Series SSRR3/3 SET-1

àíZ-nÌ H$moS>
Q.P. Code 56/3/1
amob Z§. narjmWu àíZ-nÌ H$moS> >H$mo CÎma-nwpñVH$m Ho$
Roll No. _wI-n¥ð >na Adí` {bIo§ &
Candidates must write the Q.P. Code
on the title page of the answer-book.

ZmoQ> NOTE
(I) H¥$n`m Om±M H$a b| {H$ Bg àíZ-nÌ _o§ _w{ÐV (I) Please check that this question paper
n¥ð> 27 h¢ & contains 27 printed pages.

(II) H¥$n`m Om±M H$a b| {H$ Bg àíZ-nÌ _| (II) Please check that this question paper
>33 àíZ h¢ & contains 33 questions.

(III) àíZ-nÌ _| Xm{hZo hmW H$s Amoa {XE JE (III) Q.P. Code given on the right hand
àíZ-nÌ H$moS H$mo narjmWu CÎma-nwpñVH$m Ho$ side of the question paper should be
_wI-n¥ð> na {bI| & written on the title page of the
answer-book by the candidate.
(IV) H¥$n`m àíZ H$m CÎma {bIZm ewê$ H$aZo go (IV) Please write down the serial
nhbo, CÎma-nwpñVH$m _| àíZ H$m H«$_m§H$ number of the question in the
Adí` {bI| & answer-book before attempting it.
(V) Bg àíZ-nÌ 15 {_ZQ >H$m (V) 15 minute time has been allotted to
g_` {X`m J`m h¡ & àíZ-nÌ H$m {dVaU read this question paper. The
10.15 ~Oo {H$`m OmEJm & question paper will be distributed
10.15 ~Oo go 10.30 ~Oo VH$ N>mÌ Ho$db at 10.15 a.m. From 10.15 a.m. to
10.30 a.m., the students will
àíZ- read the question paper only and
do CÎma-nwpñVH$m na H$moB© CÎma Zht {bI|Jo & will not write any answer on the
answer-book during this period.

agm`Z {dkmZ (g¡ÕmpÝVH$)

CHEMISTRY (Theory)

:3 : 70
Time allowed : 3 hours Maximum Marks : 70

56/3/1-13 1 P.T.O.
 :
:
(i) 33
(ii)
(iii) 1 16 1

(iv) 17 21 2

(v) 22 28 3
(vi) 29 30 4
(vii) 31 33 5
(viii)

(ix)
(x)

IÊS> H$
1 16 1 16 1=16

1. {ZåZ{b{IV _| go H$m¡Z-gm Xem©Vm h¡ ?

(A) Fe
(B) Cu
(C) Mn
(D) Sc

2. g§Hw$b CoCl2(en)2]+Ûmam Xem©B© g_md`dVm H$m àH$ma h¡ :

(A) Am`ZZ g_md`dVm
(B) Á`m{_Vr` g_md`dVm
(C) ~§YZr g_md`dVm
(D) Cnghg§`moOZ g_md`dVm
56/3/1-13 2
General Instructions :
Read the following instructions carefully and follow them :
(i) This question paper contains 33 questions. All questions are compulsory.
(ii) This question paper is divided into five sections Section A, B, C, D and E.
(iii) Section A questions number 1 to 16 are multiple choice type questions. Each
question carries 1 mark
(iv) Section B questions number 17 to 21 are very short answer type questions.
Each question carries 2 marks
(v) Section C questions number 22 to 28 are short answer type questions. Each
question carries 3 marks
(vi) Section D questions number 29 and 30 are case-based questions. Each
question carries 4 marks
(vii) Section E questions number 31 to 33 are long answer type questions. Each
question carries 5 marks
(viii) There is no overall choice given in the question paper. However, an internal
choice has been provided in few questions in all the sections except Section A.
(ix) Kindly note that there is a separate question paper for Visually Impaired
candidates.
(x) Use of calculators is not allowed.

SECTION A

Questions no. 1 to 16 are Multiple Choice type Questions, carrying 1 mark

each. 16 1=16
1. Which of the following does not show variable oxidation states ?
(A) Fe
(B) Cu
(C) Mn
(D) Sc
+
2. The type of isomerism shown by the complex [CoCl2(en)2] is :
(A) Ionisation isomerism
(B) Geometrical isomerism
(C) Linkage isomerism
(D) Coordination isomerism
56/3/1-13 3 P.T.O.
3. {ZåZ{b{IV _| go {H$gH$m à{VMwå~H$s` ñd^md h¡ ?
3+
(A) Co , à~b joÌ {bJÝS> Ho$ gmW AîQ>\$bH$s` g§Hw$b
3+
(B) Co , Xþ~©b joÌ {bJÝS> Ho$ gmW AîQ>\$bH$s` g§Hw$b
(C) Co3+, dJ© g_Vbr` g§Hw$b _|
3+
(D) Co , MVwî\$bH$s` g§Hw$b _|
na_mUw H«$_m§H$ : Co = 27 ]

4. {ZåZ{b{IV A{^{H«$`m na {dMma H$s{OE :

A{^{H«$`m H$m _w»` CËnmX h¡ :

5. {ZåZ{b{IV `m¡{JH$m|o _| go {H$gH$m pKa _mZ {ZåZV_ h¡ ?

(A) p-H«$sgm°b (B) p-ZmBQ´>moµ\$sZm°b

(C) m-ZmBQ´>moµ\$sZm°b (D) 2,4,6-Q´>mBZmBQ´>moµ\$sZm°b

56/3/1-13 4
3. Which of the following is diamagnetic in nature ?

3+
(A) Co , octahedral complex with strong field ligand
3+
(B) Co , octahedral complex with weak field ligand

(C) Co3+, in a square planar complex

(D) Co3+, in a tetrahedral complex

[ Atomic number : Co = 27 ]

4. Consider the following reaction :

The major product of the reaction is :

5. Which one of the following compounds has the lowest pKa value ?

(A) p-Cresol (B) p-Nitrophenol

(C) m-Nitrophenol (D) 2,4,6-Trinitrophenol

56/3/1-13 5 P.T.O.
6. (CH3)2CH O CH3 H$mo O~ HI Ho$ gmW A{^H¥$V {H$`m OmVm h¡ Vmo XoVm h¡ :

(A) (CH3)2CH I + CH3OH

(B) (CH3)2CH OH + CH3 I

(C) (CH3)2CH I + CH3 I

(D) (CH3)2CH OH + CH3OH

7. {ZåZ{b{IV `m¡{JH$m| _| go H$m¡Z-gm ~oݵOrZ gë\

jma-{dbo` Adjon {Z{_©V H$aVm h¡ ?

(A) CH3CONH2

(B) (CH3)3N

(C) (CH3)2NH

(D) CH3CH2NH2

8. Obr` _mÜ`_ _| CH3NH2 (I), (CH3)2NH (II), (CH3)3N (III) Am¡a

C6H5NH2 (IV) H$s jmaH$Vm hþAm H«$_ h¡ :

(A) IV < III < I < II

(B) II < I < IV < III

(C) I < II < III < IV

(D) II < III < I < IV

56/3/1-13 6
6. (CH3)2CH O CH3 when treated with HI gives :

(A) (CH3)2CH I + CH3OH

(B) (CH3)2CH OH + CH3 I

(C) (CH3)2CH I + CH3 I

(D) (CH3)2CH OH + CH3OH

7. Which of the following compounds on treatment with benzene sulphonyl

choride forms an alkali-soluble precipitate ?

(A) CH3CONH2

(B) (CH3)3N

(C) (CH3)2NH

(D) CH3CH2NH2

8. The order of increasing basicities of CH3NH2 (I), (CH3)2NH (II),

(CH3)3N (III) and C6H5NH2 (IV) in aqueous media is :

(A) IV < III < I < II

(B) II < I < IV < III

(C) I < II < III < IV

(D) II < III < I < IV

56/3/1-13 7 P.T.O.
9. aº$ H$m ÎdnyU© ^y{_H$m {Z^mZo dmbm {dQ>m{_Z h¡ :

(A) {dQ>m{_Z A

(B) {dQ>m{_Z E

(C) {dQ>m{_Z D

(D) {dQ>m{_Z K

10. , Vmo doJ pñWam§H$ (k) :

(A) pñWa ahVm h¡

(B) KQ>Vm h¡

(C)

(D) A{^{H«$`m H$mo{Q> na Am{lV

11. {H$gr {dbo` H$m 1% {db`Z gyH«$mog (_moba Ðì`_mZ = 342 g mol 1) Ho$ 6 {db`Z
Ho$ gmW g_namgmar h¡ & {dbo` H$m _moba Ðì`_mZ h¡ :

1
(A) 34·2 g mol

1
(B) 57 g mol

(C) 114 g mol 1

1
(D) 3·42 g mol

56/3/1-13 8
9. The vitamin which plays an important role in coagulating blood is :

(A) Vitamin A

(B) Vitamin E

(C) Vitamin D

(D) Vitamin K

10. When a catalyst increases the rate of a chemical reaction, then the rate

constant (k) :

(A) remains constant

(B) decreases

(C) increases

(D) may increase or decrease depending on the order of the reaction

11. A 1%
1
mass = 342 g mol

(A) 34·2 g mol 1

1
(B) 57 g mol

1
(C) 114 g mol

1
(D) 3·42 g mol

56/3/1-13 9 P.T.O.
12. Obr` NaCl Ho$ {dÚwV-AnKQ>Z Ho$ Xm¡amZ H¡$Wmo{S>H$ A{^{H«$`m h¡ :

(A) Cl Am`Z

+
(B) Na Am`Z H$m AnM`Z

(C) H2O

(D) H2O H$m AnM`Z

13 16 (A)
(R)
(A), (B), (C) (D)

(A) A{^H$WZ (A) Am¡a H$maU (R) XmoZm| ghr h¢ Am¡a H$maU (R), A{^H$WZ (A) H$s
ghr ì`m»`m H$aVm h¡ &

(B) A{^H$WZ (A) Am¡a H$maU (R) XmoZm| ghr h¢, naÝVw H$maU (R), A{^H$WZ (A) H$s
ghr ì`m»`m H$aVm h¡ &

(C) A{^H$WZ (A) ghr h¡, naÝVw H$maU (R) µJbV h¡ &

(D) A{^H$WZ (A) µJbV h¡, naÝVw H$maU (R) ghr h¡ &

13. (A) : Ob _| E{WbrZ ½bmBH$m°b {_bmZo na {h_m§H$ H$_ hmo OmVm h¡ &

(R) : Ob Ho$ AUwAm| Ho$ gmW hmBS´>moOZ Am~§Y ~ZmZo H$s j_Vm Z hmoZo Ho$
H$maU E{WbrZ ½bmBH$m°b Ob _| A{dbo` h¡ &
56/3/1-13 10
12. During the electrolysis of aqueous NaCl, the cathodic reaction is :

(A) Oxidation of Cl ion

(B) Reduction of Na+ ion

(C) Oxidation of H2O

(D) Reduction of H2O

For Questions number 13 to 16, two statements are given one labelled
as Assertion (A) and the other labelled as Reason (R). Select the correct
answer to these questions from the codes (A), (B), (C) and (D) as given
below.

(A) Both Assertion (A) and Reason (R) are true and Reason (R) is the
correct explanation of the Assertion (A).

(B) Both Assertion (A) and Reason (R) are true, but Reason (R) is not
the correct explanation of the Assertion (A).

(C) Assertion (A) is true, but Reason (R) is false.

(D) Assertion (A) is false, but Reason (R) is true.

13. Assertion (A) : Addition of ethylene glycol to water lowers its freezing
point.

Reason (R) : Ethylene glycol is insoluble in water due to lack of its

ability to form hydrogen bonds with water molecules.

56/3/1-13 11 P.T.O.
14. (A) : O{Q>b A{^{H«$`mAm| Ho$ {bE A{^{H«$`m H$mo{Q> Am¡a AmpÊdH$Vm gX¡d
EH$g_mZ hmoVr h¢ &
(R) : H$mo{Q> à`moJ Ûmam {ZYm©[aV hmoVr h¡ VWm AmpÊdH$Vm Ho$db àmW{_H$
A{^{H«$`mAm| Ho$ {bE hr hmoVr h¡ &

15. (A) : S>mB_o{Wb B©Wa H$s Anojm EW &

(R) : EWoZm°b AUw nañna hmBS´>moOZ Am~§YZ go gå~Õ hmoVo h¢ O~{H$ S>mB_o{Wb
B©Wa _| `h g§^d Zht h¡ &

16. (A) : Eo{ZbrZ \«$sS>ob-H«$mâQ>²g A{^{H«$`m Zht H$aVr h¡ &

(R) : \«$sS>ob-H«$mâQ>²g A{ h¡ &

IÊS> I

17. (H$) _mobb AdZ_Z pñWam§H$ H$mo n[a^m{fV H$s{OE & `h JbZ EÝW¡ënr go {H$g àH$ma
g§~§{YV h¡ ? 2

AWdm
(I) EWoZm°b Am¡a EogrQ>moZ {_lU Ûmam {H$g àH$ma H$m {dMbZ Xem©`m OmVm h¡ ? H$maU
Xr{OE & Bg {Z{_©V hmoVm h¡ ? 2

18. (H$) {H$gr A{^{H«$`m _|, `{X A{^H$maH$ H$s gm§ÐVm VrZ JwZm H$a Xr OmVr h¡, Vmo
A{^{H«$`m doJ gÎmmB©g JwZm hmo OmVm h¡ ¡?

(I) EH$ n[apñW{V ~VmBE {Og_| H$moB© {ÛAmpÊdH$ A{^{H«$`m J{VH$V: àW_ H$mo{Q> H$s
A{^{H«$`m hmoVr h¡ & Eogr A{^{H«$`m H$m EH$ CXmhaU Xr{OE & 1+1=2

56/3/1-13 12
14. Assertion (A) : Order of reaction and molecularity are always same for
complex reactions.

Reason (R) : Order is determined experimentally and molecularity is

applicable only for elementary reactions.

15. Assertion (A) : The boiling point of ethanol is higher than that of
dimethyl ether.

Reason (R) : Ethanol molecules are associated through hydrogen

bonding whereas in dimethyl ether, it is not possible.

16. Assertion (A) : Aniline does not undergo Friedel-Crafts reaction.

Reason (R) : Friedel-Crafts reaction is an electrophilic substitution

reaction.

SECTION B

17. (a) Define molal depression constant. How is it related to enthalpy of

fusion ? 2

OR

(b) What type of deviation is shown by ethanol and acetone mixture ?

Give reason. What type of azeotropic mixture is formed by that
deviation ? 2

18. (a) the rate

of reaction becomes twenty-seven times. What is the order of the
reaction ?

(b) State a condition under which a bimolecular reaction is kinetically a

first-order reaction. Give an example of such a reaction. 1+1=2

56/3/1-13 13 P.T.O.
19. {ZåZ{b{IV Am`{ZH$ A{^{H«$`mAm| H$mo nyU© H$s{OE : 2 1=2

(H$) 2MnO4 + 5SO3 + 6H+

+ 2+
(I) Cr2O7 + 14H + 6Fe

20. (H$) {ZåZ{b{IV `wJb _| go H$m¡Z-gm h¡bmoOZ `m¡{JH$ SN2 A{^{H«$`mAm| _| Vrd«Vm go
A{^{H«$`m H$a ?

CH3 CH2 I AWdm CH3 CH2 Br

(I) \ ? 1+1=2

21. {ZåZ{b{IV Ho$ gmW ½byH$mog H$s A{^{H«$`m Xr{OE : 2 1=2

(H$) HCN

(I) gmÝÐ HNO3

IÊS> J

22. 200 g Ob _| {H$gr Admînerb {dbo` Ho$ 5 g H$mo KmobH$a {db`Z ~Zm`m J`m &
300 K na BgH$m dmîn Xm~ 31·84 mm Hg h¡ & {dbo` H$m _moba Ðì`_mZ n[aH${bV
H$s{OE & 3
(300 K na ewÕ Ob H$m dmîn Xm~ = 32 mm Hg)

2 1
23. 0·2 M KCl {db`Z H$s MmbH$Vm 2·48 10 S cm h¡ & BgH$s _moba MmbH$Vm Am¡a
{d`moOZ _mÌm ( ) n[aH${bV H$s{OE & 3
{X`m J`m h¡ :
o
= 73·5 S cm2 mol 1
K
o 2 1
= 76·5 S cm mol
Cl

56/3/1-13 14
19. Complete the following ionic equations : 2 1=2

(a) 2MnO4 + 5SO3 + 6H+

+ 2+
(b) Cr2O7 + 14H + 6Fe

20. (a) Which halogen compound in the following pair will react faster in
SN2 reactions and why ?

CH3 CH2 I OR CH3 CH2 Br

(b) Why is chloroform stored in closed dark coloured bottles ? 1+1=2

21. Give reaction of glucose with the following : 2 1=2

(a) HCN
(b) Conc. HNO3

SECTION C

22. A solution is prepared by dissolving 5 g of a non-volatile solute in 200 g of

water. It has a vapour pressure of 31·84 mm Hg at 300 K. Calculate the
molar mass of the solute. 3
(Vapour pressure of pure water at 300 K = 32 mm Hg)

23. The conductivity of 0·2 M solution of KCl is 2·48 10 2 S cm 1. Calculate

its molar conductivity and degree of dissociation ( ). 3

Given :
o 2 1
= 73·5 S cm mol
K
o 2 1
= 76·5 S cm mol
Cl

56/3/1-13 15 P.T.O.
24. EH$ àW_ H$mo{Q> H$s A{^{H«$`m H$mo 25% nyU© hmoZo _| 40 {_ZQ> bJVo h¢ & doJ pñWam§H$ H$m
_mZ n[aH${bV H$s{OE & {H$VZo g_` _| `h A{^{H«$`m 80% nyU© hmoJr ? 3
{X`m J`m h¡ : log 2 = 0·30, log 3 = 0·48, log 4 = 0·60, log 5 = 0·69

25. (H$) 2-~«mo_moã`yQ>oZ

Ho$ Ob-AnKQ>Z go ( )-ã`yQ>oZ-2-Am°b ~ZZo _| {H$g àH$ma H$s
Zm{^H$amJr à{VñWmnZ (SN1 AWdm SN2) hmoVr h¡ ? H$maU Xr{OE &
(I) Am¡ a _| gmo{S>`_ YmVw
Ho$ gmW A{^H¥$V {H$`m OmVm h¡ ? 2+1=3

26. (H$) {ZåZ{b{IV A{^{H«$`mAm| _§o gpå_{bV g_rH$aU {b{IE :

(i) amB_a-Q>r_Z A{^{H«$`m
(ii) H$moë~o A{^{H«$`m

(I) µ\$sZm°b Ho$ ~«mo_rZZ go 2,4,6-Q´>mB~«mo_moµ\$sZm°b ~ZZo _| à`wº$ A{^H$_©H$ H$m Zm_
{b{IE & 2+1=3

27. Amn {ZåZ{b{IV ê$nmÝVaU {H$g àH$ma gånÞ H$a|Jo ? (H$moB© ) 3 1=3

(H$) ~oݵOmoBH$ Aåb go ~oݵO¡pëS>hmBS>

(I) EoWoZ¡b go àmonoZmoZ
(J) EogrQ>mo\$sZmoZ go ~oݵOmoBH$ Aåb
(K) >~«mo_mo~oݵOrZ go 1-µ\o${ZbEWoZm°b
1
28. {ZåZ{b{IV A{^{H«$`mAm| _| A, B Am¡a C H$s g§aMZmE± Xr{OE : 2 1 =3
2

56/3/1-13 16
24. A first-order reaction is 25 complete in 40 minutes. Calculate the value
of rate constant. In what time will the reaction be 80 complete ? 3
Given : log 2 = 0·30, log 3 = 0·48, log 4 = 0·60, log 5 = 0·69

25. (a) What type of nucleophilic substitution (SN1 or SN2) occurs in the

hydrolysis of 2-Bromobutane to form ( )-Butan-2-ol ? Give reason.

(b) What happens when chlorobenzene and methyl chloride are

treated with sodium metal in dry ether ? 2+1=3

26. (a) Write the equations of the reactions involved in the following :
(i) Reimer-Tiemann reaction
(ii)

(b) Name the reagent used in the bromination of phenol to form

2,4,6-Tribromophenol. 2+1=3

27. How will you bring about the following conversions ? (any three) 3 1=3

(a) Benzoic acid to Benzaldehyde

(b) Ethanal to Propanone

(c) Acetophenone to Benzoic acid

(d) Bromobenzene to 1-Phenylethanol

1
28. Give the structures of A, B and C in the following reactions : 2 1 =3
2

56/3/1-13 17 P.T.O.
 IÊS> K

29. g§H«$_U VÎdm| Ho$ ñd^md Ho$ g§X^© _| (n 1)d H$mo Hw$N>
{d{eîQ> JwU àXmZ H$aVr h¡ WmAm| Ho$ A{V[aº$ g§H«$_U
YmVwE± AZwMwå~H$s` JwU Am¡a CËàoaH$ JwU Xem©Vr h¢ VWm a§JrZ Am`Z ~ZmZo H$s àd¥{Îm nmB©
OmVr h¡ & g§H«$_U YmVwE± , ZmBQ´>moOZ VWm h¡bmoOZm| go
A{^{H«$`m H$aVr h¢ & KMnO4 Am¡a K2Cr2O7 BZHo$ gm_mÝ` CXmhaU h¢ &

Am§V[aH$ g§H«$_U VÎ f-ãbm°H$

H$s aMZm H$aVr h¢ & b¡ÝWoZm°`S>m| _| 4f-H$jH$ Ho$

(imperfect shielding effect) Ho$ H$maU na_mUw H«$_m§H$ _| d¥{Õ Ho$ gmW na_mUw Am_mn
_| H«${_H$ õmg hmoVm h¡ {OgHo$ H$maU AmHw§$MZ hmoVm h¡ &
{ZåZ{b{IV àíZm| Ho$ CÎma Xr{OE :

(H$) g§H«$_U YmVwE± VWm CZHo$ `m¡{JH$ AÀN>o CËàoaH$ H$s ^m± ? 1

(I) b¡ÝWoZm°`S>m| _| na_mUw Am_mn (size) _| AmHw§$MZ ? 1

(J) b¡ÝWoZm°`S> AmHw§$MZ H$mo n[a^m{fV H$s{OE & `h V¥Vr` g§H«$_U loUr Ed§ {ÛVr`
g§H«$_U loUr H$s na_mUw {ÌÁ`mAm| H$mo {H$g àH$ma à^m{dV H$aVm h¡ ? 2

AWdm

2+ 2+
(J) Obr` _mÜ`_ _|, Cr AWdm Fe _| go H$m¡Z-gm à~bVa AnMm`H$ h¡ Am¡a
? 2

56/3/1-13 18
 SECTION D

The following questions are case-based questions. Read the case carefully and
answer the questions that follow.

29. The involvement of (n 1)d electrons in the behaviour of transition

elements impart certain distinct characteristics to these elements. Thus,
in addition to variable oxidation states, they exhibit paramagnetic
behaviour, catalytic properties and tendency for the formation of coloured
ions. The transition metals react with a number of non-metals like
oxygen, nitrogen and halogens. KMnO4 and K2Cr2O7 are common

examples.

The two series of inner transition elements, lanthanoids and actinoids,

constitute the f-block of the periodic table. In the lanthanoids, there is
regular decrease in atomic size with increase in atomic number due to the
imperfect shielding effect of 4f-orbital electrons which causes contraction.

Answer the following questions :

(a) Why do transition metals and their compounds act as good

catalysts ? 1

(b) What is the cause of contraction in the atomic size of lanthanoids ? 1

(c) Define lanthanoid contraction. How does it affect the atomic radii of

the third transition series and the second transition series ? 2

OR

(c) In aqueous media, which is a stronger reducing agent

Cr2+ or Fe2+ and why ? 2

56/3/1-13 19 P.T.O.
30. àmoQ>rZ O¡d-V§Ì _| gdm©{YH$ nmE OmZo dmbo O¡d AUw h¢ & àmoQ>rZ bJ^J ~rg {^Þ -Eo_rZmo

Aåbm| Ho$ ~hþbH$ hmoVo h¢ Omo & Xg Eo_rZmo Aåb

Amdí`H$ Eo_rZmo Aåb H$hbmVo h¢ & {µÁdQ>a Am`{ZH$ ê$n _|, Eo_rZmo Aåb C^`Y_u àH¥${V
Xem©Vo h¢

AmpÊdH$ AmH¥${V Ho$ AmYma na àmoQ>rZmo§ H$mo Xmo dJm] _| dJuH¥$V {H$`m OmVm h¡ : aoeoXma Am¡a
Jmo{bH$mH$ma àmoQ>rZ & àmoQ>rZm| H$s g§aMZm Ed§ AmH¥${V H$m AÜ``Z Mma {^Þ ñVam| na {H$`m
Om gH$Vm h¡ : àmW{_H$, {ÛVr`H$, V¥Vr`H$ Ed§ MVwîH$ g§aMZmE± & àË`oH$ ñVa nyd© ñVa H$s
VwbZm _| A{YH$ O{Q>b hmoVm h¡ & pH AWdm Vmn _| n[adV©Z go àmoQ>rZm| H$s {ÛVr`H$ `m
V¥Vr`H$ g§aMZmE± ZîQ> hmo OmVr h¢ Am¡a do AnZo àH$m`© H$aZo _| gj_ Zht ahVo & Bgo àmoQ>rZ
H$m {dH¥$VrH$aU H$hVo h¢ &

{ZåZ{b{IV àíZm| Ho$ CÎma Xr{OE :

(H$) Amdí`H$ Eo_rZmo ? 1

(I) Eo_rZmo Aåbm| Ho$ pµÁd ? 1

(J) (i) aoeoXma àmoQ>rZ VWm Jmo{bH$mH$ma àmoQ>rZ H$m EH$-EH$ CXmhaU Xr{OE &

(ii) àmoQ>rZm| Ho$ EH$bH$m| H$mo {H ? 2 1=2

AWdm

(J) (i) dh H$m¡Z-gr g§aMZmË_H$ {d{eîQ>Vm h¡ Omo AnMm`r eH©$am Ho$ A{^bjU H$mo
Xem©Vr h¡ ?

(ii) ? 2 1=2

56/3/1-13 20
30. Proteins are the most abundant biomolecules of the living system.

Proteins are the polymers of about twenty different -amino acids which

are linked by peptide bonds. Ten amino acids are called essential amino

acids. In zwitter ionic form, amino acids show amphoteric behaviour as

they react both with acids and bases.

On the basis of their molecular shape, proteins are classified into two

types : Fibrous and Globular proteins. Structure and shape of proteins can

be studied at four different levels i.e., primary, secondary, tertiary and

quaternary, each level being more complex than the previous one. The

secondary or tertiary structure of proteins get disturbed on change of pH

or temperature and they are not able to perform their functions. This is

called denaturation of proteins.

Answer the following questions :

(a) What are essential amino acids ? 1

(b) What is meant by zwitter ionic form of amino acids ? 1

(c) (i) Give one example each for Fibrous protein and Globular
protein.

(ii) What type of linkages hold monomers of proteins together ? 2 1=2

OR
(c) (i) What is the structural feature which characterises a reducing
sugar ?

(ii) What is the structural difference between nucleoside and

nucleotide ? 2 1=2

56/3/1-13 21 P.T.O.
 IÊS> L>
31. (H$) (i) 25ºC na {ZåZ{b{IV gob H$m {d.dm. ~b (emf ) n[aH${bV H$s{OE :
2+ 2+
Zn (s) Zn (0·001M) Cd (0·1 M) Cd (s)

{X`m J`m h¡ : Eo 2 = 0·76 V, Eo 2 = 0·40 V [log 10 = 1]

Zn / Zn Cd /Cd

(ii) \¡$amS>o Ho$ {dÚwV-AnKQ>Z H$m {ÛVr` {Z`_ ~VmBE & NaCl Ho$ Obr` {db`Z
H$s pH {H$g àH$ma go à^m{dV hmoJr O~ BgH$m {dÚwV-AnKQ>Z {H$`m OmVm
h¡ ? 3+2=5

AWdm
o
(I) (i) {ZåZ{b{IV gob A{^{H«$`m Ho$ {bE rG Am¡a log Kc n[aH${bV H$s{OE :
+ 2+
Fe (s) + Ag (aq) Fe (aq) + Ag (s)
{X`m J`m h¡ : Eo 2 = 0·44 V, Eo = + 0·80 V
Fe / Fe Ag / Ag

1
1 F = 96500 C mol
(ii) àmW{_H$ Am¡a {ÛVr`H$ ~¡Q>[a`m| H$s Anojm BªYZ gobm| Ho$ H$moB© Xmo bm^
{b{IE &
(iii) 1 _mob H2O Ho$ O2 grH$aU Ho$ {bE {H$VZo \¡$amS>o Amdí`H$ hm|Jo ?
3+1+1=5

32. (H$) (i) {ZåZ{b{IV A{^{H«$`mAm| Ho$ _w»` CËnmX {b{IE :

56/3/1-13 22
 SECTION E

31. (a) (i) Calculate emf of the following cell at 25ºC :

2+ 2+
Zn (s) Zn (0·001M) Cd (0·1 M) Cd (s)

Given : Eo 2 = 0·76 V, Eo 2 = 0·40 V [log 10 = 1]

Zn / Zn Cd /Cd

(ii)
aqueous NaCl solution be affected when it is electrolysed ? 3+2=5

OR

o
(b) (i) Calculate the rG and log Kc for the following cell reaction :
+ 2+
Fe (s) + Ag (aq) Fe (aq) + Ag (s)

Given : Eo 2 = 0·44 V, Eo = + 0·80 V,

Fe / Fe Ag / Ag
1
1 F = 96500 C mol

(ii) Write any two advantages of the fuel cells over primary and
secondary batteries ?

(iii) How many Faradays are required for the oxidation of 1 mole
of H2O to O2 ? 3+1+1=5

32. (a) (i) Write the major product(s) in the following reactions :

56/3/1-13 23 P.T.O.
 (ii) {ZåZ{b{IV `m¡{JH$ `wJbm| _| {d^oX H$aZo Ho$ {bE gab amgm`{ZH$ narjU
Xr{OE :

(1)

(2) noÝQ>oZ¡b Am¡a noÝQ>oZ-3-Am°Z 3+2=5

AWdm
(I) (i) {ZåZ{b{IV Ho$ {bE H$maU Xr{OE :

(1) go_rH$m~m©µOmBS> _| Ho$db EH$ NH2 g_yh go_rH$m~m©µOmoZ {daMZ _|

gpå_{bV hmoVm h¡ &
(2) EogrQ>moZ H$s VwbZm _| EogrQ>¡pëS>hmBS>> HCN `moJO Ho$ à{V A{YH$
A{^{H«$`merb hmoVm h¡ &

(ii) (1) {ZåZ{b{IV H$mo CZHo$ Aåbr` gm_Ï`© Ho$ KQ>Vo hþE H«$_ _| ì`dpñWV
H$s{OE :
CH3COOH, O2N CH2 COOH, HCOOH

(2) {ZåZ{b{IV A{^{H«$`m Ho$ {bE A{^H$_©H$ H$

CH3 CH = CH CH2 CN ?

CH3 CH = CH CH2 CHO

(iii) hob-\$mobmS>©-µOoqbñH$s A{^{H«$`m _| gpå_{bV A{^{H«$`m {b{IE & 2+2+1=5

33. {ZåZ{b{IV _| go {H$Ýht àíZm§| Ho$ CÎma {b{IE : 5 1=5

2+
(H$) g§Hw$b [Co(H2O)(CN)(en)2] H$m IUPAC Zm_ {b{IE &
(I) do MVwî\$bH$s` g§Hw$b {OZ_| Xmo {^Þ àH$ma Ho$ EH$X§Vwa {bJÝS> Ho$ÝÐr` YmVw Am`Z
Á`m{_Vr` g_md`dVm g§^d Zht hmoVr ?
56/3/1-13 24
 (ii) Give simple chemical tests to distinguish between the
following pairs of compounds :

(1)

(2) Pentanal and Pentan-3-one 3+2=5

OR
(b) (i) Give reasons for the following :
(1) In semicarbazide, only one NH2 group is involved in
the formation of semicarbazone.
(2) Acetaldehyde is more reactive than acetone towards
addition of HCN.

(ii) (1) Arrange the following in decreasing order of their acidic

strength :
CH3COOH, O2N CH2 COOH, HCOOH
(2) Name the reagent in the following reaction :

CH3 CH = CH CH2 CN ?

CH3 CH = CH CH2 CHO

(iii) Write the reaction involved in Hell-Volhard-Zelinsky reaction.

2+2+1=5

33. Attempt any five of the following : 5 1=5

(a) Write the IUPAC name of the complex :

[Co(H2O)(CN)(en)2]2+

(b) Why is geometrical isomerism not possible in tetrahedral complexes

having two different types of unidentate ligands coordinated with
the central metal ion ?

56/3/1-13 25 P.T.O.
 (J) {ZåZ{b{IV g§Hw$b Am`Zm| H$mo CZH$s {H«$ñQ>b joÌ {dnmQ>Z D$Om© ( o) hþE
H«$_ _| ì`dpñWV H$s{OE :
3+ 3 3
[Co(NH3)6] , [CoF6] , [Co(CN)6]

(K) g§`moOH$Vm Am~§Y {gÕm§V Ho$ AmYma na g§Hw$b [Ni(CO)4] Ho$ g§H$aU Ed§
Mwå~H$s` ì`dhma H$mo {b{IE &
[Ni H$m na_mUw H«$_m§H = 28]

3 3
(L>) [CoF6] Am¡a [Co(C2O4)3] g§Hw$b _| go H$m¡Z-gm g§Hw$b :

(i) A{YH$ ñWm`r h¡ ?

(ii) h¡ ?

(M>) C^`XÝVr {bJÝS> Am a h¡ ?

(N>) AîQ>\$bH$s` joÌ _| d5 t2g Am¡a eg Ho$ nXm| _| {b{IE

O~ :
(i) o > P, Am¡a (ii) o <P

56/3/1-13 26
 (c) Arrange the following complex ions in increasing order of their
crystal field splitting energy ( o) :
3+ 3 3
[Co(NH3)6] , [CoF6] , [Co(CN)6]

(d) Write the hybridization and magnetic character of the complex

[Ni(CO)4] on the basis of valence bond theory.

[Atomic No. : Ni = 28]

3 3
(e) Out of [CoF6] and [Co(C2O4)3] , which one complex is :

(i) more stable ?

(ii) the high spin complex ?

(f) What is the difference between an ambidentate ligand and

bidentate ligand ?

5
(g) Write the electronic configuration of d in terms of t2g and eg in an

octahedral field when :

(i) o > P, and (ii) o <P

56/3/1-13 27 P.T.O.