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Solution Test

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drvssssmcrobertganj
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Solution & Colligative Properties

uo Økafr ikB'kkyk
PART - I : PRACTICE TEST-1 (IIT-JEE (MAIN Pattern))
Max. Marks : 120 Max. Time : 1 Hr.
Important Instructions
1. The test is of 1 hour duration.
2. The Test Booklet consists of 30 questions. The maximum marks are 120.
3. Each question is allotted 4 (four) marks for correct response.
4. Candidates will be awarded marks as stated above in Instructions No. 3 for correct response of each question.
¼ (one fourth) marks will be deducted for indicating incorrect response of each question. No deduction from
the total score will be made if no response is indicated for an item in the answer sheet.
5. There is only one correct response for each question. Filling up more than one response in any question will
be treated as wrong response and marks for wrong response will be deducted accordingly as per instructions
4 above.
1. Mole fraction of C3H5(OH)3 in a solution of 36 g of water and 46 g of glycerine is :
(1) 0.46 (2) 0.36 (3) 0.20 (4) 0.40
2. Colligative properties have many practical uses, some of them may be :
I : Melting of snow by salt
II : Desalination of sea water
III : Determination of molar mass
IV : Determination of melting point and boiling point of solvent
Actual practical uses are :
(1) I, II (2) III, IV (3) I, II, III (4) II, III, IV
3. Select correct statement(s) :
(1) When solid CaCl2 is added to liquid water, the boiling temperature rises
(2) When solid CaCl2 is added to ice at 0°C, the freezing temperature falls
(3) Both (1) and (2)
(4) None of the above

4. If pKa = – log Ka = 4, and Ka = Cx2 then Van’t Hoff factor for weak monobasic acid when C = 0.01 M is :
(1) 1.01 (2) 1.02 (3) 1.10 (4) 1.20
5. Consider following terms (m = molality) :
Tb
I : mKb ; II : mKbi III : IV : Kb
i
Terms which can be expressed in degree (temperature) are
(1) III, IV (2) I, II (3) I, II, IIII (4) I, III
6. Elevation in b.p. of an aqueous urea solution is 0.52°. (Kb = 0.52° mol–1 kg) Hence, mole-fraction of urea in
this solution is :
(1) 0.982 (2) 0.567 (3) 0.943 (4) 0.018
7. Insulin (C2H10O5)n is dissolved in a suitable solvent and the osmotic pressure of the solution of various
concentration (in kg/m3) is measured at 20ºC. The slope of a plot of against c is found to be 8.134 × 10–3
(SI units) The molecular weight of the insulin (in kg/mol) is :
(1) 4.8 × 105 (2) 9 × 105 (3) 293 × 103 (4) 8.314 × 105

1
Solution & Colligative Properties

8. What is the normal boiling point of the solution represented by the


phase diagram ?
(1) A
(2) B
(3) C
(4) D
9. An aqueous solution of a solute AB has b.p. of 101.08°C (AB is 100% ionised at boiling point of the solution)
and freezes at – 1.80°C. Hence, AB (Kb / Kf = 0.3)
(1) is 100% ionised at the f.p. of the solution (2) behaves as non-electrolyte at the f.p. of the solution
(3) forms dimer (4) none of the above
10. Density of 1M solution of a non-electrolyte C6H12O6 is 1.18 g/mL. If Kf (H2O) is 1.86° mol–1 kg, solution freezes
at :
(1) – 1.58°C (2) – 1.86°C (3) – 3.16°C (4) 1.86°C
11. Mole fraction of a non-electrolyte in aqueous solution is 0.07. If Kf is 1.86° mol–1 kg, depression in f.p., Tf, is:
(1) 0.26° (2) 1.86° (3) 0.13° (4) 7.78°
12. What is the normal freezing point of the solution represented by the phase
diagram ?
(1) T1
(2) T2
(3) T3
(4) T0
13. Total vapour pressure of mixture of 1 mol of volatile component A (pA° = 100 mmHg) and 3 mol of volatile
component B (pB° = 60 mmHg) is 75 mm. For such case :
(1) there is positive devitation from Raoult’s low
(2) boiling point has been lowered
(3) force of attraction between A and B is smaller than that between A and A or between B and B
(4) all the above statements are correct
14. A colligative property of a solution depends on the :
(1) arrangement of atoms in solute molecule (2) total number of molecules of solute and solvent
(3) number of molecules of solute in solution (4) mass of the solute molecules
15. Which has maximum freezing point ?
(1) 6g urea solution in 100 g H2O (2) 6g acetic acid solution in 100g H2O
(3) 6g sodium chloride in 100 g H2O (4) All have equal freezing point
16. Select correct statements :
(1) The fundamental cause of all colligative properties is the higher entropy of the solution relative to that of
the pure solvent
(2) The freezing point of hydrofluoride solution is larger than that of equimolal hydrogen chloride solution
(3) 1M glucose solution and 0.5 M NaCl solution are isotonic at a given temperature
(4) All are correct statements
17. The vapour pressure of a pure liquid A is 40 mmHg at 310 K. The vapour pressure of this liquid in a solution
with liquid B is 32 mmHg. Mole fraction of A in the solution, if it obeys Raoult’s law is :
(1) 0.8 (2) 0.5 (3) 0.2 (4) 0.4
18. Mole fraction of the toluene in the vapour phase which is in equilibrium with a solution of benzene (p° = 120
Torr) and toluene (p° = 80 Torr) having 2.0 mol of each is
(1) 0.50 (2) 0.25 (3) 0.60 (4) 0.40

2
Solution & Colligative Properties

19. An azeotropic solution of two liquids has a boiling point lower than either of them when it :
(1) shows negative deviation from Raoult’s law (2) shows positive deviation from Raoult’s low
(3) shows ideal behaviour (4) is saturated

20. Depression of freezing point of 0.01 molal aq. CH3COOH solution is 0.02046°. 1 molal urea solution freezes
at –1.86°C. Assuming molality equal to molarity, pH of CH3COOH solution is :
(1) 2 (2) 3 (3) 3.2 (4) 4.2
21. Which of the following azeotropic solutions has the boiling point more than boiling point of the constituents
A and B ?
(1) CH3CH2OH and CH3COCH3 (2) CS2 and CH3COCH3
(3) CHCl3 and CH3COCH3 (4) CH3CHO and CS2

22. A 0.50 molal solution of ethylene glycol in water is used as coolant in a car. If the freezing point constant of
water is 1.86° per molal, at which temperature will the mixture freeze ?
(1) 1.56°C (2) – 0.93°C (3) – 1.86°C (4) 0.93°C
23. The depression of freezing points of 0.05 molal aqueous solution of the following compounds are measured.
1. NaCl 2. K2SO4 3. C6H12O6 4. Al2(SO4)3
Which one of the above compounds will exhibit the maximum depression of freezing point ?
(1) 3 (2) 2 (3) 4 (4) 1

24. On mixing 10 mL of acetone with 40 mL of chloroform , the total volume of the solution is :
(1) < 50 mL (2) > 50 mL (3) = 50 mL (4) Cannot be predicted

25. Select correct statement ?


(1) Heats of vaporisation for a pure solvent and for a solution are similar because similar intermolecular
forces between solvent molecules must be overcome in both cases
(2) Entropy change between solution and vapour is smaller than the entropy change between pure solvent
and vapour.
(3) Boiling point of the solution is larger than that of the pure solvent
(4) All are correct statements
26. What will be the molecular weight of NaCl determined experimentally from elevation in the boiling point or
depression in freezing point method ?
(1) < 58.5 (2) > 58.5 (3) = 58.5 (4) None of these
27. Which characterises the weak intermolecular forces of attraction in a liquid ?
(1) High boiling point (2) High vapour pressure
(3) High critical temperature (4) High heat of vaporization
28. On the basis of intermolecular forces predict the correct order of decreasing boiling points of the compounds:
(1) CH3OH > H2 > CH4 (2) CH3OH > CH4 > H2
(3) CH4 > CH3OH > H2 (4) H2 > CH4 > CH3OH
29. During depression of freezing point in a solution the following are in equilibrium :
(1) Liquid solvent, solid solvent (2) Liquid solvent, solid solute
(3) Liquid solute, solid solute (4) Liquid solute, solid solvent
30. Which of the following liquid pairs shows a positive deviation from Raoult’s law ?
(1) Acetone – chloroform (2) Benzene – methanol
(3) Water – nitric acid (4) Water – hydrochloric acid

3
Solution & Colligative Properties

uo Økafr ikB'kkyk

Practice Test-1 (IIT-JEE (Main Pattern))


OBJECTIVE RESPONSE SHEET (ORS)
Que. 1 2 3 4 5 6 7 8 9 10

Ans.

Que. 11 12 13 14 15 16 17 18 19 20

Ans.

Que. 21 22 23 24 25 26 27 28 29 30

Ans.

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