3(g) + NO(g) → O2(g) + NO2(g)
(c) Identify the oxidizing agent, reducing agent, the substance being oxidized and the
substance being reduced in 01 (b) (i-iv)
(d) Calculate the Emf of the following
Pb/Pb2+a (1×10+3m)// Cu2+ (1×10-2m)/ Cu(s)
Given the following standard reduction potentials
Pb2+/Pb Eθ= - 0.126v: al2+/ Cu, Eθ = 0.34v.
01. (a) (i) State the distribution law.
(ii) Distribution of solute particles in some given solvents can be governed by
different condition and principles. Briefly explain the conditions that govern such
distribution.
(b) (i) Calculate the percentage by mass of bromo benzene (C6H5Br) in the distillate
when a mixture of bromo benzene and water distills at 65˚C in the steam. The
vapour pressure of bromo benzene and water are 1.59 × 104 and 8.50 × 104Nm-2
respectively.
(ii) Heptane (C7H16) and Octane (C8H18) form an ideal solution at 373K, the
vapour pressure of pure heptane and octave were 105.2Kpa and 46.8 Kpa
respectively. Calculate the vapour pressure of the mixture of 26.0g of heptane and
35.0g of octane.
(c) Compound P has a partition coefficient of 4.00 between the Ethoxyethane and
water. Given that 2.0g of P is obtained in solution, in 50cm3 of water, calculate the
mass of P that can be Extracted from the Aqueous solution by
(i) 50cm3 of Ethoxyethane
(ii) Two successive extractions of 25cm3 of ethoxyethane each
Page 2 of 4
 (d) To a solution containing 0.1m Cl- and 0.01m CrO42- a solution of AgNO3 is added
slowly.
(i) Which salt will precipitate first between AgCl and AgCrO4? Show clearly how
you arrived to your answer.
(ii) Find the concentration of the Ion that will precipitate first at the time the
second
Ion will start precipitating.
Use Ksp (AgCl) = 2.72 × 10-10 and Ksp (Ag2CrO4) = 2.4 × 10-12
02. (a) Rate of chemical reaction can proceed fast or slow depending on some factors in a
given chemical reaction. Briefly explain.
(b) consider the following reaction
H2(g) + I2 (g) → 2HI(g)

If the rate constant K at 310˚C and 420˚C is 1.3 × 10-3dm-3mol-s- and 6.3 × 10-3dm
3
mol-s- respectively, what is the activation energy Ea for the reaction?
(c) The reaction of nitric oxide with hydrogen at 1280˚c is given by the equation
2NO2 (g) + 2H2 (g) → N2 + 4H2O
This reaction was studied and the following results were obtained
(NO2) M (H2) M RATE (M/S)
0.42 0.7 0.41
0.84 0.7 0.82
0.84 1.4 0.82
(i) Determine the order with respect to each reactant and the overall order of the
reaction
(ii) Establish the rate law for the reaction
(iii) Calculate the rate constant
03. a) An aromatic compound D (C8H8O) give a positive result with 2.4 dinitro – phenyl
hydrozone but gives yellow precipitate of compound E treatment with iodine and
sodium solution. Compound D give negative Tollens or Fehling test. On drastic
oxidation with KMnO4 forms a carboxylic acid F (C7H6O2) which is also formed along
with the yellow compound in the above reaction. Identify the structure D, E, and F
also write all chemical reaction involved.
(b) A compound A of Molecular formula of C3H7O2N On reaction with iron and
concentrated hydrochloric acid give the compound B of molecular formula C3H8O.
Compound C Gives Effervescence with sodium on oxidation with CrO3 compound C
given saturated aldehyde containing three carbonic atoms deduce the structure of A, B
and C
04. (a) (i) Generally extraction of metals from their ores involves four stages. Obtaining the
ore, concentrating the ore, concentrating the compound of interest in the ore,
chemical reduction and refining of the crude metal. Describe how Aluminium is
extracted from its ore basing on these stages.
(ii) Show that the properties of aluinium suit its wide range use.
 (b) Transitional elements show a variety of behaviors. With vivid example explain five
(05) properties shown by such metals.

(c) Give the IUPAC name of the following

i. [Cr(H2O)4(NH3)2]Cl3
ii. [CoCl(NO2) (en)2]+
iii. K4[Fe(CN)6]
iv. [FeBr2(H2O)4]+
v. [CoCl2(NH3)4]3 [Cr(CN)6]

05. (a) (i) Arrange the following compound in the order of increasing acidic strength
Phenol, phenyl methanol, 2-nitrobenzoic acid, benzoic acid
(ii) A compound with the following structural formula was extracted from certain
yellow flowers H2N-CO-H2CHOH-CO-OH.
From your knowledge in organic chemistry give the product that will be formed
when this compound is treated with
i)Nitrous acid (ii) Ethanol (iii) LiAlH4 (iv) Potassium dichromate (v) PCl5
(b) Show the initiation step and propagation step for the following Polymerization types
for Polytetrafluoroethene (PTFE) polymer.
i. Free radical polymerization
ii. Cation polymerization
iii. An ionic polymerization
(c) Write the monomers forming the following polymers and show the polymerization method
used
i. PVC
ii. Bakelite
iii. Teflon
iv. Nylonbile
v. Dacron