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SAFETY DATA SHEET

1. Identification

Material name: EUCLID NS GROUT

Material: 088 50

Recommended use and restriction on use

Recommended use: Cement, Portland, chemicals
Restrictions on use: Not known.

Manufacturer/Importer/Supplier/Distributor Information
EUCLID CHEMICAL COMPANY
19218 REDWOOD ROAD
CLEVELAND OH 44110
US

Contact person: EH&S Department

Telephone: 216-531-9222
Emergency telephone number: 1-800-424-9300 (US); 1-613-996-6666 (Canada)

2. Hazard(s) identification

Hazard Classification
Health Hazards
Acute toxicity (Inhalation - dust and Category 4
mist)
Skin Corrosion/Irritation Category 2
Serious Eye Damage/Eye Irritation Category 1
Skin sensitizer Category 1
Carcinogenicity Category 1A
Specific Target Organ Toxicity - Category 31.
Single Exposure
1.
Specific Target Organ Toxicity - Category 1
Repeated Exposure

Target Organs
1. Respiratory tract irritation.
2. Lung

Unknown toxicity - Health

Acute toxicity, oral 96.19 %
Acute toxicity, dermal 97.06 %
Acute toxicity, inhalation, vapor 99.98 %
Acute toxicity, inhalation, dust 98.31 %
or mist

Label Elements
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Hazard Symbol:

Signal Word: Danger

Hazard Statement: Harmful if inhaled.

Causes skin irritation.
Causes serious eye damage.
May cause an allergic skin reaction.
May cause cancer.
May cause respiratory irritation.
Causes damage to organs through prolonged or repeated exposure.

Precautionary
Statements

Prevention: Use only outdoors or in a well-ventilated area. Wash thoroughly after

handling. Wear protective gloves/protective clothing/eye protection/face
protection. Contaminated work clothing should not be allowed out of the
workplace. Obtain special instructions before use. Do not handle until all
safety precautions have been read and understood. Use personal protective
equipment as required. Do not breathe dust/fume/gas/mist/vapors/spray. Do
not eat, drink or smoke when using this product.

Response: IF INHALED: Remove person to fresh air and keep comfortable for
breathing. IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. IF ON
SKIN: Wash with plenty of water/D If skin irritation or rash occurs: Get
medical advice/attention. Immediately call a POISON CENTER/doctor.
Specific treatment (see on this label). Wash contaminated clothing before
reuse.

Storage: Store locked up. Store in a well-ventilated place. Keep container tightly
closed.

Disposal: Dispose of contents/container to an appropriate treatment and disposal

facility in accordance with applicable laws and regulations, and product
characteristics at time of disposal.

Hazard(s) not otherwise None.

classified (HNOC):

3. Composition/information on ingredients

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Mixtures

Chemical Identity CAS number Content in percent (%)*

Crystalline Silica (Quartz)/ 14808-60-7 50 - <100%

Silica Sand
Portland cement 65997-15-1 20 - <50%
Fused calcium aluminate 65997-16-2 1 - <5%
Fumed silica 69012-64-2 1 - <5%
Calcium salt 7778-18-9 0.1 - <1%
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.

4. First-aid measures

Ingestion: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth.

Inhalation: Move to fresh air.

Skin Contact: Get medical attention. Destroy or thoroughly clean contaminated shoes.
Immediately remove contaminated clothing and shoes and wash skin with
soap and plenty of water. If skin irritation or an allergic skin reaction
develops, get medical attention.

Eye contact: Immediately flush with plenty of water for at least 15 minutes. If easy to do,
remove contact lenses. Call a physician or poison control center
immediately.

Most important symptoms/effects, acute and delayed

Symptoms: Prolonged or repeated contact with skin may cause redness, itching,
irritation and eczema/chapping. Extreme irritation of eyes and mucous
membranes, including burning and tearing. Respiratory tract irritation.

Indication of immediate medical attention and special treatment needed

Treatment: Symptoms may be delayed.

5. Fire-fighting measures

General Fire Hazards: No unusual fire or explosion hazards noted.

Suitable (and unsuitable) extinguishing media

Suitable extinguishing Use fire-extinguishing media appropriate for surrounding materials.

media:

Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media:

Specific hazards arising from During fire, gases hazardous to health may be formed.
the chemical:
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Special protective equipment and precautions for firefighters

Special fire fighting No data available.

procedures:

Special protective equipment Self-contained breathing apparatus and full protective clothing must be
for fire-fighters: worn in case of fire.

6. Accidental release measures

Personal precautions, See Section 8 of the SDS for Personal Protective Equipment. Do not touch
protective equipment and damaged containers or spilled material unless wearing appropriate
emergency procedures: protective clothing. Keep unauthorized personnel away.

Methods and material for Collect spillage in containers, seal securely and deliver for disposal
containment and cleaning according to local regulations.
up:

Notification Procedures: In the event of a spill or accidental release, notify relevant authorities in
accordance with all applicable regulations.

Environmental Precautions: Do not contaminate water sources or sewer. Prevent further leakage or
spillage if safe to do so.

7. Handling and storage

Precautions for safe handling: Wash hands thoroughly after handling. Do not handle until all safety
precautions have been read and understood. Obtain special instructions
before use. Use personal protective equipment as required. Do not get in
eyes. Avoid contact with skin. Avoid contact with eyes, skin, and clothing.
Ventilate well, avoid breathing vapors. Use approved respirator if air
contamination is above accepted level. Use mechanical ventilation in case
of handling which causes formation of dust.

Conditions for safe storage, Store locked up.

including any
incompatibilities:

8. Exposure controls/personal protection

Control Parameters
Occupational Exposure Limits
Chemical Identity Type Exposure Limit Values Source

Crystalline Silica (Quartz)/ TWA 0.025 mg/m3 US. ACGIH Threshold Limit Values (2011)
Silica Sand - Respirable
fraction.
Crystalline Silica (Quartz)/ TWA 0.05 mg/m3 US. OSHA Specifically Regulated Substances
Silica Sand - Respirable dust. (29 CFR 1910.1001-1053) (03 2016)
OSHA_AC 0.025 mg/m3 US. OSHA Specifically Regulated Substances
T (29 CFR 1910.1001-1053) (03 2016)
Crystalline Silica (Quartz)/ PEL 0.05 mg/m3 US. OSHA Table Z-1 Limits for Air
Silica Sand - Respirable dust. Contaminants (29 CFR 1910.1000) (03 2016)
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Crystalline Silica (Quartz)/ TWA 2.4 millions US. OSHA Table Z-3 (29 CFR 1910.1000)
Silica Sand - Respirable. of particles (2000)
per cubic foot
of air
TWA 0.1 mg/m3 US. OSHA Table Z-3 (29 CFR 1910.1000)
(2000)
Portland cement - Respirable TWA 1 mg/m3 US. ACGIH Threshold Limit Values (2011)
fraction.
Portland cement - Total dust. PEL 15 mg/m3 US. OSHA Table Z-1 Limits for Air
Contaminants (29 CFR 1910.1000) (02 2006)
Portland cement - Respirable PEL 5 mg/m3 US. OSHA Table Z-1 Limits for Air
fraction. Contaminants (29 CFR 1910.1000) (02 2006)
Portland cement TWA 50 millions of US. OSHA Table Z-3 (29 CFR 1910.1000)
particles per (2000)
cubic foot of
air
Fumed silica TWA 20 millions of US. OSHA Table Z-3 (29 CFR 1910.1000)
particles per (2000)
cubic foot of
air
TWA 0.8 mg/m3 US. OSHA Table Z-3 (29 CFR 1910.1000)
(2000)
Calcium salt - Total REL 10 mg/m3 US. NIOSH: Pocket Guide to Chemical
Hazards (2010)
Calcium salt - Respirable. REL 5 mg/m3 US. NIOSH: Pocket Guide to Chemical
Hazards (2010)
Calcium salt - Total dust. TWA 15 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
Calcium salt - Respirable TWA 5 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000)
fraction. (1989)
Calcium salt - Total dust. TWA 15 mg/m3 US. Tennessee. OELs. Occupational Exposure
Limits, Table Z1A (06 2008)
Calcium salt - Respirable TWA 5 mg/m3 US. Tennessee. OELs. Occupational Exposure
fraction. Limits, Table Z1A (06 2008)
Calcium salt AN ESL 5 µg/m3 US. Texas. Effects Screening Levels (Texas
Commission on Environmental Quality) (03
2014)
ST ESL 50 µg/m3 US. Texas. Effects Screening Levels (Texas
Commission on Environmental Quality) (03
2014)
Calcium salt - Inhalable TWA 10 mg/m3 US. ACGIH Threshold Limit Values (2011)
fraction.
Calcium salt - Total dust. PEL 15 mg/m3 US. OSHA Table Z-1 Limits for Air
Contaminants (29 CFR 1910.1000) (02 2006)
Calcium salt - Respirable PEL 5 mg/m3 US. OSHA Table Z-1 Limits for Air
fraction. Contaminants (29 CFR 1910.1000) (02 2006)

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Chemical name Type Exposure Limit Values Source

Crystalline Silica (Quartz)/ TWA 0.025 mg/m3 Canada. British Columbia OELs. (Occupational
Silica Sand - Respirable Exposure Limits for Chemical Substances,
fraction. Occupational Health and Safety Regulation
296/97, as amended) (07 2007)
Crystalline Silica (Quartz)/ TWA 0.10 mg/m3 Canada. Ontario OELs. (Control of Exposure to
Silica Sand - Respirable Biological or Chemical Agents) (06 2015)
fraction.
Crystalline Silica (Quartz)/ TWA 0.1 mg/m3 Canada. Quebec OELs. (Ministry of Labor -
Silica Sand - Respirable dust. Regulation Respecting the Quality of the Work
Environment) (09 2017)
Portland cement - Respirable TWA 1 mg/m3 Canada. Ontario OELs. (Control of Exposure to
fraction. Biological or Chemical Agents) (06 2015)
Portland cement - Total dust. TWA 10 mg/m3 Canada. Quebec OELs. (Ministry of Labor -
Regulation Respecting the Quality of the Work
Environment) (09 2017)
Portland cement - Respirable TWA 5 mg/m3 Canada. Quebec OELs. (Ministry of Labor -
dust. Regulation Respecting the Quality of the Work
Environment) (09 2017)
Portland cement - TWA 1 mg/m3 Canada. British Columbia OELs. (Occupational
Respirable. Exposure Limits for Chemical Substances,
Occupational Health and Safety Regulation
296/97, as amended) (06 2017)
Fumed silica - Total fume. TWA 4 mg/m3 Canada. British Columbia OELs. (Occupational
Exposure Limits for Chemical Substances,
Occupational Health and Safety Regulation
296/97, as amended) (07 2007)
Fumed silica - Respirable TWA 1.5 mg/m3 Canada. British Columbia OELs. (Occupational
fume. Exposure Limits for Chemical Substances,
Occupational Health and Safety Regulation
296/97, as amended) (07 2007)
Fumed silica - Respirable TWA 2 mg/m3 Canada. Ontario OELs. (Control of Exposure to
fraction. Biological or Chemical Agents) (06 2015)
Fumed silica - Respirable TWA 2 mg/m3 Canada. Quebec OELs. (Ministry of Labor -
dust and/or fume. Regulation Respecting the Quality of the Work
Environment) (09 2017)
Calcium salt TWA 10 mg/m3 Canada. Alberta OELs (Occupational Health &
Safety Code, Schedule 1, Table 2) (07 2009)
Calcium salt - Inhalable TWA 10 mg/m3 Canada. British Columbia OELs. (Occupational
Exposure Limits for Chemical Substances,
Occupational Health and Safety Regulation
296/97, as amended) (07 2007)
Calcium salt - Inhalable TWA 10 mg/m3 Canada. Ontario OELs. (Control of Exposure to
fraction. Biological or Chemical Agents) (11 2010)
Calcium salt - Total dust. TWA 10 mg/m3 Canada. Quebec OELs. (Ministry of Labor -
Regulation Respecting the Quality of the Work
Environment) (09 2017)
Calcium salt - Respirable TWA 5 mg/m3 Canada. Quebec OELs. (Ministry of Labor -
dust. Regulation Respecting the Quality of the Work
Environment) (09 2017)
Aluminum - Respirable. TWA 1 mg/m3 Canada. British Columbia OELs. (Occupational
Exposure Limits for Chemical Substances,
Occupational Health and Safety Regulation
296/97, as amended) (07 2007)
Aluminum - Respirable TWA 1 mg/m3 Canada. Ontario OELs. (Control of Exposure to
fraction. Biological or Chemical Agents) (11 2010)
Aluminum TWA 10 mg/m3 Canada. Quebec OELs. (Ministry of Labor -
Regulation Respecting the Quality of the Work
Environment) (09 2017)
Aluminum - as Al TWA 5 mg/m3 Canada. Quebec OELs. (Ministry of Labor -
Regulation Respecting the Quality of the Work
Environment) (09 2017)
Aluminum - Welding fume. - TWA 5 mg/m3 Canada. Quebec OELs. (Ministry of Labor -
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as Al Regulation Respecting the Quality of the Work

Environment) (09 2017)
Stearic acid TWA 10 mg/m3 Canada. British Columbia OELs. (Occupational
Exposure Limits for Chemical Substances,
Occupational Health and Safety Regulation
296/97, as amended) (07 2007)
Stearic acid TWA 10 mg/m3 Canada. Ontario OELs. (Control of Exposure to
Biological or Chemical Agents) (11 2010)

Appropriate Engineering Mechanical ventilation or local exhaust ventilation may be required.

Controls Observe good industrial hygiene practices. Observe occupational exposure
limits and minimize the risk of inhalation of dust.

Individual protection measures, such as personal protective equipment

General information: Provide easy access to water supply and eye wash facilities. Good general
ventilation (typically 10 air changes per hour) should be used. Ventilation
rates should be matched to conditions. If applicable, use process
enclosures, local exhaust ventilation, or other engineering controls to
maintain airborne levels below recommended exposure limits. If exposure
limits have not been established, maintain airborne levels to an acceptable
level.

Eye/face protection: Wear a full-face respirator, if needed. Wear safety glasses with side shields
(or goggles) and a face shield.

Skin Protection
Hand Protection: Use suitable protective gloves if risk of skin contact.

Other: Wear suitable protective clothing. Wear chemical-resistant gloves,

footwear, and protective clothing appropriate for the risk of exposure.
Contact health and safety professional or manufacturer for specific
information.

Respiratory Protection: In case of inadequate ventilation use suitable respirator. Seek advice from
local supervisor.

Hygiene measures: Observe good industrial hygiene practices. Wash hands before breaks and
immediately after handling the product. Do not get in eyes. Wash
contaminated clothing before reuse. Avoid contact with skin. Contaminated
work clothing should not be allowed out of the workplace.

9. Physical and chemical properties

Appearance
Physical state: solid
Form: Powder
Color: Gray
Odor: Odorless
Odor threshold: No data available.
pH: No data available.
Melting point/freezing point: No data available.

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Initial boiling point and boiling range: No data available.

Flash Point: No data available.
Evaporation rate: No data available.
Flammability (solid, gas): No
Upper/lower limit on flammability or explosive limits
Flammability limit - upper (%): No data available.
Flammability limit - lower (%): No data available.
Explosive limit - upper (%): No data available.
Explosive limit - lower (%): No data available.
Vapor pressure: No data available.
Vapor density: No data available.
Relative density: 3.45
Solubility(ies)
Solubility in water: Miscible with water.
Solubility (other): No data available.
Partition coefficient (n-octanol/water): No data available.

Auto-ignition temperature: No data available.

Decomposition temperature: No data available.
Viscosity: No data available.

10. Stability and reactivity

Reactivity: No data available.

Chemical Stability: Material is stable under normal conditions.

Possibility of hazardous No data available.

reactions:

Conditions to avoid: Avoid heat or contamination.

Incompatible Materials: No data available.

Hazardous Decomposition Thermal decomposition or combustion may liberate carbon oxides and
Products: other toxic gases or vapors.

11. Toxicological information

Information on likely routes of exposure

Inhalation: In high concentrations, vapors, fumes or mists may irritate nose, throat and
mucus membranes.

Skin Contact: May be harmful in contact with skin. Causes skin irritation. May cause an
allergic skin reaction.

Eye contact: Causes serious eye damage.

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Ingestion: May be harmful if swallowed.

Symptoms related to the physical, chemical and toxicological characteristics

Inhalation: No data available.

Skin Contact: No data available.

Eye contact: No data available.

Ingestion: No data available.

Information on toxicological effects

Acute toxicity (list all possible routes of exposure)

Oral
Product: Not classified for acute toxicity based on available data.

Specified substance(s):
Fused calcium aluminate LD 50 (Rat): > 2,000 mg/kg

Fumed silica LD 50 (Rat): > 5,000 mg/kg

Calcium salt LD 50 (Rat): > 1,581 mg/kg

Dermal
Product: Not classified for acute toxicity based on available data.

Specified substance(s):
Fused calcium aluminate LD 50 (Rat): > 2,000 mg/kg

Fumed silica LD 50 (Rabbit): > 5,000 mg/kg

Inhalation
Product: ATEmix: 1.92 mg/l

Repeated dose toxicity

Product: No data available.

Skin Corrosion/Irritation
Product: No data available.

Specified substance(s):

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Fused calcium in vivo (Rabbit): Not irritant Experimental result, Key study
aluminate

Fumed silica in vivo (Rabbit): Not irritant Read-across from supporting substance
(structural analogue or surrogate), Weight of Evidence study

Calcium salt in vivo (Rabbit): Not irritant Experimental result, Key study

Serious Eye Damage/Eye Irritation

Product: No data available.
Specified substance(s):

Calcium salt Rabbit, 72 hrs: Not irritating

Respiratory or Skin Sensitization

Product: No data available.

Carcinogenicity
Product: No data available.

IARC Monographs on the Evaluation of Carcinogenic Risks to Humans:

Crystalline Silica Overall evaluation: Carcinogenic to humans.

(Quartz)/ Silica
Sand

US. National Toxicology Program (NTP) Report on Carcinogens:

Crystalline Silica Known To Be Human Carcinogen.
(Quartz)/ Silica
Sand

US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050):

Crystalline Silica
(Quartz)/ Silica Cancer
Sand

Germ Cell Mutagenicity

In vitro
Product: No data available.

In vivo
Product: No data available.

Reproductive toxicity
Product: No data available.

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Specific Target Organ Toxicity - Single Exposure

Product: No data available.

Specific Target Organ Toxicity - Repeated Exposure

Product: No data available.

Target Organs
Specific Target Organ Toxicity - Single Exposure: Respiratory tract irritation.
Specific Target Organ Toxicity - Repeated Exposure: Lung

Aspiration Hazard
Product: No data available.

Other effects: No data available.

12. Ecological information

Ecotoxicity:

Acute hazards to the aquatic environment:

Fish
Product: No data available.

Specified substance(s):
Calcium salt LC 50 (Fathead minnow (Pimephales promelas), 96 h): > 1,970 mg/l
Mortality

Aquatic Invertebrates
Product: No data available.

Chronic hazards to the aquatic environment:

Fish
Product: No data available.

Aquatic Invertebrates
Product: No data available.

Toxicity to Aquatic Plants

Product: No data available.

Persistence and Degradability

Biodegradation
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Product: No data available.

BOD/COD Ratio
Product: No data available.

Bioaccumulative potential
Bioconcentration Factor (BCF)
Product: No data available.

Partition Coefficient n-octanol / water (log Kow)

Product: No data available.

Mobility in soil: No data available.

Other adverse effects: No data available.

13. Disposal considerations

Disposal instructions: Dispose of waste at an appropriate treatment and disposal facility in

accordance with applicable laws and regulations, and product
characteristics at time of disposal.

Contaminated Packaging: No data available.

14. Transport information

TDG:

Not Regulated

CFR / DOT:

Not Regulated

IMDG:

Not Regulated

15. Regulatory information

US Federal Regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
None present or none present in regulated quantities.

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US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Chemical Identity OSHA hazard(s)
Crystalline Silica kidney effects
(Quartz)/ Silica Sand lung effects
immune system effects
Cancer

CERCLA Hazardous Substance List (40 CFR 302.4):

None present or none present in regulated quantities.

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Hazard categories
Immediate (Acute) Health Hazards
Delayed (Chronic) Health Hazard
Acute toxicity (any route or exposure)
Skin Corrosion or Irritation
Serious eye damage or eye irritation
Respiratory or Skin Sensitization
Carcinogenicity
Specific target organ toxicity (single or repeated exposure)

SARA 302 Extremely Hazardous Substance

None present or none present in regulated quantities.

SARA 304 Emergency Release Notification

None present or none present in regulated quantities.

SARA 311/312 Hazardous Chemical

Chemical Identity Threshold Planning Quantity
Crystalline Silica (Quartz)/ 10000 lbs
Silica Sand
Portland cement 10000 lbs
Fused calcium aluminate 10000 lbs
Fumed silica 10000 lbs
Calcium salt 10000 lbs

SARA 313 (TRI Reporting)

None present or none present in regulated quantities.

Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
None present or none present in regulated quantities.

Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3)
None present or none present in regulated quantities.

US State Regulations

US. California Proposition 65

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WARNING
Cancer - www.P65Warnings.ca.gov

US. New Jersey Worker and Community Right-to-Know Act

Chemical Identity
Crystalline Silica (Quartz)/ Silica Sand
Portland cement
Fumed silica

US. Massachusetts RTK - Substance List

Chemical Identity
Crystalline Silica (Quartz)/ Silica Sand
Portland cement
Fumed silica

US. Pennsylvania RTK - Hazardous Substances

Chemical Identity
Crystalline Silica (Quartz)/ Silica Sand
Portland cement
Fumed silica

US. Rhode Island RTK

Chemical Identity
Crystalline Silica (Quartz)/ Silica Sand
Portland cement

International regulations

Montreal protocol
Not applicable

Stockholm convention
Not applicable

Rotterdam convention
Not applicable

Kyoto protocol
Not applicable

VOC:
Regulatory VOC (less water and : 0 g/l
exempt solvent)
VOC Method 310 : 0.00 %

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Inventory Status:
Australia AICS: All components in this product are listed on or
exempt from the Inventory.

Canada DSL Inventory List: All components in this product are listed on or
exempt from the Inventory.

EINECS, ELINCS or NLP: One or more components in this product are

not listed on or exempt from the Inventory.

Japan (ENCS) List: One or more components in this product are

not listed on or exempt from the Inventory.

China Inv. Existing Chemical Substances: All components in this product are listed on or
exempt from the Inventory.

Korea Existing Chemicals Inv. (KECI): All components in this product are listed on or
exempt from the Inventory.

Canada NDSL Inventory: One or more components in this product are

not listed on or exempt from the Inventory.

Philippines PICCS: One or more components in this product are

not listed on or exempt from the Inventory.

US TSCA Inventory: All components in this product are listed on or

exempt from the Inventory.

New Zealand Inventory of Chemicals: All components in this product are listed on or
exempt from the Inventory.

Japan ISHL Listing: One or more components in this product are

not listed on or exempt from the Inventory.

Japan Pharmacopoeia Listing: One or more components in this product are

not listed on or exempt from the Inventory.

Mexico INSQ: One or more components in this product are

not listed on or exempt from the Inventory.

Ontario Inventory: One or more components in this product are

not listed on or exempt from the Inventory.

Taiwan Chemical Substance Inventory: One or more components in this product are
not listed on or exempt from the Inventory.

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16.Other information, including date of preparation or last revision

Revision Date: 11/01/2018

Version #: 1.0

Further Information: No data available.

Disclaimer: For Industrial Use Only. Keep out of Reach of Children. The hazard
information herein is offered solely for the consideration of the user, subject
to their own investigation of compliance with applicable regulations, including
the safe use of the product under every foreseeable condition.

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