CHEMTREC Transportation

Emergency Phone: 800-

Material 424-9300
Pittsburgh Poison Control

Safety Data Center

Health Emergency No.: 412-
681-6669
Sheet NOTE: The CHEMTREC Transportation
Emergency Phone is to be used only in the
event of chemical emergencies involving a
spill, leak, fire, exposure or accident
involving chemicals

Section 1 - Chemical Product / Company Information

KOP-COAT A-788 SPLASH ZONE Revision

Product Name: 04/08/2009
CMP. PT A Date:
Identification
PLMSDS 0969A5NL Supercedes : 11/10/2008
Number:
Product Epoxy Polyamide - FOR
Use/Class: INDUSTRIAL USE ONLY
Preparer: Regulatory, Department
Manufacturer: Carboline Company
2150 Schuetz Road
St. Louis, MO 63146

Section 2 - Composition / Information On Ingredients

Chemical Name CAS Number Weight % Less Than ACGIH TLV-TWA ACGIH TLV-STEL OSHA PEL-TWA OSHA-CEIL
TALC 14807-96-6 35.0 N/E N/E N/E N/E
MICROCRYSTALLINE 14808-60-7 25.0 0.025 MG/M3 N/E 0.1 MG/M3 N/E
SILICA (respirable) (respirable)

Section 3 - Hazards Identification

Emergency Overview: Contains SILICA which can cause cancer. Risk of Cancer depends on duration
and level of exposure.

Effects Of Overexposure - Eye Contact: May cause eye irritation.

Effects Of Overexposure - Skin Contact: May cause skin irritation.

Effects Of Overexposure - Inhalation: Harmful if inhaled, may affect the brain or nervous system,
causing dizziness, headache, or nausea. May cause nose and throat irritation.

Effects Of Overexposure - Ingestion: May be harmful if swallowed.

Effects Of Overexposure - Chronic Hazards: Crystalline silica is known to cause silicosis. Crystalline
silica (Quartz) is classified as a known human carcinogen (Group 1) by IARC. Exposure is by route of
inhalation. If material is in a liquid matrix it is unlikely to be inhaled. However, when sanding or grinding
the finished product, there may be potential for crystalline silica to become airborne. Reports have
associated repeated and prolonged occupational overexposure to solvents with permanent brain and
nervous system damage.

Primary Route(s) Of Entry: Skin Contact, Inhalation, Ingestion, Eye Contact

Medical Conditions Prone to Aggravation by Exposure: No Information.

Section 4 - First Aid Measures

First Aid - Eye Contact: If material gets into eyes, flush with water immediately for 15 minutes. Consult

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 a physician.

First Aid - Skin Contact: In case of contact, wash skin immediately with soap and water.

First Aid - Inhalation: If inhaled, remove to fresh air. Administer oxygen if necessary. Consult a
physician if symptoms persist or exposure was severe.

First Aid - Ingestion: If swallowed do not induce vomiting. Seek immediate medical attention.

Section 5 - Fire Fighting Measures

Flash Point, F: 201F (93C) Lower Explosive Limit, %: N/A
(Setaflash) Upper Explosive Limit, %: N/A

Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Fog

Unusual Fire And Explosion Hazards: This product contains less than 1% volatile components. The
amount of vapors that could accumulate are minimal. However, vapors are heavier than air and could
travel long distances, ignite, and flashback. Eliminate all ignition sources. Keep away from sparks, open
flames, and heat sources. All electrical equipment and installations should be made and grounded in
accordance with the National Electrical Code. In areas where explosion hazards exist, workers should be
required to use nonferrous tools and to wear conductive and non-sparking shoes.

Special Firefighting Procedures: Evacuate hazard area of unprotected personnel. Use a NIOSH
approved self-contained breathing unit and complete body protection. Cool surrounding containers with
water in case of fire exposure.

Section 6 - Accidental Release Measures

Steps To Be Taken If Material Is Released Or Spilled: Eliminate all ignition sources. Handling
equipment must be grounded to prevent sparking. Evacuate the area of unprotected personnel. Wear
appropriate personal protection clothing and equipment. Follow exposure controls/personal protection
guidelines in Section 8. Contain and soak up residual with an aborbent (clay or sand). Take up absorbant
material and seal tightly for proper disposal. Dispose of in accordance with local, state and federal
regulations. Refer to Section 15 for SARA Title III and CERCLA information.

Section 7 - Handling And Storage

Handling: Do not get in eyes, on skin, or on clothing. Keep container tightly closed when not in use. Wear
personal protection equipment. Do not breathe vapors. Wash thoroughly after handling. If pouring or
transferring materials, ground all containers and tools. Do not weld, heat, cut or drill on full or empty
containers. Use only in accordance with Carboline application instructions, container label and Product
Data Sheet. Avoid breathing vapors or spray mist.

Storage: Keep away from heat, sparks, open flames and oxidizing agents. Keep containers closed. Store
in a cool, dry place with adequate ventilation.

Section 8 - Exposure Controls / Personal Protection

Engineering Controls: Use explosion-proof ventilation when required to keep below health exposure
guidelines and Lower Explosion Limit (LEL).

Respiratory Protection: Use only with ventilation to keep levels below exposure guidelines listed in
Section 2. User should test and monitor exposure levels to ensure all personnel are below guidelines. If
not sure, or not able to monitor, use MSHA/NIOSH approved supplied air respirator. Follow all current
OSHA requirements for respirator use. For silica containing coatings in a liquid state, and/or if no
exposure limits are established in Section 2 above, supplied air respirators are generally not required.

Skin Protection: Recommend impervious gloves and clothing to avoid skin contact. If material penetrates
to skin, change gloves and clothing. The use of protective creams may be beneficial to certain individuals.
Protective creams should be applied before exposure.

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 Eye Protection: Recommend safety glasses with side shields or chemical goggles to avoid eye contact.

Other protective equipment: Eye wash and safety showers should be readily available.

Hygienic Practices: Wash with soap and water before eating, drinking, smoking, applying cosmetics, or
using toilet facilities. Use of a hand cleaner is recommended. Launder contaminated clothing before
reuse. Leather shoes can absorb and allow hazardous materials to pass through. Check shoes carefully
after soaking before reuse.

Section 9 - Physical And Chemical Properties

Boiling Range: N/A - N/A Vapor Density: Heavier than Air
Odor: Epoxy Odor Threshold: N/D
Appearance: Viscous Yellowish Liquid Evaporation Rate: Slower Than Ether
Solubility in H2O: N/D
Freeze Point: N/D Specific Gravity: 1.78
Vapor Pressure: N/D PH: N/D
Physical State: Liquid

(See section 16 for abbreviation legend)

Section 10 - Stability And Reactivity

Conditions To Avoid: Heat, sparks and open flames.

Incompatibility: Avoid contact with strong oxidizing agents.

Hazardous Decomposition Products: Carbon monoxide, nitrogen oxides, and unidentified organic
compounds. Consider all smoke and fumes from burning material as very hazardous. Welding, cutting or
abrasive grinding can create smoke and fumes. Do not breathe any fumes or smoke from these
operations.

Hazardous Polymerization: Will not occur under normal conditions.

Stability: This product is stable under normal storage conditions.

Section 11 - Toxicological Information

Product LD50: N/D Product LC50: N/D

Chemical Name CAS Number LD50 LC50

TALC 14807-96-6 NOT AVAILABLE NOT AVAILABLE
MICROCRYSTALLINE SILICA 14808-60-7 NOT AVAILABLE NOT AVAILABLE

Section 12 - Ecological Information

Ecological Information: No data

Section 13 - Disposal Information

Disposal Information: Dispose of in accordance with State, Local, and Federal Environmental
regulations. Responsibility for proper waste disposal is with the owner of the waste.

Section 14 - Transportation Information

DOT Proper Shipping Not Regulated Packing Group: N/A

Name:
DOT Technical Name: N/A Hazard N/A
Subclass:

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 DOT Hazard Class: None Resp. Guide N/A
Page:
DOT UN/NA Number: N/A

Additional Notes: None.

Section 15 - Regulatory Information

CERCLA - SARA HAZARD CATEGORY

This product has been reviewed according to the EPA Hazard Categories promulgated under Sections
311and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is
considered, under applicable definitions, to meet the following categories:

IMMEDIATE HEALTH HAZARD, CHRONIC HEALTH HAZARD

SARA SECTION 313

This product contains the following substances subject to the reporting requirements of Section 313 of
Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:

No Section 313 Substances exist in this product

TOXIC SUBSTANCES CONTROL ACT

All components of this product are listed on the TSCA inventory.

This product contains the following chemical substances subject to the reporting requirements of TSCA
12(B) if exported from the United States:

No TSCA 12(B) Substances exist in this product

U.S. STATE REGULATIONS AS FOLLOWS:

NEW JERSEY RIGHT-TO-KNOW

The following materials are non-hazardous, but are among the top five components in this product.

Chemical Name CAS Number

EPOXY RESIN 25085-99-8
YELLOW IRON OXIDE 51274-00-1
CHLORITE 71949-90-1

PENNSYLVANIA RIGHT-TO-KNOW

The following non-hazardous ingredients are present in the product at greater than 3%.

Chemical Name CAS Number

EPOXY RESIN 25085-99-8
YELLOW IRON OXIDE 51274-00-1

CALIFORNIA PROPOSITION 65

Warning: The following ingredients present in the product are known to the state of California to
cause Cancer:

Chemical Name CAS Number

MICROCRYSTALLINE SILICA 14808-60-7

Warning: The following ingredients present in the product are known to the state of California to
cause birth defects, or other reproductive hazards:

No California Proposition 65 Reproductive Toxins exist

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 INTERNATIONAL REGULATIONS AS FOLLOWS:

CANADIAN WHMIS

This MSDS has been prepared in compliance with Controlled Product Regulations except for the use of
the 16 headings.

CANADIAN WHMIS CLASS: D2A D2B

Section 16 - Other Information

HMIS Ratings
Health: 2 Flammability: 1 Reactivity: 0 Personal Protection: X

VOLATILE ORGANIC COMPOUNDS, GR/LTR MIXED (UNTHINNED): 0

REASON FOR REVISION: Changes made in Section(s) 1 and 3

Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined

The information contained herein is, to the best of our knowledge and belief accurate. However, since the
conditions of handling and use are beyond our control, we make no guarantee of results, and assume no
liability for damages incurred by use of this material. It is the responsibility of the user to comply with all
applicable federal, state, and local laws and regulations

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