1.

Blood cells do not shrink in blood because blood is

(A) hypotonic
(B) isotonic
(C) equimolar
(D) hypertonic
2. Which of the following is Raoult's law applicable to, in order to determine molar masses correctly?
(A) Ionic solute in liquid
(B) Non-ionic solute in dilute solution
(C) Non-ionic solute in concentrated solution
(D) Ionic solid in insoluble form in solvent
3. If the concentration of glucose (C6H12O6) in blood is 0.9 g L–1, what will be the molarity of glucose in blood?
(A) 5M
(B) 0.5 M
(C) 0.005 M
(D) 50 M
4. An open beaker containing a pure solvent and a second beaker containing a solution in the same solvent with a
non-volatile solute are sealed in a container. Over a period of time
(A) Volume of both solution and solvent will decrease
(B) Volume of both solution and solvent will increase
(C) Volume of solution will decrease while volume of solvent will increase
(D) Volume of solution will increase and volume of solvent will decrease
5. Out of following which one is not an example of solution?
(A) Air
(B) Brass
(C) Benzene in water
(D) Both A and C
6. The law which states that “the partial pressure of the gas in vapour phase (p) is proportional to the mole fraction
of the gas (χ) in the solution” is:
(A) Raoult’s law
(B) Henry’s law
(C) Dalton’s law
(D) Van’t Hoff’s law
7. Mole fraction of 𝑁𝑎𝑂𝐻 in 4.5 molal aqueous 𝑁𝑎𝑂𝐻 solution is:

3
(A) 20
4.5
(B) 60.05
55.55
(C) 60.05
4.5
(D) 55.55
8. Which of the following mixture does not show positive deviation from the Raoult’s law?
(A) Benzene + acetone
(B) Acetone + ethanol
(C) Acetone + chloroform
(D) Water + ethanol
9. The freezing point depression constant for water is 1.86∘ 𝐶 𝑚−1. If 10.00 𝑔 𝑜𝑓 𝑁𝑎2 𝑆𝑂4 is dissolved in 90.0 𝑔 of
𝐻2 𝑂, the freezing point is changed by 3.82∘ 𝐶. The van't Hoff (i) factor for 𝑁𝑎2 𝑆𝑂4 is: (Molality of the solution is
0.782 mol/kg)
(A) 2.05
(B) 2.63
(C) 3.11
(D) 0.381
10. How does the solubility of gas change in a liquid, as described?
(A) Increases with decreasing pressure
(B) Increases with increasing temperature
(C) Decreases with increasing temperature
(D) Decreases with increasing pressure
11. According to Raoult’s law, relative lowering of vapour pressure for a solution is equal to:
(A) Moles of solute
(B) Moles of solvent
(C) Mole fraction of solute
(D) Mole fraction of solvent
12. 1 mole of a non-volatile solid is dissolved in 200 moles of water. The solution in taken to a temperature 𝑇𝐾 (lower
than the freezing point of solution) to cause ice formation. After removal of ice, the remaining solution is taken to
373 𝐾 where vapour pressure is observed to be 740 𝑚𝑚 of 𝐻𝑔. Identify the correct option.
[Given data: 𝐾𝑓 (𝐻2 𝑂) = 2 𝐾 𝑘𝑔 𝑚𝑜𝑙 −1 and normal boiling point of 𝐻2 𝑂 = 373 𝐾.]
(A) 163 moles of ice will be formed.
2000
(B) 𝑇𝑘 = 373 − 37×18 𝐾.
10
(C) Freezing point of original solution should be − 18 ∘ 𝐶.
1
(D) Relative lowering of vapour pressure of final solution will be 201.
13. The statement "the relative lowering of the vapour pressure is equal to the ratio of moles of the solute to the total
number of the moles in the solution“ refers to:
(A) Henry's law
(B) Faraday's law
(C) Raoult’s law
(D) Kohlrausch's law
14. A solution containing 6 g urea per litre is isotonic with a solution containing;
(Molar mass of urea = 60, NaCl = 58.5, sucrose = 342, glucose = 180)
(A) 5.85 g NaCl per litre
(B) 34.2 g sucrose per litre
(C) 36.0 g glucose per litre
(D) 6.0 g sucrose per litre
15. The boiling point of C6H6, CH3OH, C6H5NH2 and C6H5NO2 are 80°C, 65°C, 184°C and 212°C respectively.
Which will show highest vapour pressure at room temperature?
(A) C6H6
(B) CH3OH
(C) C6H5NH2
(D) C6H5NO2
16. The freezing point depression constant for water is 1.86ºC m –1. If 5.00 g Na2SO4 is dissolved in 45.0 g H2O, the
freezing point is changed by 3.82ºC. Calculate the van't Hoff factor (i) for Na2SO4.
[The molality of the solution is 0.782 mol/kg]
(A) 2.05
(B) 2.63
(C) 3.11
(D) 0.381
17. Which of the following will form an ideal solution?
(A) 𝐶2 𝐻5 𝑂𝐻 and water
(B) 𝐻𝑁𝑂3 and water
(C) 𝐶𝐻𝐶𝑙3 and 𝐶𝐻3 𝐶𝑂𝐶𝐻3
(D) 𝐶6 𝐻6 and 𝐶6 𝐻5 𝐶𝐻3
18. 5 moles of liquid X and 10 moles of liquid Y make a solution having a total vapour pressure 70 torr. The vapour
pressures of pure X and pure Y are 60 torr and 90 torr respectively. Which of the following is true regarding the
described solution?
(A) The solution shows positive deviation
(B) The solution shows negative deviation
(C) The solution is ideal
(D) The solution has volume greater than the sum of individual volumes
19. When 10 g of a non-volatile solute dissolved in 100 g of benzene, it raises boiling point by 1°C then molar mass
of the solute is:
(Kb for benzene = 2.53 K m–1)
(A) 223 g/mol
(B) 233 g/mol
(C) 243 g/mol
(D) 253 g/mol
20. When 10 g of a non-volatile solute dissolved in 100 g of benzene, it raises boiling point by 1°C then molar mass
of the solute is:
–1
(Kb for benzene = 2.53 Km )
(A) 223 g/mol
(B) 233 g/mol
(C) 243 g/mol
(D) 253 g/mol
21. How many grams of 𝐶𝑂2 gas is dissolved in a 1 𝐿 bottle of carbonated water if the manufacturer uses a pressure
of 2.4 atmosphere in the bottling process at 25∘ 𝐶 Given 𝐾𝐻 of 𝐶𝑂2 water = 29.76 𝑎𝑡𝑚/𝑚𝑜𝑙𝑒/𝐿 at 25∘ 𝐶
(A) 3.52
(B) 4.2
(C) 3.1
(D) 2.5
22. Lead storage battery contains 38% by weight solution of 𝐻2 𝑆𝑂4 . The van't Hoff factor is 2.67 at this
concentration. The temperature in Kelvin at which the solution in the battery will freeze is
Given 𝐾𝑓 = 1.8 𝐾𝑘𝑔𝑚𝑜𝑙 −1
(A) 249 K
(B) 242 K
(C) 258 K
(D) 273 K
23. The vapour pressure lowering caused by the addition of 342 g of sucrose (molar mass is 342 g mol -1) to 522 g of
water if the vapour pressure of pure water at 25ºC is 23.8 mm of Hg is:
(A) 1.25 mm of Hg
(B) 0.8 mm of Hg
(C) 1.15 mm of Hg
(D) 0.012 mm of Hg
24. A living cell contains a solution which is isotonic with 0.2 𝑀 glucose solution. What osmotic pressure develops
when the cell is placed in 0.05 M 𝐵𝑎𝐶𝑙2 solution at 300 K?
(A) 1.23 𝑎𝑡𝑚
(B) 6.15 𝑎𝑡𝑚
(C) 3.69 𝑎𝑡𝑚
(D) None of these
25. The concentration of same aqueous solution of glucose is determined by two students-Sawan and Gautam. Sawan
reported the concentration as 20% (𝑤/𝑤) and Gautam reported the concentration as 25%(𝑤/𝑣). If both
concentrations are correct, then the density of the solution is
(A) 0.8 g/ml
(B) 1.0 g/ml
(C) 1.25 g/ml
(D) 1.33 g/ml
26. The molal elevation constant is the ratio of the elevation in boiling point to:
(A) molarity.
(B) molality.
(C) mole fraction of solute.
(D) mole fraction of solvent.
27. Which of the following gases has highest solubility in water at 298 K?
(A) A (KH = 40.3 k bar)
(B) B (KH = 1.67 k bar)
(C) C (KH = 1.83×10–5 k bar)
(D) D (KH = 145.2 k bar)
28. On mixing, heptane and octane form an ideal solution, At 373 𝐾, the vapour pressures of the two liquid
components (heptane and octane) are 105 kPa and 45 kPa respectively. Vapour pressure of the solution obtained
by mixing 25.0 𝑔 of heptane and 35 𝑔 of octane will be: (molar mass of heptane = 100 𝑔 𝑚𝑜𝑙 −1 and of octane
= 114 𝑔 𝑚𝑜𝑙 −1 )
(A) 96.2𝑘𝑃𝑎
(B) 144.5𝑘𝑃𝑎
(C) 72.0𝑘𝑃𝑎
(D) 36.1𝑘𝑃𝑎
29. For a binary ideal liquid solution, the total pressure of the solution is given as:
∘ ∘ ∘
(A) 𝑃total = 𝑃𝐴 + (𝑃𝐴 − 𝑃𝐵 )𝑋𝐵

∘ ∘ ∘
(B) 𝑃total = 𝑃𝐵 + (𝑃𝐴 − 𝑃𝐵 )𝑋𝐴
∘ ∘ ∘
(C) 𝑃total = 𝑃𝐵 + (𝑃𝐵 − 𝑃𝐴 )𝑋𝐴
∘ ∘ ∘
(D) 𝑃total = 𝑃𝐵 + (𝑃𝐵 − 𝑃𝐴 )𝑋𝐵
30. Elevation in boiling point was 0.52ºC when 6 g of a compound X was dissolved in 100 g of water. Molar mass of
X is:
–1
(Kb for water = 0.52 K kg mol )
(A) 120 g mol–1
(B) 60 g mol–1
(C) 90 g mol–1
(D) 30 g mol–1
31. How many moles and how many grams of NaCl are present in 250 mL of a 0.5 M NaCl solution?
(A) 0.125 mol; 7.31 g
(B) 7.31 mol; 0.125 g
(C) 0.125 mol; 0.125 g
(D) 7.31 mol; 7.31 g
32. Reverse osmosis is a process:
(A) in which applies pressure to the solution side is larger than the osmotic pressure.
(B) in which solvent moves from solution of higher concentration to solution of lower concentration
(C) which is used for desalination of sea water.
(D) All of these
33. A 40% HCl solution has density 1.2 g mL–1. The molarity of the solution is nearly:
(A) 11 M
(B) 12 M
(C) 13 M
(D) 14 M
34. 5 𝑚𝐿 of 𝑁 𝐻𝐶𝑙, 20 𝑚𝐿 of 𝑁/2 𝐻2 𝑆𝑂4 and 30 𝑚𝐿 of 𝑁/3 𝐻𝑁𝑂3 are mixed together and volume made to one
litre. The normality of the resulting solution is:
𝑁
(A) 5
𝑁
(B) 10
𝑁
(C)
20
𝑁
(D) 40
35. In one molal solution that contains 0.5 mole of a solute, there is
(A) 1000 𝑔 of solvent
(B) 500 𝑚𝐿 of solvent
(C) 500 𝑔 of solvent
(D) 100 𝑚𝐿 of solvent
36. A solution containing 10.2 g glycerine per litre is isotonic with a 2% (w/v) solution of glucose. Molecular mass of
glucose is 180 g/mol, then molecular mass of glycerine is:
(A) 9.18 g/mol
(B) 95 g/mol
(C) 91.8 g/mol
(D) 100 g/mol
37. At 80°C, the vapour pressure of pure liquid 'A' is 400 mm of Hg and that of pure liquid 'B' is 800 mm of Hg. If a
solution of 'A' and 'B' boils at 80°C and 1 atm pressure, then amount of 'A' in the mixture is: (Given: 1 atm = 760
mm of Hg)
(A) 52 mole percent.
(B) 34 mole percent.
(C) 10 mole percent.
(D) 48 mole percent.
38. The molal elevation constant depends upon
(A) nature of solute.
(B) nature of the solvent.
(C) vapour pressure of the solution.
(D) enthalpy change
39. In the phenomenon of osmosis through the semipermeable membrane:
(A) Solvent molecules pass from high concentrated to less concentrated solution.
(B) Solvent molecules pass from less concentrated to more concentrated solution.
(C) Solute molecules pass from high concentrated to less concentrated solution.
(D) Solute molecules pass from less concentrated to high concentrated solution.
40. If the various terms in the given below expressions have usual meanings, the van't Hoff factor (i) cannot be
calculated by which one of the following expressions?
(A) 𝜋𝑉 = √𝑖𝑛𝑅𝑇
(B) 𝛥𝑇𝑓 = 𝑖𝐾𝑓 ⋅ 𝑚
(C) 𝛥𝑇𝑏 = 𝑖𝐾𝑏 ⋅ 𝑚
∘
𝑃solvent −𝑃solution 𝑛
(D) ∘ = 𝑖( )
𝑃solvent 𝑁+𝑛
41. What is the number of moles in 650 mL of 98% (v/v) sulfuric acid solution if density of sulfuric acid is 1.83
g/mL?
(A) 63.7
(B) 11.9
(C) 6.5
(D) 11.66
42. What is molar concentration of Na+ in a solution obtained by mixing 50.0 mL of 0.100 mol/L NaNO3 (aq) and
25.0 mL of 0.100 mol/L Na2CO3(aq)?

(A) 0.133 𝑚𝑜𝑙 𝐿−1

(B) 0.200 𝑚𝑜𝑙𝐿−1
(C) 0.300 𝑚𝑜𝑙 𝐿−1
(D) 0.167 𝑚𝑜𝑙𝐿−1
43. If the solubility of a gas is 1.2 mmol/L at a pressure of 2 bar, what is the Henry’s law constant at the same
temperature?
(A) 0.6 mmol L–1 bar–1
(B) 1.67 mmol L–1 bar–1
(C) 3.33 mmol L–1 bar–1
(D) 5.0 mmol L–1 bar–1
44. The substance when dissolved in water would decrease the vapour pressure of water to the maximum extent is:
(A) 0.1 𝑀 𝐾𝐶𝑙
(B) 0.1 𝑀 urea
(C) 0.1 𝑀 𝐵𝑎𝐶𝑙2
(D) 0.1 𝑀 𝑁𝑎𝐶𝑙
45. KH value for Ar(g), CO2(g), HCHO (g) CH4(g)are 40.39, 1.67, 1.83 × 10–5 and 0.413 respectively.
Arrange these gases in the order of their increasing solubility.
(A) HCHO < CH4 < CO2 < Ar
(B) HCHO < CO2 < CH4 < Ar
(C) Ar < CO2 < CH4 < HCHO
(D) Ar < CH4 < CO2 < HCHO
46. The vapour pressure of a liquid in a closed container depends upon
(A) Amount of liquid
(B) Surface area of the container
(C) Temperature
(D) Volume of the container
47. According to Henry's law, the solubility of a gas in a given volume of liquid increases with increase in:
(A) Temperature
(B) Pressure
(C) Both (A) and (B)
(D) None of these
1. (B)
2. (B)
3. (C)
4. (D)
5. (C)
6. (B)
7. (B)
8. (C)
9. (B)
10. (C)
11. (C)
12. (A)
13. (C)
14. (B)
15. (B)
16. (B)
17. (D)
18. (B)
19. (D)
20. (D)
21. (A)
22. (B)
23. (B)
24. (A)
25. (C)
26. (B)
27. (C)
28. (C)
29. (B)
30. (B)
31. (A)
32. (D)
33. (C)
34. (D)
35. (C)
36. (C)
37. (C)
38. (B)
39. (B)
40. (A)
41. (B)
42. (A)
43. (A)
44. (C)
45. (C)
46. (C)
47. (B)