2.5 Glycol Dehydration System
2.5 Glycol Dehydration System
PPA PLATFORM
SECTION: 2.5
Contents
ABBREVIATIONS
UNITS OF MEASUREMENT
Note that
Standard conditions Defined at 15.6o C and 101.3 kPa abs)
Normal conditions Defined at 0o C and 101.3 kPa (abs)
PPA has a design capacity of processing 240 MMSCFD gas. The gas
produced from the platform is totally saturated with water. Wet gas, if
transported as such, can partly condense in sub-sea pipeline resulting in
undesirable two-phase flow. To avoid this, gas is dehydrated on PPA using
Trio-ethylene Glycol (TEG) in a contactor. Water content in the dehydrated
gas is maintained below 6 lbs / MMSCF.
Dehydrated gas has H2S content in the range of 350 to 500 ppm. This meets
the mainstream gas consumer’s specification and supplied as such. Fuel Gas
/ Lift Gas H2S spec is 10 ppm. To achieve this, stream is sent for sweetening
/ H2S removal to Amine scrubbing unit where H 2S content is reduced to 10
ppm.
The system consists of two Glycol towers, one flash gas separator and one
Glycol Regeneration System. The system is designed to dehydrate the gas
to contain water below 6 lb / MMSCF. Tri-ethylene Glycol is used as a
dehydrating medium. As per design, 3 gallons of lean glycol needs to be
circulated for every lb of water removed from the wet gas. Water content of
wet gas depends upon the temperature and pressure at the inlet of contactor.
The flow of lean Glycol is adjusted to get desired quality of gas at the outlet
of the contactors. Following graphs depict the effect of various parameters on
the dehydration mechanism.
a) Water Content of Hydrocarbon Gas
b) Dew Point of Natural Gas
c) Equilibrium Water Dew Points with Various Concentrations of
TEG
The dehydrated gas is split into two streams. The main stream is metered
and exported to Hazira by subsea pipeline. The second stream is used for
fuel and lift gas. The flow of the fuel/lift gas can vary from 2.5 MMSCFD to 25
MMSCFD. It is further treated in Amine contactor to remove H 2S. The off
gas from the Amine Contactor is water saturated and therefore it is again
dehydrated to get the water content below 6 lb/MMSCF.
The design parameters for the major equipment of the dehydration system are given below:
The Glycol system consists of two Glycol Towers, one Flash Gas Separator
and one Glycol Regeneration System.
The gas stream at 100oF and 970 psig nominal pressure (During minimum
ambient temperature 971 psig & during maximum ambient temperature 966
psig ) enters the Contactor Inlet Scrubber MBF–1100 where free liquid, if
any, is separated from the gas. The gas exits the scrubber through a high
efficient vane pack, where the residual droplets in the stream are coalesced.
The liquid separated in the vane pack is piped to the bottom of the scrubber
and mixes with the free liquid. The liquid goes back to the crude oil header.
The gas stream from the Contactor Gas Separator enters the Contactor Inlet
Filter Separator MAK–1110, where any carry over in the gas stream is
removed. The Separator is divided into two sections. The first section
removes the free carry-over liquid. In the second section at the top, finer
entrapped liquid droplets are separated when the gas passes through eleven
Apex Porous media coalescing filter elements.
The Contactor inlet filter/separator can be bypassed, blocked in, and
depressurised to change the elements, if they are plugged.
LC–1111, controls the liquid level, a snap action level controller that
operates the LV–1111, level control valve.
The gas then passes through eleven (11) Apex Porous Media
Coalescing Filter Elements in top section.
Level Controller LC-1112, A snap action controller, operating LV–
1112 controls the level in the second section.
Outlet from both Level control valves go back to the Crude oil
header.
Differential Pressure meter PDI–1111 installed across Filter
Separator indicates the fouling of the filters. Filter elements should
be changed when delta-P is between 12 to 15 psig.
Bursting Disc PSE-1111 and a Pressure Safety Valve, PSV–1111
both set at 1380 psig protect the Filter Separator from over
pressurising.
Pressure Transmitter PT-1111A will give pressure alarm high at 10
psig in control panel if there is leak in the bursting disk.
A 1” line provided around the relief valve to flare is used to de-
pressurise the filter.
The Separator must be isolated and fully depressurised before opening of top
cover head. Failure to depressurise the Separator before opening can result
in serious injury or damage.
The gas stream enters the Bulk Glycol Contactor below the structured pack-
ing section of the tower and flows upward through the packing where the gas
and lean glycol are contacted in counter-current direction. TEG comes in
close contact with water saturated as. TEG has a high affinity for water and
dehydrates the gas. Glycol absorbs the water from gas thereby reducing wa-
ter below 6 lbs per MMSCF. Dry gas comes out of the top of the contactor
and water laden rich glycol comes off from the bottom of the tower.
FE-1121 / FQI-1121 measure Glycol flow to the Contactor and con-
trolled by flow controller FC-1121 operating flow control valve FV-
1121.
At 240 MMSCFD gas rate, glycol circulation is 25USGPM of 99.2
weight % glycol. The gas stream from the Filter Separator enters the
Bulk Glycol Contactor MAF–1120 below the structured packing sec-
tion of the tower, flows upward through the packing where the gas
and lean glycol are contacted counter–current. Water laden rich
glycol comes to the bottom of Contactor.
Level Controller LC–1121 controls the bottom level of the column by
operating the control valve LV–1121 with a proportional action to
keep the liquid flowing smoothly to regeneration. LT-1121A trips on
high high LSHH-1121A & low low LSLL-1121A to alert HH & LL
Level.
The Choke FO–1121 is located down stream of level control valve is
to prevent the washing out of SDV-1121 due to the high pressure
drop.
Valve SDV–1121 located on the line to shut off the line in the event
of an emergency.
Low Low pressure transmitter (PT-1121A) PSLL-1121A, set at 850
445 psig will activate based on 3 out of 4 voting alongwith PT-
1101B, PT-7501B and PT-1451 C.A 2” by-pass around the PSV for
manual flaring or depressurising.
Document No. BGEP-LNTA-P121-POXX- Rev.1DC Page 15 of 55
PR-12-158-0001-D
PPA Platform BGEPIL, India Section 2.5
Valve BDV-1121 is located on the HP flare line.
TAH-7003 set at 120 oF is provided at the inlet line of bulk glycol
contactor.
TI-7003 is provided on inlet line of Bulk Glycol Contactor for
temperature indication.
Dry gas from the Bulk Glycol Contactor is compressed in third stage of Pro-
cess Gas Compressor. In PGC pressure is raised from 1000 psig to 1350
psig. Due to increase in pressure, heavier components in the gas get partially
condensed, as the compressed gas is cooled to remove the heat of compres-
sion, in the compression section. The compressed and cooled gas is then
sent to the Bulk gas Filter Separator MAK–9390. In Bulk gas Filter a distrib-
utor is provided in gas inlet line for evenly distribution of the gas entering.
The liquid separated at bottom gets knocked out and its level is controlled by
LC-1131 with the operation of control valve LV-1131. For removal of mist in
gas, the gas flows to down stream filter media, made of glass fibre + nylon.
Here mist is condensed and separates in form of fine liquid droplets. The
droplets gets collected at the bottom of the separator.
The gas dehydrated to 6 lbs. H2O / MMSCF and filtered in MAK-1130 is split
into two streams. The main stream is metered at the sales gas meter station
and dispatched from the Platform to ONGC terminal at Hazira.
The second stream is used for Fuel and Lift Gas. Its flow can vary from 25
MMSCFD (When the Lift System is in operation) to 2.5 MMSCFD. (When
only Fuel Gas system is being processed)
The process gas contains 1070 ppm H2S. Fuel / Lift gas specifications are 10
ppm H2S. This stream is sweetened in an Amine Contactor located in Amine
unit. In this unit H2S content of the gas is reduced from 1070ppm to 10 ppm
but it becomes fully saturated with water. Water saturated gas is dehydrated
again to attain water content of 6 lbs. per MMSCF. Outlet gas from Amine
Contactor at 137o F is cooled to 120oF in Amine Contactor. outlet gas Cooler.
The cooled gas stream then flows through either of the two Amine Contactor
Filter Separators MAK–1150 or MAK–1160. One Unit remains on line,
second unit remains stand-by; either of the two can handle the entire flow.
The cooled gas stream enters the bottom of the filter separator. Amine
Contactor outlet filter separator is divided in two sections. The free liquid is
removed in the first section. The Level controller LC–1151/1161, controls the
level of the knocked out liquid in the vessel. In the second section, the gas
stream then flows through two Apex Porous Media Coalescing Filters. The
fine liquid droplets are removed and collected at the bottom of this section.
Liquid so recovered by the separators is returned to the Amine Flash
Separator.
Level control LC –1151 / 1161 operates the control valves LV–1151 /
1161 to maintain the level in the bottom section.
If the level gets too high, the high level alarm LAH 1151A/1161A will
alarm at the control panel.
Level control LC–1151 / 1161 operate level control valves LV–1151 /
1161 to control the liquid level in top section.
Level control LC –1152 / 1162 operates the control valves LV–1152 /
1162 to maintain the level in the second section.
Separators are protected from over pressurising by a Bursting Disc in
series with PSV, The Bursting Discs PSE–1151 / 1161 are set at
1380 psig.
Pressure Relief Valves, PSV–1151 / 1161 are set at 1380 psig. If
there is a leak in the Bursting Disc the pressure to PSV rises to 10
psig, pressure Transmitter PT-1151 A/1161A will send a High High
alarm to control panel.
The separator can be by-passed, blocked / isolated to change the
filter elements. The filter elements should be changed when the
differential pressure on PDI–1151/1161 reads 12 to 15 psig across
the elements.
The Separator must be isolated and fully depressurised before opening of top
closure head. Failure to depressurise the Separator before opening can
result in serious injury or damage.
1
PPA Platform BGEPIL, India Section 2.5
Lean Glycol stream prior to entering Glycol Contactor is first cooled in gas /
glycol exchanger HBG-4090, by outgoing gases from the Contactor.
The Gas /Glycol heat Exchanger HBG-4090, is shell tube type heat ex-
changer, installed down stream of TEG Contactor MAF-1170, to cool the lean
TEG.
This ensures that the Glycol does not enter the contactor at an elevated tem-
perature. A high glycol return temperature may lead to significant heat trans-
fer at the top of the tower and elevate of the dry gas temperature this would
lead to the following.
The cooled glycol flows to three tier stainless steel distribution section and
spreads evenly over the packing and flow downward absorbing water from
the wet gas moving upwards.
The outlet from Filter Separator MAK–1150 or MAK–1160 enters the Fuel /
Lift gas Glycol Contactor MAF-1170 below the structured packing section of
the tower, flows upward through the packing where the gas and lean glycol
is contacted counter-currently. The dry gas coming out from the top of the
Contactor and water rich glycol coming off from the bottom of the tower. Ef -
fluent gas from the top of the contactor flows through the Gas / Glycol ex-
changer HBG–4090 to the high pressure fuel gas scrubber and power gas
accumulators.
Water Rich Glycol from Bulk Contactor MAF-1120 and from Fuel/lift Glycol
Contactor MAF-1170 jointly flow as coolant through the reflux condenser at
the top of still column. Glycol is further heated in Glycol/Glycol Pre-heater
HBG-4150 to 210F and then it enters the Glycol Flash Drum.
Hot, water rich Glycol at 210F and a pressure of 1350 psig flashes in Glycol
Flash Drum to a pressure between 50 to 60 psig. Dissolved gaseous and
entrained liquid hydrocarbon droplets are removed in Glycol Flash drum. The
dissolved vapours are flashed off. Typically these vapours are about 1
SCF/gallon of Glycol. Partial heating of the Glycol stream reduces the
foaming tendency in flash tank. Entrained droplets of hydrocarbon liquid rise
to the surface of the liquid Glycol, where they accumulate as hydrocarbon
layer. This layer is skimmed off by raising the vessel level until the liquid
spills into the skim bucket in side the separator.
Level in skim section can be seen can be seen in level gauge LI-
1261.
Level Controller LC-1261 controls the level of skim section by
operating control valve LV-1261. The liquid is drained to a closed
drain system.
Low Low level trip LSLL-1261A of LT-1261A initiates from ESD if
level drops beyond limit.
High high & low low level trip LSHH/LSLL-1262A of LT-1262A
initiates from ESD if level drops/goes beyond limit.
Pressure Controller PCV-1261 set at 60 psig releases the gas to LP
flares in case pressure increases.
Pressure Controller PCV-1262 set at 50 psig make-up gas from Fuel
Gas System when ever pressure drops.
Pressure transmitter (PT-1261A) with Low Low and High High
Pressure trips PSLL-1261A and PSHH-1261A set at 43 40 psig and
69 135 psig respectively send alarm to ESD in case pressure goes
beyond the limits.
Bursting Disc PSE-1261 set at 150 psig, and a pressure Relief Valve
PSV-1261 set at 150 psig protect the system against over
pressurising.
Separator level is controlled by LC-1262 by operating control valve
LV-1262, located down stream of Glycol Sock Filter, MAJ-1270 and
Charcoal Filter MAJ-1280.
GLYCOL FILTERATION :
(Refer to P & ID No: BGEP-LNTA-P121-PPAX-PR-11-158-4122-D)
Glycol Separator liquid level control valve is located down stream of Charcoal
Filter MAJ-1280. Filtered Glycol is heated from 2100F to 310F in Glycol /
Glycol exchanger HBG-4160 before it enters the Still Column for
regeneration. Regeneration column is a simple packed distillation column.
Regenerator operates at atmospheric Pressure and re-boiler of Glycol
Regenerator is designed to operate at a temperature of 395F. Under these
conditions Glycol Thermally Regenerates to a concentration of 99.2 weight
%.
The separation of water vapours from Glycol takes place in the distillation
column. Vapours from the overhead of the column are partially condensed by
cooling coil / condenser HAL-4330/4330A. Both the Glycol Vapour Condens-
ers, operates in parallel are designed for thermal rating 0.6 MMBTU/HR
each. The condensed vapours from both the vapour condensers are drained
to overhead accumulator MBL-1560 and generate reflux for the column.
Pumps PBE-6550 / 6560, pump water from overhead accumulator MBL-1560
to closed drain. 25% of the overhead vapours are condensed and fall back
as reflux, which maintains desired temperature profile of the column.
Regenerated hot lean solution overflows to Glycol reboiler surge tank BBC-
2010 from the reboiler. Submergence of the overflow pipe isolates the surge
tank from the wet reboiler vapours. From here the hot lean solution flows
from the surge tank where it exchanges heat in heat-exchanger, HBG-4160,
with incoming water rich Glycol, and flows to the suction inlet of glycol
circulation pumps, PBA-6110/6120 .
A simple visual inspection of the TEG sample can provide clues for identifying many common
glycol problems. The following conditions can indicate major operating problems.
* A black viscous TEG solution (compared with clean TEG from a supply drum) may
be the result of heavy hydrocarbon contamination or glycol polymerisation due to
thermal breakdown or interaction with hydrocarbons.
* The presence of two liquid phases indicates the hydrocarbon contamination of the
TEG indicate the poor separation in the Flash Drum (MBA-1260)
.
* The presence of finely divided black precipitate is the result of iron corrosion.
The foaming tendency of the TEG can be can be checked by sparging air through a sample
in a test tube, The formation of a stable bubble or foam on the TEG surface (stable for
greater than 10 seconds) indicates the foaming character of the Glycol. In case the foaming
is detected, anti foam chemical should be added to the TEG and checked again if foaming
tendency remains.
The pH of the TEG should be approximately 7.0. However it should be noted that thermal
degradation of TEG will result in the formation of acid and the pH of the TEG will fall. A pH of
6 or less will result in poor dehydration and increased corrosion. The pH should be modified
by the batch addition of base i. e. DEA or Sodium Acetate. A pH above 9 is also not desirable
because it leads to emulsification in the presence of hydrocarbons and foaming in the
contactor.
DP type Level transmitter (LT-2011A/2012A) with high high (LSHH-2011A/2012A) and low
low (LSLL-2011A/2012A) on Glycol Reboiler/Surge tank (BBC-2010) are provided.
Document No. BGEP-LNTA-P121-POXX- Rev.1DC Page 21 of 55
PR-12-158-0001-D
PPA Platform BGEPIL, India Section 2.5
START-UP
Slowly admit gas into the Absorber, checking the leaks until the
pressure in vessel reaches the line pressure. Close the inlet valve.
Slowly admit gas into the contactors, checking the leaks until the
pressure in vessels reaches the line pressure. Close the inlet valve.
1) Bulk Contactor
2) Fuel/Lift Gas Contactor.
After stabilising the Glycol dehydration plant for liquid circulation, gas
can be introduced. Before introduction of the gas into Glycol
dehydration system, it is essential to ensure that the relevant
upstream and downstream process units are in ready condition. The
In order to carry out the safe shutting down of the unit it is essential to carry
out various steps in proper sequence. The guiding principal for carrying out
the safe shut down is as follows.
1) Close the isolation valves on following level control valves in the field
to hold glycol level in the respective vessel.
a) LV-1121 (MAF-1120)
b) LV-1170 (MAF-1170)
c) LV-1262 (MBD-1260)
2) Stop HAL-4330, glycol vapour condenser, cooling fan.
3) Isolate Glycol Sock Filter, MAJ-1270 and Charcoal Filter, MAJ-1280.
Low stripping/ no
stripping gas through
the packed column of
the reboiler,
Flooding of still
column
Improper separation
in the flash drum,
BMD-1260
Excessive circulation
(low residence time)
Contactors’ LIC-
1121/1171
malfunction/valve
closed
Check gas distributor
inlet/internals
Excessive gas
flowrate
Plugged packing and
demister pads.
Fouling on packing
Channelling in
packing
Glycol foaming
2. High glycol The common symptom of many problems Carry over due to
losses is excess glycol loss. This loss is due to Excessive foaming.
(Maximum one, or a combination of the following:
glycol losses
to be 0.1
gal/mmscf) Foaming, Degradation, Salt plugging the Mist extractor
regenerator still column, inadequate mist plugged or
extraction, Lean glycol absorber is too hot, channelling/damage.
spillage of glycol or pump leakage.
Lean glycol entering
Loss from contactor contactor too hot.
Excessive stripping
gas
Insufficient reflux
cooling at top of still
Temperature at top of
still is too high.
Excessive packing
gland leakage
Contactor pressure
too high.
6.Low High flow through the reflux Check and adjust the
Temperature condenser. bypass valve of reflux
-Glycol condenser.
Regenerator Low reboiler temperature.
Increase the
Packing choked. temperature of
reboiler.
Check reboiler
pressures compare
for any abnormal rise.
7.High Packing in the still column is broken
Pressure - and/or plugged with tar, dirt
Glycol
Regenerator Restricted vent line not sloped.
reboiler.
Still column is flooded by excessive
boil up rates and/or excessive reflux
cooling.
2.5.9 ANNEX
2.5.9.3 P&IDs
PI-6121 - -
* Ability to :
- Detect the deviation
- Continuously and patiently monitor the
operations
- communicate to the group involved in the
process
- trouble shooting
- Take corrective action
- Report the deviation
- Follow SOP's
Training * Technical
- Plant Control System
* Non Technical
- Report writing skills
- Communication skills
* HSE
- HSE Management
* IT
- MS Office