Practice Sheet

for
CAREER FOUNDATION
Academic Session : 2023-24
TIM BATCH STOICHIOMETRY CHEMISTRY

Level -1
1. 1.80 g of a certain metal burnt in oxygen gave 3.0 g of its oxide. 1.50 g of the same metal heated
in O2 gave 2.50 g of its oxide. Show that these results illustrate the law of constant proportion.

2. The charge on 1 gm–ions of Al3+ is : (NA = Avogadro number, e = charge on one electron)
1 1 1
(A) N e coulomb (B) × NAe coulomb (C) × NAe coulomb (D) 3 × NAe coulomb
27 A 3 9

3. 5.325g sample of methyl benzoate, a compound used in the manufacture of perfumes is found to
contain 3.758 g of carbon, 0.316g hydrogen and 1.251g of oxygen. What is empirical formulae, of
compound. If mol. weight of methyl benzoate is 136.0, calculate its molecular formula.

4. What is the V.D. of SO2 with respect to CH4

5. How much marble of 90.5 % purity would be required to prepare 10 litres of CO 2 at STP when
the marble is acted upon by dilute HCl ?

6. 10 ml of liquid carbon disulphide (sp. gravity 2.63) is burnt in oxygen. Find the volume of the
resulting gases measured at STP.

7. In a gravimetric determination of P of an aqueous solution of dihydrogen phosphate in

H2PO–4 is treated with a mixture of ammonium and magnesium ions to precipitate magnesium
ammonium phosphate, Mg(NH4)PO4.6H2O. This is heated and decomposed to magnesium
pyrophosphate, Mg2P2O7. A solution of H2PO–4 yielded 2.054 g of (Mg2P2O7) which is weighed.
What weight of NaH2PO4 was present originally?

8. When 100 g of ethylene polymerises entirely to polyethene, the weight of polyethene formed as per
the equation nCH2 = CH2  (CH2 – CH2)n is :
(A) (n/2)g (B) 100g (C) (100/n)g (D) 100n g

9. A mixture of KBr, NaBr weighing 0.56 g was treated with aqueous solution of Ag + and the bromide
ion was recovered as 0.97 g of pure AgBr. What was the weight of KBr in the sample ?

10. The reaction

2C + O2  2CO is carried out by taking 24 g of carbon and 128 g of O2.
Find out :
(i) Which reactant is left in excess ?
(ii) How much of it is left ?
(iii) How many moles of CO are formed ?
(iv) How many grams of other reactant should be taken so that nothing is left at the end of
reaction?

11. A solid mixture weighing 5.00 g containing lead nitrate and sodium nitrate was heated below
600°C until the mass of the residue was constant. If the loss of mass is 30 %, find the mass of lead
nitrate and sodium nitrate in mixture. (At. wt. of Pb = 207, Na = 23, N = 14, O = 16)
Given : 2Pb(NO3)2(s) 

 2PbO(s) + 4NO2(g) + O2(g) and
2NaNO3(s) 

 2NaNO2(s) + O2(g)
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12. A sample of 3 g containing Na2CO3 and NaHCO3 loses 0.248 g when heated to 300°C, the
temperature at which NaHCO3 decomposes to Na2CO3, CO2 and H2O. What is the percentage
of Na2CO3 in the given mixture ?

2NaHCO3 (s)   Na 2CO3 (s)  CO2 (g)  H2O(g)

13. NX is produced by the following step of reactions

M + X2  M X2
3MX2 + X2  M3X8
M3 X8 + N2CO3  NX + CO2 + M3O4
How much M (metal) is consumed to produce 206 gm of NX. (Take at wt of M = 56, N=23, X =
80)
14 7
(A) 42 gm (B) 56 gm (C) gm (D) gm
3 4

14. An ore contains 1.34% of the mineral argentite, Ag 2S, by weight. How many grams of this ore
would have to be processed in order to obtain 1.00g of pure silver. (Ag) -
(A) 74.6g (B) 85.7g (C) 107.9g (D) 134.0g

15. Calculate the percent of BaO in 29.0 g of a mixture of BaO and CaO which just reacts with 100.8
mL of 6.00 M HCl.
BaO + 2HCl BaCl2 + H2O
CaO + 2HCl CaCl2 + H2O

16. Calculate the amount of 95% pure Na2CO3 required to prepare 5 litre of 0.5 M solution.

Level -2

1. A certain compound has the molecular formula X4O6. If 10 g of X4O6 has 5.72 g of X, atomic mass
of X is

2. The incorrect statement(s) regarding 2M MgCl2 aqueous solution is/are (dsolution = 1.09 gm/ml)
(A) Molality of Cl¯ is 4.44 m (B) Mole fraction of MgCl2 is exactly 0.035
(C) The conc. of MgCl2 is 19% w/v (D) The conc. of MgCl2 is 19 × 104 ppm

Paragraph (3 to 5): NaBr, used to produce AgBr for use in photography can be self prepared as
follows :
Fe + Br2  FeBr2
FeBr2 + Br2  Fe3Br8
Fe3Br8 + Na2CO3  NaBr + CO2 + Fe3O4
How much Fe in kg is consumed to produce 2.06 × 103 kg NaBr

3. Mass of iron required to produce 2.06 × 103 kg NaBr

(A) 420 g (B) 420 kg (C) 4.2 × 105 kg (D) 4.2 × 108 g

4. If the yield of (ii) is 60% & (iii) reaction is 70% then mass of iron required to produce 2.06 ×
103 kg NaBr.
(A) 105 kg (B) 105 g (C) 103 kg (D) none

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5. If yield of (iii) reaction is 90% then mole of CO2 formed when 2.06 × 103 g NaBr is formed.
(A) 20 (B) 10 (C) 40 (D) none

6. Match the following:

Column I Column II
(A) 100 ml of 0.2 M AlCl3 solution (p) Total concentration of cation(s) = 0.12 M
+ 400 ml of 0.1 M HCl solution
(B) 50 ml of 0.4 M KCl + 50 ml H2O (q) [SO42–] = 0.06 M
(C) 30 ml of 0.2 M K2SO4 + 70 ml H2O (r) [SO42–] = 2.5 M
(D) 200 ml 24.5% (w/v) H2SO4 (s) [Cl¯] = 0.2 M

7. Match the following:

Column I Column II
(A) Zn(s) + 2HCl(aq)  ZnCl2(s) + H2(g) (p) 50% of excess reagent left
above reaction is carried out by taking
2 moles each of Zn and HCl

(B) AgNO3(aq) + HCl(aq)  AgCl(s) + HNO3(g) (q) 22.4 L of gas at STP is liberated
above reaction is carried out by taking
170 g AgNO3 and 18.25 g HCl (Ag = 108)

(C) CaCO3(s)  CaO(s) + CO2(g) (r) 1 moles of solid (product) obtained.

100 g CaCO3 is decomposed

(D) 2KClO3(s)  2KCl(s) + 3O2(g) (s) HCl is the limiting reagent

2/3 moles of KClO3 decomposed

8. If 10–4 dm3 of water is introduced into a 1.0 dm3 flask at 300 K, how many moles of water are in
the vapour phase when equilibrium is established ?
(Given : Vapour pressure of H2O at 300 K is 3170 Pa ; R = 8.314 JK–1 mol–1) :-
(A) 1.27 × 10–3 mol (B) 5.56 × 10–3 mol
(C) 1.53 × 10–2 mol (D) 4.46 × 10–2 mol

9. When CO2(g) is passed over red hot coke it partially gets reduced to CO(g). Upon passing 0.5 litre
of CO2(g) over red hot coke, the total volume of the gases increased to 700 mL. The composition
of the gaseous mixture at STP is:-
(A) CO2 = 200 mL ; CO = 500 mL (B) CO2 = 350 mL ; CO = 350 mL
(C) CO2 = 0.0 mL ; CO = 700 mL (D) CO2 = 300 mL ; CO = 400 mL

10. A + 2B + 3C  AB2C3
Reaction of 6.0 g of A, 6.0 x 1023 atoms of B, and 0.036 mol of C yields 4.8 g of compound AB2C3.
If the atomic mass of A and C are 60 and 80 amu, respectively, the atomic mass of B is (Avogadro
no. = 6xl023):
(A) 70 amu (B) 60 amu (C) 40 amu (D) 50 amu

3
11. Excess of NaOH(aq) was added to 100 mL of FeCl3(aq) resulting into 2.14 g of Fe(OH)3. The molarity
of FeCl3(aq) is :
(Given molar mass of Fe = 56 g mol–1 and molar mass of Cl = 35.5 g mol–1)
(A) 1.8 M (B) 0.6 M (C) 0.2 M (D) 0.3 M

12. The ratio of mass percent of C and H of an organic compound (CXHYOZ) is 6 : 1. If one molecule
of the above compound (CXHYOZ) contains half as much oxygen as required to burn one molecule
of compound CXHY completely to CO2 and H2O. The empirical formula of compound CXHYOZ is :
(A) C3H6O3 (B) C2H4O (C) C3H4O2 (D) C2H4O3

13. A compound H2X with molar weight of 80 g is dissolved in a solvent having density of 0.4 g ml–1.
Assuming no change in volume upon dissolution, the molality of a 3.2 molar solution is

Level -3

1. A chemist wants to prepare diborane by the reaction

6 LiH + 8 BF3  6 Li BF4 + B2H6
If the starts with 2.0 moles each of LiH & BF3. How many moles B2H6 can be prepared.
(A) 0.250 (B) 0.550 (C) 0.850 (D) 1.00

2. A 10 g sample of a mixture of calcium chloride and sodium chloride is treated with Na 2CO3 to
precipitate calcium as calcium carbonate. This CaCO3 is heated to convert all the calcium to CaO
and the final mass of CaO is 1.62 g. Calculate % by mass of NaCl in the original mixture.
(A) 12% (B) 28.9% (C) 67.9% (D) 91%

3. Carbon combines with hydrogen in P, Q, R. The % of hydrogen in P, Q, R are 25, 14.3, 7.7
respectively. Which law of chemical combination is illustrated ?
(A) Law of conservation of mass (B) Law of constant proportion
(C) Law of multiple proportion (D) Law of reciprocal proportion

4. 120 g Mg was burnt in air to give a mixture of MgO and Mg 3N2. The mixture is now dissolved in
HCl to form MgCl2 and NH4Cl, if 107 grams NH4Cl is produced. Then the moles of MgCl2 formed is:
(At. wt. Mg = 24, N = 14, Cl = 35.5)
(A) 3 moles (B) 6 moles (C) 5 moles (D) 10 moles

5. Formation of polyethene (CH2CH2)nfrom calcium carbide takes place as follows :

CaC2+H2O  Ca(OH)2 + C2H2;
C2H2 + H2  C2H4;
n(C2H4)  (CH2CH2)n.
The amount of polyethylene (CH2CH2)n possibly obtainable from 64.0 kg CaC2 can be
(A) 28Kg (B) 14kg (C) 21kg (D) 42 kg

6. What is the number of moles of Fe(OH)3(s) that can be produced by allowing 1 mole of Fe2S3, 2
moles of H2O and 3 moles of O2 to react?
2Fe 2 S 3 (s)  6H 2 O(l)  3O 2 (g)  4Fe(OH)3 (s)  6S(s)
(A) 5.34 (B) 6.638 (C) 1.34 (D) 3.08

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7. A chemist has synthesized a greenish yellow gaseous compound of chlorine and oxygen and finds
that its density
is 7.71 g/L at 36°C and 2.88 atm. Then the molecular formula of the compound will be :
(A) ClO3 (B) ClO2 (C) ClO (D) Cl2O2

8. What conclusions would you draw from the following graphs :

P V

0 K(–273.15°C) T 0 K(–273.15°C) T

(A) As the temperature is reduced, the volume as well as pressure increase.

(B) As the temperature is reduced, the volume becomes zero and the pressure reaches infinity.
(C) As the temperature is reduced, the volume as well as the pressure decrease.
(D) A point is reached where theoretically, the volume as well as the pressure become zero.

9. A gas occupies 300 ml. vol. at 270C temperature & 730 mm pressure. Then its volume at STP is–
(A) 162.2 ml (B) 262.2 ml (C) 362.2 ml (D) 462.2 ml

10. If 13.1 g Na2SO4. x H2O contains 6g H2O the value of ‘x’ is

(A) 10 (B) 5 (C) 3 (D) 7

11. For the redox reaction, MnO4– + C2O42– + H+  Mn2+ + CO2 + H2O
the correct coefficients of the reactants for the balanced reaction are respectively MnO4–, C2O–2
4
, H+
(A) 2, 5, 16 (B) 16, 3, 12 (C) 15, 16, 12 (D) 2, 16, 5

12. 5 moles of hydrogen gas, 3 moles of white phosphorus P4(s) and 12 moles of Oxygen gas are taken
in a sealed flask and allowed to react as follows.
H2(g) + P4(s) + O2(g)  H3PO4.
Determine the moles of H3PO4 that can be produced considering 90% yield of reaction.
(A) 3 moles (B) 4 moles (C) 3.33 moles (D) 5 moles

13. 5 moles of A, 6 moles of Z are mixed with sufficient amount of C to produce final product ‘F’, then
find maximum moles of ‘F’ which can be produced. Assuming that the product formed can also be
reused. Reaction are :
A + 2Z  B
B+CZ+F
(A) 3 moles (B) 4.5 moles (C) 5 moles (D) 6 moles

14. A giant molecule contains 0.25% of a metal whose atomic weight is 59. Its molecule contains one
atom of that metal. Its minimum molecular weight is -

100  59
(A) 5900 (B) 23600 (C) 11800 (D)
0.4
5
15. Match the column
Column-I Column-II (mass of product)
(a) 2H2 + O2 2H2O (p) 1.028 g
1g 1g
(b) 3H2 + N2 2NH3 (q) 1.333 g
1g 1g
(c) H2 + Cl2 2HCl (r) 1.125 g
1g 1g
(d) 2H2 + C CH4 (s) 1.214 g
1g 1g
(A) (a) r ; (b) s ; (c)  p ; (d) q (B) (a)p ; (b) q ; (c)  r ; (d) s
(C) (a) r ; (b) s ; (c)  q ; (d) p (D) (a) q ;(b) p ; (c)  r ; (d) s

16. 1.0×10–3 mol of Ag+ and 1.0×10–3 mol of CrO42– react together to form solid Ag2CrO4. What is the
amount of Ag2CrO4 formed ? (Molecular weight of Ag2CrO4 = 332)
(A) 0.268 gm (B) 0.166 gm (C) 0.212 gm (D) 1.66 gm

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 Answer Key
Level-1

1. 1.5 2. (D) 3. C8H8O2 4. 4

5. 40.39 g 6. 23.26 lit. 7. 2.22 g 8. (B)

9. 37.93%

10. (i) O2 is left in excess.

(ii) 3 moles of O2 or 96 g of O2 is left.
(iii) 2 moles of CO or 56 g of CO is formed.
(iv) To use O2 completely, total 8 moles of carbon or 96 g of carbon is needed.

11. 0.95 g , 4.05 g 12. 77.48% 13. (A) 14. (B)

NaNO3 Pb(NO3)2

15. 65.65% 16. 278.94 g

Level-2

1. 32.07 2. (BD) 3. (B) 4. (C)

5. (B) 6. (A) - (ps), (B) - (s), (C) - (pq), (D) - (r)
7. (A) - (pqrs), (B) - (ps), (C) - (qr), (D) - (q) 8. (1) 9. (4)
10.(4) 11.(3) 12.(4) 13.(8)

Level-3

Que. 1 2 3 4 5 6 7 8 9 10
Ans. A C C C A C B CD B D
Que. 11 12 13 14 15 16
Ans. A A D B A B