General Science Chemistry For Railway Exams
General Science Chemistry For Railway Exams
2 Matter 10
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
Properties such as shape, size, colour and state of a substance are called its physical properties. A change in which a
substance undergoes a change in its physical properties is called a physical change. A physical change is generally
reversible. In such a change no new substance is formed.
CHEMICAL CHANGE
A change in which one or more new substances are formed is called a chemical change. A chemical change is also
called a chemical reaction
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
Rusting of iron
Metathesis
Digestion
Cooking an egg
Souring of milk
Rotting bananas
Exothermic reactions are reactions or processes that release energy, usually in the form of heat or light
Reactions in which energy is absorbed are known as endothermic reactions.
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
NOTE: Calcium hydroxide reacts slowly with the carbon dioxide in air to form a thin layer of calcium
carbonate on the walls. Calcium carbonate is formed after two to three days of whitewashing and gives a
shiny finish to the walls. It is interesting to note that the chemical formula for marble is also CaCO3.
2. DECOMPOSITION REACTION
Decomposition reactions are opposite to combination reactions. In a decomposition reaction, a single
substance decomposes to give two or more substances
In this reaction, you can observe that a single reactant breaks down to give simpler products. This is a
decomposition reaction.
3. DISPLACEMENT RECTION
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
It is a reaction between an element and a compound. When they react, one of the elements of the compound-
reactant is replaced by the element-reactant to form a new compound and an element.
Fe+ CuSO4 --> FeSO4 + Cu
In this reaction, iron has displaced or removed another element copper from copper sulphate solution. This
reaction is known as displacement reaction
Ant bite
When an ant bites, it injects the acidic liquid (formic acid) into the skin. The effect of the acid can be
neutralised by rubbing moist baking soda (sodium hydrogencarbonate) or calamine solution, which contains
zinc carbonate.
Soil treatment
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
Excessive use of chemical fertilisers makes the soil acidic. Plants do not grow well when the soil is either too
acidic or too basic. When the soil is too acidic, it is treated with bases like quick lime (calcium oxide) or
slaked lime (calcium hydroxide). If the soil is basic, organic matter (compost) is added to it. Organic matter
releases acids which neutralises the basic nature of the soil.
Factory wastes
The wastes of many factories contain acids. If they are allowed to flow into the water bodies, the acids will
kill fish and other organisms. The factory wastes are, therefore, neutralised by adding basic substances.
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
Oxidation Reduction
RANCIDITY
When oils and fats or foods containing oils and fats are exposed to air, they get oxidized due to which the
food becomes stale and gives a bad taste or smell. This is called Rancidity.
Following ways to preventing rancidity
Adding antioxidants
Refrigerating
Storing food in airtight containers with nitrogen gas
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
When carbon dioxide is passed through lime water, calcium carbonate is formed, which makes lime water
milky. The turning of lime water into milky is a standard test of carbon dioxide.
Carbon dioxide (CO2 ) + Lime water [Ca(OH)2 ] → Calcium Carbonate (CaCO3 ) + Water (H2O)
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
Glucose C6H12O6
CHEMICAL BONDING
Attraction between atoms, ions or molecules that enables the formation of chemical compounds is called
chemical bonding
TYPES OF CHEMICAL BONDING
1. Ionic bond
Chemical bond formed between two atoms due to transfer of electron from one atom to the other atom
2. Covalent bond
A covalent bond is a chemical bond that involves the sharing of electron between two atoms
3. Metallic bond
Metallic bond is the force of attraction between metal ions to a number of electrons within its sphere of
influence.
MATTER
Matter is made up of small particles
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
The matter around us exists in three states— solid, liquid and gas.
The forces of attraction between the particles are maximum in solids, intermediate in liquids and minimum in
gases
The spaces in between the constituent particles and kinetic energy of the particles are minimum in the case of
solids, intermediate in liquids and maximum in gases
Particles of matter are continuously moving, that is, they possess what we call the kinetic energy. As the
temperature rises, particles move faster. So, we can say that with increase in temperature the kinetic energy
of the particles also increases
The states of matter are inter-convertible. The state of matter can be changed by changing temperature or
pressure.
DIFFUSION
The mixing of a substance with another substance due to the motion of its particles is called diffusion. It is
one of the properties of material. The diffusion of one substance to another substance goes on until a uniform
mixture is formed. Diffusion takes place in gases, liquids and solids. Diffusion increases on increasing the
temperature of the diffusing substance.
STATES OF MATTER
Matter around us exists in three different states– solid, liquid and gas. These states of matter arise due to the
variation in the characteristics of the particles of matter
1. THE SOLID STATE
Solid have a definite shape, distinct boundaries and fixed volumes, that is, have negligible compressibility.
Solids have a tendency to maintain their shape when subjected to outside force. Solids may break under force
but it is difficult to change their shape, so they are rigid.
Liquids have no fixed shape but have a fixed volume. They take up the shape of the container in which they
are kept. Liquids flow and change shape, so they are not rigid but can be called fluid
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
We come to know of what is being cooked in the kitchen without even entering there, the smell of hot cooked
food reaches us in seconds because rate of diffusion of gas is higher than that of solids and liquids.
The melting point of a solid is an indication of the strength of the force of attraction between its particles.
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
The process of melting, that is, change of solid state into liquid state is also known as fusion.
Supply heat energy to water, particles start moving even faster. At a certain temperature, a point is reached when the
particles have enough energy to break free from the forces of attraction of each other. At this temperature the liquid
starts changing into gas. The temperature at which a liquid starts boiling at the atmospheric pressure is known as its
boiling point
State of matter can be changed into another state by changing the temperature
LATENT HEAT
The heat energy required to convert a solid into a liquid or vapour, or a liquid into a vapour, without change of
temperature known as latent heat
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
Evaporation
Evaporation is a surface phenomenon. Particles from the surface gain enough energy to overcome the forces
of attraction present in the liquid and change into the vapour state.
Rate of evaporation depends upon the surface area exposed to the atmosphere, the temperature, the humidity and the
wind speed.
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
Temperature Kelvin
Length Metre
Mass Kilogram
Weight Newton
Pressure Pascal
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
Now scientists are talking of five states of matter: Solid, Liquid, Gas, Plasma and BoseEinstein
Condensate.
Plasma: The state consists of super energetic and super excited particles. These particles are in the
form of ionised gases. The fluorescent tube and neon sign bulbs consist of plasma. Inside a neon
sign bulb there is neon gas and inside a fluorescent tube there is helium gas or some other gas. The
gas gets ionised, that is, gets charged when electrical energy flows through it. This charging up
creates a plasma glowing inside the tube or bulb. The plasma glows with a special colour depending
on the nature of gas. The Sun and the stars glow because of the presence of plasma in them. The
plasma is created in stars because of very high temperature.
Bose-Einstein Condensate: In 1920, Indian physicist Satyendra Nath Bose had done some
calculations for a fifth state of matter. Building on his calculations, Albert Einstein predicted a new
state of matter – the Bose-Einstein Condensate (BEC). In 2001, Eric A. Cornell, Wolfgang Ketterle
and Carl E. Wieman of USA received the Nobel prize in physics for achieving ―Bose-Einstein
condensation‖. The BEC is formed by cooling a gas of extremely low density, about one-hundred-
thousandth the density of normal air, to super low temperatures.
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
1. A mixture in which the components cannot be seen separately is called a homogeneous mixture.
2. It has a uniform composition and every part of the mixture has the same properties
3. Tap water, milk, air, ice cream, sugar syrup, ink, steel, bronze and salt solutions are homogeneous mixtures
Heterogeneous mixture
1. A mixture in which the components can be seen separately is called a heterogeneous mixture.
2. It does not have a uniform composition and properties.
3. Soil, a mixture of iodine and common salt, a mixture of sugar and sand, a mixture of oil and water, a mixture
of sulphur and iron filings and a mixture of milk and cereals are heterogeneous mixture.
SOLUTIONS
A solution is a homogeneous mixture of two or more substances. You come across various types of solutions
in your daily life. Lemonade, soda water etc.
Aerated drinks like soda water etc., are gas in liquid solutions. These contain carbon dioxide (gas) as solute
and water (liquid) as solvent.
We can also have solid solutions (alloys) and gaseous solutions (air)
The particles of a solution are smaller than 1 nm (10-9 metre) in diameter. So, they cannot be seen by naked
eyes
Because of very small particle size, they do not scatter a beam of light passing through the solution. So, the
path of light is not visible in a solution
The solute particles cannot be separated from the mixture by the process of filtration. The solute particles do
not settle down when left undisturbed, that is, a solution is stable.
A solution has a solvent and a solute as its components. The component of the solution that dissolves the
other component in it (usually the component present in larger amount) is called the solvent. The component
of the solution that is dissolved in the solvent (usually present in lesser quantity) is called the solute.
The concentration of a solution is the amount of solute present per unit volume or per unit mass of the
solution.
Alloys: Alloys are mixtures of two or more metals or a metal andanon-metal and cannot be separated into
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
their components by physical methods. But still, an alloy is considered as a mixture because it shows the
properties of its constituents and can have variable composition. For example, brass is a mixture of
approximately 30% zinc and 70% copper.
SUSPENSION
Materials that are insoluble in a solvent and have particles that are visible to naked eyes , form a suspension.
A suspension is a heterogeneous mixture.
The particles of a suspension scatter a beam of light passing through it and make its path visible.
The particles of a suspension can be seen by the naked eye.
COLLOIDS
A colloid is a heterogeneous mixture.
The size of particles of a colloid is too small to be individually seen by naked eyes.
Colloids are big enough to scatter a beam of light passing through it and make its path visible.
Tyndall effect can also be observed when a fine beam of light enters a room through a small hole.
This happens due to the scattering of light by the particles of dust and smoke in the air
EXAMPLES OF COLLOIDS
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
Separation of components of a mixture containing two miscible liquids that boil without decomposition and
have sufficient difference in their boiling points this method is called distillation
Applications:
1. Salt water turned to fresh water using distillation process
The crystallization method is used to purify solids. Crystallisation is a process that separates a pure solid in
the form of its crystals from a solution.
Applications:
1. Purification of salt that we get from sea water.
2. Separation of crystals of alum from impure samples.
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
Has the same uniform appearance and Has different non uniform appearance and
composition composition
Examples: Air, saline solution and Example: Sand, oil and water
bitumen
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
ATOMS
An atom is the smallest particle of an element that can take part in a chemical reaction
Atomic radius is measured in nanometers.
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
1/109 m = 1 nm
1 m = 109 nm
Hydrogen atom is smallest atom of all. Atomic radius of hydrogen atom is
0.037 x 10-9
Radii Example
10–3 Ant
10–1 Apple
Atoms of most elements are not able to exist independently. Atoms form molecules and ions. These molecules
or ions aggregate in large numbers to form the matter that we can see, feel or touch.
ATOMIC MASS
The most remarkable concept that Dalton‘s atomic theory proposed was that of the atomic mass. According to
him, each element had a characteristic atomic mass.
Atomic mass is defined as the mass of a single atom of a chemical element
One atomic mass unit is a mass unit equal to exactly one-twelfth (1/12th) the mass of one atom of carbon-12.
The relative atomic masses of all elements have been found with respect to an atom of carbon-12
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
Hydrogen 1
Carbon 12
Nitrogen 14
Oxygen 16
Sodium 23
Magnesium 24
Sulphur 32
Chlorine 35.5
Calcium 40
Avogadro constant
The Avogadro constant 6.022 × 1023 is defined as the number of atoms in exactly 12 g of carbon-12.
MOLECULE
A molecule is in general a group of two or more atoms that are chemically bonded together, that is, tightly
held together by attractive forces. A molecule can be defined as the smallest particle of an element or a
compound that is capable of an independent existence and shows all the properties of that substance. Atoms of
the same element or of different elements can join together to form molecules.
MOLECULES OF ELEMENTS
The molecules of an element are constituted by the same type of atoms. Molecules of many elements, such as
argon (Ar), helium (He) etc. are made up of only one atom of that element. But this is not the case with most
of the nonmetals. For example, a molecule of oxygen consists of two atoms of oxygen and hence it is known
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
as a diatomic molecule, O2 . If 3 atoms of oxygen unite into a molecule, instead of the usual 2, we get ozone,
O3 . The number of atoms constituting a molecule is known as its atomicity.
Atomicity of some elements
Argon Monoatomic
Helium Monoatomic
Oxygen Diatomic
Hydrogen Diatomic
Nitrogen Diatomic
Chlorine Diatomic
Phosphorus Tetra-atomic
Sulphur Poly-atomic
MOLECULES OF COMPOUNDS
Atoms of different elements join together in definite proportions to form molecules of compounds
Molecules of some compounds
Compound Ratio by Mass
ION
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
Compounds composed of metals and nonmetals contain charged species. The charged species are known as
ions. Ions may consist of a single charged atom or a group of atoms that have a net charge on them.
An ion can be negatively or positively charged. A negatively charged ion is called an ‗anion‘ and the
positively charged ion, a ‗cation‘. Take, for example, sodium chloride (NaCl). Its constituent particles are
positively charged sodium ions (Na+ ) and negatively charged chloride ions (Cl–).
MOLECULAR MASS
The molecular mass of a substance is the sum of the atomic masses of all the atoms in a molecule of the
substance. It is therefore the relative mass of a molecule expressed in atomic mass units (u).
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
E. Rutherford (1871-1937) was born at Spring Grove on 30 August 1871. He was known as the ‗Father‘ of
nuclear physics. He is famous for his work on radioactivity and the discovery of the nucleus of an atom with
the gold foil experiment. He got the Nobel prize in chemistry in 1908.
(i) The Theory of Spectra and Atomic Constitution, (ii) Atomic Theory and, (iii) The Description of Nature.
NEUTRONS
J. Chadwick discovered the neutron
Neutrons are present in the nucleus of all atoms, except hydrogen
Mass of an atom equal to sum of the masses of protons and neutrons present in the nucleus
ELECTRONS DISTRIBUTED IN DIFFERENT ORBITS (SHELLS)
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
Distribution of electrons into different orbits of an atom was suggested by Bohr and Bury.
Maximum number of electrons present in a shell is given by the formula 2n2
Where n=1,2,3,4,….
These orbits or shells are represented by the letters K,L,M,N,…
The maximum number of electrons that can be accommodated in the outermost orbit is 8.
Electrons are not accommodated in a given shell, unless the inner shells are filled. That is, the shells are filled
in a step-wise manner.
VALENCE ELECTRONS
Electrons present in the outermost shell of an atom are known as the valence electrons
The elements with same number of electrons in the valence shell show similar properties and those with
different number of valence electrons show different chemical properties
Elements, which have 1 or 2 or 3 valence electrons (except Hydrogen), are metals.
Elements with 4 to 7 electrons in their valence shell are non-metals.
VALANCY
Valency of an element is the combining capacity of the element with other elements and is equal to the
number of electrons that take part in a chemical reaction
Valency of the elements having valence electrons 1, 2, 3, 4 is 1, 2, 3, 4 respectively
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
Valency of an element with 5, 6 and 7 valence electrons is 3, 2 and 1 (8–valence electrons) respectively.
Because 8 is the number of electrons required by an element to attain stable electronic configuration
Elements having completely filled outermost shell show Zero valency
ATOMIC NUMBER
Atomic number of an element is the same as the number of protons in the nucleus of its atom.
MASS NUMBER
Mass number of an atom is equal to the number of protons and neutrons in a nucleus
ISOTOPES
Two or more forms of an element having the same atomic number, but different mass number are called
Isotopes (17Cl35, 17Cl37).
Many elements consist of a mixture of isotopes. Each isotope of an element is a pure substance. The chemical
properties of isotopes are similar but their physical properties are different.
Applications
1. An isotope of uranium is used as a fuel in nuclear reactors.
2. An isotope of cobalt is used in the treatment of cancer.
3. An isotope of iodine is used in the treatment of goitre.
Isotopes of Hydrogen
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
ISOBARS
Atoms of different elements having the same mass number, but different atomic numbers are called Isobars
(18Ar40, 20Ca40).
ISOTONES
Atoms of different elements having the same number of neutrons, but different atomic number and different
mass number are called Isotones ( 6C13, 7N14 ).
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
COVALENT BOND
Carbon always have a covalent bond
The bond formed by sharing of electrons between two atoms are known as covalent bond
The boiling and melting points of the carbon compounds is low
Most carbon compounds are poor conductors of electricity because they form covalent bond so it does not
give rise to free electrons. All electrons are used in making the covalent bond
Graphite is a good conductor of heat and electricity because it has free electrons
Melting & boiling points compounds of carbon
Compound Formula Melting point (K) Boiling point (K)
Allotropes of carbon
Allotropy is a property by which an element can exist in more than one form that are physically different and
chemically similar. The different forms of that element are called its allotropes
The element carbon occurs in different forms in nature with widely varying physical properties. Both diamond
and graphite are formed by carbon atoms, the difference lies in the manner in which the carbon atoms are
bonded to one another
Carbon exists in different allotropic forms and based on their physical nature they are classified as below.
Crystalline forms of Carbon
1. Diamond
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
2. Graphite
3. Fullerene
Amorphous forms of carbon
1. Charcoal
2. coke
3. Lamp black
4. Gas carbon
SOME FUCTIONAL GROUPS OF CARBON COMPOUNDS
Hetero atom Class of compounds Formula of functional group
2. Aldehyde
3. Ketone
4. Carboxylic acid
1 Methane CH4
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
2 Ethane C2H6
3 Propane C3H8
4 Butane C4H10
5 Pentane C5H12
6 Hexane C6H14
7 Heptane C7H16
8 Octane C8H18
9 Nonane C9H20
10 Decane C10H22
ETHANOL
Ethanol is commonly known as alcohol. All alcoholic beverages and some cough syrups contain ethanol. Its
molecular formula is C2H5OH
Ethanol and ethanoic acid are carbon compounds of importance in our daily lives
Ethanol is a liquid at room temperature. Ethanol is commonly called alcohol and is the active ingredient of all
alcoholic drinks
Ethanol is a colourless liquid, having a pleasant smell and a burning taste.
Ethanol is used as an anti-freeze in automobile radiators
Ethanol is used in medical wipes, as an antiseptic
Ethanol is a good solvent, it is also used in medicines such as tincture iodine, cough syrups, and many tonics
Ethanol is used for effectively killing microorganisms like bacteria, fungi, etc., by including it in many hand
sanitizers.
Sugarcane plants are one of the most efficient convertors of sunlight into chemical energy. Sugarcane juice
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
can be used to prepare molasses which is fermented to give alcohol (ethanol). Some countries now use alcohol
as an additive in petrol since it is a cleaner fuel which gives rise to only carbon dioxide and water on burning
in sufficient air (oxygen).
ETHANOIC ACID
Ethanoic acid or acetic acid is one of the most important members of the carboxylic acid family. Its molecular
formula is C2H4O2.
Ethanoic acid is commonly called acetic acid and belongs to a group of acids called carboxylic acids
5-8% solution of acetic acid in water is called vinegar and is used widely as a preservative in pickles.
Ethanoic acid is used in printing on fabrics
The melting point of pure ethanoic acid is 290k and hence it often freezes during winter. They look like
glaciers, so it is called glacial acetic acid
SOAPS & DETERGENTS
Soap is a sodium or potassium salt of long chain carboxylic acid
Soap is effective only in soft water
Detergent is ammonium or sulphonate salt of long chain of carboxylic acid
Detergent are effective both soft and hard water
ORGANIC COMPOUNDS IN DAILY LIFE
Organic compounds are inseparable in human life
Various classes of organic compounds and their uses in our daily life as follows:
Hydrocarbons
1. Fuels like LPG, Petrol, Kerosene.
2. Raw materials for various important synthetic materials.
3. Polymeric materials like tyre, plastic containers.
Alcohols
1. As a solvent and an antiseptic agent.
2. Raw materials for various important synthetic materials.
Aldehydes
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
1. Formaldehyde as a disinfectant.
2. Raw materials for synthetic materials.
Ketones
1. As a solvent.
2. Stain Remover.
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
He started with the element having the lowest atomic mass (hydrogen) and ended at thorium which was the
56th element. He found that every eighth element had properties similar to that of the first. This arrangement
was known as 'law of octaves'
Law of Octaves was applicable only upto calcium, as after calcium every eighth element did not possess
properties similar to that of the first.
Newlands‘ Law of Octaves worked well with lighter elements only
Newlands‘ table was restricted to only 56 elements and did not leave any room for new elements
Mendeleev periodic table
At the time of Mendeleev started his work, 63 elements were known. He examined the relationship between
the atomic masses of the elements and their physical and chemical properties
He observed that most of the elements got a place in a Periodic Table and were arranged in the order of their
increasing atomic masses
Mendeleev‘s Periodic Table contains vertical columns called ‗groups‘ and horizontal rows called ‗periods‘
It has eight vertical columns called ‗groups‘ and seven horizontal rows called ‗period‘.
Limitations
The increasing order of atomic mass was not strictly followed throughout.
Eg. Co & Ni, Te & I.
No place for isotopes in the periodic table
No proper position could be given to the element hydrogen. Non-metallic hydrogen was placed along with
metals like lithium (Li), sodium (Na) and potassium (K).
Modern Periodic Table
Elements are arranged in order of increasing atomic number
Modern Periodic Law can be stated as follows ―The chemical and physical properties of the elements are the
periodic functions of their atomic numbers‖. Based on the modern periodic law, the modern periodic table is
derived
Modern Periodic Table has 18 vertical columns known as groups and 7 horizontal rows known as ‗periods‘.
Elements present in any one group have the same number of valence electrons
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
The valence of an element is determined by the number of valence electrons present in the outermost shell of
its atom
Metals are found on the left-hand side of the Periodic Table
Non-metals are found on the right-hand side of the Periodic Table
Modern Periodic Table, a zig-zag line separates metals from non-metals. The borderline elements boron,
silicon, germanium, arsenic, antimony, tellurium and polonium are intermediate in properties and are called
metalloids
Halogens are located on the 17th group on the periodic table
Noble gases are located on the 18th group on the periodic table
Based on the physical and chemical properties of elements, they are grouped into various families.
Groups in modern periodic table
Group 1 Alkali metals
Group 17 Halogens
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
30 Zn Zinc
31 Ga Gallium
32 Ge Germanium
33 As Arsenic
34 Se Selenium
35 Br Bromine
36 Kr Krypton
37 Rb Rubidium
38 Sr Strontium
39 Y Yttrium
40 Zr Zirconium
41 Nb Niobium
42 Mo Molybdenum
43 Tc Technetium
44 Ru Ruthenium
45 Rh Rhodium
46 Pd Palladium
47 Ag Silver
48 Cd Cadmium
49 In Indium
50 Sn Tin
51 Sb Antimony
52 Te Tellurium
53 I Iodine
54 Xe Xenon
55 Cs Cesium
56 Ba Barium
57 La Lanthanum
58 Ce Cerium
59 Pr Praseodymium
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60 Nd Neodymium
61 Pm Promethium
62 Sm Samarium
63 Eu Europium
64 Gd Gadolinium
65 Tb Terbium
66 Dy Dysprosium
67 Ho Holmium
68 Er Erbium
69 Tm Thulium
70 Yb Ytterbium
71 Lu Lutetium
72 Hf Hafnium
73 Ta Tantalum
74 W Tungsten
75 Re Rhenium
76 Os Osmium
77 Ir Iridium
78 Pt Platinum
79 Au Gold
80 Hg Mercury
81 Tl Thallium
82 Pb Lead
83 Bi Bismuth
84 Po Polonium
85 At Astatine
86 Rn Radon
87 Fr Francium
88 Ra Radium
89 Ac Actinium
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
90 Th Thorium
91 Pa Protactinium
92 U Uranium
93 Np Neptunium
94 Pu Plutonium
95 Am Americium
96 Cm Curium
97 Bk Berkelium
98 Cf Californium
99 Es Einsteinium
100 Fm Fermium
101 Md Mendelevium
102 No Nobelium
103 Lr Lawrencium
104 Rf Rutherfordium
105 Db Dubnium
106 Sg Seaborgium
107 Bh Bohrium
108 Hs Hassium
109 Mt Meitnerium
110 Ds Darmstadtium
111 Rg Roentgenium
112 Cn Copernicium
113 Nh Nihonium
114 Fl Flerovium
115 Mc Moscovium
116 Lv Livermorium
117 Ts Tennessine
118 Og Oganesson
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
Inexhaustible Natural Resources: These resources are present in unlimited quantity in nature and are not
likely to be exhausted by human activities. Examples are: sunlight, air.
Exhaustible Natural Resources: The amount of these resources in nature is limited. They can be exhausted
by human activities. Examples of these resources are forests, wildlife, minerals, coal, petroleum, natural gas
etc.
COAL
It is as hard as stone and is black in colour
Coal is processed in industry get some useful products such as coke, coal tar and coal gas
Coke is a tough, porous and black substance. It is an almost pure form of carbon. Coke is used in the
manufacture of steel and in the extraction of many metals.
Coal Tar is a black, thick liquid with an unpleasant smell. Products obtained from coal tar are used as starting
materials for manufacturing various substances used in everyday life and in industry, like synthetic dyes,
drugs, explosives, perfumes, plastics, paints, photographic materials, Roofing materials.
Coal gas is obtained during the processing of coal to get coke
Different types of coals are peat, lignite, bituminous, and anthracite
Anthracite is one of variety of coal contains the highest percentage of carbon
Lignite coal is called brown coal, is the lowest grade coal with the least concentration of carbon
Petroleum and Natural Gas
Petrol and diesel are obtained from a natural resource called petroleum. Petroleum is a mixture of
Hydrocarbon
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Petroleum is a dark oily liquid. It has an unpleasant odour. It is a mixture of various constituents such as
petroleum gas, petrol, diesel, lubricating oil, paraffin wax, etc.
The process of separating the various constituents/ fractions of petroleum is known as refining
Petroleum was formed from organisms living in the sea. As these organisms died, their bodies settled at the
bottom of the sea and got covered with layers of sand and clay. Over millions of years, absence of air, high
temperature and high pressure transformed the dead organisms into petroleum and natural gas.
Natural gas is a very important fossil fuel because it is easy to transport through pipes.
Natural gas is stored under high pressure as compressed natural gas (CNG). CNG is used for power
generation. It is a cleaner fuel.
Many useful substances are obtained from petroleum and natural gas. These are termed as ‗Petrochemicals‘.
These are used in the manufacture of detergents, fibres (polyester, nylon, acrylic etc.), polythene and other
man-made plastics. Hydrogen gas obtained from natural gas, is used in the production of fertilisers (urea).
Due to its great commercial importance, petroleum is also called ‗black gold‘.
The world‘s first oil well was drilled in Pennsylvania, USA, in 1859. Eight years later, in 1867, oil was
struck at Makum in Assam. In India, oil is found in Assam, Gujarat, Mumbai High and in the river basins of
Godavari and Krishna.
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
Some metals do not react with acid and liberate hydrogen gas. Example: Ag, Cu.
When an acid reacts with a metal carbonate or metal hydrogen carbonate, it gives the corresponding salt, carbon
dioxide gas and water
Na2 CO3 + 2HCl → 2NaCl + H2 O + CO2
NaHCO3 + HCl → NaCl + H2 O + CO2
Acidic solutions in water conduct electricity because they produce hydrogen ions
Acid is a molecule or ion which is capable of donating proton
An acid is a substance which can accept the electron
Some naturally occurring acids
Note
The atmosphere of Venus is made up of thick white and yellowish clouds of sulphuric acid
The accidental touch of Nettle leaves creates a pain and burning sensation, which is due to inject of Methanoic
acid into the skin of the person
BASE
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
A scale for measuring hydrogen ion concentration in a solution is called pH scale. The ‗p‘ in pH stands for
‗potenz‘ in German meaning power. pH scale is a set of numbers from 0 to 14 which is used to indicate
whether a solution is acidic, basic or neutral
The pH of a neutral solution is 7. Values less than 7 on the pH scale represent an acidic solution. As the pH
value increases from 7 to 14, it represents an increase in OH– ion concentration in the solution, that is,
increase in the strength of alkali
1 Acids have pH less than 7
2 Bases have pH greater than 7
3 A neutral solution has pH equal to 7
Strength of acids and bases depends upon the number of H+ ions and OH– ions produced, respectively. If we
take hydrochloric acid and acetic acid of the same concentration, say one molar, then these produce different
amounts of hydrogen ions. Acids that give rise to more H+ ions are said to be strong acids, and acids that give
less H+ ions are said to be weak acids.
Substances pH values
Human blood 7.35-7.45
Pure water 7
Lemon juice 2.2
Gastric juice 1.2
Milk of magnesia 10
Human urine 6
Beers 4.5
Wines 2.8-3.8
Black coffee 5.2
Milk 6.5 – 6.7
Normal rain 5.6 - 6
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
USES OF ACIDS „
Sulphuric acid is called King of Chemicals because it is used in the preparation of many other compounds.
It is used in car batteries also.
Hydrochloric acid is used as a cleansing agent in toilets.
Carbonic acid is used in aerated drinks. „
Tartaric acid is a constituent of baking powder
Citric acid is used in the preparation of effervescent salts and as a food preservative. „
Nitric acid is used in the manufacture of fertilizers, dyes, paints and drugs. „
Oxalic acid is used to clean iron and manganese deposits from quartz crystals. It is also used as bleach for
wood and removing black stains. „
USES OF BASES
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
SALTS
Salt is the product of reaction between acids and bases.
Salts of a strong acid and a strong base are neutral with pH value of 7. On the other hand, salts of a strong acid
and weak base are acidic with pH value less than 7 and those of a strong base and weak acid are basic in
nature, with pH value more than 7.
Most of the salts are soluble in water. For example, chloride salts of potassium and sodium are soluble in
water. But, silver chloride is insoluble in water
Salt is hygroscopic in nature.
USES OF SALTS
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
Baking soda is also an ingredient in antacids. Being alkaline, it neutralizes excess acid in the stomach and
provides relief.
It is also used in soda-acid fire extinguishers
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
Metals react with acids and produce metal salts and hydrogen gas. Generally, non-metals do not react with
acids.
Some metals react with bases to produce hydrogen gas.
METALS
Metals, in their pure state, have a shining surface. This property is Called metallic lustre.
The property of metals by which they can be beaten into thin sheets is called malleability.
Metals can be beaten into thin sheets. This property is called malleability. Gold and silver are most
malleability metal.
Ability of metals to be drawn into thin wires is called ductility. Gold is the most ductile metal. You will be
surprised to know that a wire of about 2 km length can be drawn from one gram of gold.
Metals are good conductors of heat and have high melting points. The best conductors of heat are silver and
copper. Lead and mercury are comparatively poor conductors of heats
Metals are good conductors of electricity. The best conductors of electricity is silver
Since metals produce ringing sounds, they are said to be sonorous. The materials other than metals are not
sonorous.
When an acid reacts with a metal, hydrogen gas is evolved and a corresponding salt is formed
Acid + Metal → Salt + Hydrogen gas
All metals except mercury exist as solids at room temperature
Gallium and cesium have very low melting points. These two metals will melt if you keep them on your
palm
Alkali metals (lithium, sodium, potassium) are so soft that they can be cut with a knife. They have low
densities and low melting points
Concentrated Acid: It has relatively large amount of acid dissolved in a solvent.
Dilute Acid: It has relatively smaller amount of acid dissolved in solvent.
Almost all metals combine with oxygen to form metal oxides.
Metal + Oxygen → Metal oxide
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
All metals do not react with oxygen at the same rate. Different metals show different relativities towards
oxygen. Metals such as potassium and sodium react so vigorously.
Metals such as potassium and sodium react so vigorously that they catch fire if kept in the open. Hence, to
protect them and to prevent accidental fires, they are kept immersed in kerosene oil.
Anodising is a process of forming a thick oxide layer of aluminium. Aluminium develops a thin oxide layer
when exposed to air. This aluminium oxide coat makes it resistant to further corrosion. The resistance can be
improved further by making the oxide layer thicker.
Silver and gold do not react with oxygen even at high temperatures
When a copper vessel is exposed to moist air for long, it acquires a dull green coating. The green material is
a mixture of copper hydroxide (Cu(OH)2 ) and copper carbonate (CuCO3 ).
2Cu+H2O+CO2 +O2→Cu (OH)2 + CuCO3
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
Metals such as lead, copper, silver and gold do not react with water at all
When Metals react with Acids?
Metals react with acids to give a salt and hydrogen gas.
Metal + Acid → Salt + Hydrogen
Hydrogen gas is not evolved when a metal reacts with nitric acid. It is because HNO3 is a strong oxidising
agent. It oxidises the H2 produced to water and itself gets reduced to any of the nitrogen oxides (N2O, NO,
NO2 ). But magnesium (Mg) and manganese (Mn) react with very dilute HNO3 to evolve H2 gas.
Aqua regia is a freshly prepared mixture of concentrated hydrochloric acid and concentrated nitric acid in
the ratio of 3:1. Aqua regia is a highly corrosive, fuming liquid. It is one of the few reagents that is able to
dissolve gold and platinum. It is used for cleaning and refining gold.
Symbol Metal
Sk Potassium
Na Sodium
Ca Calcium
Mg Magnesium
Al Aluminum
Zn Zinc
Fe Iron
Pb Lead
H Hydrogen
Cu Copper
Hg Mercury
Ag Silver
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
Au Gold
Sodium Trona
Borax
Common salt
Aluminum Bauxite
Potassium Nitrate
Carnalite
Magnesium Magnesite
Dolomite
Epsom salt
Mercury Cinnabar
Tin Cassiterite
Lead Galena
Gold Calaverite
Silvenites
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Calcium Dolomite
Gypsum
Fluorspar
Asbestos
Iron Haemethite
Magnetite
Bismuth Bismuthate
Refining of Metals
The most widely used method for refining impure metals is electrolytic refining.
Many metals, such as copper, zinc,tin, nickel, silver, gold, etc., are refined electrolytically.
NON-METALS
Examples of non-metals are carbon, sulphur, iodine, oxygen, hydrogen, etc.
Non-metals are either solids or gases except bromine which is a liquid at room temperature
Iodine is a non-metal but it is lustrous
Carbon is a non-metal that can exist in different forms. Each form is called an allotrope.
Diamond, an allotrope of carbon, is the hardest natural substance known and has a very high melting and
boiling point.Graphite, another allotrope of carbon, is a conductor of electricity
Non-metals produce acidic oxides when dissolve in water
CORROSION
When a metal is attacked by substances around it such as moisture, acids, etc., it is said to corrode and this
process is called corrosion. The black coating on silver and the green coating on copper are other examples
of corrosion
PREVENTION OF CORROSION
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Rusting of iron can be prevented by painting, oiling, greasing, galvanizing , chrome plating, anodizing or
making alloys
Galvanization is a method of protecting steel and iron from rusting by coating them with a thin layer of zinc.
Stainless steel is made by mixing iron with carbon and metals like chromium, nickel and manganese.
It does not rust.
ALLOYING
Alloying is a very good method of improving the properties of a metal.
Alloy is a homogeneous mixture of two or more metals, or a metal and a Non-metal.
Iron is the most widely used metal. But it is never used in its pure state. This is because pure iron is very soft
and stretches easily when hot. But, if it is mixed with a small amount of carbon, it becomes hard and strong.
When iron is mixed with nickel and chromium, we get stainless steel, which is hard and does not rust.
Pure gold, known as 24 carat gold, is very soft. It is, therefore, not suitable for making jewellery. It is alloyed
with either silver or copper to make it hard. Generally, in India, 22 carat gold is used for making ornaments. It
means that 22 parts of pure gold is alloyed with 2 parts of either copper or silver.
IMPORTANT ALLOYS
Alloy Combinations
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Some alloys have lower melting point than pure metals (Example: Solder is an alloy of lead and tin which has
lower melting point than each of the metals).
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THE COMPLETE General Science Notes (Chemistry) for Railway Exams
The lowest temperature at which a substance catches fire is called its ignition temperature.
The substances which have very low ignition temperature and can easily catch fire with a flame are called
inflammable substances. Examples of inflammable substances are petrol, alcohol, Liquified Petroleum Gas
(LPG) etc.
The most common fire extinguisher is water. But water works only when things like wood and paper
are on fire. If electrical equipment is on fire, water may conduct electricity and harm those trying to
douse the fire. Water is also not suitable for fires involving oil and petrol.
For fires involving electrical equipment and inflammable materials like petrol, carbon dioxide (CO2 )
is the best extinguisher. CO2 , being heavier than oxygen, covers the fire like a blanket. Since the
contact between the fuel and oxygen is cut off, the fire is controlled. The added advantage of CO2 is
that in most cases it does not harm the electrical equipment
Unburnt carbon particles in air are dangerous pollutants causing respiratory problems.
Incomplete combustion of a fuel gives poisonous carbon monoxide gas. It is a very poisonous gas. It is
dangerous to burn coal in a closed room. The carbon monoxide gas produced can kill persons sleeping
in that room.
Combustion of most fuels releases carbon dioxide in the environment. Increased concentration of
carbon dioxide in the air is believed to cause global warming.
Global warming is the rise in temperature of the atmosphere of the earth. This results, among
other things, in the melting of polar glaciers, which leads to a rise in the sea level, causing
floods in the coastal areas. Low lying coastal areas may even be permanently submerged under
water.
Burning of coal and diesel releases sulphur dioxide gas. It is an extremely suffocating and corrosive
gas. Moreover, petrol engines give off gaseous oxides of nitrogen. Oxides of sulphur and nitrogen
dissolve in rain water and form acids. Such rain is called acid rain. It is very harmful for crops,
buildings and soil.
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