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July Month Class XII MCQ

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23 views8 pages

July Month Class XII MCQ

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ramavarriervv
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© © All Rights Reserved
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Velsvidyashram Sr sec school

Class XII Chemistry July month Mcqs


I week

1.In comparison to a 0.01 M solution of glucose, the depression in freezing point


of a 0.01 M MgSO4
solution is
(a) the same
(b) about twice
(c) about three times
(d) about six times
2.The value of Henry’s Law constant is:
(a) larger for gases with higher solubility
(b) larger for gases with lower solubility
(c) constant for all gases
(d) not related to the solubility of gases
3.Which of the following aqueous solutions should have the highest boiling point?
(a) 1.0 M Glucose
(b) 1.0 M Na2SO4
(c) 1.0 M KCl
(d) 1.0 M Urea
4.If a molecule AB undergoes dimerization in Benzene, its Van’t Hoff factor is
found to be 0.60. The degree of dissociation of AB is
(a) 20%
(b) 60%
(c) 80%
(d) 50%
5.12g of Urea is dissolved in 1L of water and 68.4g sucrose is dissolved in 1L of
water. Relative lowering of vapour pressure of Urea solution is:
(a) Greater than sucrose solution
(b) Less than sucrose solution
(c) Double that of sucrose solution
(d) Equal to that of sucrose solution
6.Density of a 2.05 M solution of acetic acid in water is 1.02 g/mL. The molality of
the solution is
(a) 3.28 mol kg–1
(b) 2.28 mol kg–1
(c) 0.44 mol kg–1
(d) 1.14 mol kg–1
7.Which is not a colligative property?
(a) Osmotic pressure
(b) Lowering of vapour pressure
(c) Depression in freezing point
(d) Molal elevation constant
8.KH value for Ar(g), CO2 (g), HCHO (g) and CH4 (g) are 40.39, 1.67, 1.83×10–5
and 0.413 respectively. Arrange these gases in the order of their increasing
solubility.
(a) HCHO < CH4 < CO2 < Ar
(b) HCHO < CO2 < CH4 < Ar
(c) Ar < CO2 < CH4 < HCHO
(d) Ar < CH4 < CO2 < HCHO
9.An unripe mango placed in a concentrated salt solution to prepare pickles
shrinks because
(a) it gains water due to osmosis
(b) it loses water due to reverse osmosis
(c) it gains water due to reverse osmosis
(d) it loses water due to osmosis
10.The solution that forms maximum boiling azeotropes is
(a) Carbon disulphide – Acetone
(b) Benzene - Toluene
(c) Acetone – Chloroform
(d) n-Hexane – n-Hectane

II week
11.Which of the following is dependent on temperature?
(a) Molality
(b) Molarity
(c) Mole Fraction
(d) Mass percentage
12.Osmotic pressure of a solution is 0.0821 atm at a temperature of 300 K. The
concentration in moles/lit will be:
(a) 0.33
(b) 0.666
(c) 0.0033
(d) 3
13.The type of intermolecular interaction present in a solution of n- Hexane and
n-Octane is:
(a) London dispersion forces
(b) Dipole-dipole interaction
(c) Hydrogen bonding
(d) Ion-dipole interaction
14.Colligative properties depend on
(a) the nature of the solute
(b) the number of solute particles in solution
(c) the physical properties of solute
(d) the nature of the solvent
15.Which among the following is least soluble in water?
(a) Phenol
(b) Toluene
(c) Ethylene glycol
(d) Pentanol
16)1. Mole fraction of glycerine C3H5(OH)3 in solution containing 36 g of water and 46 g
of glycerine is
(a) 0.46
(b) 0.40
(c) 0.20
(d) 0.36
17)Which of the following condition is not satisfied by an ideal solution?
(a) ΔHmixing = 0
(b) ΔVmixing = 0
(c) Raoult’s Law is obeyed
(d) Formation of an azeotropic mixture
18)The boiling point of an azeotropic mixture of water and ethanol is less than that of
water and ethanol. The mixture shows
(a) no deviation from Raoult’s Law.
(b) positive deviation from Raoult’s Law.
(c) negative deviation from Raoult’s Law.
(d) that the solution is unsaturated.
19)Which has the lowest boiling point at 1 atm pressure?
(a) 0.1 M KCl
(b) 0.1 M Urea
(c) 0.1 M CaCl2
(d) 0.1 M A1Cl3
20)People add sodium chloride to water while boiling eggs. This is to
(a) decrease the boiling point.
(b) increase the boiling point.
(c) prevent the breaking of eggs.
(d) make eggs tasty.

III week

21). The van’t Hoff factor (i) accounts for


(a) degree of solubilisation of solute.
(b) the extent of dissociation of solute.
(c) the extent of dissolution of solute.
(d) the degree of decomposition of solution.
22)Which relationship is not correct?

23)The molal elevation constant depends upon


(a) nature of solute.
(b) nature of the solvent.
(c) vapour pressure of the solution.
(d) enthalpy change.
24).While heating one end of a metal plate, the other end gets hot because of
(a) the resistance of the metal
(b) mobility of atoms in the metal
(c) energised electrons moving to the other end
(d) minor perturbation in the energy of atoms.
25)The EoM3+/M2+ values for Cr, Mn, Fe and Co are -0.41, +1.57, + 0.77 and +1.97 V
respectively. For which one of the metals, the change in oxidation state from +2 to +3 is
easiest?
(a) Cr
(b) Mn
(c) Fe
(d) Co
26).Fused NaCl on electrolysis gives .............. on cathode.
(a) Chlroine
(b) Sodium
(c) Sodium amalgam
(d) Hydrogen
27)The highest electrical conductivity out of the following aqueous solutions is of?
(a) 0.1 M acetic acid
(b) 0.1 M chloro acetic acid
(c) 0.1 M fluoroacetic acid
(d) 0.1 M difluoro acetic acid
28).The amount of electricity required to deposit 1 mol of aluminium from a solution of
AlCl3 will be
(a) 0.33 F
(b) 1 F
(c) 3 F
(d) 1 ampere
29)Which of the following is supplied to the cathode of a fuel cell?
(a) Hydrogen
(b) Nitrogen
(c) Oxygen
(d) Chlorine
30)The reaction, 3ClO–(aq) → ClO3(aq) + 2Cl–(aq) is an example of
(a) Oxidation reaction
(b) Reduction reaction
(c) Disproportionation reaction
(d) Decomposition reaction

IV week
31).Molar conductivity of 0.15 M solution of KCl at 298 K, if its conductivity is 0.0152 S
cm-1 will be
(a) 124 Ω-1 cm2 mol-1
(b) 204 Ω-1 cm2 mol-1
(c) 101 Ω-1 cm2 mol-1
(d) 300 Ω-1 cm2 mol-1
32)How long would it take to deposit 50 g of Al from an electrolytic cell containing Al2O3
using a
current of 105 amperes?
(a) 1.54 h
(b) 1.42 h
(c) 1.32 h
(d) 2.15 h
33).How many coulombs of electricity is required to reduce 1 mole of Cr2O72- in acidic
medium?
(a) 4 × 96500 C
(b) 6 × 96500 C
(c) 2 × 96500 C
(d) 1 × 96500 C
34).The equivalent conductance of Ba2+ and Cl– are respectively 127 and 76 ohm−1 cm2
eq−1 at
infinite dilution. The equivalent conductance of BaCl2 at infinite dilution will be
(a) 139.5 ohm−1 cm2 eq−1
(b) 203 ohm−1 cm2 eq−1
(c) 279 ohm−1 cm2 eq−1
(d) 101.5 ohm−1 cm2 eq−1
35).Standard solution of KNO3 is used to make a salt bridge because
(a) Velocity of K+ is greater than that of NO3−
(b) Velocity of NO3− is greater than that of K+
(c) Velocity of both K+ and NO3− are nearly same
(d) KNO3 is highly soluble in water.
36).The standard reduction potentials of Cu2+/Cu and Cu2+/Cu+ are 0.337 and 0.153
respectively.
The standard electrode potential of Cu+/Cu half cell is
(a) 0.184 V
(b) 0.827 V
(c) 0.521V
(d) 0.490 V
37).Without losing its concentration ZnCl2 solution cannot be kept in contact with
(a) Au
(b) Al
(c) Pb
(d) Ag
38)The standard reduction potentials of X, Y, Z metals are 0.52, -3.03, -1.18
respectively. The order of reducing power of the corresponding metals is:
(a) Y > Z > X
(b) X > Y > Z
(c) Z > Y > X
(d) Z > X > Y

39)The charge required for the reduction of 1 mol of MnO4– to MnO2 is

(a) 1 F
(b) 3 F
(c) 5 F
(d) 6 F
40)The cell reaction of the galvanic cell.

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