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Autumn break assignment
Class –XI
1. What is the number of significant figures in 0.00368 ?
2. If the density of methanol is 0.793 Kg L-1 , what is its volume needed for making 2.5 L of its 0.25 M solution ? 3. Define – Molarity , Molality ,Mole fraction ,Limiting reagent , Significant figure 4. What is S.I. unit of Luminous intensity ? 5. How many moles of methane are required to produce 22g of CO2 after combustion ? 6. Explain- i)Law of definite proportion ii)Avogadro Law iii)Mole 7. The density of 3M solution of NaCl is 1.25 g/ml . Calculate molality of the solution . 8. Calcium carbonate reacts with aqueous HCl to give CaCl2 and CO2 according to the reaction CaCO3 +2 HCl → CaCl2 +CO2 + H2O What mass of CaCO3 is required to react completely with 25 ml of 0.75 M HCl ? 9. Determine the molecular formula of an oxide of iron in which the mass percent of iron and oxygen are 69.9 and 30.1 respectively. 10. Calculate the radius of Bohr’s first orbit for hydrogen atom. 11. Calculate the wavelength of an electron moving with a velocity of 2.05×107m/s. 12. What are the limitations of Bohr’s model? 13. Explain- i)Aufbau Principal ii) Pauli Exclusion principal iii) Hund, s rule 14. What is the number of photons of light with a wavelength of 4000 pm that provide 1 Joule of energy? 15. How many electrons are present in all subshells with n+l = 5 ? 16. Write the electronic configuration of- i)Cu+ ii) Fe 3+ iii) Zn 2+ 17. What is the basic theme of organization in the periodic table? 18. What is the basic difference between the term electron gain enthalpy and electronegativity. 19. Write the general outer electronic configuration of s,p,d,f block elements. 20. In terms of period and group where would you locate the elements with Z=114? 21. Give reasons- I)Cations are smaller than parent atom ii)First ionization enthalpy of sodium is lower than that of Mg but its second ionization enthalpy is higher than that of Mg . iii) Electron gain enthalpy of fluorine is less negative as compared to that of chlorine . iv) Nitrogen has higher first ionization enthalpy as compared to oxygen . 22. Write the resonating structures of – CO2 ,NO2- , O3, CO32-. 23. Compare the relative stabilities of N2+ and O2 – and comment on their magnetic behavior . 24. Distinguish between sigma and pi bond . 25. Using VSEPR theory , explain the shapes of – i) NH3 II) H2O III)SF4 IV) ClF3 V)AsF5 VI) PCl5 vii) SF4 26. Write the important conditions required for the linear combination of atomic orbitals to form molecular orbital 27. What is meant by the term bond order ? Calculate the bond order of N2 ,O2 and Be2 . 28. Define – i)Enthalpy ii) Entropy iii) Gibbs energy iv) Closed system v) Intensive propertie vi) First law of Thermodynamics vii)Enthalpy of reaction . 29. Define Hess’s law of constant het summation.Calculate the standard enthalphy of formation of CS 2(l) from following data- CS2 +3O2 → CO2 +2SO2 ∆rH =-1108.76 KJ mol -1 C+O2 → CO2 ∆H =-393.3 KJ mol -1 S +O2 → SO2 ∆H= -293.72 KJ mol -1