1

Case Name: Aspen finally done.hsc

2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
7 Workbook: EDC Reboiler Absorber (COL2)
8
9
10
Material Streams Fluid Pkg: All

11 Name 14 @COL2 To Reboiler @COL2 Boilup @COL2 16 @COL2 13 @COL2

12 Vapour Fraction 1.0000 0.0000 1.0000 0.0000 0.0000
13 Temperature (C) 121.9 135.9 136.7 136.7 14.90
14 Pressure (kPa) 405.3 405.3 405.3 405.3 405.3
15 Molar Flow (kgmole/h) 289.6 2217 1019 1198 1488
16 Mass Flow (kg/h) 1.983e+004 2.156e+005 9.813e+004 1.175e+005 1.373e+005
17 Liquid Volume Flow (m3/h) 16.62 172.7 78.62 94.03 110.6
18 Heat Flow (kJ/h) -4.364e+007 -3.406e+008 -1.271e+008 -1.826e+008 -2.571e+008
19
20
Compositions Fluid Pkg: All

21 Name 14 @COL2 To Reboiler @COL2 Boilup @COL2 16 @COL2 13 @COL2

22 Comp Mole Frac (Ethylene) 0.0010 0.0000 0.0000 0.0000 0.0002
23 Comp Mole Frac (Cl2) 0.0000 0.0000 0.0000 0.0000 0.0000
24 Comp Mole Frac (12-ClC2) 0.5946 0.9788 0.9675 0.9884 0.9118
25 Comp Mole Frac (HCl) 0.1052 0.0000 0.0000 0.0000 0.0205
26 Comp Mole Frac (VinylCl) 0.0081 0.0000 0.0000 0.0000 0.0016
27 Comp Mole Frac (H2O) 0.2889 0.0212 0.0325 0.0116 0.0655
28 Comp Mole Frac (Oxygen) 0.0001 0.0000 0.0000 0.0000 0.0000
29 Comp Mole Frac (Nitrogen) 0.0021 0.0000 0.0000 0.0000 0.0004
30
31
Energy Streams Fluid Pkg: All

32 Name EDC_Bdt @COL2

33 Heat Flow (kJ/h) 3.085e+007
34
35
Unit Ops
36 Operation Name Operation Type Feeds Products Ignored Calc Level
37 13 @COL2 To Reboiler @COL2
Main Tower @COL2 Tower No 500.0 *
38 Boilup @COL2 14 @COL2
39 To Reboiler @COL2 16 @COL2
Reboiler @COL2 Reboiler No 500.0 *
40 EDC_Bdt @COL2 Boilup @COL2
41
42 Workbook: column 1 (COL3)
43
44
45
Material Streams Fluid Pkg: All

46 Name Reflux @COL3 To Condenser @COL3 Boilup @COL3 To Reboiler @COL3 Hcl @COL3
47 Vapour Fraction 0.0000 1.0000 1.0000 0.0000 0.0000
48 Temperature (C) -16.89 -13.60 112.2 99.68 -16.89
49 Pressure (kPa) 1621 1621 1621 1621 1621
50 Molar Flow (kgmole/h) 416.2 1123 1098 2290 707.0
51 Mass Flow (kg/h) 1.527e+004 4.122e+004 7.149e+004 1.630e+005 2.595e+004
52 Liquid Volume Flow (m3/h) 17.54 47.32 75.20 161.0 29.79
53 Heat Flow (kJ/h) -4.443e+007 -1.047e+008 2.532e+007 -5.705e+007 -7.547e+007
54 Name C1 bottoms @COL3 21 @COL3
55 Vapour Fraction 0.0000 0.1239
56 Temperature (C) 112.2 33.75
57 Pressure (kPa) 1621 1621
58 Molar Flow (kgmole/h) 1192 1899
59 Mass Flow (kg/h) 9.152e+004 1.175e+005
60 Liquid Volume Flow (m3/h) 85.75 115.5
61 Heat Flow (kJ/h) -6.174e+007 -1.427e+008
62
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 1 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
7 Workbook: column 1 (COL3) (continued)
8
9
10
Compositions Fluid Pkg: All

11 Name Reflux @COL3 To Condenser @COL3 Boilup @COL3 To Reboiler @COL3 Hcl @COL3
12 Comp Mole Frac (Ethylene) 0.0000 0.0000 0.0000 0.0000 0.0000
13 Comp Mole Frac (Cl2) 0.0000 0.0000 0.0000 0.0000 0.0000
14 Comp Mole Frac (12-ClC2) 0.0000 0.0000 0.0817 0.2505 0.0000
15 Comp Mole Frac (HCl) 0.9908 0.9908 0.0004 0.0002 0.9908
16 Comp Mole Frac (VinylCl) 0.0092 0.0092 0.9102 0.7395 0.0092
17 Comp Mole Frac (H2O) 0.0000 0.0000 0.0077 0.0097 0.0000
18 Comp Mole Frac (Oxygen) 0.0000 0.0000 0.0000 0.0000 0.0000
19 Comp Mole Frac (Nitrogen) 0.0000 0.0000 0.0000 0.0000 0.0000
20 Name C1 bottoms @COL3 21 @COL3
21 Comp Mole Frac (Ethylene) 0.0000 0.0000
22 Comp Mole Frac (Cl2) 0.0000 0.0000
23 Comp Mole Frac (12-ClC2) 0.4060 0.2549
24 Comp Mole Frac (HCl) 0.0001 0.3689
25 Comp Mole Frac (VinylCl) 0.5823 0.3689
26 Comp Mole Frac (H2O) 0.0116 0.0073
27 Comp Mole Frac (Oxygen) 0.0000 0.0000
28 Comp Mole Frac (Nitrogen) 0.0000 0.0000
29
30
Energy Streams Fluid Pkg: All

31 Name C1_Ddt @COL3 C1Bdt @COL3

32 Heat Flow (kJ/h) 1.515e+007 2.063e+007
33
34
Unit Ops
35 Operation Name Operation Type Feeds Products Ignored Calc Level
36 To Reboiler @COL3 C1 bottoms @COL3
Reboiler @COL3 Reboiler No 500.0 *
37 C1Bdt @COL3 Boilup @COL3
38 Reflux @COL3 To Reboiler @COL3
39 Main Tower @COL3 Tower Boilup @COL3 To Condenser @COL3 No 500.0 *
40 21 @COL3
41 To Condenser @COL3 Hcl @COL3
42 Condenser @COL3 Total Condenser C1_Ddt @COL3 Reflux @COL3 No 500.0 *
43 C1_Ddt @COL3
44
45 Workbook: Column 2 (COL4)
46
47
48
Material Streams Fluid Pkg: All

49 Name Reflux @COL4 To Condenser @COL4 Boilup @COL4 To Reboiler @COL4 VCM @COL4
50 Vapour Fraction 0.0000 1.0000 1.0000 0.0000 0.0000
51 Temperature (C) 32.33 32.65 143.9 142.4 32.33
52 Pressure (kPa) 486.4 486.4 486.4 486.4 486.4
53 Molar Flow (kgmole/h) 197.9 895.8 455.4 949.5 698.0
54 Mass Flow (kg/h) 1.232e+004 5.576e+004 4.306e+004 9.114e+004 4.344e+004
55 Liquid Volume Flow (m3/h) 13.40 60.65 34.54 73.05 47.25
56 Heat Flow (kJ/h) 2.812e+006 2.993e+007 -5.765e+007 -1.465e+008 9.919e+006
57
58
59
60
61
62
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 2 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
7 Workbook: Column 2 (COL4) (continued)
8
9
10
Material Streams (continued) Fluid Pkg: All

11 Name EDC-1 @COL4 to c2 @COL4

12 Vapour Fraction 0.0000 0.3121
13 Temperature (C) 143.9 62.69
14 Pressure (kPa) 486.4 480.0
15 Molar Flow (kgmole/h) 494.0 1192
16 Mass Flow (kg/h) 4.808e+004 9.152e+004
17 Liquid Volume Flow (m3/h) 38.50 85.75
18 Heat Flow (kJ/h) -7.525e+007 -6.174e+007
19
20
Compositions Fluid Pkg: All

21 Name Reflux @COL4 To Condenser @COL4 Boilup @COL4 To Reboiler @COL4 VCM @COL4
22 Comp Mole Frac (Ethylene) 0.0000 0.0000 0.0000 0.0000 0.0000
23 Comp Mole Frac (Cl2) 0.0000 0.0000 0.0000 0.0000 0.0000
24 Comp Mole Frac (12-ClC2) 0.0000 0.0000 0.9448 0.9630 0.0000
25 Comp Mole Frac (HCl) 0.0001 0.0001 0.0000 0.0000 0.0001
26 Comp Mole Frac (VinylCl) 0.9944 0.9944 0.0011 0.0006 0.9944
27 Comp Mole Frac (H2O) 0.0055 0.0055 0.0541 0.0364 0.0055
28 Comp Mole Frac (Oxygen) 0.0000 0.0000 0.0000 0.0000 0.0000
29 Comp Mole Frac (Nitrogen) 0.0000 0.0000 0.0000 0.0000 0.0000
30 Name EDC-1 @COL4 to c2 @COL4
31 Comp Mole Frac (Ethylene) 0.0000 0.0000
32 Comp Mole Frac (Cl2) 0.0000 0.0000
33 Comp Mole Frac (12-ClC2) 0.9797 0.4060
34 Comp Mole Frac (HCl) 0.0000 0.0001
35 Comp Mole Frac (VinylCl) 0.0001 0.5823
36 Comp Mole Frac (H2O) 0.0202 0.0116
37 Comp Mole Frac (Oxygen) 0.0000 0.0000
38 Comp Mole Frac (Nitrogen) 0.0000 0.0000
39
40
Energy Streams Fluid Pkg: All

41 Name C2ddt @COL4 C2Rdt @COL4

42 Heat Flow (kJ/h) 1.720e+007 1.361e+007
43
44
Unit Ops
45 Operation Name Operation Type Feeds Products Ignored Calc Level
46 To Reboiler @COL4 EDC-1 @COL4
Reboiler @COL4 Reboiler No 500.0 *
47 C2Rdt @COL4 Boilup @COL4
48 Reflux @COL4 To Reboiler @COL4
49 Main Tower @COL4 Tower Boilup @COL4 To Condenser @COL4 No 500.0 *
50 to c2 @COL4
51 To Condenser @COL4 VCM @COL4
52 Condenser @COL4 Total Condenser C2ddt @COL4 Reflux @COL4 No 500.0 *
53 C2ddt @COL4
54
55
56
57
58
59
60
61
62
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 3 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
7 Workbook: Case (Main)
8
9
10
Material Streams Fluid Pkg: All

11 Name Cl2 C2H4 Air HCl_a 1

12 Vapour Fraction 1.0000 1.0000 1.0000 1.0000 1.0000
13 Temperature (C) 25.00 * 25.00 * 25.00 * 25.00 * 25.00
14 Pressure (kPa) 152.0 * 152.0 * 152.0 * 152.0 * 152.0
15 Molar Flow (kgmole/h) 368.0 * 775.0 * 1000 * 800.0 * 387.5
16 Mass Flow (kg/h) 2.609e+004 2.174e+004 2.885e+004 2.917e+004 1.087e+004
17 Liquid Volume Flow (m3/h) 16.71 56.73 33.35 33.51 28.37
18 Heat Flow (kJ/h) -4.305e+004 4.050e+007 -1.020e+004 -7.394e+007 2.025e+007
19 Name 2 3 4 5 R1_HeatedFeed
20 Vapour Fraction 1.0000 1.0000 1.0000 1.0000 1.0000
21 Temperature (C) 25.00 24.96 36.47 155.2 60.00 *
22 Pressure (kPa) 152.0 152.0 152.0 405.3 * 152.0
23 Molar Flow (kgmole/h) 387.5 755.5 2894 2894 755.5
24 Mass Flow (kg/h) 1.087e+004 3.696e+004 9.483e+004 9.483e+004 3.696e+004
25 Liquid Volume Flow (m3/h) 28.37 45.08 125.0 125.0 45.08
26 Heat Flow (kJ/h) 2.025e+007 2.021e+007 -1.172e+008 -1.061e+008 2.128e+007
27 Name R2_Heatedfeed 6 7 8 9
28 Vapour Fraction 1.0000 1.0000 0.0000 0.0576 1.0000
29 Temperature (C) 225.0 * 60.00 60.00 60.00 225.0
30 Pressure (kPa) 405.3 152.0 152.0 152.0 405.3
31 Molar Flow (kgmole/h) 2894 22.33 365.2 387.5 2313
32 Mass Flow (kg/h) 9.483e+004 1049 3.592e+004 3.696e+004 9.483e+004
33 Liquid Volume Flow (m3/h) 125.0 1.670 28.89 30.56 96.40
34 Heat Flow (kJ/h) -9.924e+007 1.238e+005 -5.841e+007 -5.829e+007 -1.921e+008
35 Name 10 To_EDC_SEP Lights 11 water
36 Vapour Fraction 0.8116 0.4677 1.0000 0.0000 0.0000
37 Temperature (C) 66.20 15.00 * 15.00 15.00 15.00 *
38 Pressure (kPa) 152.0 152.0 152.0 152.0 101.3 *
39 Molar Flow (kgmole/h) 3482 3482 1629 1854 100.0 *
40 Mass Flow (kg/h) 1.995e+005 1.995e+005 5.560e+004 1.439e+005 1802
41 Liquid Volume Flow (m3/h) 181.9 181.9 64.66 117.2 1.805
42 Heat Flow (kJ/h) -3.830e+008 -4.397e+008 -7.756e+007 -3.621e+008 -2.872e+007
43 Name 12 13 water out 14 16
44 Vapour Fraction 0.0000 0.0000 0.0000 1.0000 0.0000
45 Temperature (C) 15.02 14.90 14.90 121.9 136.7
46 Pressure (kPa) 405.3 * 405.3 405.3 405.3 405.3
47 Molar Flow (kgmole/h) 100.0 1488 465.6 289.6 1198
48 Mass Flow (kg/h) 1802 1.373e+005 8390 1.983e+004 1.175e+005
49 Liquid Volume Flow (m3/h) 1.805 110.6 8.407 16.62 94.03
50 Heat Flow (kJ/h) -2.871e+007 -2.571e+008 -1.337e+008 -4.364e+007 -1.826e+008
51 Name 15 Recycled _EDC_SEP 17 R3_Heated feed 18
52 Vapour Fraction 0.0900 0.0900 0.0000 1.0000 1.0000
53 Temperature (C) 60.00 * 60.00 * 138.2 550.0 * 550.0
54 Pressure (kPa) 405.3 405.3 * 2634 * 2634 2634
55 Molar Flow (kgmole/h) 289.6 289.6 * 1198 1198 1899
56 Mass Flow (kg/h) 1.983e+004 1.983e+004 1.175e+005 1.175e+005 1.175e+005
57 Liquid Volume Flow (m3/h) 16.62 16.62 94.03 94.03 115.5
58 Heat Flow (kJ/h) -5.391e+007 -5.392e+007 -1.823e+008 -9.069e+007 -3.963e+007
59
60
61
62
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 4 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
7 Workbook: Case (Main) (continued)
8
9
10
Material Streams (continued) Fluid Pkg: All

11 Name 19 20 21 Hcl C1 bottoms

12 Vapour Fraction 1.0000 0.0000 0.1239 0.0000 0.0000
13 Temperature (C) 186.0 * 50.00 * 33.75 -16.89 112.2
14 Pressure (kPa) 2634 2634 1621 * 1621 1621
15 Molar Flow (kgmole/h) 1899 1899 1899 707.0 1192
16 Mass Flow (kg/h) 1.175e+005 1.175e+005 1.175e+005 2.595e+004 9.152e+004
17 Liquid Volume Flow (m3/h) 115.5 115.5 115.5 29.79 85.75
18 Heat Flow (kJ/h) -9.208e+007 -1.427e+008 -1.427e+008 -7.547e+007 -6.174e+007
19 Name to c2 VCM EDC-1 22 EDC Recycled
20 Vapour Fraction 0.3121 0.0000 0.0000 0.0000 0.0000
21 Temperature (C) 62.69 32.33 143.9 90.00 * 90.00 *
22 Pressure (kPa) 480.0 * 486.4 486.4 486.4 486.4 *
23 Molar Flow (kgmole/h) 1192 698.0 494.0 494.0 491.8 *
24 Mass Flow (kg/h) 9.152e+004 4.344e+004 4.808e+004 4.808e+004 4.786e+004
25 Liquid Volume Flow (m3/h) 85.75 47.25 38.50 38.50 38.33
26 Heat Flow (kJ/h) -6.174e+007 9.919e+006 -7.525e+007 -7.902e+007 -7.867e+007
27 Name 23 HCL Recycled
28 Vapour Fraction 1.0000 1.0000
29 Temperature (C) 90.00 * 90.00 *
30 Pressure (kPa) 1621 1621 *
31 Molar Flow (kgmole/h) 707.0 707.0 *
32 Mass Flow (kg/h) 2.595e+004 2.594e+004
33 Liquid Volume Flow (m3/h) 29.79 29.78
34 Heat Flow (kJ/h) -6.345e+007 -6.346e+007
35
36
Compositions Fluid Pkg: All

37 Name Cl2 C2H4 Air HCl_a 1

38 Comp Mole Frac (Ethylene) 0.0000 * 1.0000 * 0.0000 * 0.0000 * 1.0000
39 Comp Mole Frac (Cl2) 1.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000
40 Comp Mole Frac (12-ClC2) 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000
41 Comp Mole Frac (HCl) 0.0000 * 0.0000 * 0.0000 * 1.0000 * 0.0000
42 Comp Mole Frac (VinylCl) 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000
43 Comp Mole Frac (H2O) 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000
44 Comp Mole Frac (Oxygen) 0.0000 * 0.0000 * 0.2100 * 0.0000 * 0.0000
45 Comp Mole Frac (Nitrogen) 0.0000 * 0.0000 * 0.7900 * 0.0000 * 0.0000
46 Name 2 3 4 5 R1_HeatedFeed
47 Comp Mole Frac (Ethylene) 1.0000 0.5129 0.1339 0.1339 0.5129
48 Comp Mole Frac (Cl2) 0.0000 0.4871 0.0000 0.0000 0.4871
49 Comp Mole Frac (12-ClC2) 0.0000 0.0000 0.0000 0.0000 0.0000
50 Comp Mole Frac (HCl) 0.0000 0.0000 0.5184 0.5184 0.0000
51 Comp Mole Frac (VinylCl) 0.0000 0.0000 0.0022 0.0022 0.0000
52 Comp Mole Frac (H2O) 0.0000 0.0000 0.0000 0.0000 0.0000
53 Comp Mole Frac (Oxygen) 0.0000 0.0000 0.0726 0.0726 0.0000
54 Comp Mole Frac (Nitrogen) 0.0000 0.0000 0.2729 0.2729 0.0000
55
56
57
58
59
60
61
62
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 5 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
7 Workbook: Case (Main) (continued)
8
9
10
Compositions (continued) Fluid Pkg: All

11 Name R2_Heatedfeed 6 7 8 9
12 Comp Mole Frac (Ethylene) 0.1339 0.7331 0.0086 0.0504 0.0000
13 Comp Mole Frac (Cl2) 0.0000 0.0002 0.0000 0.0000 0.0000
14 Comp Mole Frac (12-ClC2) 0.0000 0.2667 0.9914 0.9496 0.1675
15 Comp Mole Frac (HCl) 0.5184 0.0000 0.0000 0.0000 0.3137
16 Comp Mole Frac (VinylCl) 0.0022 0.0000 0.0000 0.0000 0.0028
17 Comp Mole Frac (H2O) 0.0000 0.0000 0.0000 0.0000 0.1675
18 Comp Mole Frac (Oxygen) 0.0726 0.0000 0.0000 0.0000 0.0070
19 Comp Mole Frac (Nitrogen) 0.2729 0.0000 0.0000 0.0000 0.3415
20 Name 10 To_EDC_SEP Lights 11 water
21 Comp Mole Frac (Ethylene) 0.0057 0.0057 0.0120 0.0001 0.0000 *
22 Comp Mole Frac (Cl2) 0.0000 0.0000 0.0000 0.0000 0.0000 *
23 Comp Mole Frac (12-ClC2) 0.4048 0.4048 0.0324 0.7320 0.0000 *
24 Comp Mole Frac (HCl) 0.2171 0.2171 0.4455 0.0165 0.0000 *
25 Comp Mole Frac (VinylCl) 0.0025 0.0025 0.0040 0.0013 0.0000 *
26 Comp Mole Frac (H2O) 0.1382 0.1382 0.0111 0.2498 1.0000 *
27 Comp Mole Frac (Oxygen) 0.0047 0.0047 0.0100 0.0000 0.0000 *
28 Comp Mole Frac (Nitrogen) 0.2270 0.2270 0.4851 0.0003 0.0000 *
29 Name 12 13 water out 14 16
30 Comp Mole Frac (Ethylene) 0.0000 0.0002 0.0000 0.0010 0.0000
31 Comp Mole Frac (Cl2) 0.0000 0.0000 0.0000 0.0000 0.0000
32 Comp Mole Frac (12-ClC2) 0.0000 0.9118 0.0000 0.5946 0.9884
33 Comp Mole Frac (HCl) 0.0000 0.0205 0.0002 0.1052 0.0000
34 Comp Mole Frac (VinylCl) 0.0000 0.0016 0.0000 0.0081 0.0000
35 Comp Mole Frac (H2O) 1.0000 0.0655 0.9998 0.2889 0.0116
36 Comp Mole Frac (Oxygen) 0.0000 0.0000 0.0000 0.0001 0.0000
37 Comp Mole Frac (Nitrogen) 0.0000 0.0004 0.0000 0.0021 0.0000
38 Name 15 Recycled _EDC_SEP 17 R3_Heated feed 18
39 Comp Mole Frac (Ethylene) 0.0010 0.0010 * 0.0000 0.0000 0.0000
40 Comp Mole Frac (Cl2) 0.0000 0.0000 * 0.0000 0.0000 0.0000
41 Comp Mole Frac (12-ClC2) 0.5946 0.5946 * 0.9884 0.9884 0.2549
42 Comp Mole Frac (HCl) 0.1052 0.1052 * 0.0000 0.0000 0.3689
43 Comp Mole Frac (VinylCl) 0.0081 0.0081 * 0.0000 0.0000 0.3689
44 Comp Mole Frac (H2O) 0.2889 0.2889 * 0.0116 0.0116 0.0073
45 Comp Mole Frac (Oxygen) 0.0001 0.0001 * 0.0000 0.0000 0.0000
46 Comp Mole Frac (Nitrogen) 0.0021 0.0021 * 0.0000 0.0000 0.0000
47 Name 19 20 21 Hcl C1 bottoms
48 Comp Mole Frac (Ethylene) 0.0000 0.0000 0.0000 0.0000 0.0000
49 Comp Mole Frac (Cl2) 0.0000 0.0000 0.0000 0.0000 0.0000
50 Comp Mole Frac (12-ClC2) 0.2549 0.2549 0.2549 0.0000 0.4060
51 Comp Mole Frac (HCl) 0.3689 0.3689 0.3689 0.9908 0.0001
52 Comp Mole Frac (VinylCl) 0.3689 0.3689 0.3689 0.0092 0.5823
53 Comp Mole Frac (H2O) 0.0073 0.0073 0.0073 0.0000 0.0116
54 Comp Mole Frac (Oxygen) 0.0000 0.0000 0.0000 0.0000 0.0000
55 Comp Mole Frac (Nitrogen) 0.0000 0.0000 0.0000 0.0000 0.0000
56
57
58
59
60
61
62
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 6 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
7 Workbook: Case (Main) (continued)
8
9
10
Compositions (continued) Fluid Pkg: All

11 Name to c2 VCM EDC-1 22 EDC Recycled

12 Comp Mole Frac (Ethylene) 0.0000 0.0000 0.0000 0.0000 0.0000 *
13 Comp Mole Frac (Cl2) 0.0000 0.0000 0.0000 0.0000 0.0000 *
14 Comp Mole Frac (12-ClC2) 0.4060 0.0000 0.9797 0.9797 0.9796 *
15 Comp Mole Frac (HCl) 0.0001 0.0001 0.0000 0.0000 0.0000 *
16 Comp Mole Frac (VinylCl) 0.5823 0.9944 0.0001 0.0001 0.0001 *
17 Comp Mole Frac (H2O) 0.0116 0.0055 0.0202 0.0202 0.0203 *
18 Comp Mole Frac (Oxygen) 0.0000 0.0000 0.0000 0.0000 0.0000 *
19 Comp Mole Frac (Nitrogen) 0.0000 0.0000 0.0000 0.0000 0.0000 *
20 Name 23 HCL Recycled
21 Comp Mole Frac (Ethylene) 0.0000 0.0000 *
22 Comp Mole Frac (Cl2) 0.0000 0.0000 *
23 Comp Mole Frac (12-ClC2) 0.0000 0.0000 *
24 Comp Mole Frac (HCl) 0.9908 0.9910 *
25 Comp Mole Frac (VinylCl) 0.0092 0.0090 *
26 Comp Mole Frac (H2O) 0.0000 0.0000 *
27 Comp Mole Frac (Oxygen) 0.0000 0.0000 *
28 Comp Mole Frac (Nitrogen) 0.0000 0.0000 *
29
30
Energy Streams Fluid Pkg: All

31 Name Q-100 Q-101 Q-102 Q-103 Q-104

32 Heat Flow (kJ/h) 1.106e+007 1.068e+006 6.850e+006 -7.957e+007 9.285e+007
33 Name Q-105 Q-106 EDC EDC_Bdt Q-107
34 Heat Flow (kJ/h) 5.671e+007 719.5 --- 3.085e+007 1.026e+007
35 Name Q-108 Q-109 Q-110 Q-111 Q-112
36 Heat Flow (kJ/h) 3.288e+005 9.163e+007 -5.106e+007 5.244e+007 5.061e+007
37 Name C1_Ddt C1Bdt C2ddt C2Rdt Q-113
38 Heat Flow (kJ/h) 1.515e+007 2.063e+007 1.720e+007 1.361e+007 3.772e+006
39 Name Q-114
40 Heat Flow (kJ/h) 1.202e+007
41
42
Unit Ops
43 Operation Name Operation Type Feeds Products Ignored Calc Level
44 Cl2 3
MIX-100 Mixer No 500.0 *
45 1
46 2 4
47 Air
MIX-101 Mixer No 500.0 *
48 HCL Recycled
49 HCl_a
50 6 8
MIX-102 Mixer No 500.0 *
51 7
52 8 10
53 9
MIX-103 Mixer No 500.0 *
54 Recycled _EDC_SEP
55 EDC Recycled
56 C2H4 1
TEE-100 Tee No 500.0 *
57 2
58 3 R1_HeatedFeed
E-100 Heater No 500.0 *
59 Q-101
60 5 R2_Heatedfeed
E-101 Heater No 500.0 *
61 Q-102
62 E-104 Heater 17 R3_Heated feed No 500.0 *
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 7 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
7 Workbook: Case (Main) (continued)
8
9
10
Unit Ops (continued)
11 Operation Name Operation Type Feeds Products Ignored Calc Level
12 E-104 Heater Q-109 No 500.0 *
13 Hcl 23
E-106 Heater No 500.0 *
14 Q-114
15 4 5
K-100 Compressor No 500.0 *
16 Q-100
17 R1_HeatedFeed 7
18 Reactor-1 Cont. Stirred Tank Reactor Q-103 6 No 500.0 *
19 Q-103
20 R2_Heatedfeed 9
Reactor-2 Plug Flow Reactor No 500.0 *
21 Q-104
22 R3_Heated feed 18
Reactor 3 Plug Flow Reactor No 500.0 *
23 Q-110
24 SET-1 Set No 500.0 *
25 SET-2 Set No 500.0 *
26 SET-3 Set No 500.0 *
27 ADJ-1 Adjust No 3500 *
28 ADJ-2 Adjust No 3500 *
29 ADJ-3 Adjust No 3500 *
30 ADJ-4 Adjust No 3500 *
31 R1-SS Spreadsheet No 500.0 *
32 R2-SS Spreadsheet No 500.0 *
33 R3-SS Spreadsheet No 500.0 *
34 10 To_EDC_SEP
E-102 Cooler No 500.0 *
35 Q-105
36 14 15
E-103 Cooler No 500.0 *
37 Q-107
38 18 19
Quench Cooler No 500.0 *
39 Q-111
40 19 20
Condenser Cooler No 500.0 *
41 Q-112
42 EDC-1 22
E-105 Cooler No 500.0 *
43 Q-113
44 To_EDC_SEP 11
Flash Separator No 500.0 *
45 Lights
46 water 12
P-100 Pump No 500.0 *
47 Q-106
48 16 17
P-101 Pump No 500.0 *
49 Q-108
50 12 water out
EDC extractor Liquid-Liquid Extractor No 2500 *
51 11 13
52 13 16
EDC Reboiler Absorber Reboiled Absorber No 2500 *
53 EDC_Bdt 14
54 RCY-1 Recycle 15 Recycled _EDC_SEP No 3500 *
55 RCY-2 Recycle 22 EDC Recycled No 3500 *
56 RCY-3 Recycle 23 HCL Recycled No 3500 *
57 VLV-100 Valve 20 21 No 500.0 *
58 VLV-101 Valve C1 bottoms to c2 No 500.0 *
59 21 C1 bottoms
60 column 1 Distillation C1Bdt Hcl No 2500 *
61 C1_Ddt
62 Column 2 Distillation to c2 EDC-1 No 2500 *
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 8 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
7 Workbook: Case (Main) (continued)
8
9
10
Unit Ops (continued)
11 Operation Name Operation Type Feeds Products Ignored Calc Level
12 C2Rdt VCM
Column 2 Distillation No 2500 *
13 C2ddt
14
Fluid Package: Basis-1
15 Material Stream: 1 Property Package: SRK
16
17
18
CONDITIONS
19 Overall Vapour Phase
20 Vapour / Phase Fraction 1.0000 1.0000
21 Temperature: (C) 25.00 25.00
22 Pressure: (kPa) 152.0 152.0
23 Molar Flow (kgmole/h) 387.5 387.5
24 Mass Flow (kg/h) 1.087e+004 1.087e+004
25 Std Ideal Liq Vol Flow (m3/h) 28.37 28.37
26 Molar Enthalpy (kJ/kgmole) 5.226e+004 5.226e+004
27 Molar Entropy (kJ/kgmole-C) 172.7 172.7
28 Heat Flow (kJ/h) 2.025e+007 2.025e+007
29 Liq Vol Flow @Std Cond (m3/h) 9103 * 9103
30
31
PROPERTIES
32 Overall Vapour Phase
33 Molecular Weight 28.05 28.05
34 Molar Density (kgmole/m3) 6.185e-002 6.185e-002
35 Mass Density (kg/m3) 1.735 1.735
36 Act. Volume Flow (m3/h) 6265 6265
37 Mass Enthalpy (kJ/kg) 1863 1863
38 Mass Entropy (kJ/kg-C) 6.158 6.158
39 Heat Capacity (kJ/kgmole-C) 44.29 44.29
40 Mass Heat Capacity (kJ/kg-C) 1.579 1.579
41 LHV Molar Basis (Std) (kJ/kgmole) 1.324e+006 1.324e+006
42 HHV Molar Basis (Std) (kJ/kgmole) 1.406e+006 1.406e+006
43 HHV Mass Basis (Std) (kJ/kg) 5.010e+004 5.010e+004
44 CO2 Loading --- ---
45 CO2 Apparent Mole Conc. (kgmole/m3) --- ---
46 CO2 Apparent Wt. Conc. (kgmol/kg) --- ---
47 LHV Mass Basis (Std) (kJ/kg) 4.718e+004 4.718e+004
48 Phase Fraction [Vol. Basis] 1.000 1.000
49 Phase Fraction [Mass Basis] 1.000 1.000
50 Phase Fraction [Act. Vol. Basis] 1.000 1.000
51 Mass Exergy (kJ/kg) 35.57 ---
52 Partial Pressure of CO2 (kPa) 0.0000 ---
53 Cost Based on Flow (Cost/s) 0.0000 0.0000
54 Act. Gas Flow (ACT_m3/h) 6265 6265
55 Avg. Liq. Density (kgmole/m3) 13.66 13.66
56 Specific Heat (kJ/kgmole-C) 44.29 44.29
57 Std. Gas Flow (STD_m3/h) 9162 9162
58 Std. Ideal Liq. Mass Density (kg/m3) 383.2 383.2
59 Act. Liq. Flow (m3/s) --- ---
60 Z Factor 0.9912 0.9912
61 Watson K 17.53 17.53
62 User Property --- ---
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 9 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 1 (continued) Property Package: SRK
8
9
10
PROPERTIES
11 Overall Vapour Phase
12 Partial Pressure of H2S (kPa) 0.0000 ---
13 Cp/(Cp - R) 1.231 1.231
14 Cp/Cv 1.242 1.242
15 Ideal Gas Cp/Cv 1.233 1.233
16 Ideal Gas Cp (kJ/kgmole-C) 43.93 43.93
17 Mass Ideal Gas Cp (kJ/kg-C) 1.566 1.566
18 Heat of Vap. (kJ/kgmole) 1.336e+004 ---
19 Kinematic Viscosity (cSt) 5.875 5.875
20 Liq. Mass Density (Std. Cond) (kg/m3) 1.194 1.194
21 Liq. Vol. Flow (Std. Cond) (m3/h) 9103 9103
22 Liquid Fraction 0.0000 0.0000
23 Molar Volume (m3/kgmole) 16.17 16.17
24 Mass Heat of Vap. (kJ/kg) 476.1 ---
25 Phase Fraction [Molar Basis] 1.0000 1.0000
26 Surface Tension (dyne/cm) --- ---
27 Thermal Conductivity (W/m-K) 2.146e-002 2.146e-002
28 Bubble Point Pressure (kPa) --- ---
29 Viscosity (cP) 1.019e-002 1.019e-002
30 Cv (Semi-Ideal) (kJ/kgmole-C) 35.98 35.98
31 Mass Cv (Semi-Ideal) (kJ/kg-C) 1.282 1.282
32 Cv (kJ/kgmole-C) 35.66 35.66
33 Mass Cv (kJ/kg-C) 1.271 1.271
34 Cv (Ent. Method) (kJ/kgmole-C) --- ---
35 Mass Cv (Ent. Method) (kJ/kg-C) --- ---
36 Cp/Cv (Ent. Method) --- ---
37 Reid VP at 37.8 C (kPa) --- ---
38 True VP at 37.8 C (kPa) --- ---
39 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 9103 9103
40 Viscosity Index -8.904 ---
41
42
COMPOSITION
43
44
Overall Phase Vapour Fraction 1.0000

45 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
46 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
47 Ethylene 387.5000 1.0000 10870.8477 1.0000 28.3667 1.0000
48 Cl2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
49 12-ClC2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
50 HCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
51 VinylCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
52 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
53 Oxygen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
54 Nitrogen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
55 Total 387.5000 1.0000 10870.8477 1.0000 28.3667 1.0000
56
57
Vapour Phase Phase Fraction 1.000

58 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
59 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
60 Ethylene 387.5000 1.0000 10870.8477 1.0000 28.3667 1.0000
61 Cl2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
62 12-ClC2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 10 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 1 (continued) Property Package: SRK
8
9
10
COMPOSITION
11
12
Vapour Phase (continued) Phase Fraction 1.000

13 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
14 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
15 HCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
16 VinylCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
17 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 Oxygen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Nitrogen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
20 Total 387.5000 1.0000 10870.8477 1.0000 28.3667 1.0000
21
22
K VALUE
23 COMPONENTS MIXED LIGHT HEAVY
24 Ethylene --- --- ---
25 Cl2 --- --- ---
26 12-ClC2 --- --- ---
27 HCl --- --- ---
28 VinylCl --- --- ---
29 H2O --- --- ---
30 Oxygen --- --- ---
31 Nitrogen --- --- ---
32
33
UNIT OPERATIONS
34 FEED TO PRODUCT FROM LOGICAL CONNECTION
35 Mixer: MIX-100 Tee: TEE-100
36
37
UTILITIES
38 ( No utilities reference this stream )
39
40
PROCESS UTILITY
41
42
43
DYNAMICS
44 Pressure Specification (Inactive): 152.0 kPa
45 Flow Specification (Inactive) Molar: 387.5 kgmole/h Mass: 1.087e+004 kg/h Std Ideal Liq Volume: 28.37 m3/h
46
47
User Variables
48
49
NOTES
50
51
52
Description
53
54
Fluid Package: Basis-1
55 Material Stream: 2 Property Package: SRK
56
57
58
CONDITIONS
59 Overall Vapour Phase
60 Vapour / Phase Fraction 1.0000 1.0000
61 Temperature: (C) 25.00 25.00
62 Pressure: (kPa) 152.0 152.0
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 11 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 2 (continued) Property Package: SRK
8
9
10
CONDITIONS
11 Overall Vapour Phase
12 Molar Flow (kgmole/h) 387.5 387.5
13 Mass Flow (kg/h) 1.087e+004 1.087e+004
14 Std Ideal Liq Vol Flow (m3/h) 28.37 28.37
15 Molar Enthalpy (kJ/kgmole) 5.226e+004 5.226e+004
16 Molar Entropy (kJ/kgmole-C) 172.7 172.7
17 Heat Flow (kJ/h) 2.025e+007 2.025e+007
18 Liq Vol Flow @Std Cond (m3/h) 9103 * 9103
19
20
PROPERTIES
21 Overall Vapour Phase
22 Molecular Weight 28.05 28.05
23 Molar Density (kgmole/m3) 6.185e-002 6.185e-002
24 Mass Density (kg/m3) 1.735 1.735
25 Act. Volume Flow (m3/h) 6265 6265
26 Mass Enthalpy (kJ/kg) 1863 1863
27 Mass Entropy (kJ/kg-C) 6.158 6.158
28 Heat Capacity (kJ/kgmole-C) 44.29 44.29
29 Mass Heat Capacity (kJ/kg-C) 1.579 1.579
30 LHV Molar Basis (Std) (kJ/kgmole) 1.324e+006 1.324e+006
31 HHV Molar Basis (Std) (kJ/kgmole) 1.406e+006 1.406e+006
32 HHV Mass Basis (Std) (kJ/kg) 5.010e+004 5.010e+004
33 CO2 Loading --- ---
34 CO2 Apparent Mole Conc. (kgmole/m3) --- ---
35 CO2 Apparent Wt. Conc. (kgmol/kg) --- ---
36 LHV Mass Basis (Std) (kJ/kg) 4.718e+004 4.718e+004
37 Phase Fraction [Vol. Basis] 1.000 1.000
38 Phase Fraction [Mass Basis] 1.000 1.000
39 Phase Fraction [Act. Vol. Basis] 1.000 1.000
40 Mass Exergy (kJ/kg) 35.57 ---
41 Partial Pressure of CO2 (kPa) 0.0000 ---
42 Cost Based on Flow (Cost/s) 0.0000 0.0000
43 Act. Gas Flow (ACT_m3/h) 6265 6265
44 Avg. Liq. Density (kgmole/m3) 13.66 13.66
45 Specific Heat (kJ/kgmole-C) 44.29 44.29
46 Std. Gas Flow (STD_m3/h) 9162 9162
47 Std. Ideal Liq. Mass Density (kg/m3) 383.2 383.2
48 Act. Liq. Flow (m3/s) --- ---
49 Z Factor 0.9912 0.9912
50 Watson K 17.53 17.53
51 User Property --- ---
52 Partial Pressure of H2S (kPa) 0.0000 ---
53 Cp/(Cp - R) 1.231 1.231
54 Cp/Cv 1.242 1.242
55 Ideal Gas Cp/Cv 1.233 1.233
56 Ideal Gas Cp (kJ/kgmole-C) 43.93 43.93
57 Mass Ideal Gas Cp (kJ/kg-C) 1.566 1.566
58 Heat of Vap. (kJ/kgmole) 1.336e+004 ---
59 Kinematic Viscosity (cSt) 5.875 5.875
60 Liq. Mass Density (Std. Cond) (kg/m3) 1.194 1.194
61 Liq. Vol. Flow (Std. Cond) (m3/h) 9103 9103
62 Liquid Fraction 0.0000 0.0000
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 12 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 2 (continued) Property Package: SRK
8
9
10
PROPERTIES
11 Overall Vapour Phase
12 Molar Volume (m3/kgmole) 16.17 16.17
13 Mass Heat of Vap. (kJ/kg) 476.1 ---
14 Phase Fraction [Molar Basis] 1.0000 1.0000
15 Surface Tension (dyne/cm) --- ---
16 Thermal Conductivity (W/m-K) 2.146e-002 2.146e-002
17 Bubble Point Pressure (kPa) --- ---
18 Viscosity (cP) 1.019e-002 1.019e-002
19 Cv (Semi-Ideal) (kJ/kgmole-C) 35.98 35.98
20 Mass Cv (Semi-Ideal) (kJ/kg-C) 1.282 1.282
21 Cv (kJ/kgmole-C) 35.66 35.66
22 Mass Cv (kJ/kg-C) 1.271 1.271
23 Cv (Ent. Method) (kJ/kgmole-C) --- ---
24 Mass Cv (Ent. Method) (kJ/kg-C) --- ---
25 Cp/Cv (Ent. Method) --- ---
26 Reid VP at 37.8 C (kPa) --- ---
27 True VP at 37.8 C (kPa) --- ---
28 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 9103 9103
29 Viscosity Index -8.904 ---
30
31
COMPOSITION
32
33
Overall Phase Vapour Fraction 1.0000

34 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
35 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
36 Ethylene 387.5000 1.0000 10870.8477 1.0000 28.3667 1.0000
37 Cl2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 12-ClC2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 HCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 VinylCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
41 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
42 Oxygen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
43 Nitrogen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
44 Total 387.5000 1.0000 10870.8477 1.0000 28.3667 1.0000
45
46
Vapour Phase Phase Fraction 1.000

47 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
48 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
49 Ethylene 387.5000 1.0000 10870.8477 1.0000 28.3667 1.0000
50 Cl2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
51 12-ClC2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
52 HCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
53 VinylCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
54 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
55 Oxygen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
56 Nitrogen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
57 Total 387.5000 1.0000 10870.8477 1.0000 28.3667 1.0000
58
59
K VALUE
60 COMPONENTS MIXED LIGHT HEAVY
61 Ethylene --- --- ---
62 Cl2 --- --- ---
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 13 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 2 (continued) Property Package: SRK
8
9
10
K VALUE
11 COMPONENTS MIXED LIGHT HEAVY
12 12-ClC2 --- --- ---
13 HCl --- --- ---
14 VinylCl --- --- ---
15 H2O --- --- ---
16 Oxygen --- --- ---
17 Nitrogen --- --- ---
18
19
UNIT OPERATIONS
20 FEED TO PRODUCT FROM LOGICAL CONNECTION
21 Mixer: MIX-101 Tee: TEE-100
22
23
UTILITIES
24 ( No utilities reference this stream )
25
26
PROCESS UTILITY
27
28
29
DYNAMICS
30 Pressure Specification (Inactive): 152.0 kPa
31 Flow Specification (Inactive) Molar: 387.5 kgmole/h Mass: 1.087e+004 kg/h Std Ideal Liq Volume: 28.37 m3/h
32
33
User Variables
34
35
NOTES
36
37
38
Description
39
40
Fluid Package: Basis-1
41 Material Stream: 3 Property Package: SRK
42
43
44
CONDITIONS
45 Overall Vapour Phase
46 Vapour / Phase Fraction 1.0000 1.0000
47 Temperature: (C) 24.96 24.96
48 Pressure: (kPa) 152.0 152.0
49 Molar Flow (kgmole/h) 755.5 755.5
50 Mass Flow (kg/h) 3.696e+004 3.696e+004
51 Std Ideal Liq Vol Flow (m3/h) 45.08 45.08
52 Molar Enthalpy (kJ/kgmole) 2.675e+004 2.675e+004
53 Molar Entropy (kJ/kgmole-C) 187.4 187.4
54 Heat Flow (kJ/h) 2.021e+007 2.021e+007
55 Liq Vol Flow @Std Cond (m3/h) 45.24 * 45.24
56
57
PROPERTIES
58 Overall Vapour Phase
59 Molecular Weight 48.93 48.93
60 Molar Density (kgmole/m3) 6.211e-002 6.211e-002
61 Mass Density (kg/m3) 3.039 3.039
62 Act. Volume Flow (m3/h) 1.216e+004 1.216e+004
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 14 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 3 (continued) Property Package: SRK
8
9
10
PROPERTIES
11 Overall Vapour Phase
12 Mass Enthalpy (kJ/kg) 546.7 546.7
13 Mass Entropy (kJ/kg-C) 3.830 3.830
14 Heat Capacity (kJ/kgmole-C) 39.55 39.55
15 Mass Heat Capacity (kJ/kg-C) 0.8084 0.8084
16 LHV Molar Basis (Std) (kJ/kgmole) --- ---
17 HHV Molar Basis (Std) (kJ/kgmole) --- ---
18 HHV Mass Basis (Std) (kJ/kg) --- ---
19 CO2 Loading --- ---
20 CO2 Apparent Mole Conc. (kgmole/m3) --- ---
21 CO2 Apparent Wt. Conc. (kgmol/kg) --- ---
22 LHV Mass Basis (Std) (kJ/kg) --- ---
23 Phase Fraction [Vol. Basis] 1.000 1.000
24 Phase Fraction [Mass Basis] 1.000 1.000
25 Phase Fraction [Act. Vol. Basis] 1.000 1.000
26 Mass Exergy (kJ/kg) 20.33 ---
27 Partial Pressure of CO2 (kPa) 0.0000 ---
28 Cost Based on Flow (Cost/s) 0.0000 0.0000
29 Act. Gas Flow (ACT_m3/h) 1.216e+004 1.216e+004
30 Avg. Liq. Density (kgmole/m3) 16.76 16.76
31 Specific Heat (kJ/kgmole-C) 39.55 39.55
32 Std. Gas Flow (STD_m3/h) 1.786e+004 1.786e+004
33 Std. Ideal Liq. Mass Density (kg/m3) 820.0 820.0
34 Act. Liq. Flow (m3/s) --- ---
35 Z Factor 0.9873 0.9873
36 Watson K 8.635 8.635
37 User Property --- ---
38 Partial Pressure of H2S (kPa) 0.0000 ---
39 Cp/(Cp - R) 1.266 1.266
40 Cp/Cv 1.283 1.283
41 Ideal Gas Cp/Cv 1.270 1.270
42 Ideal Gas Cp (kJ/kgmole-C) 39.10 39.10
43 Mass Ideal Gas Cp (kJ/kg-C) 0.7991 0.7991
44 Heat of Vap. (kJ/kgmole) 1.899e+004 ---
45 Kinematic Viscosity (cSt) 3.840 3.840
46 Liq. Mass Density (Std. Cond) (kg/m3) 817.1 817.1
47 Liq. Vol. Flow (Std. Cond) (m3/h) 45.24 45.24
48 Liquid Fraction 0.0000 0.0000
49 Molar Volume (m3/kgmole) 16.10 16.10
50 Mass Heat of Vap. (kJ/kg) 388.1 ---
51 Phase Fraction [Molar Basis] 1.0000 1.0000
52 Surface Tension (dyne/cm) --- ---
53 Thermal Conductivity (W/m-K) 1.454e-002 1.454e-002
54 Bubble Point Pressure (kPa) 3708 ---
55 Viscosity (cP) 1.167e-002 1.167e-002
56 Cv (Semi-Ideal) (kJ/kgmole-C) 31.24 31.24
57 Mass Cv (Semi-Ideal) (kJ/kg-C) 0.6385 0.6385
58 Cv (kJ/kgmole-C) 30.84 30.84
59 Mass Cv (kJ/kg-C) 0.6302 0.6302
60 Cv (Ent. Method) (kJ/kgmole-C) --- ---
61 Mass Cv (Ent. Method) (kJ/kg-C) --- ---
62 Cp/Cv (Ent. Method) --- ---
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 15 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 3 (continued) Property Package: SRK
8
9
10
PROPERTIES
11 Overall Vapour Phase
12 Reid VP at 37.8 C (kPa) 3889 3889
13 True VP at 37.8 C (kPa) 4571 4571
14 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 45.24 45.24
15 Viscosity Index --- ---
16
17
COMPOSITION
18
19
Overall Phase Vapour Fraction 1.0000

20 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
21 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
22 Ethylene 387.5000 0.5129 10870.8477 0.2941 28.3667 0.6293
23 Cl2 368.0000 0.4871 26093.2979 0.7059 16.7123 0.3707
24 12-ClC2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
25 HCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
26 VinylCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
27 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
28 Oxygen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
29 Nitrogen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
30 Total 755.5000 1.0000 36964.1456 1.0000 45.0790 1.0000
31
32
Vapour Phase Phase Fraction 1.000

33 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
34 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
35 Ethylene 387.5000 0.5129 10870.8477 0.2941 28.3667 0.6293
36 Cl2 368.0000 0.4871 26093.2979 0.7059 16.7123 0.3707
37 12-ClC2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 HCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 VinylCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
41 Oxygen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
42 Nitrogen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
43 Total 755.5000 1.0000 36964.1456 1.0000 45.0790 1.0000
44
45
K VALUE
46 COMPONENTS MIXED LIGHT HEAVY
47 Ethylene --- --- ---
48 Cl2 --- --- ---
49 12-ClC2 --- --- ---
50 HCl --- --- ---
51 VinylCl --- --- ---
52 H2O --- --- ---
53 Oxygen --- --- ---
54 Nitrogen --- --- ---
55
56
UNIT OPERATIONS
57 FEED TO PRODUCT FROM LOGICAL CONNECTION
58 Heater: E-100 Mixer: MIX-100
59
60
UTILITIES
61 ( No utilities reference this stream )
62
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 16 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 3 (continued) Property Package: SRK
8
9
10
PROCESS UTILITY
11
12
13
DYNAMICS
14 Pressure Specification (Inactive): 152.0 kPa
15 Flow Specification (Inactive) Molar: 755.5 kgmole/h Mass: 3.696e+004 kg/h Std Ideal Liq Volume: 45.08 m3/h
16
17
User Variables
18
19
NOTES
20
21
22
Description
23
24
Fluid Package: Basis-1
25 Material Stream: 4 Property Package: SRK
26
27
28
CONDITIONS
29 Overall Vapour Phase
30 Vapour / Phase Fraction 1.0000 1.0000
31 Temperature: (C) 36.47 36.47
32 Pressure: (kPa) 152.0 152.0
33 Molar Flow (kgmole/h) 2894 2894
34 Mass Flow (kg/h) 9.483e+004 9.483e+004
35 Std Ideal Liq Vol Flow (m3/h) 125.0 125.0
36 Molar Enthalpy (kJ/kgmole) -4.048e+004 -4.048e+004
37 Molar Entropy (kJ/kgmole-C) 171.0 171.0
38 Heat Flow (kJ/h) -1.172e+008 -1.172e+008
39 Liq Vol Flow @Std Cond (m3/h) 6.820e+004 * 6.820e+004
40
41
PROPERTIES
42 Overall Vapour Phase
43 Molecular Weight 32.76 32.76
44 Molar Density (kgmole/m3) 5.929e-002 5.929e-002
45 Mass Density (kg/m3) 1.942 1.942
46 Act. Volume Flow (m3/h) 4.882e+004 4.882e+004
47 Mass Enthalpy (kJ/kg) -1235 -1235
48 Mass Entropy (kJ/kg-C) 5.220 5.220
49 Heat Capacity (kJ/kgmole-C) 31.73 31.73
50 Mass Heat Capacity (kJ/kg-C) 0.9685 0.9685
51 LHV Molar Basis (Std) (kJ/kgmole) 1.946e+005 1.946e+005
52 HHV Molar Basis (Std) (kJ/kgmole) 2.057e+005 2.057e+005
53 HHV Mass Basis (Std) (kJ/kg) 6278 6278
54 CO2 Loading --- ---
55 CO2 Apparent Mole Conc. (kgmole/m3) --- ---
56 CO2 Apparent Wt. Conc. (kgmol/kg) --- ---
57 LHV Mass Basis (Std) (kJ/kg) 5939 5939
58 Phase Fraction [Vol. Basis] 1.000 1.000
59 Phase Fraction [Mass Basis] 1.000 1.000
60 Phase Fraction [Act. Vol. Basis] 1.000 1.000
61 Mass Exergy (kJ/kg) 30.77 ---
62 Partial Pressure of CO2 (kPa) 0.0000 ---
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 17 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 4 (continued) Property Package: SRK
8
9
10
PROPERTIES
11 Overall Vapour Phase
12 Cost Based on Flow (Cost/s) 0.0000 0.0000
13 Act. Gas Flow (ACT_m3/h) 4.882e+004 4.882e+004
14 Avg. Liq. Density (kgmole/m3) 23.15 23.15
15 Specific Heat (kJ/kgmole-C) 31.73 31.73
16 Std. Gas Flow (STD_m3/h) 6.844e+004 6.844e+004
17 Std. Ideal Liq. Mass Density (kg/m3) 758.6 758.6
18 Act. Liq. Flow (m3/s) --- ---
19 Z Factor 0.9959 0.9959
20 Watson K 8.483 8.483
21 User Property --- ---
22 Partial Pressure of H2S (kPa) 0.0000 ---
23 Cp/(Cp - R) 1.355 1.355
24 Cp/Cv 1.365 1.365
25 Ideal Gas Cp/Cv 1.358 1.358
26 Ideal Gas Cp (kJ/kgmole-C) 31.53 31.53
27 Mass Ideal Gas Cp (kJ/kg-C) 0.9622 0.9622
28 Heat of Vap. (kJ/kgmole) 1.812e+004 ---
29 Kinematic Viscosity (cSt) 7.813 7.813
30 Liq. Mass Density (Std. Cond) (kg/m3) 1.391 1.391
31 Liq. Vol. Flow (Std. Cond) (m3/h) 6.820e+004 6.820e+004
32 Liquid Fraction 0.0000 0.0000
33 Molar Volume (m3/kgmole) 16.87 16.87
34 Mass Heat of Vap. (kJ/kg) 553.1 ---
35 Phase Fraction [Molar Basis] 1.0000 1.0000
36 Surface Tension (dyne/cm) --- ---
37 Thermal Conductivity (W/m-K) 2.126e-002 2.126e-002
38 Bubble Point Pressure (kPa) --- ---
39 Viscosity (cP) 1.518e-002 1.518e-002
40 Cv (Semi-Ideal) (kJ/kgmole-C) 23.42 23.42
41 Mass Cv (Semi-Ideal) (kJ/kg-C) 0.7147 0.7147
42 Cv (kJ/kgmole-C) 23.24 23.24
43 Mass Cv (kJ/kg-C) 0.7094 0.7094
44 Cv (Ent. Method) (kJ/kgmole-C) --- ---
45 Mass Cv (Ent. Method) (kJ/kg-C) --- ---
46 Cp/Cv (Ent. Method) --- ---
47 Reid VP at 37.8 C (kPa) --- ---
48 True VP at 37.8 C (kPa) --- ---
49 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 6.820e+004 6.820e+004
50 Viscosity Index -9.054 ---
51
52
COMPOSITION
53
54
Overall Phase Vapour Fraction 1.0000

55 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
56 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
57 Ethylene 387.5000 0.1339 10870.8477 0.1146 28.3667 0.2269
58 Cl2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
59 12-ClC2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
60 HCl 1500.6101 0.5184 54713.4435 0.5769 62.8652 0.5029
61 VinylCl 6.3723 0.0022 398.2182 0.0042 0.4332 0.0035
62 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 18 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 4 (continued) Property Package: SRK
8
9
10
COMPOSITION
11
12
Overall Phase (continued) Vapour Fraction 1.0000

13 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
14 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
15 Oxygen 210.0000 0.0726 6720.0000 0.0709 5.9068 0.0472
16 Nitrogen 790.0000 0.2729 22130.2704 0.2334 27.4442 0.2195
17 Total 2894.4824 1.0000 94832.7798 1.0000 125.0160 1.0000
18
19
Vapour Phase Phase Fraction 1.000

20 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
21 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
22 Ethylene 387.5000 0.1339 10870.8477 0.1146 28.3667 0.2269
23 Cl2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
24 12-ClC2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
25 HCl 1500.6101 0.5184 54713.4435 0.5769 62.8652 0.5029
26 VinylCl 6.3723 0.0022 398.2182 0.0042 0.4332 0.0035
27 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
28 Oxygen 210.0000 0.0726 6720.0000 0.0709 5.9068 0.0472
29 Nitrogen 790.0000 0.2729 22130.2704 0.2334 27.4442 0.2195
30 Total 2894.4824 1.0000 94832.7798 1.0000 125.0160 1.0000
31
32
K VALUE
33 COMPONENTS MIXED LIGHT HEAVY
34 Ethylene --- --- ---
35 Cl2 --- --- ---
36 12-ClC2 --- --- ---
37 HCl --- --- ---
38 VinylCl --- --- ---
39 H2O --- --- ---
40 Oxygen --- --- ---
41 Nitrogen --- --- ---
42
43
UNIT OPERATIONS
44 FEED TO PRODUCT FROM LOGICAL CONNECTION
45 Compressor: K-100 Mixer: MIX-101
46
47
UTILITIES
48 ( No utilities reference this stream )
49
50
PROCESS UTILITY
51
52
53
DYNAMICS
54 Pressure Specification (Inactive): 152.0 kPa
55 Flow Specification (Inactive) Molar: 2894 kgmole/h Mass: 9.483e+004 kg/h Std Ideal Liq Volume: 125.0 m3/h
56
57
User Variables
58
59
NOTES
60
61
62
Description
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 19 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 4 (continued) Property Package: SRK
8
9
10
Fluid Package: Basis-1
11 Material Stream: 5 Property Package: SRK
12
13
14
CONDITIONS
15 Overall Vapour Phase
16 Vapour / Phase Fraction 1.0000 1.0000
17 Temperature: (C) 155.2 155.2
18 Pressure: (kPa) 405.3 * 405.3
19 Molar Flow (kgmole/h) 2894 2894
20 Mass Flow (kg/h) 9.483e+004 9.483e+004
21 Std Ideal Liq Vol Flow (m3/h) 125.0 125.0
22 Molar Enthalpy (kJ/kgmole) -3.665e+004 -3.665e+004
23 Molar Entropy (kJ/kgmole-C) 173.3 173.3
24 Heat Flow (kJ/h) -1.061e+008 -1.061e+008
25 Liq Vol Flow @Std Cond (m3/h) 6.820e+004 * 6.820e+004
26
27
PROPERTIES
28 Overall Vapour Phase
29 Molecular Weight 32.76 32.76
30 Molar Density (kgmole/m3) 0.1141 0.1141
31 Mass Density (kg/m3) 3.739 3.739
32 Act. Volume Flow (m3/h) 2.536e+004 2.536e+004
33 Mass Enthalpy (kJ/kg) -1119 -1119
34 Mass Entropy (kJ/kg-C) 5.290 5.290
35 Heat Capacity (kJ/kgmole-C) 33.43 33.43
36 Mass Heat Capacity (kJ/kg-C) 1.020 1.020
37 LHV Molar Basis (Std) (kJ/kgmole) 1.946e+005 1.946e+005
38 HHV Molar Basis (Std) (kJ/kgmole) 2.057e+005 2.057e+005
39 HHV Mass Basis (Std) (kJ/kg) 6278 6278
40 CO2 Loading --- ---
41 CO2 Apparent Mole Conc. (kgmole/m3) --- ---
42 CO2 Apparent Wt. Conc. (kgmol/kg) --- ---
43 LHV Mass Basis (Std) (kJ/kg) 5939 5939
44 Phase Fraction [Vol. Basis] 1.000 1.000
45 Phase Fraction [Mass Basis] 1.000 1.000
46 Phase Fraction [Act. Vol. Basis] 1.000 1.000
47 Mass Exergy (kJ/kg) 126.4 ---
48 Partial Pressure of CO2 (kPa) 0.0000 ---
49 Cost Based on Flow (Cost/s) 0.0000 0.0000
50 Act. Gas Flow (ACT_m3/h) 2.536e+004 2.536e+004
51 Avg. Liq. Density (kgmole/m3) 23.15 23.15
52 Specific Heat (kJ/kgmole-C) 33.43 33.43
53 Std. Gas Flow (STD_m3/h) 6.844e+004 6.844e+004
54 Std. Ideal Liq. Mass Density (kg/m3) 758.6 758.6
55 Act. Liq. Flow (m3/s) --- ---
56 Z Factor 0.9972 0.9972
57 Watson K 8.483 8.483
58 User Property --- ---
59 Partial Pressure of H2S (kPa) 0.0000 ---
60 Cp/(Cp - R) 1.331 1.331
61 Cp/Cv 1.342 1.342
62 Ideal Gas Cp/Cv 1.334 1.334
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 20 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 5 (continued) Property Package: SRK
8
9
10
PROPERTIES
11 Overall Vapour Phase
12 Ideal Gas Cp (kJ/kgmole-C) 33.17 33.17
13 Mass Ideal Gas Cp (kJ/kg-C) 1.013 1.013
14 Heat of Vap. (kJ/kgmole) 1.798e+004 ---
15 Kinematic Viscosity (cSt) 5.558 5.558
16 Liq. Mass Density (Std. Cond) (kg/m3) 1.391 1.391
17 Liq. Vol. Flow (Std. Cond) (m3/h) 6.820e+004 6.820e+004
18 Liquid Fraction 0.0000 0.0000
19 Molar Volume (m3/kgmole) 8.763 8.763
20 Mass Heat of Vap. (kJ/kg) 548.9 ---
21 Phase Fraction [Molar Basis] 1.0000 1.0000
22 Surface Tension (dyne/cm) --- ---
23 Thermal Conductivity (W/m-K) 2.914e-002 2.914e-002
24 Bubble Point Pressure (kPa) --- ---
25 Viscosity (cP) 2.078e-002 2.078e-002
26 Cv (Semi-Ideal) (kJ/kgmole-C) 25.12 25.12
27 Mass Cv (Semi-Ideal) (kJ/kg-C) 0.7667 0.7667
28 Cv (kJ/kgmole-C) 24.91 24.91
29 Mass Cv (kJ/kg-C) 0.7604 0.7604
30 Cv (Ent. Method) (kJ/kgmole-C) --- ---
31 Mass Cv (Ent. Method) (kJ/kg-C) --- ---
32 Cp/Cv (Ent. Method) --- ---
33 Reid VP at 37.8 C (kPa) --- ---
34 True VP at 37.8 C (kPa) --- ---
35 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 6.820e+004 6.820e+004
36 Viscosity Index -10.01 ---
37
38
COMPOSITION
39
40
Overall Phase Vapour Fraction 1.0000

41 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
42 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
43 Ethylene 387.5000 0.1339 10870.8477 0.1146 28.3667 0.2269
44 Cl2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
45 12-ClC2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
46 HCl 1500.6101 0.5184 54713.4435 0.5769 62.8652 0.5029
47 VinylCl 6.3723 0.0022 398.2182 0.0042 0.4332 0.0035
48 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
49 Oxygen 210.0000 0.0726 6720.0000 0.0709 5.9068 0.0472
50 Nitrogen 790.0000 0.2729 22130.2704 0.2334 27.4442 0.2195
51 Total 2894.4824 1.0000 94832.7798 1.0000 125.0160 1.0000
52
53
Vapour Phase Phase Fraction 1.000

54 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
55 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
56 Ethylene 387.5000 0.1339 10870.8477 0.1146 28.3667 0.2269
57 Cl2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
58 12-ClC2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
59 HCl 1500.6101 0.5184 54713.4435 0.5769 62.8652 0.5029
60 VinylCl 6.3723 0.0022 398.2182 0.0042 0.4332 0.0035
61 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
62 Oxygen 210.0000 0.0726 6720.0000 0.0709 5.9068 0.0472
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 21 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 5 (continued) Property Package: SRK
8
9
10
COMPOSITION
11
12
Vapour Phase (continued) Phase Fraction 1.000

13 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
14 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
15 Nitrogen 790.0000 0.2729 22130.2704 0.2334 27.4442 0.2195
16 Total 2894.4824 1.0000 94832.7798 1.0000 125.0160 1.0000
17
18
K VALUE
19 COMPONENTS MIXED LIGHT HEAVY
20 Ethylene --- --- ---
21 Cl2 --- --- ---
22 12-ClC2 --- --- ---
23 HCl --- --- ---
24 VinylCl --- --- ---
25 H2O --- --- ---
26 Oxygen --- --- ---
27 Nitrogen --- --- ---
28
29
UNIT OPERATIONS
30 FEED TO PRODUCT FROM LOGICAL CONNECTION
31 Heater: E-101 Compressor: K-100
32
33
UTILITIES
34 ( No utilities reference this stream )
35
36
PROCESS UTILITY
37
38
39
DYNAMICS
40 Pressure Specification (Active): 405.3 kPa *
41 Flow Specification (Inactive) Molar: 2894 kgmole/h Mass: 9.483e+004 kg/h Std Ideal Liq Volume: 125.0 m3/h
42
43
User Variables
44
45
NOTES
46
47
48
Description
49
50
Fluid Package: Basis-1
51 Material Stream: 6 Property Package: SRK
52
53
54
CONDITIONS
55 Overall Vapour Phase Liquid Phase
56 Vapour / Phase Fraction 1.0000 1.0000 0.0000
57 Temperature: (C) 60.00 60.00 60.00
58 Pressure: (kPa) 152.0 152.0 152.0
59 Molar Flow (kgmole/h) 22.33 22.33 0.0000
60 Mass Flow (kg/h) 1049 1049 0.0000
61 Std Ideal Liq Vol Flow (m3/h) 1.670 1.670 0.0000
62 Molar Enthalpy (kJ/kgmole) 5545 5545 -1.600e+005
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 22 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 6 (continued) Property Package: SRK
8
9
10
CONDITIONS
11 Overall Vapour Phase Liquid Phase
12 Molar Entropy (kJ/kgmole-C) 200.6 200.6 152.7
13 Heat Flow (kJ/h) 1.238e+005 1.238e+005 0.0000
14 Liq Vol Flow @Std Cond (m3/h) 1.547 * 1.547 0.0000
15
16
PROPERTIES
17 Overall Vapour Phase Liquid Phase
18 Molecular Weight 46.97 46.97 98.35
19 Molar Density (kgmole/m3) 5.563e-002 5.563e-002 12.00
20 Mass Density (kg/m3) 2.613 2.613 1181
21 Act. Volume Flow (m3/h) 401.5 401.5 0.0000
22 Mass Enthalpy (kJ/kg) 118.1 118.1 -1626
23 Mass Entropy (kJ/kg-C) 4.271 4.271 1.553
24 Heat Capacity (kJ/kgmole-C) 56.86 56.86 130.1
25 Mass Heat Capacity (kJ/kg-C) 1.210 1.210 1.323
26 LHV Molar Basis (Std) (kJ/kgmole) --- --- ---
27 HHV Molar Basis (Std) (kJ/kgmole) --- --- ---
28 HHV Mass Basis (Std) (kJ/kg) --- --- ---
29 CO2 Loading --- --- ---
30 CO2 Apparent Mole Conc. (kgmole/m3) --- --- ---
31 CO2 Apparent Wt. Conc. (kgmol/kg) --- --- ---
32 LHV Mass Basis (Std) (kJ/kg) --- --- ---
33 Phase Fraction [Vol. Basis] 1.000 1.000 ---
34 Phase Fraction [Mass Basis] 1.000 1.000 0.0000
35 Phase Fraction [Act. Vol. Basis] 1.000 1.000 0.0000
36 Mass Exergy (kJ/kg) 30.55 --- ---
37 Partial Pressure of CO2 (kPa) 0.0000 --- ---
38 Cost Based on Flow (Cost/s) 0.0000 0.0000 0.0000
39 Act. Gas Flow (ACT_m3/h) 401.5 401.5 ---
40 Avg. Liq. Density (kgmole/m3) 13.37 13.37 12.64
41 Specific Heat (kJ/kgmole-C) 56.86 56.86 130.1
42 Std. Gas Flow (STD_m3/h) 528.0 528.0 0.0000
43 Std. Ideal Liq. Mass Density (kg/m3) 628.1 628.1 1243
44 Act. Liq. Flow (m3/s) --- --- ---
45 Z Factor --- 0.9864 4.571e-003
46 Watson K 11.60 11.60 6.915
47 User Property --- --- ---
48 Partial Pressure of H2S (kPa) 0.0000 --- ---
49 Cp/(Cp - R) 1.171 1.171 1.068
50 Cp/Cv 1.182 1.182 1.068
51 Ideal Gas Cp/Cv 1.173 1.173 1.112
52 Ideal Gas Cp (kJ/kgmole-C) 56.33 56.33 82.48
53 Mass Ideal Gas Cp (kJ/kg-C) 1.199 1.199 0.8387
54 Heat of Vap. (kJ/kgmole) 2.833e+004 --- ---
55 Kinematic Viscosity (cSt) 4.245 4.245 0.4161
56 Liq. Mass Density (Std. Cond) (kg/m3) 678.0 678.0 1246
57 Liq. Vol. Flow (Std. Cond) (m3/h) 1.547 1.547 0.0000
58 Liquid Fraction 0.0000 0.0000 1.000
59 Molar Volume (m3/kgmole) 17.98 17.98 8.330e-002
60 Mass Heat of Vap. (kJ/kg) 603.2 --- ---
61 Phase Fraction [Molar Basis] 1.0000 1.0000 0.0000
62 Surface Tension (dyne/cm) --- --- 26.23
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 23 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 6 (continued) Property Package: SRK
8
9
10
PROPERTIES
11 Overall Vapour Phase Liquid Phase
12 Thermal Conductivity (W/m-K) 1.989e-002 1.989e-002 0.1170
13 Bubble Point Pressure (kPa) 9187 --- ---
14 Viscosity (cP) 1.109e-002 1.109e-002 0.4912
15 Cv (Semi-Ideal) (kJ/kgmole-C) 48.54 48.54 121.8
16 Mass Cv (Semi-Ideal) (kJ/kg-C) 1.033 1.033 1.239
17 Cv (kJ/kgmole-C) 48.08 48.08 121.8
18 Mass Cv (kJ/kg-C) 1.024 1.024 1.239
19 Cv (Ent. Method) (kJ/kgmole-C) --- --- ---
20 Mass Cv (Ent. Method) (kJ/kg-C) --- --- ---
21 Cp/Cv (Ent. Method) --- --- ---
22 Reid VP at 37.8 C (kPa) 5147 5147 54.81
23 True VP at 37.8 C (kPa) 6820 6820 105.2
24 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 1.547 1.547 0.0000
25 Viscosity Index --- --- ---
26
27
COMPOSITION
28
29
Overall Phase Vapour Fraction 1.0000

30 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
31 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
32 Ethylene 16.3716 0.7331 459.2863 0.4378 1.1985 0.7176
33 Cl2 0.0045 0.0002 0.3203 0.0003 0.0002 0.0001
34 12-ClC2 5.9562 0.2667 589.4258 0.5619 0.4715 0.2823
35 HCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
36 VinylCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
37 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 Oxygen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 Nitrogen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 Total 22.3324 1.0000 1049.0324 1.0000 1.6702 1.0000
41
42
Vapour Phase Phase Fraction 1.000

43 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
44 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
45 Ethylene 16.3716 0.7331 459.2863 0.4378 1.1985 0.7176
46 Cl2 0.0045 0.0002 0.3203 0.0003 0.0002 0.0001
47 12-ClC2 5.9562 0.2667 589.4258 0.5619 0.4715 0.2823
48 HCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
49 VinylCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
50 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
51 Oxygen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
52 Nitrogen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
53 Total 22.3324 1.0000 1049.0324 1.0000 1.6702 1.0000
54
55
Liquid Phase Phase Fraction 0.0000

56 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
57 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
58 Ethylene 0.0000 0.0086 0.0000 0.0025 0.0000 0.0080
59 Cl2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
60 12-ClC2 0.0000 0.9914 0.0000 0.9975 0.0000 0.9920
61 HCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
62 VinylCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 24 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 6 (continued) Property Package: SRK
8
9
10
COMPOSITION
11
12
Liquid Phase (continued) Phase Fraction 0.0000

13 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
14 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
15 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
16 Oxygen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
17 Nitrogen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
19
20
K VALUE
21 COMPONENTS MIXED LIGHT HEAVY
22 Ethylene 85.25 85.25 ---
23 Cl2 10.08 10.08 ---
24 12-ClC2 0.2690 0.2690 ---
25 HCl 0.0000 0.0000 ---
26 VinylCl 0.0000 0.0000 ---
27 H2O 0.0000 0.0000 ---
28 Oxygen 0.0000 0.0000 ---
29 Nitrogen 0.0000 0.0000 ---
30
31
UNIT OPERATIONS
32 FEED TO PRODUCT FROM LOGICAL CONNECTION
33 Mixer: MIX-102 Cont. Stirred Tank Reactor: Reactor-1 Set: SET-1
34
35
UTILITIES
36 ( No utilities reference this stream )
37
38
PROCESS UTILITY
39
40
41
DYNAMICS
42 Pressure Specification (Inactive): 152.0 kPa
43 Flow Specification (Inactive) Molar: 22.33 kgmole/h Mass: 1049 kg/h Std Ideal Liq Volume: 1.670 m3/h
44
45
User Variables
46
47
NOTES
48
49
50
Description
51
52
Fluid Package: Basis-1
53 Material Stream: 7 Property Package: SRK
54
55
56
CONDITIONS
57 Overall Vapour Phase Liquid Phase
58 Vapour / Phase Fraction 0.0000 0.0000 1.0000
59 Temperature: (C) 60.00 60.00 60.00
60 Pressure: (kPa) 152.0 152.0 152.0
61 Molar Flow (kgmole/h) 365.2 0.0000 365.2
62 Mass Flow (kg/h) 3.592e+004 0.0000 3.592e+004
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 25 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 7 (continued) Property Package: SRK
8
9
10
CONDITIONS
11 Overall Vapour Phase Liquid Phase
12 Std Ideal Liq Vol Flow (m3/h) 28.89 0.0000 28.89
13 Molar Enthalpy (kJ/kgmole) -1.600e+005 5545 -1.600e+005
14 Molar Entropy (kJ/kgmole-C) 152.7 200.6 152.7
15 Heat Flow (kJ/h) -5.841e+007 0.0000 -5.841e+007
16 Liq Vol Flow @Std Cond (m3/h) 28.82 * 0.0000 28.82
17
18
PROPERTIES
19 Overall Vapour Phase Liquid Phase
20 Molecular Weight 98.35 46.97 98.35
21 Molar Density (kgmole/m3) 12.00 5.563e-002 12.00
22 Mass Density (kg/m3) 1181 2.613 1181
23 Act. Volume Flow (m3/h) 30.42 0.0000 30.42
24 Mass Enthalpy (kJ/kg) -1626 118.1 -1626
25 Mass Entropy (kJ/kg-C) 1.553 4.271 1.553
26 Heat Capacity (kJ/kgmole-C) 130.1 56.86 130.1
27 Mass Heat Capacity (kJ/kg-C) 1.323 1.210 1.323
28 LHV Molar Basis (Std) (kJ/kgmole) --- --- ---
29 HHV Molar Basis (Std) (kJ/kgmole) --- --- ---
30 HHV Mass Basis (Std) (kJ/kg) --- --- ---
31 CO2 Loading --- --- ---
32 CO2 Apparent Mole Conc. (kgmole/m3) --- --- ---
33 CO2 Apparent Wt. Conc. (kgmol/kg) --- --- ---
34 LHV Mass Basis (Std) (kJ/kg) --- --- ---
35 Phase Fraction [Vol. Basis] --- --- 1.000
36 Phase Fraction [Mass Basis] 0.0000 0.0000 1.000
37 Phase Fraction [Act. Vol. Basis] 0.0000 0.0000 1.000
38 Mass Exergy (kJ/kg) 2.526 --- ---
39 Partial Pressure of CO2 (kPa) 0.0000 --- ---
40 Cost Based on Flow (Cost/s) 0.0000 0.0000 0.0000
41 Act. Gas Flow (ACT_m3/h) --- --- ---
42 Avg. Liq. Density (kgmole/m3) 12.64 13.37 12.64
43 Specific Heat (kJ/kgmole-C) 130.1 56.86 130.1
44 Std. Gas Flow (STD_m3/h) 8634 0.0000 8634
45 Std. Ideal Liq. Mass Density (kg/m3) 1243 628.1 1243
46 Act. Liq. Flow (m3/s) 8.450e-003 --- 8.450e-003
47 Z Factor --- 0.9864 4.571e-003
48 Watson K 6.915 11.60 6.915
49 User Property --- --- ---
50 Partial Pressure of H2S (kPa) 0.0000 --- ---
51 Cp/(Cp - R) 1.068 1.171 1.068
52 Cp/Cv 1.068 1.182 1.068
53 Ideal Gas Cp/Cv 1.112 1.173 1.112
54 Ideal Gas Cp (kJ/kgmole-C) 82.48 56.33 82.48
55 Mass Ideal Gas Cp (kJ/kg-C) 0.8387 1.199 0.8387
56 Heat of Vap. (kJ/kgmole) 3.764e+004 --- ---
57 Kinematic Viscosity (cSt) 0.4161 4.245 0.4161
58 Liq. Mass Density (Std. Cond) (kg/m3) 1246 678.0 1246
59 Liq. Vol. Flow (Std. Cond) (m3/h) 28.82 0.0000 28.82
60 Liquid Fraction 1.000 0.0000 1.000
61 Molar Volume (m3/kgmole) 8.330e-002 17.98 8.330e-002
62 Mass Heat of Vap. (kJ/kg) 382.7 --- ---
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 26 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 7 (continued) Property Package: SRK
8
9
10
PROPERTIES
11 Overall Vapour Phase Liquid Phase
12 Phase Fraction [Molar Basis] 0.0000 0.0000 1.0000
13 Surface Tension (dyne/cm) 26.23 --- 26.23
14 Thermal Conductivity (W/m-K) 0.1170 1.989e-002 0.1170
15 Bubble Point Pressure (kPa) 152.0 --- ---
16 Viscosity (cP) 0.4912 1.109e-002 0.4912
17 Cv (Semi-Ideal) (kJ/kgmole-C) 121.8 48.54 121.8
18 Mass Cv (Semi-Ideal) (kJ/kg-C) 1.239 1.033 1.239
19 Cv (kJ/kgmole-C) 121.8 48.08 121.8
20 Mass Cv (kJ/kg-C) 1.239 1.024 1.239
21 Cv (Ent. Method) (kJ/kgmole-C) --- --- ---
22 Mass Cv (Ent. Method) (kJ/kg-C) --- --- ---
23 Cp/Cv (Ent. Method) --- --- ---
24 Reid VP at 37.8 C (kPa) 54.81 5147 54.81
25 True VP at 37.8 C (kPa) 105.2 6820 105.2
26 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 28.82 0.0000 28.82
27 Viscosity Index -12.74 --- ---
28
29
COMPOSITION
30
31
Overall Phase Vapour Fraction 0.0000

32 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
33 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
34 Ethylene 3.1402 0.0086 88.0950 0.0025 0.2299 0.0080
35 Cl2 0.0073 0.0000 0.5194 0.0000 0.0003 0.0000
36 12-ClC2 362.0319 0.9914 35826.6090 0.9975 28.6613 0.9920
37 HCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 VinylCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 Oxygen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
41 Nitrogen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
42 Total 365.1795 1.0000 35915.2233 1.0000 28.8915 1.0000
43
44
Vapour Phase Phase Fraction 0.0000

45 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
46 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
47 Ethylene 0.0000 0.7331 0.0000 0.4378 0.0000 0.7176
48 Cl2 0.0000 0.0002 0.0000 0.0003 0.0000 0.0001
49 12-ClC2 0.0000 0.2667 0.0000 0.5619 0.0000 0.2823
50 HCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
51 VinylCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
52 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
53 Oxygen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
54 Nitrogen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
55 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
56
57
Liquid Phase Phase Fraction 1.000

58 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
59 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
60 Ethylene 3.1402 0.0086 88.0950 0.0025 0.2299 0.0080
61 Cl2 0.0073 0.0000 0.5194 0.0000 0.0003 0.0000
62 12-ClC2 362.0319 0.9914 35826.6090 0.9975 28.6613 0.9920
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 27 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 7 (continued) Property Package: SRK
8
9
10
COMPOSITION
11
12
Liquid Phase (continued) Phase Fraction 1.000

13 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
14 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
15 HCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
16 VinylCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
17 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 Oxygen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Nitrogen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
20 Total 365.1795 1.0000 35915.2233 1.0000 28.8915 1.0000
21
22
K VALUE
23 COMPONENTS MIXED LIGHT HEAVY
24 Ethylene 85.25 85.25 ---
25 Cl2 10.08 10.08 ---
26 12-ClC2 0.2690 0.2690 ---
27 HCl 0.0000 0.0000 ---
28 VinylCl 0.0000 0.0000 ---
29 H2O 0.0000 0.0000 ---
30 Oxygen 0.0000 0.0000 ---
31 Nitrogen 0.0000 0.0000 ---
32
33
UNIT OPERATIONS
34 FEED TO PRODUCT FROM LOGICAL CONNECTION
35 Mixer: MIX-102 Cont. Stirred Tank Reactor: Reactor-1
36
37
UTILITIES
38 ( No utilities reference this stream )
39
40
PROCESS UTILITY
41
42
43
DYNAMICS
44 Pressure Specification (Inactive): 152.0 kPa
45 Flow Specification (Inactive) Molar: 365.2 kgmole/h Mass: 3.592e+004 kg/h Std Ideal Liq Volume: 28.89 m3/h
46
47
User Variables
48
49
NOTES
50
51
52
Description
53
54
Fluid Package: Basis-1
55 Material Stream: 8 Property Package: SRK
56
57
58
CONDITIONS
59 Overall Vapour Phase Liquid Phase
60 Vapour / Phase Fraction 0.0576 0.0576 0.9424
61 Temperature: (C) 60.00 60.00 60.00
62 Pressure: (kPa) 152.0 152.0 152.0
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 28 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 8 (continued) Property Package: SRK
8
9
10
CONDITIONS
11 Overall Vapour Phase Liquid Phase
12 Molar Flow (kgmole/h) 387.5 22.33 365.2
13 Mass Flow (kg/h) 3.696e+004 1049 3.592e+004
14 Std Ideal Liq Vol Flow (m3/h) 30.56 1.670 28.89
15 Molar Enthalpy (kJ/kgmole) -1.504e+005 5545 -1.600e+005
16 Molar Entropy (kJ/kgmole-C) 155.5 200.6 152.7
17 Heat Flow (kJ/h) -5.829e+007 1.238e+005 -5.841e+007
18 Liq Vol Flow @Std Cond (m3/h) 30.23 * 1.547 28.82
19
20
PROPERTIES
21 Overall Vapour Phase Liquid Phase
22 Molecular Weight 95.39 46.97 98.35
23 Molar Density (kgmole/m3) 0.8972 5.563e-002 12.00
24 Mass Density (kg/m3) 85.59 2.613 1181
25 Act. Volume Flow (m3/h) 431.9 401.5 30.42
26 Mass Enthalpy (kJ/kg) -1577 118.1 -1626
27 Mass Entropy (kJ/kg-C) 1.630 4.271 1.553
28 Heat Capacity (kJ/kgmole-C) 125.9 56.86 130.1
29 Mass Heat Capacity (kJ/kg-C) 1.320 1.210 1.323
30 LHV Molar Basis (Std) (kJ/kgmole) --- --- ---
31 HHV Molar Basis (Std) (kJ/kgmole) --- --- ---
32 HHV Mass Basis (Std) (kJ/kg) --- --- ---
33 CO2 Loading --- --- ---
34 CO2 Apparent Mole Conc. (kgmole/m3) --- --- ---
35 CO2 Apparent Wt. Conc. (kgmol/kg) --- --- ---
36 LHV Mass Basis (Std) (kJ/kg) --- --- ---
37 Phase Fraction [Vol. Basis] 5.465e-002 5.465e-002 0.9453
38 Phase Fraction [Mass Basis] 2.838e-002 2.838e-002 0.9716
39 Phase Fraction [Act. Vol. Basis] 0.9296 0.9296 7.043e-002
40 Mass Exergy (kJ/kg) 3.325 --- ---
41 Partial Pressure of CO2 (kPa) 0.0000 --- ---
42 Cost Based on Flow (Cost/s) 0.0000 0.0000 0.0000
43 Act. Gas Flow (ACT_m3/h) 401.5 401.5 ---
44 Avg. Liq. Density (kgmole/m3) 12.68 13.37 12.64
45 Specific Heat (kJ/kgmole-C) 125.9 56.86 130.1
46 Std. Gas Flow (STD_m3/h) 9162 528.0 8634
47 Std. Ideal Liq. Mass Density (kg/m3) 1209 628.1 1243
48 Act. Liq. Flow (m3/s) 8.450e-003 --- 8.450e-003
49 Z Factor --- 0.9864 4.571e-003
50 Watson K 7.050 11.60 6.915
51 User Property --- --- ---
52 Partial Pressure of H2S (kPa) 0.0000 --- ---
53 Cp/(Cp - R) 1.071 1.171 1.068
54 Cp/Cv 1.004 1.182 1.068
55 Ideal Gas Cp/Cv 1.114 1.173 1.112
56 Ideal Gas Cp (kJ/kgmole-C) 80.98 56.33 82.48
57 Mass Ideal Gas Cp (kJ/kg-C) 0.8489 1.199 0.8387
58 Heat of Vap. (kJ/kgmole) 4.773e+004 --- ---
59 Kinematic Viscosity (cSt) --- 4.245 0.4161
60 Liq. Mass Density (Std. Cond) (kg/m3) 1223 678.0 1246
61 Liq. Vol. Flow (Std. Cond) (m3/h) 30.23 1.547 28.82
62 Liquid Fraction 0.9424 0.0000 1.000
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 29 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 8 (continued) Property Package: SRK
8
9
10
PROPERTIES
11 Overall Vapour Phase Liquid Phase
12 Molar Volume (m3/kgmole) 1.115 17.98 8.330e-002
13 Mass Heat of Vap. (kJ/kg) 500.4 --- ---
14 Phase Fraction [Molar Basis] 0.0576 0.0576 0.9424
15 Surface Tension (dyne/cm) 26.23 --- 26.23
16 Thermal Conductivity (W/m-K) --- 1.989e-002 0.1170
17 Bubble Point Pressure (kPa) 699.2 --- ---
18 Viscosity (cP) --- 1.109e-002 0.4912
19 Cv (Semi-Ideal) (kJ/kgmole-C) 117.6 48.54 121.8
20 Mass Cv (Semi-Ideal) (kJ/kg-C) 1.233 1.033 1.239
21 Cv (kJ/kgmole-C) 125.4 48.08 121.8
22 Mass Cv (kJ/kg-C) 1.314 1.024 1.239
23 Cv (Ent. Method) (kJ/kgmole-C) --- --- ---
24 Mass Cv (Ent. Method) (kJ/kg-C) --- --- ---
25 Cp/Cv (Ent. Method) --- --- ---
26 Reid VP at 37.8 C (kPa) 249.0 5147 54.81
27 True VP at 37.8 C (kPa) 539.6 6820 105.2
28 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 30.37 1.547 28.82
29 Viscosity Index -14.06 --- ---
30
31
COMPOSITION
32
33
Overall Phase Vapour Fraction 0.0576

34 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
35 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
36 Ethylene 19.5118 0.0504 547.3813 0.0148 1.4284 0.0467
37 Cl2 0.0118 0.0000 0.8397 0.0000 0.0005 0.0000
38 12-ClC2 367.9882 0.9496 36416.0347 0.9852 29.1328 0.9532
39 HCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 VinylCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
41 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
42 Oxygen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
43 Nitrogen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
44 Total 387.5118 1.0000 36964.2558 1.0000 30.5617 1.0000
45
46
Vapour Phase Phase Fraction 5.763e-002

47 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
48 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
49 Ethylene 16.3716 0.7331 459.2863 0.4378 1.1985 0.7176
50 Cl2 0.0045 0.0002 0.3203 0.0003 0.0002 0.0001
51 12-ClC2 5.9562 0.2667 589.4260 0.5619 0.4715 0.2823
52 HCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
53 VinylCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
54 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
55 Oxygen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
56 Nitrogen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
57 Total 22.3324 1.0000 1049.0326 1.0000 1.6702 1.0000
58
59
Liquid Phase Phase Fraction 0.9424

60 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
61 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
62 Ethylene 3.1402 0.0086 88.0950 0.0025 0.2299 0.0080
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 30 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 8 (continued) Property Package: SRK
8
9
10
COMPOSITION
11
12
Liquid Phase (continued) Phase Fraction 0.9424

13 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
14 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
15 Cl2 0.0073 0.0000 0.5194 0.0000 0.0003 0.0000
16 12-ClC2 362.0319 0.9914 35826.6088 0.9975 28.6613 0.9920
17 HCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 VinylCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
20 Oxygen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
21 Nitrogen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
22 Total 365.1795 1.0000 35915.2231 1.0000 28.8915 1.0000
23
24
K VALUE
25 COMPONENTS MIXED LIGHT HEAVY
26 Ethylene 85.25 85.25 ---
27 Cl2 10.08 10.08 ---
28 12-ClC2 0.2690 0.2690 ---
29 HCl 0.0000 0.0000 ---
30 VinylCl 0.0000 0.0000 ---
31 H2O 0.0000 0.0000 ---
32 Oxygen 0.0000 0.0000 ---
33 Nitrogen 0.0000 0.0000 ---
34
35
UNIT OPERATIONS
36 FEED TO PRODUCT FROM LOGICAL CONNECTION
37 Mixer: MIX-103 Mixer: MIX-102
38
39
UTILITIES
40 ( No utilities reference this stream )
41
42
PROCESS UTILITY
43
44
45
DYNAMICS
46 Pressure Specification (Inactive): 152.0 kPa
47 Flow Specification (Inactive) Molar: 387.5 kgmole/h Mass: 3.696e+004 kg/h Std Ideal Liq Volume: 30.56 m3/h
48
49
User Variables
50
51
NOTES
52
53
54
Description
55
56
Fluid Package: Basis-1
57 Material Stream: 9 Property Package: SRK
58
59
60
CONDITIONS
61 Overall Vapour Phase Aqueous Phase
62 Vapour / Phase Fraction 1.0000 1.0000 0.0000
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 31 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 9 (continued) Property Package: SRK
8
9
10
CONDITIONS
11 Overall Vapour Phase Aqueous Phase
12 Temperature: (C) 225.0 225.0 225.0
13 Pressure: (kPa) 405.3 405.3 405.3
14 Molar Flow (kgmole/h) 2313 2313 0.0000
15 Mass Flow (kg/h) 9.483e+004 9.483e+004 0.0000
16 Std Ideal Liq Vol Flow (m3/h) 96.40 96.40 0.0000
17 Molar Enthalpy (kJ/kgmole) -8.304e+004 -8.304e+004 -2.578e+005
18 Molar Entropy (kJ/kgmole-C) 195.6 195.6 104.5
19 Heat Flow (kJ/h) -1.921e+008 -1.921e+008 0.0000
20 Liq Vol Flow @Std Cond (m3/h) 121.9 * 121.9 0.0000
21
22
PROPERTIES
23 Overall Vapour Phase Aqueous Phase
24 Molecular Weight 41.00 41.00 20.71
25 Molar Density (kgmole/m3) 9.836e-002 9.836e-002 29.61
26 Mass Density (kg/m3) 4.033 4.033 613.1
27 Act. Volume Flow (m3/h) 2.352e+004 2.352e+004 0.0000
28 Mass Enthalpy (kJ/kg) -2026 -2026 -1.245e+004
29 Mass Entropy (kJ/kg-C) 4.772 4.772 5.044
30 Heat Capacity (kJ/kgmole-C) 43.76 43.76 99.10
31 Mass Heat Capacity (kJ/kg-C) 1.068 1.068 4.785
32 LHV Molar Basis (Std) (kJ/kgmole) 1.973e+005 1.973e+005 2.872e+004
33 HHV Molar Basis (Std) (kJ/kgmole) 2.180e+005 2.180e+005 6.922e+004
34 HHV Mass Basis (Std) (kJ/kg) 5319 5319 3343
35 CO2 Loading --- --- ---
36 CO2 Apparent Mole Conc. (kgmole/m3) --- --- ---
37 CO2 Apparent Wt. Conc. (kgmol/kg) --- --- ---
38 LHV Mass Basis (Std) (kJ/kg) 4812 4812 1387
39 Phase Fraction [Vol. Basis] 1.000 1.000 ---
40 Phase Fraction [Mass Basis] 1.000 1.000 0.0000
41 Phase Fraction [Act. Vol. Basis] 1.000 1.000 0.0000
42 Mass Exergy (kJ/kg) 143.6 --- ---
43 Partial Pressure of CO2 (kPa) 0.0000 --- ---
44 Cost Based on Flow (Cost/s) 0.0000 0.0000 0.0000
45 Act. Gas Flow (ACT_m3/h) 2.352e+004 2.352e+004 ---
46 Avg. Liq. Density (kgmole/m3) 23.99 23.99 48.89
47 Specific Heat (kJ/kgmole-C) 43.76 43.76 99.10
48 Std. Gas Flow (STD_m3/h) 5.470e+004 5.470e+004 0.0000
49 Std. Ideal Liq. Mass Density (kg/m3) 983.7 983.7 1012
50 Act. Liq. Flow (m3/s) 0.0000 --- 0.0000
51 Z Factor --- 0.9948 3.305e-003
52 Watson K 7.011 7.011 7.169
53 User Property --- --- ---
54 Partial Pressure of H2S (kPa) 0.0000 --- ---
55 Cp/(Cp - R) 1.235 1.235 1.092
56 Cp/Cv 1.245 1.245 1.092
57 Ideal Gas Cp/Cv 1.237 1.237 1.292
58 Ideal Gas Cp (kJ/kgmole-C) 43.41 43.41 36.82
59 Mass Ideal Gas Cp (kJ/kg-C) 1.059 1.059 1.778
60 Heat of Vap. (kJ/kgmole) 3.698e+004 --- ---
61 Kinematic Viscosity (cSt) 5.459 5.459 0.1278
62 Liq. Mass Density (Std. Cond) (kg/m3) 777.9 777.9 1049
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 32 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 9 (continued) Property Package: SRK
8
9
10
PROPERTIES
11 Overall Vapour Phase Aqueous Phase
12 Liq. Vol. Flow (Std. Cond) (m3/h) 121.9 121.9 0.0000
13 Liquid Fraction 0.0000 0.0000 1.000
14 Molar Volume (m3/kgmole) 10.17 10.17 3.378e-002
15 Mass Heat of Vap. (kJ/kg) 902.1 --- ---
16 Phase Fraction [Molar Basis] 1.0000 1.0000 0.0000
17 Surface Tension (dyne/cm) --- --- 30.19
18 Thermal Conductivity (W/m-K) 3.035e-002 3.035e-002 0.5750
19 Bubble Point Pressure (kPa) --- --- ---
20 Viscosity (cP) 2.201e-002 2.201e-002 7.833e-002
21 Cv (Semi-Ideal) (kJ/kgmole-C) 35.45 35.45 90.79
22 Mass Cv (Semi-Ideal) (kJ/kg-C) 0.8647 0.8647 4.384
23 Cv (kJ/kgmole-C) 35.16 35.16 90.79
24 Mass Cv (kJ/kg-C) 0.8576 0.8576 4.384
25 Cv (Ent. Method) (kJ/kgmole-C) --- --- ---
26 Mass Cv (Ent. Method) (kJ/kg-C) --- --- ---
27 Cp/Cv (Ent. Method) --- --- ---
28 Reid VP at 37.8 C (kPa) 1.350e+004 1.350e+004 3033
29 True VP at 37.8 C (kPa) 9.438e+004 9.438e+004 8127
30 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 121.9 121.9 0.0000
31 Viscosity Index -7.272 --- ---
32
33
COMPOSITION
34
35
Overall Phase Vapour Fraction 1.0000

36 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
37 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
38 Ethylene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 Cl2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 12-ClC2 387.5012 0.1675 38347.0388 0.4044 30.6776 0.3182
41 HCl 725.6079 0.3137 26456.2441 0.2790 30.3979 0.3153
42 VinylCl 6.3723 0.0028 398.2182 0.0042 0.4332 0.0045
43 H2O 387.5012 0.1675 6980.8726 0.0736 6.9950 0.0726
44 Oxygen 16.2494 0.0070 519.9814 0.0055 0.4571 0.0047
45 Nitrogen 790.0002 0.3415 22130.2765 0.2334 27.4442 0.2847
46 Total 2313.2322 1.0000 94832.6315 1.0000 96.4050 1.0000
47
48
Vapour Phase Phase Fraction 1.000

49 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
50 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
51 Ethylene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
52 Cl2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
53 12-ClC2 387.5012 0.1675 38347.0388 0.4044 30.6776 0.3182
54 HCl 725.6079 0.3137 26456.2441 0.2790 30.3979 0.3153
55 VinylCl 6.3723 0.0028 398.2182 0.0042 0.4332 0.0045
56 H2O 387.5012 0.1675 6980.8726 0.0736 6.9950 0.0726
57 Oxygen 16.2494 0.0070 519.9814 0.0055 0.4571 0.0047
58 Nitrogen 790.0002 0.3415 22130.2765 0.2334 27.4442 0.2847
59 Total 2313.2322 1.0000 94832.6315 1.0000 96.4050 1.0000
60
61
62
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 33 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 9 (continued) Property Package: SRK
8
9
10
COMPOSITION
11
12
Aqueous Phase Phase Fraction 0.0000

13 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
14 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
15 Ethylene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
16 Cl2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
17 12-ClC2 0.0000 0.0249 0.0000 0.1191 0.0000 0.0965
18 HCl 0.0000 0.0350 0.0000 0.0617 0.0000 0.0717
19 VinylCl 0.0000 0.0001 0.0000 0.0004 0.0000 0.0005
20 H2O 0.0000 0.9376 0.0000 0.8156 0.0000 0.8275
21 Oxygen 0.0000 0.0001 0.0000 0.0002 0.0000 0.0002
22 Nitrogen 0.0000 0.0021 0.0000 0.0029 0.0000 0.0036
23 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
24
25
K VALUE
26 COMPONENTS MIXED LIGHT HEAVY
27 Ethylene 0.0000 --- 0.0000
28 Cl2 0.0000 --- 0.0000
29 12-ClC2 6.719 --- 6.719
30 HCl 8.954 --- 8.954
31 VinylCl 19.24 --- 19.24
32 H2O 0.1787 --- 0.1787
33 Oxygen 53.26 --- 53.26
34 Nitrogen 159.2 --- 159.2
35
36
UNIT OPERATIONS
37 FEED TO PRODUCT FROM LOGICAL CONNECTION
38 Mixer: MIX-103 Plug Flow Reactor: Reactor-2 Set: SET-2
39
40
UTILITIES
41 ( No utilities reference this stream )
42
43
PROCESS UTILITY
44
45
46
DYNAMICS
47 Pressure Specification (Inactive): 405.3 kPa
48 Flow Specification (Inactive) Molar: 2313 kgmole/h Mass: 9.483e+004 kg/h Std Ideal Liq Volume: 96.40 m3/h
49
50
User Variables
51
52
NOTES
53
54
55
Description
56
57
58
59
60
61
62
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 34 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 10 Property Package: SRK
8
9
10
CONDITIONS
11 Overall Vapour Phase Liquid Phase
12 Vapour / Phase Fraction 0.8116 0.8116 0.1884
13 Temperature: (C) 66.20 66.20 66.20
14 Pressure: (kPa) 152.0 152.0 152.0
15 Molar Flow (kgmole/h) 3482 2826 656.1
16 Mass Flow (kg/h) 1.995e+005 1.413e+005 5.823e+004
17 Std Ideal Liq Vol Flow (m3/h) 181.9 135.0 46.93
18 Molar Enthalpy (kJ/kgmole) -1.100e+005 -9.514e+004 -1.739e+005
19 Molar Entropy (kJ/kgmole-C) 190.0 199.4 149.3
20 Heat Flow (kJ/h) -3.830e+008 -2.689e+008 -1.141e+008
21 Liq Vol Flow @Std Cond (m3/h) 191.2 * 149.2 46.80
22
23
PROPERTIES
24 Overall Vapour Phase Liquid Phase
25 Molecular Weight 57.29 49.98 88.75
26 Molar Density (kgmole/m3) 6.710e-002 5.451e-002 13.20
27 Mass Density (kg/m3) 3.844 2.725 1171
28 Act. Volume Flow (m3/h) 5.190e+004 5.185e+004 49.72
29 Mass Enthalpy (kJ/kg) -1920 -1903 -1959
30 Mass Entropy (kJ/kg-C) 3.316 3.990 1.682
31 Heat Capacity (kJ/kgmole-C) 61.47 46.81 124.6
32 Mass Heat Capacity (kJ/kg-C) 1.073 0.9364 1.404
33 LHV Molar Basis (Std) (kJ/kgmole) --- --- 9.647e+005
34 HHV Molar Basis (Std) (kJ/kgmole) --- --- 1.041e+006
35 HHV Mass Basis (Std) (kJ/kg) --- --- 1.173e+004
36 CO2 Loading --- --- ---
37 CO2 Apparent Mole Conc. (kgmole/m3) --- --- ---
38 CO2 Apparent Wt. Conc. (kgmol/kg) --- --- ---
39 LHV Mass Basis (Std) (kJ/kg) --- --- 1.087e+004
40 Phase Fraction [Vol. Basis] 0.7420 0.7420 0.2580
41 Phase Fraction [Mass Basis] 0.7081 0.7081 0.2919
42 Phase Fraction [Act. Vol. Basis] 0.9990 0.9990 9.581e-004
43 Mass Exergy (kJ/kg) 29.00 --- ---
44 Partial Pressure of CO2 (kPa) 0.0000 --- ---
45 Cost Based on Flow (Cost/s) 0.0000 0.0000 0.0000
46 Act. Gas Flow (ACT_m3/h) 5.185e+004 5.185e+004 ---
47 Avg. Liq. Density (kgmole/m3) 19.14 20.94 13.98
48 Specific Heat (kJ/kgmole-C) 61.47 46.81 124.6
49 Std. Gas Flow (STD_m3/h) 8.233e+004 6.682e+004 1.551e+004
50 Std. Ideal Liq. Mass Density (kg/m3) 1097 1046 1241
51 Act. Liq. Flow (m3/s) 1.381e-002 --- 1.381e-002
52 Z Factor --- 0.9883 4.082e-003
53 Watson K 6.926 6.977 6.889
54 User Property --- --- ---
55 Partial Pressure of H2S (kPa) 0.0000 --- ---
56 Cp/(Cp - R) 1.156 1.216 1.071
57 Cp/Cv 1.130 1.229 1.395
58 Ideal Gas Cp/Cv 1.190 1.219 1.120
59 Ideal Gas Cp (kJ/kgmole-C) 52.18 46.35 77.33
60 Mass Ideal Gas Cp (kJ/kg-C) 0.9109 0.9272 0.8712
61 Heat of Vap. (kJ/kgmole) 4.516e+004 --- ---
62 Kinematic Viscosity (cSt) --- 5.050 0.4053
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 35 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 10 (continued) Property Package: SRK
8
9
10
PROPERTIES
11 Overall Vapour Phase Liquid Phase
12 Liq. Mass Density (Std. Cond) (kg/m3) 1043 946.5 1244
13 Liq. Vol. Flow (Std. Cond) (m3/h) 191.2 149.2 46.80
14 Liquid Fraction 0.1884 0.0000 1.000
15 Molar Volume (m3/kgmole) 14.90 18.35 7.578e-002
16 Mass Heat of Vap. (kJ/kg) 788.2 --- ---
17 Phase Fraction [Molar Basis] 0.8116 0.8116 0.1884
18 Surface Tension (dyne/cm) 30.22 --- 30.22
19 Thermal Conductivity (W/m-K) --- 1.852e-002 0.1516
20 Bubble Point Pressure (kPa) 5.627e+004 --- ---
21 Viscosity (cP) --- 1.376e-002 0.4747
22 Cv (Semi-Ideal) (kJ/kgmole-C) 53.16 38.49 116.3
23 Mass Cv (Semi-Ideal) (kJ/kg-C) 0.9278 0.7701 1.310
24 Cv (kJ/kgmole-C) 54.39 38.09 89.33
25 Mass Cv (kJ/kg-C) 0.9494 0.7620 1.006
26 Cv (Ent. Method) (kJ/kgmole-C) --- --- 86.40
27 Mass Cv (Ent. Method) (kJ/kg-C) --- --- 0.9734
28 Cp/Cv (Ent. Method) --- --- 1.442
29 Reid VP at 37.8 C (kPa) 5078 7724 36.72
30 True VP at 37.8 C (kPa) 6.497e+004 8.215e+004 95.69
31 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 196.0 149.2 46.80
32 Viscosity Index --- --- ---
33
34
COMPOSITION
35
36
Overall Phase Vapour Fraction 0.8116

37 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
38 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
39 Ethylene 19.7898 0.0057 555.1792 0.0028 1.4487 0.0080
40 Cl2 0.0149 0.0000 1.0555 0.0000 0.0007 0.0000
41 12-ClC2 1409.4533 0.4048 139479.2218 0.6992 111.5834 0.6134
42 HCl 756.0767 0.2171 27567.1604 0.1382 31.6744 0.1741
43 VinylCl 8.7935 0.0025 549.5265 0.0028 0.5978 0.0033
44 H2O 481.1339 0.1382 8667.6759 0.0434 8.6852 0.0477
45 Oxygen 16.2792 0.0047 520.9338 0.0026 0.4579 0.0025
46 Nitrogen 790.6093 0.2270 22147.3399 0.1110 27.4653 0.1510
47 Total 3482.1507 1.0000 199488.0929 1.0000 181.9133 1.0000
48
49
Vapour Phase Phase Fraction 0.8116

50 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
51 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
52 Ethylene 19.7533 0.0070 554.1548 0.0039 1.4460 0.0107
53 Cl2 0.0146 0.0000 1.0348 0.0000 0.0007 0.0000
54 12-ClC2 836.9875 0.2962 82828.1135 0.5864 66.2625 0.4909
55 HCl 752.6421 0.2663 27441.9331 0.1943 31.5305 0.2336
56 VinylCl 8.5644 0.0030 535.2082 0.0038 0.5822 0.0043
57 H2O 401.3363 0.1420 7230.1136 0.0512 7.2447 0.0537
58 Oxygen 16.2725 0.0058 520.7216 0.0037 0.4577 0.0034
59 Nitrogen 790.4454 0.2797 22142.7467 0.1568 27.4596 0.2034
60 Total 2826.0161 1.0000 141254.0264 1.0000 134.9839 1.0000
61
62
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 36 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 10 (continued) Property Package: SRK
8
9
10
COMPOSITION
11
12
Liquid Phase Phase Fraction 0.1884

13 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
14 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
15 Ethylene 0.0365 0.0001 1.0244 0.0000 0.0027 0.0001
16 Cl2 0.0003 0.0000 0.0207 0.0000 0.0000 0.0000
17 12-ClC2 572.4659 0.8725 56651.1083 0.9728 45.3209 0.9657
18 HCl 3.4346 0.0052 125.2273 0.0022 0.1439 0.0031
19 VinylCl 0.2291 0.0003 14.3183 0.0002 0.0156 0.0003
20 H2O 79.7976 0.1216 1437.5622 0.0247 1.4405 0.0307
21 Oxygen 0.0066 0.0000 0.2122 0.0000 0.0002 0.0000
22 Nitrogen 0.1640 0.0002 4.5932 0.0001 0.0057 0.0001
23 Total 656.1346 1.0000 58234.0665 1.0000 46.9294 1.0000
24
25
K VALUE
26 COMPONENTS MIXED LIGHT HEAVY
27 Ethylene 125.6 125.6 ---
28 Cl2 11.63 11.63 ---
29 12-ClC2 0.3395 0.3395 ---
30 HCl 50.88 50.88 ---
31 VinylCl 8.679 8.679 ---
32 H2O 1.168 1.168 ---
33 Oxygen 569.8 569.8 ---
34 Nitrogen 1119 1119 ---
35
36
UNIT OPERATIONS
37 FEED TO PRODUCT FROM LOGICAL CONNECTION
38 Cooler: E-102 Mixer: MIX-103
39
40
UTILITIES
41 ( No utilities reference this stream )
42
43
PROCESS UTILITY
44
45
46
DYNAMICS
47 Pressure Specification (Inactive): 152.0 kPa
48 Flow Specification (Inactive) Molar: 3482 kgmole/h Mass: 1.995e+005 kg/h Std Ideal Liq Volume: 181.9 m3/h
49
50
User Variables
51
52
NOTES
53
54
55
Description
56
57
58
59
60
61
62
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 37 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 11 Property Package: SRK
8
9
10
CONDITIONS
11 Overall Vapour Phase Liquid Phase Aqueous Phase
12 Vapour / Phase Fraction 0.0000 0.0000 0.8029 0.1971
13 Temperature: (C) 15.00 15.00 15.00 15.00
14 Pressure: (kPa) 152.0 152.0 152.0 152.0
15 Molar Flow (kgmole/h) 1854 0.0000 1488 365.3
16 Mass Flow (kg/h) 1.439e+005 0.0000 1.373e+005 6583
17 Std Ideal Liq Vol Flow (m3/h) 117.2 0.0000 110.7 6.597
18 Molar Enthalpy (kJ/kgmole) -1.954e+005 -4.762e+004 -1.728e+005 -2.871e+005
19 Molar Entropy (kJ/kgmole-C) 116.0 165.6 132.0 50.60
20 Heat Flow (kJ/h) -3.621e+008 0.0000 -2.572e+008 -1.049e+008
21 Liq Vol Flow @Std Cond (m3/h) 116.3 * 0.0000 110.2 6.487
22
23
PROPERTIES
24 Overall Vapour Phase Liquid Phase Aqueous Phase
25 Molecular Weight 77.63 34.14 92.26 18.02
26 Molar Density (kgmole/m3) 15.88 6.374e-002 13.50 56.32
27 Mass Density (kg/m3) 1233 2.176 1246 1015
28 Act. Volume Flow (m3/h) 116.7 0.0000 110.2 6.487
29 Mass Enthalpy (kJ/kg) -2517 -1395 -1873 -1.593e+004
30 Mass Entropy (kJ/kg-C) 1.494 4.850 1.431 2.808
31 Heat Capacity (kJ/kgmole-C) 110.6 31.35 118.1 80.03
32 Mass Heat Capacity (kJ/kg-C) 1.424 0.9182 1.280 4.441
33 LHV Molar Basis (Std) (kJ/kgmole) --- --- --- 21.27
34 HHV Molar Basis (Std) (kJ/kgmole) --- --- --- 4.102e+004
35 HHV Mass Basis (Std) (kJ/kg) --- --- --- 2277
36 CO2 Loading --- --- --- ---
37 CO2 Apparent Mole Conc. (kgmole/m3) --- --- --- ---
38 CO2 Apparent Wt. Conc. (kgmol/kg) --- --- --- ---
39 LHV Mass Basis (Std) (kJ/kg) --- --- --- 1.181
40 Phase Fraction [Vol. Basis] --- --- 0.9437 5.626e-002
41 Phase Fraction [Mass Basis] 0.0000 0.0000 0.9542 4.575e-002
42 Phase Fraction [Act. Vol. Basis] 0.0000 0.0000 0.9444 5.559e-002
43 Mass Exergy (kJ/kg) 0.3357 --- --- ---
44 Partial Pressure of CO2 (kPa) 0.0000 --- --- ---
45 Cost Based on Flow (Cost/s) 0.0000 0.0000 0.0000 0.0000
46 Act. Gas Flow (ACT_m3/h) --- --- --- ---
47 Avg. Liq. Density (kgmole/m3) 15.81 25.19 13.45 55.38
48 Specific Heat (kJ/kgmole-C) 110.6 31.35 118.1 80.03
49 Std. Gas Flow (STD_m3/h) 4.383e+004 0.0000 3.519e+004 8638
50 Std. Ideal Liq. Mass Density (kg/m3) 1227 859.8 1241 998.0
51 Act. Liq. Flow (m3/s) 3.241e-002 --- 3.061e-002 1.802e-003
52 Z Factor --- 0.9953 4.698e-003 1.126e-003
53 Watson K 6.895 7.316 6.895 7.712
54 User Property --- --- --- ---
55 Partial Pressure of H2S (kPa) 0.0000 --- --- ---
56 Cp/(Cp - R) 1.081 1.361 1.076 1.116
57 Cp/Cv 1.377 1.373 1.434 1.136
58 Ideal Gas Cp/Cv 1.148 1.365 1.130 1.330
59 Ideal Gas Cp (kJ/kgmole-C) 64.55 31.12 72.17 33.52
60 Mass Ideal Gas Cp (kJ/kg-C) 0.8316 0.9116 0.7822 1.860
61 Heat of Vap. (kJ/kgmole) 4.294e+004 --- --- ---
62 Kinematic Viscosity (cSt) 0.8261 6.940 0.6693 1.119
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 38 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 11 (continued) Property Package: SRK
8
9
10
PROPERTIES
11 Overall Vapour Phase Liquid Phase Aqueous Phase
12 Liq. Mass Density (Std. Cond) (kg/m3) 1237 1.448 1246 1015
13 Liq. Vol. Flow (Std. Cond) (m3/h) 116.3 0.0000 110.2 6.487
14 Liquid Fraction 1.000 0.0000 1.000 1.000
15 Molar Volume (m3/kgmole) 6.296e-002 15.69 7.405e-002 1.776e-002
16 Mass Heat of Vap. (kJ/kg) 553.1 --- --- ---
17 Phase Fraction [Molar Basis] 0.0000 0.0000 0.8029 0.1971
18 Surface Tension (dyne/cm) --- --- 35.02 73.81
19 Thermal Conductivity (W/m-K) 0.1566 2.016e-002 0.1459 0.5953
20 Bubble Point Pressure (kPa) 151.9 --- --- ---
21 Viscosity (cP) 1.019 1.510e-002 0.8339 1.136
22 Cv (Semi-Ideal) (kJ/kgmole-C) 102.3 23.03 109.7 71.71
23 Mass Cv (Semi-Ideal) (kJ/kg-C) 1.317 0.6747 1.190 3.980
24 Cv (kJ/kgmole-C) 80.32 22.84 82.34 70.47
25 Mass Cv (kJ/kg-C) 1.035 0.6690 0.8925 3.911
26 Cv (Ent. Method) (kJ/kgmole-C) --- --- 83.50 67.90
27 Mass Cv (Ent. Method) (kJ/kg-C) --- --- 0.9051 3.768
28 Cp/Cv (Ent. Method) --- --- 1.414 1.179
29 Reid VP at 37.8 C (kPa) 88.57 --- 88.43 5659
30 True VP at 37.8 C (kPa) 196.9 --- 198.8 159.2
31 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 116.7 0.0000 110.2 6.487
32 Viscosity Index -1.771 --- --- ---
33
34
COMPOSITION
35
36
Overall Phase Vapour Fraction 0.0000

37 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
38 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
39 Ethylene 0.2779 0.0001 7.7958 0.0001 0.0203 0.0002
40 Cl2 0.0030 0.0000 0.2150 0.0000 0.0001 0.0000
41 12-ClC2 1356.7328 0.7320 134262.0031 0.9331 107.4096 0.9161
42 HCl 30.5391 0.0165 1113.4804 0.0077 1.2794 0.0109
43 VinylCl 2.3535 0.0013 147.0758 0.0010 0.1600 0.0014
44 H2O 463.0149 0.2498 8341.2601 0.0580 8.3581 0.0713
45 Oxygen 0.0298 0.0000 0.9529 0.0000 0.0008 0.0000
46 Nitrogen 0.6113 0.0003 17.1251 0.0001 0.0212 0.0002
47 Total 1853.5623 1.0000 143889.9083 1.0000 117.2496 1.0000
48
49
Vapour Phase Phase Fraction 0.0000

50 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
51 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
52 Ethylene 0.0000 0.0120 0.0000 0.0098 0.0000 0.0221
53 Cl2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
54 12-ClC2 0.0000 0.0324 0.0000 0.0938 0.0000 0.0645
55 HCl 0.0000 0.4455 0.0000 0.4758 0.0000 0.4700
56 VinylCl 0.0000 0.0040 0.0000 0.0072 0.0000 0.0068
57 H2O 0.0000 0.0111 0.0000 0.0059 0.0000 0.0051
58 Oxygen 0.0000 0.0100 0.0000 0.0094 0.0000 0.0071
59 Nitrogen 0.0000 0.4851 0.0000 0.3980 0.0000 0.4244
60 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
61
62
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 39 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 11 (continued) Property Package: SRK
8
9
10
COMPOSITION
11
12
Liquid Phase Phase Fraction 0.8029

13 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
14 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
15 Ethylene 0.2779 0.0002 7.7958 0.0001 0.0203 0.0002
16 Cl2 0.0030 0.0000 0.2149 0.0000 0.0001 0.0000
17 12-ClC2 1356.7273 0.9116 134261.4617 0.9778 107.4092 0.9707
18 HCl 30.4790 0.0205 1111.2898 0.0081 1.2769 0.0115
19 VinylCl 2.3535 0.0016 147.0754 0.0011 0.1600 0.0014
20 H2O 97.7405 0.0657 1760.8046 0.0128 1.7644 0.0159
21 Oxygen 0.0298 0.0000 0.9526 0.0000 0.0008 0.0000
22 Nitrogen 0.6097 0.0004 17.0785 0.0001 0.0212 0.0002
23 Total 1488.2207 1.0000 137306.6732 1.0000 110.6529 1.0000
24
25
Aqueous Phase Phase Fraction 0.1971

26 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
27 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
28 Ethylene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
29 Cl2 0.0000 0.0000 0.0002 0.0000 0.0000 0.0000
30 12-ClC2 0.0055 0.0000 0.5414 0.0001 0.0004 0.0001
31 HCl 0.0601 0.0002 2.1907 0.0003 0.0025 0.0004
32 VinylCl 0.0000 0.0000 0.0005 0.0000 0.0000 0.0000
33 H2O 365.2744 0.9998 6580.4555 0.9996 6.5937 0.9995
34 Oxygen 0.0000 0.0000 0.0003 0.0000 0.0000 0.0000
35 Nitrogen 0.0017 0.0000 0.0465 0.0000 0.0001 0.0000
36 Total 365.3417 1.0000 6583.2351 1.0000 6.5967 1.0000
37
38
K VALUE
39 COMPONENTS MIXED LIGHT HEAVY
40 Ethylene 79.92 64.16 2.077e+009
41 Cl2 4.448 3.574 1146
42 12-ClC2 4.423e-002 3.551e-002 2162
43 HCl 27.04 21.75 2709
44 VinylCl 3.114 2.501 1.836e+005
45 H2O 4.454e-002 0.1694 1.113e-002
46 Oxygen 621.1 498.8 3.783e+005
47 Nitrogen 1471 1184 1.067e+005
48
49
UNIT OPERATIONS
50 FEED TO PRODUCT FROM LOGICAL CONNECTION
51 Liquid-Liquid Extractor: EDC extractor Separator: Flash
52
53
UTILITIES
54 ( No utilities reference this stream )
55
56
PROCESS UTILITY
57
58
59
DYNAMICS
60 Pressure Specification (Inactive): 152.0 kPa
61 Flow Specification (Inactive) Molar: 1854 kgmole/h Mass: 1.439e+005 kg/h Std Ideal Liq Volume: 117.2 m3/h
62
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 40 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 11 (continued) Property Package: SRK
8
9
10
User Variables
11
12
NOTES
13
14
15
Description
16
17
Fluid Package: Basis-1
18 Material Stream: 12 Property Package: SRK
19
20
21
CONDITIONS
22 Overall Aqueous Phase
23 Vapour / Phase Fraction 0.0000 1.0000
24 Temperature: (C) 15.02 15.02
25 Pressure: (kPa) 405.3 * 405.3
26 Molar Flow (kgmole/h) 100.0 100.0
27 Mass Flow (kg/h) 1802 1802
28 Std Ideal Liq Vol Flow (m3/h) 1.805 1.805
29 Molar Enthalpy (kJ/kgmole) -2.871e+005 -2.871e+005
30 Molar Entropy (kJ/kgmole-C) 50.57 50.57
31 Heat Flow (kJ/h) -2.871e+007 -2.871e+007
32 Liq Vol Flow @Std Cond (m3/h) 1.775 * 1.775
33
34
PROPERTIES
35 Overall Aqueous Phase
36 Molecular Weight 18.02 18.02
37 Molar Density (kgmole/m3) 56.34 56.34
38 Mass Density (kg/m3) 1015 1015
39 Act. Volume Flow (m3/h) 1.775 1.775
40 Mass Enthalpy (kJ/kg) -1.594e+004 -1.594e+004
41 Mass Entropy (kJ/kg-C) 2.807 2.807
42 Heat Capacity (kJ/kgmole-C) 80.03 80.03
43 Mass Heat Capacity (kJ/kg-C) 4.442 4.442
44 LHV Molar Basis (Std) (kJ/kgmole) 0.0000 0.0000
45 HHV Molar Basis (Std) (kJ/kgmole) 4.101e+004 4.101e+004
46 HHV Mass Basis (Std) (kJ/kg) 2276 2276
47 CO2 Loading --- ---
48 CO2 Apparent Mole Conc. (kgmole/m3) --- ---
49 CO2 Apparent Wt. Conc. (kgmol/kg) --- ---
50 LHV Mass Basis (Std) (kJ/kg) 0.0000 0.0000
51 Phase Fraction [Vol. Basis] 0.0000 1.000
52 Phase Fraction [Mass Basis] 0.0000 1.000
53 Phase Fraction [Act. Vol. Basis] 0.0000 1.000
54 Mass Exergy (kJ/kg) 1.162 ---
55 Partial Pressure of CO2 (kPa) 0.0000 ---
56 Cost Based on Flow (Cost/s) 0.0000 0.0000
57 Act. Gas Flow (ACT_m3/h) --- ---
58 Avg. Liq. Density (kgmole/m3) 55.40 55.40
59 Specific Heat (kJ/kgmole-C) 80.03 80.03
60 Std. Gas Flow (STD_m3/h) 2364 2364
61 Std. Ideal Liq. Mass Density (kg/m3) 998.0 998.0
62 Act. Liq. Flow (m3/s) 4.931e-004 4.931e-004
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 41 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 12 (continued) Property Package: SRK
8
9
10
PROPERTIES
11 Overall Aqueous Phase
12 Z Factor 3.003e-003 3.003e-003
13 Watson K --- ---
14 User Property --- ---
15 Partial Pressure of H2S (kPa) 0.0000 ---
16 Cp/(Cp - R) 1.116 1.116
17 Cp/Cv 1.136 1.136
18 Ideal Gas Cp/Cv 1.330 1.330
19 Ideal Gas Cp (kJ/kgmole-C) 33.52 33.52
20 Mass Ideal Gas Cp (kJ/kg-C) 1.861 1.861
21 Heat of Vap. (kJ/kgmole) 3.871e+004 ---
22 Kinematic Viscosity (cSt) 1.119 1.119
23 Liq. Mass Density (Std. Cond) (kg/m3) 1015 1015
24 Liq. Vol. Flow (Std. Cond) (m3/h) 1.775 1.775
25 Liquid Fraction 1.000 1.000
26 Molar Volume (m3/kgmole) 1.775e-002 1.775e-002
27 Mass Heat of Vap. (kJ/kg) 2149 ---
28 Phase Fraction [Molar Basis] 0.0000 1.0000
29 Surface Tension (dyne/cm) 73.82 73.82
30 Thermal Conductivity (W/m-K) 0.5954 0.5954
31 Bubble Point Pressure (kPa) 1.653 ---
32 Viscosity (cP) 1.135 1.135
33 Cv (Semi-Ideal) (kJ/kgmole-C) 71.71 71.71
34 Mass Cv (Semi-Ideal) (kJ/kg-C) 3.981 3.981
35 Cv (kJ/kgmole-C) 70.47 70.47
36 Mass Cv (kJ/kg-C) 3.912 3.912
37 Cv (Ent. Method) (kJ/kgmole-C) --- ---
38 Mass Cv (Ent. Method) (kJ/kg-C) --- ---
39 Cp/Cv (Ent. Method) --- ---
40 Reid VP at 37.8 C (kPa) --- ---
41 True VP at 37.8 C (kPa) --- ---
42 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 1.775 1.775
43 Viscosity Index 4.751 ---
44
45
COMPOSITION
46
47
Overall Phase Vapour Fraction 0.0000

48 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
49 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
50 Ethylene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
51 Cl2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
52 12-ClC2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
53 HCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
54 VinylCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
55 H2O 100.0000 1.0000 1801.5100 1.0000 1.8051 1.0000
56 Oxygen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
57 Nitrogen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
58 Total 100.0000 1.0000 1801.5100 1.0000 1.8051 1.0000
59
60
61
62
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 42 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 12 (continued) Property Package: SRK
8
9
10
COMPOSITION
11
12
Aqueous Phase Phase Fraction 1.000

13 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
14 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
15 Ethylene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
16 Cl2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
17 12-ClC2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 HCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 VinylCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
20 H2O 100.0000 1.0000 1801.5100 1.0000 1.8051 1.0000
21 Oxygen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
22 Nitrogen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
23 Total 100.0000 1.0000 1801.5100 1.0000 1.8051 1.0000
24
25
K VALUE
26 COMPONENTS MIXED LIGHT HEAVY
27 Ethylene 0.0000 --- 0.0000
28 Cl2 0.0000 --- 0.0000
29 12-ClC2 0.0000 --- 0.0000
30 HCl 0.0000 --- 0.0000
31 VinylCl 0.0000 --- 0.0000
32 H2O 0.0000 --- 0.0000
33 Oxygen 0.0000 --- 0.0000
34 Nitrogen 0.0000 --- 0.0000
35
36
UNIT OPERATIONS
37 FEED TO PRODUCT FROM LOGICAL CONNECTION
38 Liquid-Liquid Extractor: EDC extractor Pump: P-100
39
40
UTILITIES
41 ( No utilities reference this stream )
42
43
PROCESS UTILITY
44
45
46
DYNAMICS
47 Pressure Specification (Active): 405.3 kPa *
48 Flow Specification (Inactive) Molar: 100.0 kgmole/h Mass: 1802 kg/h Std Ideal Liq Volume: 1.805 m3/h
49
50
User Variables
51
52
NOTES
53
54
55
Description
56
57
58
59
60
61
62
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 43 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 13 Property Package: SRK
8
9
10
CONDITIONS
11 Overall Liquid Phase
12 Vapour / Phase Fraction 0.0000 1.0000
13 Temperature: (C) 14.90 14.90
14 Pressure: (kPa) 405.3 405.3
15 Molar Flow (kgmole/h) 1488 1488
16 Mass Flow (kg/h) 1.373e+005 1.373e+005
17 Std Ideal Liq Vol Flow (m3/h) 110.6 110.6
18 Molar Enthalpy (kJ/kgmole) -1.728e+005 -1.728e+005
19 Molar Entropy (kJ/kgmole-C) 132.0 132.0
20 Heat Flow (kJ/h) -2.571e+008 -2.571e+008
21 Liq Vol Flow @Std Cond (m3/h) 110.2 * 110.2
22
23
PROPERTIES
24 Overall Liquid Phase
25 Molecular Weight 92.27 92.27
26 Molar Density (kgmole/m3) 13.51 13.51
27 Mass Density (kg/m3) 1246 1246
28 Act. Volume Flow (m3/h) 110.2 110.2
29 Mass Enthalpy (kJ/kg) -1873 -1873
30 Mass Entropy (kJ/kg-C) 1.430 1.430
31 Heat Capacity (kJ/kgmole-C) 118.0 118.0
32 Mass Heat Capacity (kJ/kg-C) 1.279 1.279
33 LHV Molar Basis (Std) (kJ/kgmole) --- ---
34 HHV Molar Basis (Std) (kJ/kgmole) --- ---
35 HHV Mass Basis (Std) (kJ/kg) --- ---
36 CO2 Loading --- ---
37 CO2 Apparent Mole Conc. (kgmole/m3) --- ---
38 CO2 Apparent Wt. Conc. (kgmol/kg) --- ---
39 LHV Mass Basis (Std) (kJ/kg) --- ---
40 Phase Fraction [Vol. Basis] 0.0000 1.000
41 Phase Fraction [Mass Basis] 0.0000 1.000
42 Phase Fraction [Act. Vol. Basis] 0.0000 1.000
43 Mass Exergy (kJ/kg) 0.5145 ---
44 Partial Pressure of CO2 (kPa) 0.0000 ---
45 Cost Based on Flow (Cost/s) 0.0000 0.0000
46 Act. Gas Flow (ACT_m3/h) --- ---
47 Avg. Liq. Density (kgmole/m3) 13.45 13.45
48 Specific Heat (kJ/kgmole-C) 118.0 118.0
49 Std. Gas Flow (STD_m3/h) 3.518e+004 3.518e+004
50 Std. Ideal Liq. Mass Density (kg/m3) 1241 1241
51 Act. Liq. Flow (m3/s) 3.060e-002 3.060e-002
52 Z Factor 1.253e-002 1.253e-002
53 Watson K 6.895 6.895
54 User Property --- ---
55 Partial Pressure of H2S (kPa) 0.0000 ---
56 Cp/(Cp - R) 1.076 1.076
57 Cp/Cv 1.433 1.433
58 Ideal Gas Cp/Cv 1.130 1.130
59 Ideal Gas Cp (kJ/kgmole-C) 72.16 72.16
60 Mass Ideal Gas Cp (kJ/kg-C) 0.7820 0.7820
61 Heat of Vap. (kJ/kgmole) 3.568e+004 ---
62 Kinematic Viscosity (cSt) 0.6701 0.6701
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 44 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 13 (continued) Property Package: SRK
8
9
10
PROPERTIES
11 Overall Liquid Phase
12 Liq. Mass Density (Std. Cond) (kg/m3) 1246 1246
13 Liq. Vol. Flow (Std. Cond) (m3/h) 110.2 110.2
14 Liquid Fraction 1.000 1.000
15 Molar Volume (m3/kgmole) 7.404e-002 7.404e-002
16 Mass Heat of Vap. (kJ/kg) 386.7 ---
17 Phase Fraction [Molar Basis] 0.0000 1.0000
18 Surface Tension (dyne/cm) 35.02 35.02
19 Thermal Conductivity (W/m-K) 0.1459 0.1459
20 Bubble Point Pressure (kPa) 151.6 ---
21 Viscosity (cP) 0.8351 0.8351
22 Cv (Semi-Ideal) (kJ/kgmole-C) 109.7 109.7
23 Mass Cv (Semi-Ideal) (kJ/kg-C) 1.189 1.189
24 Cv (kJ/kgmole-C) 82.33 82.33
25 Mass Cv (kJ/kg-C) 0.8922 0.8922
26 Cv (Ent. Method) (kJ/kgmole-C) 82.56 82.56
27 Mass Cv (Ent. Method) (kJ/kg-C) 0.8948 0.8948
28 Cp/Cv (Ent. Method) 1.429 1.429
29 Reid VP at 37.8 C (kPa) 88.39 88.39
30 True VP at 37.8 C (kPa) 198.7 198.7
31 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 110.2 110.2
32 Viscosity Index -2.887 ---
33
34
COMPOSITION
35
36
Overall Phase Vapour Fraction 0.0000

37 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
38 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
39 Ethylene 0.2779 0.0002 7.7958 0.0001 0.0203 0.0002
40 Cl2 0.0030 0.0000 0.2148 0.0000 0.0001 0.0000
41 12-ClC2 1356.7258 0.9118 134261.3178 0.9779 107.4091 0.9707
42 HCl 30.4626 0.0205 1110.6923 0.0081 1.2762 0.0115
43 VinylCl 2.3535 0.0016 147.0752 0.0011 0.1600 0.0014
44 H2O 97.5015 0.0655 1756.4985 0.0128 1.7600 0.0159
45 Oxygen 0.0298 0.0000 0.9525 0.0000 0.0008 0.0000
46 Nitrogen 0.6092 0.0004 17.0656 0.0001 0.0212 0.0002
47 Total 1487.9633 1.0000 137301.6125 1.0000 110.6477 1.0000
48
49
Liquid Phase Phase Fraction 1.000

50 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
51 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
52 Ethylene 0.2779 0.0002 7.7958 0.0001 0.0203 0.0002
53 Cl2 0.0030 0.0000 0.2148 0.0000 0.0001 0.0000
54 12-ClC2 1356.7258 0.9118 134261.3178 0.9779 107.4091 0.9707
55 HCl 30.4626 0.0205 1110.6923 0.0081 1.2762 0.0115
56 VinylCl 2.3535 0.0016 147.0752 0.0011 0.1600 0.0014
57 H2O 97.5015 0.0655 1756.4985 0.0128 1.7600 0.0159
58 Oxygen 0.0298 0.0000 0.9525 0.0000 0.0008 0.0000
59 Nitrogen 0.6092 0.0004 17.0656 0.0001 0.0212 0.0002
60 Total 1487.9633 1.0000 137301.6125 1.0000 110.6477 1.0000
61
62
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 45 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 13 (continued) Property Package: SRK
8
9
10
K VALUE
11 COMPONENTS MIXED LIGHT HEAVY
12 Ethylene 0.0000 0.0000 ---
13 Cl2 0.0000 0.0000 ---
14 12-ClC2 0.0000 0.0000 ---
15 HCl 0.0000 0.0000 ---
16 VinylCl 0.0000 0.0000 ---
17 H2O 0.0000 0.0000 ---
18 Oxygen 0.0000 0.0000 ---
19 Nitrogen 0.0000 0.0000 ---
20
21
UNIT OPERATIONS
22 FEED TO PRODUCT FROM LOGICAL CONNECTION
23 Reboiled Absorber: EDC Reboiler Absorber Liquid-Liquid Extractor: EDC extractor
24
25
UTILITIES
26 ( No utilities reference this stream )
27
28
PROCESS UTILITY
29
30
31
DYNAMICS
32 Pressure Specification (Inactive): 405.3 kPa
33 Flow Specification (Inactive) Molar: 1488 kgmole/h Mass: 1.373e+005 kg/h Std Ideal Liq Volume: 110.6 m3/h
34
35
User Variables
36
37
NOTES
38
39
40
Description
41
42
Fluid Package: Basis-1
43 Material Stream: 14 Property Package: SRK
44
45
46
CONDITIONS
47 Overall Vapour Phase
48 Vapour / Phase Fraction 1.0000 1.0000
49 Temperature: (C) 121.9 121.9
50 Pressure: (kPa) 405.3 405.3
51 Molar Flow (kgmole/h) 289.6 289.6
52 Mass Flow (kg/h) 1.983e+004 1.983e+004
53 Std Ideal Liq Vol Flow (m3/h) 16.62 16.62
54 Molar Enthalpy (kJ/kgmole) -1.507e+005 -1.507e+005
55 Molar Entropy (kJ/kgmole-C) 226.0 226.0
56 Heat Flow (kJ/h) -4.364e+007 -4.364e+007
57 Liq Vol Flow @Std Cond (m3/h) 16.22 * 16.22
58
59
PROPERTIES
60 Overall Vapour Phase
61 Molecular Weight 68.48 68.48
62 Molar Density (kgmole/m3) 0.1303 0.1303
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 46 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 14 (continued) Property Package: SRK
8
9
10
PROPERTIES
11 Overall Vapour Phase
12 Mass Density (kg/m3) 8.925 8.925
13 Act. Volume Flow (m3/h) 2222 2222
14 Mass Enthalpy (kJ/kg) -2201 -2201
15 Mass Entropy (kJ/kg-C) 3.300 3.300
16 Heat Capacity (kJ/kgmole-C) 70.17 70.17
17 Mass Heat Capacity (kJ/kg-C) 1.025 1.025
18 LHV Molar Basis (Std) (kJ/kgmole) --- ---
19 HHV Molar Basis (Std) (kJ/kgmole) --- ---
20 HHV Mass Basis (Std) (kJ/kg) --- ---
21 CO2 Loading --- ---
22 CO2 Apparent Mole Conc. (kgmole/m3) --- ---
23 CO2 Apparent Wt. Conc. (kgmol/kg) --- ---
24 LHV Mass Basis (Std) (kJ/kg) --- ---
25 Phase Fraction [Vol. Basis] 1.000 1.000
26 Phase Fraction [Mass Basis] 1.000 1.000
27 Phase Fraction [Act. Vol. Basis] 1.000 1.000
28 Mass Exergy (kJ/kg) 117.9 ---
29 Partial Pressure of CO2 (kPa) 0.0000 ---
30 Cost Based on Flow (Cost/s) 0.0000 0.0000
31 Act. Gas Flow (ACT_m3/h) 2222 2222
32 Avg. Liq. Density (kgmole/m3) 17.42 17.42
33 Specific Heat (kJ/kgmole-C) 70.17 70.17
34 Std. Gas Flow (STD_m3/h) 6846 6846
35 Std. Ideal Liq. Mass Density (kg/m3) 1193 1193
36 Act. Liq. Flow (m3/s) --- ---
37 Z Factor 0.9467 0.9467
38 Watson K 6.943 6.943
39 User Property --- ---
40 Partial Pressure of H2S (kPa) 0.0000 ---
41 Cp/(Cp - R) 1.134 1.134
42 Cp/Cv 1.170 1.170
43 Ideal Gas Cp/Cv 1.139 1.139
44 Ideal Gas Cp (kJ/kgmole-C) 68.03 68.03
45 Mass Ideal Gas Cp (kJ/kg-C) 0.9934 0.9934
46 Heat of Vap. (kJ/kgmole) 5.214e+004 ---
47 Kinematic Viscosity (cSt) 1.361 1.361
48 Liq. Mass Density (Std. Cond) (kg/m3) 1222 1222
49 Liq. Vol. Flow (Std. Cond) (m3/h) 16.22 16.22
50 Liquid Fraction 0.0000 0.0000
51 Molar Volume (m3/kgmole) 7.672 7.672
52 Mass Heat of Vap. (kJ/kg) 761.4 ---
53 Phase Fraction [Molar Basis] 1.0000 1.0000
54 Surface Tension (dyne/cm) --- ---
55 Thermal Conductivity (W/m-K) 1.715e-002 1.715e-002
56 Bubble Point Pressure (kPa) 2549 ---
57 Viscosity (cP) 1.215e-002 1.215e-002
58 Cv (Semi-Ideal) (kJ/kgmole-C) 61.85 61.85
59 Mass Cv (Semi-Ideal) (kJ/kg-C) 0.9032 0.9032
60 Cv (kJ/kgmole-C) 59.98 59.98
61 Mass Cv (kJ/kg-C) 0.8760 0.8760
62 Cv (Ent. Method) (kJ/kgmole-C) --- ---
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 47 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 14 (continued) Property Package: SRK
8
9
10
PROPERTIES
11 Overall Vapour Phase
12 Mass Cv (Ent. Method) (kJ/kg-C) --- ---
13 Cp/Cv (Ent. Method) --- ---
14 Reid VP at 37.8 C (kPa) 544.7 544.7
15 True VP at 37.8 C (kPa) 1221 1221
16 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 16.22 16.22
17 Viscosity Index -36.95 ---
18
19
COMPOSITION
20
21
Overall Phase Vapour Fraction 1.0000

22 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
23 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
24 Ethylene 0.2779 0.0010 7.7958 0.0004 0.0203 0.0012
25 Cl2 0.0030 0.0000 0.2148 0.0000 0.0001 0.0000
26 12-ClC2 172.1650 0.5946 17037.4162 0.8593 13.6299 0.8202
27 HCl 30.4626 0.1052 1110.6923 0.0560 1.2762 0.0768
28 VinylCl 2.3535 0.0081 147.0752 0.0074 0.1600 0.0096
29 H2O 83.6532 0.2889 1507.0209 0.0760 1.5101 0.0909
30 Oxygen 0.0298 0.0001 0.9525 0.0000 0.0008 0.0001
31 Nitrogen 0.6092 0.0021 17.0656 0.0009 0.0212 0.0013
32 Total 289.5543 1.0000 19828.2333 1.0000 16.6186 1.0000
33
34
Vapour Phase Phase Fraction 1.000

35 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
36 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
37 Ethylene 0.2779 0.0010 7.7958 0.0004 0.0203 0.0012
38 Cl2 0.0030 0.0000 0.2148 0.0000 0.0001 0.0000
39 12-ClC2 172.1650 0.5946 17037.4162 0.8593 13.6299 0.8202
40 HCl 30.4626 0.1052 1110.6923 0.0560 1.2762 0.0768
41 VinylCl 2.3535 0.0081 147.0752 0.0074 0.1600 0.0096
42 H2O 83.6532 0.2889 1507.0209 0.0760 1.5101 0.0909
43 Oxygen 0.0298 0.0001 0.9525 0.0000 0.0008 0.0001
44 Nitrogen 0.6092 0.0021 17.0656 0.0009 0.0212 0.0013
45 Total 289.5543 1.0000 19828.2333 1.0000 16.6186 1.0000
46
47
K VALUE
48 COMPONENTS MIXED LIGHT HEAVY
49 Ethylene --- --- ---
50 Cl2 --- --- ---
51 12-ClC2 --- --- ---
52 HCl --- --- ---
53 VinylCl --- --- ---
54 H2O --- --- ---
55 Oxygen --- --- ---
56 Nitrogen --- --- ---
57
58
UNIT OPERATIONS
59 FEED TO PRODUCT FROM LOGICAL CONNECTION
60 Cooler: E-103 Reboiled Absorber: EDC Reboiler Absorber
61
62
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 48 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 14 (continued) Property Package: SRK
8
9
10
UTILITIES
11 ( No utilities reference this stream )
12
13
PROCESS UTILITY
14
15
16
DYNAMICS
17 Pressure Specification (Inactive): 405.3 kPa
18 Flow Specification (Inactive) Molar: 289.6 kgmole/h Mass: 1.983e+004 kg/h Std Ideal Liq Volume: 16.62 m3/h
19
20
User Variables
21
22
NOTES
23
24
25
Description
26
27
Fluid Package: Basis-1
28 Material Stream: 15 Property Package: SRK
29
30
31
CONDITIONS
32 Overall Vapour Phase Liquid Phase Aqueous Phase
33 Vapour / Phase Fraction 0.0900 0.0900 0.7272 0.1829
34 Temperature: (C) 60.00 * 60.00 60.00 60.00
35 Pressure: (kPa) 405.3 405.3 405.3 405.3
36 Molar Flow (kgmole/h) 289.6 26.05 210.6 52.95
37 Mass Flow (kg/h) 1.983e+004 1076 1.780e+004 955.4
38 Std Ideal Liq Vol Flow (m3/h) 16.62 1.163 14.50 0.9574
39 Molar Enthalpy (kJ/kgmole) -1.862e+005 -9.552e+004 -1.730e+005 -2.834e+005
40 Molar Entropy (kJ/kgmole-C) 132.2 173.7 144.7 62.30
41 Heat Flow (kJ/h) -5.391e+007 -2.488e+006 -3.642e+007 -1.500e+007
42 Liq Vol Flow @Std Cond (m3/h) 16.22 * 1.113 14.37 0.9411
43
44
PROPERTIES
45 Overall Vapour Phase Liquid Phase Aqueous Phase
46 Molecular Weight 68.48 41.31 84.52 18.04
47 Molar Density (kgmole/m3) 1.523 0.1497 13.88 54.36
48 Mass Density (kg/m3) 104.3 6.185 1174 980.9
49 Act. Volume Flow (m3/h) 190.2 174.0 15.16 0.9741
50 Mass Enthalpy (kJ/kg) -2719 -2312 -2046 -1.570e+004
51 Mass Entropy (kJ/kg-C) 1.931 4.206 1.712 3.453
52 Heat Capacity (kJ/kgmole-C) 105.0 36.14 119.8 80.01
53 Mass Heat Capacity (kJ/kg-C) 1.534 0.8749 1.418 4.434
54 LHV Molar Basis (Std) (kJ/kgmole) --- --- --- 218.2
55 HHV Molar Basis (Std) (kJ/kgmole) --- --- --- 4.120e+004
56 HHV Mass Basis (Std) (kJ/kg) --- --- --- 2283
57 CO2 Loading --- --- --- ---
58 CO2 Apparent Mole Conc. (kgmole/m3) --- --- --- ---
59 CO2 Apparent Wt. Conc. (kgmol/kg) --- --- --- ---
60 LHV Mass Basis (Std) (kJ/kg) --- --- --- 12.09
61 Phase Fraction [Vol. Basis] 7.001e-002 7.001e-002 0.8724 5.761e-002
62 Phase Fraction [Mass Basis] 5.428e-002 5.428e-002 0.8975 4.819e-002
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 49 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 15 (continued) Property Package: SRK
8
9
10
PROPERTIES
11 Overall Vapour Phase Liquid Phase Aqueous Phase
12 Phase Fraction [Act. Vol. Basis] 0.9151 0.9151 7.975e-002 5.123e-003
13 Mass Exergy (kJ/kg) 8.448 --- --- ---
14 Partial Pressure of CO2 (kPa) 0.0000 --- --- ---
15 Cost Based on Flow (Cost/s) 0.0000 0.0000 0.0000 0.0000
16 Act. Gas Flow (ACT_m3/h) 174.0 174.0 --- ---
17 Avg. Liq. Density (kgmole/m3) 17.42 22.39 14.52 55.30
18 Specific Heat (kJ/kgmole-C) 105.0 36.14 119.8 80.01
19 Std. Gas Flow (STD_m3/h) 6846 616.0 4978 1252
20 Std. Ideal Liq. Mass Density (kg/m3) 1193 925.0 1228 997.9
21 Act. Liq. Flow (m3/s) 4.483e-003 --- 4.212e-003 2.706e-004
22 Z Factor --- 0.9774 1.054e-002 2.692e-003
23 Watson K 6.943 7.763 6.910 7.536
24 User Property --- --- --- ---
25 Partial Pressure of H2S (kPa) 0.0000 --- --- ---
26 Cp/(Cp - R) 1.086 1.299 1.075 1.116
27 Cp/Cv 1.008 1.337 1.075 1.160
28 Ideal Gas Cp/Cv 1.153 1.309 1.128 1.326
29 Ideal Gas Cp (kJ/kgmole-C) 62.68 35.22 73.34 33.80
30 Mass Ideal Gas Cp (kJ/kg-C) 0.9153 0.8524 0.8677 1.873
31 Heat of Vap. (kJ/kgmole) 5.214e+004 --- --- ---
32 Kinematic Viscosity (cSt) --- 2.325 0.4118 0.5051
33 Liq. Mass Density (Std. Cond) (kg/m3) 1222 966.6 1239 1015
34 Liq. Vol. Flow (Std. Cond) (m3/h) 16.22 1.113 14.37 0.9411
35 Liquid Fraction 0.9100 0.0000 1.000 1.000
36 Molar Volume (m3/kgmole) 0.6567 6.680 7.202e-002 1.840e-002
37 Mass Heat of Vap. (kJ/kg) 761.4 --- --- ---
38 Phase Fraction [Molar Basis] 0.0900 0.0900 0.7272 0.1829
39 Surface Tension (dyne/cm) --- --- 30.65 65.90
40 Thermal Conductivity (W/m-K) --- 1.825e-002 0.1537 0.6525
41 Bubble Point Pressure (kPa) 1498 --- --- ---
42 Viscosity (cP) --- 1.438e-002 0.4833 0.4955
43 Cv (Semi-Ideal) (kJ/kgmole-C) 96.72 27.83 111.5 71.69
44 Mass Cv (Semi-Ideal) (kJ/kg-C) 1.412 0.6736 1.320 3.973
45 Cv (kJ/kgmole-C) 104.2 27.03 111.5 68.99
46 Mass Cv (kJ/kg-C) 1.521 0.6542 1.320 3.823
47 Cv (Ent. Method) (kJ/kgmole-C) --- --- --- 65.28
48 Mass Cv (Ent. Method) (kJ/kg-C) --- --- --- 3.618
49 Cp/Cv (Ent. Method) --- --- --- 1.226
50 Reid VP at 37.8 C (kPa) 544.7 5315 185.8 4365
51 True VP at 37.8 C (kPa) 1221 7315 280.5 372.7
52 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 16.42 1.113 14.37 0.9411
53 Viscosity Index -14.26 --- --- ---
54
55
COMPOSITION
56
57
Overall Phase Vapour Fraction 0.0900

58 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
59 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
60 Ethylene 0.2779 0.0010 7.7958 0.0004 0.0203 0.0012
61 Cl2 0.0030 0.0000 0.2148 0.0000 0.0001 0.0000
62 12-ClC2 172.1650 0.5946 17037.4162 0.8593 13.6299 0.8202
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 50 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 15 (continued) Property Package: SRK
8
9
10
COMPOSITION
11
12
Overall Phase (continued) Vapour Fraction 0.0900

13 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
14 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
15 HCl 30.4626 0.1052 1110.6923 0.0560 1.2762 0.0768
16 VinylCl 2.3535 0.0081 147.0752 0.0074 0.1600 0.0096
17 H2O 83.6532 0.2889 1507.0209 0.0760 1.5101 0.0909
18 Oxygen 0.0298 0.0001 0.9525 0.0000 0.0008 0.0001
19 Nitrogen 0.6092 0.0021 17.0656 0.0009 0.0212 0.0013
20 Total 289.5543 1.0000 19828.2333 1.0000 16.6186 1.0000
21
22
Vapour Phase Phase Fraction 8.997e-002

23 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
24 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
25 Ethylene 0.2380 0.0091 6.6768 0.0062 0.0174 0.0150
26 Cl2 0.0010 0.0000 0.0708 0.0001 0.0000 0.0000
27 12-ClC2 2.2621 0.0868 223.8583 0.2080 0.1791 0.1539
28 HCl 20.9568 0.8045 764.1004 0.7100 0.8779 0.7546
29 VinylCl 0.6387 0.0245 39.9117 0.0371 0.0434 0.0373
30 H2O 1.3276 0.0510 23.9173 0.0222 0.0240 0.0206
31 Oxygen 0.0287 0.0011 0.9179 0.0009 0.0008 0.0007
32 Nitrogen 0.5977 0.0229 16.7437 0.0156 0.0208 0.0178
33 Total 26.0506 1.0000 1076.1968 1.0000 1.1635 1.0000
34
35
Liquid Phase Phase Fraction 0.7272

36 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
37 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
38 Ethylene 0.0399 0.0002 1.1190 0.0001 0.0029 0.0002
39 Cl2 0.0020 0.0000 0.1436 0.0000 0.0001 0.0000
40 12-ClC2 169.8937 0.8069 16812.6467 0.9447 13.4501 0.9277
41 HCl 9.4607 0.0449 344.9464 0.0194 0.3963 0.0273
42 VinylCl 1.7148 0.0081 107.1589 0.0060 0.1166 0.0080
43 H2O 29.4323 0.1398 530.2255 0.0298 0.5313 0.0366
44 Oxygen 0.0011 0.0000 0.0345 0.0000 0.0000 0.0000
45 Nitrogen 0.0115 0.0001 0.3213 0.0000 0.0004 0.0000
46 Total 210.5560 1.0000 17796.5960 1.0000 14.4978 1.0000
47
48
Aqueous Phase Phase Fraction 0.1829

49 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
50 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
51 Ethylene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
52 Cl2 0.0000 0.0000 0.0004 0.0000 0.0000 0.0000
53 12-ClC2 0.0092 0.0002 0.9112 0.0010 0.0007 0.0008
54 HCl 0.0451 0.0009 1.6455 0.0017 0.0019 0.0020
55 VinylCl 0.0001 0.0000 0.0046 0.0000 0.0000 0.0000
56 H2O 52.8933 0.9990 952.8781 0.9973 0.9548 0.9973
57 Oxygen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
58 Nitrogen 0.0000 0.0000 0.0006 0.0000 0.0000 0.0000
59 Total 52.9477 1.0000 955.4405 1.0000 0.9574 1.0000
60
61
62
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 51 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 15 (continued) Property Package: SRK
8
9
10
K VALUE
11 COMPONENTS MIXED LIGHT HEAVY
12 Ethylene 60.36 48.23 3.274e+007
13 Cl2 4.977 3.988 376.9
14 12-ClC2 0.1347 0.1076 499.3
15 HCl 22.30 17.90 943.8
16 VinylCl 3.767 3.010 1.751e+004
17 H2O 0.1631 0.3646 5.102e-002
18 Oxygen 268.5 214.8 4.926e+004
19 Nitrogen 526.1 421.2 5.354e+004
20
21
UNIT OPERATIONS
22 FEED TO PRODUCT FROM LOGICAL CONNECTION
23 Recycle: RCY-1 Cooler: E-103
24
25
UTILITIES
26 ( No utilities reference this stream )
27
28
PROCESS UTILITY
29
30
31
DYNAMICS
32 Pressure Specification (Inactive): 405.3 kPa
33 Flow Specification (Inactive) Molar: 289.6 kgmole/h Mass: 1.983e+004 kg/h Std Ideal Liq Volume: 16.62 m3/h
34
35
User Variables
36
37
NOTES
38
39
40
Description
41
42
Fluid Package: Basis-1
43 Material Stream: 16 Property Package: SRK
44
45
46
CONDITIONS
47 Overall Liquid Phase
48 Vapour / Phase Fraction 0.0000 1.0000
49 Temperature: (C) 136.7 136.7
50 Pressure: (kPa) 405.3 405.3
51 Molar Flow (kgmole/h) 1198 1198
52 Mass Flow (kg/h) 1.175e+005 1.175e+005
53 Std Ideal Liq Vol Flow (m3/h) 94.03 94.03
54 Molar Enthalpy (kJ/kgmole) -1.524e+005 -1.524e+005
55 Molar Entropy (kJ/kgmole-C) 180.8 180.8
56 Heat Flow (kJ/h) -1.826e+008 -1.826e+008
57 Liq Vol Flow @Std Cond (m3/h) 93.97 * 93.97
58
59
PROPERTIES
60 Overall Liquid Phase
61 Molecular Weight 98.02 98.02
62 Molar Density (kgmole/m3) 10.83 10.83
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 52 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 16 (continued) Property Package: SRK
8
9
10
PROPERTIES
11 Overall Liquid Phase
12 Mass Density (kg/m3) 1062 1062
13 Act. Volume Flow (m3/h) 110.6 110.6
14 Mass Enthalpy (kJ/kg) -1555 -1555
15 Mass Entropy (kJ/kg-C) 1.845 1.845
16 Heat Capacity (kJ/kgmole-C) 147.5 147.5
17 Mass Heat Capacity (kJ/kg-C) 1.505 1.505
18 LHV Molar Basis (Std) (kJ/kgmole) 1.092e+006 1.092e+006
19 HHV Molar Basis (Std) (kJ/kgmole) 1.174e+006 1.174e+006
20 HHV Mass Basis (Std) (kJ/kg) 1.197e+004 1.197e+004
21 CO2 Loading --- ---
22 CO2 Apparent Mole Conc. (kgmole/m3) --- ---
23 CO2 Apparent Wt. Conc. (kgmol/kg) --- ---
24 LHV Mass Basis (Std) (kJ/kg) 1.114e+004 1.114e+004
25 Phase Fraction [Vol. Basis] 0.0000 1.000
26 Phase Fraction [Mass Basis] 0.0000 1.000
27 Phase Fraction [Act. Vol. Basis] 0.0000 1.000
28 Mass Exergy (kJ/kg) 23.96 ---
29 Partial Pressure of CO2 (kPa) 0.0000 ---
30 Cost Based on Flow (Cost/s) 0.0000 0.0000
31 Act. Gas Flow (ACT_m3/h) --- ---
32 Avg. Liq. Density (kgmole/m3) 12.75 12.75
33 Specific Heat (kJ/kgmole-C) 147.5 147.5
34 Std. Gas Flow (STD_m3/h) 2.834e+004 2.834e+004
35 Std. Ideal Liq. Mass Density (kg/m3) 1249 1249
36 Act. Liq. Flow (m3/s) 3.073e-002 3.073e-002
37 Z Factor 1.098e-002 1.098e-002
38 Watson K 6.888 6.888
39 User Property --- ---
40 Partial Pressure of H2S (kPa) 0.0000 ---
41 Cp/(Cp - R) 1.060 1.060
42 Cp/Cv 1.492 1.492
43 Ideal Gas Cp/Cv 1.098 1.098
44 Ideal Gas Cp (kJ/kgmole-C) 92.72 92.72
45 Mass Ideal Gas Cp (kJ/kg-C) 0.9459 0.9459
46 Heat of Vap. (kJ/kgmole) 3.016e+004 ---
47 Kinematic Viscosity (cSt) 0.2358 0.2358
48 Liq. Mass Density (Std. Cond) (kg/m3) 1250 1250
49 Liq. Vol. Flow (Std. Cond) (m3/h) 93.97 93.97
50 Liquid Fraction 1.000 1.000
51 Molar Volume (m3/kgmole) 9.232e-002 9.232e-002
52 Mass Heat of Vap. (kJ/kg) 307.7 ---
53 Phase Fraction [Molar Basis] 0.0000 1.0000
54 Surface Tension (dyne/cm) 16.52 16.52
55 Thermal Conductivity (W/m-K) 9.898e-002 9.898e-002
56 Bubble Point Pressure (kPa) 405.3 ---
57 Viscosity (cP) 0.2504 0.2504
58 Cv (Semi-Ideal) (kJ/kgmole-C) 139.2 139.2
59 Mass Cv (Semi-Ideal) (kJ/kg-C) 1.420 1.420
60 Cv (kJ/kgmole-C) 98.88 98.88
61 Mass Cv (kJ/kg-C) 1.009 1.009
62 Cv (Ent. Method) (kJ/kgmole-C) --- ---
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 53 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 16 (continued) Property Package: SRK
8
9
10
PROPERTIES
11 Overall Liquid Phase
12 Mass Cv (Ent. Method) (kJ/kg-C) --- ---
13 Cp/Cv (Ent. Method) --- ---
14 Reid VP at 37.8 C (kPa) 15.86 15.86
15 True VP at 37.8 C (kPa) 16.50 16.50
16 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 93.97 93.97
17 Viscosity Index -37.68 ---
18
19
COMPOSITION
20
21
Overall Phase Vapour Fraction 0.0000

22 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
23 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
24 Ethylene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
25 Cl2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
26 12-ClC2 1184.5608 0.9884 117223.9016 0.9979 93.7791 0.9973
27 HCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
28 VinylCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
29 H2O 13.8483 0.0116 249.4776 0.0021 0.2500 0.0027
30 Oxygen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
31 Nitrogen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
32 Total 1198.4091 1.0000 117473.3792 1.0000 94.0291 1.0000
33
34
Liquid Phase Phase Fraction 1.000

35 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
36 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
37 Ethylene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 Cl2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 12-ClC2 1184.5608 0.9884 117223.9016 0.9979 93.7791 0.9973
40 HCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
41 VinylCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
42 H2O 13.8483 0.0116 249.4776 0.0021 0.2500 0.0027
43 Oxygen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
44 Nitrogen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
45 Total 1198.4091 1.0000 117473.3792 1.0000 94.0291 1.0000
46
47
K VALUE
48 COMPONENTS MIXED LIGHT HEAVY
49 Ethylene 0.0000 0.0000 ---
50 Cl2 0.0000 0.0000 ---
51 12-ClC2 0.0000 0.0000 ---
52 HCl 0.0000 0.0000 ---
53 VinylCl 0.0000 0.0000 ---
54 H2O 0.0000 0.0000 ---
55 Oxygen 0.0000 0.0000 ---
56 Nitrogen 0.0000 0.0000 ---
57
58
UNIT OPERATIONS
59 FEED TO PRODUCT FROM LOGICAL CONNECTION
60 Pump: P-101 Reboiled Absorber: EDC Reboiler Absorber
61
62
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 54 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 16 (continued) Property Package: SRK
8
9
10
UTILITIES
11 ( No utilities reference this stream )
12
13
PROCESS UTILITY
14
15
16
DYNAMICS
17 Pressure Specification (Inactive): 405.3 kPa
18 Flow Specification (Inactive) Molar: 1198 kgmole/h Mass: 1.175e+005 kg/h Std Ideal Liq Volume: 94.03 m3/h
19
20
User Variables
21
22
NOTES
23
24
25
Description
26
27
Fluid Package: Basis-1
28 Material Stream: 17 Property Package: SRK
29
30
31
CONDITIONS
32 Overall Liquid Phase
33 Vapour / Phase Fraction 0.0000 1.0000
34 Temperature: (C) 138.2 138.2
35 Pressure: (kPa) 2634 * 2634
36 Molar Flow (kgmole/h) 1198 1198
37 Mass Flow (kg/h) 1.175e+005 1.175e+005
38 Std Ideal Liq Vol Flow (m3/h) 94.03 94.03
39 Molar Enthalpy (kJ/kgmole) -1.521e+005 -1.521e+005
40 Molar Entropy (kJ/kgmole-C) 180.9 180.9
41 Heat Flow (kJ/h) -1.823e+008 -1.823e+008
42 Liq Vol Flow @Std Cond (m3/h) 93.97 * 93.97
43
44
PROPERTIES
45 Overall Liquid Phase
46 Molecular Weight 98.02 98.02
47 Molar Density (kgmole/m3) 10.86 10.86
48 Mass Density (kg/m3) 1064 1064
49 Act. Volume Flow (m3/h) 110.4 110.4
50 Mass Enthalpy (kJ/kg) -1552 -1552
51 Mass Entropy (kJ/kg-C) 1.846 1.846
52 Heat Capacity (kJ/kgmole-C) 146.4 146.4
53 Mass Heat Capacity (kJ/kg-C) 1.493 1.493
54 LHV Molar Basis (Std) (kJ/kgmole) 1.092e+006 1.092e+006
55 HHV Molar Basis (Std) (kJ/kgmole) 1.174e+006 1.174e+006
56 HHV Mass Basis (Std) (kJ/kg) 1.197e+004 1.197e+004
57 CO2 Loading --- ---
58 CO2 Apparent Mole Conc. (kgmole/m3) --- ---
59 CO2 Apparent Wt. Conc. (kgmol/kg) --- ---
60 LHV Mass Basis (Std) (kJ/kg) 1.114e+004 1.114e+004
61 Phase Fraction [Vol. Basis] 0.0000 1.000
62 Phase Fraction [Mass Basis] 0.0000 1.000
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 55 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 17 (continued) Property Package: SRK
8
9
10
PROPERTIES
11 Overall Liquid Phase
12 Phase Fraction [Act. Vol. Basis] 0.0000 1.000
13 Mass Exergy (kJ/kg) 26.43 ---
14 Partial Pressure of CO2 (kPa) 0.0000 ---
15 Cost Based on Flow (Cost/s) 0.0000 0.0000
16 Act. Gas Flow (ACT_m3/h) --- ---
17 Avg. Liq. Density (kgmole/m3) 12.75 12.75
18 Specific Heat (kJ/kgmole-C) 146.4 146.4
19 Std. Gas Flow (STD_m3/h) 2.834e+004 2.834e+004
20 Std. Ideal Liq. Mass Density (kg/m3) 1249 1249
21 Act. Liq. Flow (m3/s) 3.066e-002 3.066e-002
22 Z Factor 7.095e-002 7.095e-002
23 Watson K 6.888 6.888
24 User Property --- ---
25 Partial Pressure of H2S (kPa) 0.0000 ---
26 Cp/(Cp - R) 1.060 1.060
27 Cp/Cv 1.482 1.482
28 Ideal Gas Cp/Cv 1.098 1.098
29 Ideal Gas Cp (kJ/kgmole-C) 92.92 92.92
30 Mass Ideal Gas Cp (kJ/kg-C) 0.9479 0.9479
31 Heat of Vap. (kJ/kgmole) 1.962e+004 ---
32 Kinematic Viscosity (cSt) 0.2332 0.2332
33 Liq. Mass Density (Std. Cond) (kg/m3) 1250 1250
34 Liq. Vol. Flow (Std. Cond) (m3/h) 93.97 93.97
35 Liquid Fraction 1.000 1.000
36 Molar Volume (m3/kgmole) 9.211e-002 9.211e-002
37 Mass Heat of Vap. (kJ/kg) 200.1 ---
38 Phase Fraction [Molar Basis] 0.0000 1.0000
39 Surface Tension (dyne/cm) 16.33 16.33
40 Thermal Conductivity (W/m-K) 9.852e-002 9.852e-002
41 Bubble Point Pressure (kPa) 419.8 ---
42 Viscosity (cP) 0.2481 0.2481
43 Cv (Semi-Ideal) (kJ/kgmole-C) 138.1 138.1
44 Mass Cv (Semi-Ideal) (kJ/kg-C) 1.408 1.408
45 Cv (kJ/kgmole-C) 98.79 98.79
46 Mass Cv (kJ/kg-C) 1.008 1.008
47 Cv (Ent. Method) (kJ/kgmole-C) 86.68 86.68
48 Mass Cv (Ent. Method) (kJ/kg-C) 0.8843 0.8843
49 Cp/Cv (Ent. Method) 1.689 1.689
50 Reid VP at 37.8 C (kPa) 15.86 15.86
51 True VP at 37.8 C (kPa) 16.50 16.50
52 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 93.97 93.97
53 Viscosity Index -38.78 ---
54
55
COMPOSITION
56
57
Overall Phase Vapour Fraction 0.0000

58 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
59 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
60 Ethylene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
61 Cl2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
62 12-ClC2 1184.5608 0.9884 117223.9016 0.9979 93.7791 0.9973
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 56 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 17 (continued) Property Package: SRK
8
9
10
COMPOSITION
11
12
Overall Phase (continued) Vapour Fraction 0.0000

13 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
14 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
15 HCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
16 VinylCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
17 H2O 13.8483 0.0116 249.4776 0.0021 0.2500 0.0027
18 Oxygen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Nitrogen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
20 Total 1198.4091 1.0000 117473.3792 1.0000 94.0291 1.0000
21
22
Liquid Phase Phase Fraction 1.000

23 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
24 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
25 Ethylene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
26 Cl2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
27 12-ClC2 1184.5608 0.9884 117223.9016 0.9979 93.7791 0.9973
28 HCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
29 VinylCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
30 H2O 13.8483 0.0116 249.4776 0.0021 0.2500 0.0027
31 Oxygen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
32 Nitrogen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
33 Total 1198.4091 1.0000 117473.3792 1.0000 94.0291 1.0000
34
35
K VALUE
36 COMPONENTS MIXED LIGHT HEAVY
37 Ethylene 0.0000 0.0000 ---
38 Cl2 0.0000 0.0000 ---
39 12-ClC2 0.0000 0.0000 ---
40 HCl 0.0000 0.0000 ---
41 VinylCl 0.0000 0.0000 ---
42 H2O 0.0000 0.0000 ---
43 Oxygen 0.0000 0.0000 ---
44 Nitrogen 0.0000 0.0000 ---
45
46
UNIT OPERATIONS
47 FEED TO PRODUCT FROM LOGICAL CONNECTION
48 Heater: E-104 Pump: P-101
49
50
UTILITIES
51 ( No utilities reference this stream )
52
53
PROCESS UTILITY
54
55
56
DYNAMICS
57 Pressure Specification (Active): 2634 kPa *
58 Flow Specification (Inactive) Molar: 1198 kgmole/h Mass: 1.175e+005 kg/h Std Ideal Liq Volume: 94.03 m3/h
59
60
User Variables
61
62
NOTES
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 57 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 17 (continued) Property Package: SRK
8
9
10
11
Description
12
13
Fluid Package: Basis-1
14 Material Stream: 18 Property Package: SRK
15
16
17
CONDITIONS
18 Overall Vapour Phase Liquid Phase
19 Vapour / Phase Fraction 1.0000 1.0000 0.0000
20 Temperature: (C) 550.0 550.0 550.0
21 Pressure: (kPa) 2634 2634 2634
22 Molar Flow (kgmole/h) 1899 1899 0.0000
23 Mass Flow (kg/h) 1.175e+005 1.175e+005 0.0000
24 Std Ideal Liq Vol Flow (m3/h) 115.5 115.5 0.0000
25 Molar Enthalpy (kJ/kgmole) -2.087e+004 -2.087e+004 -2.087e+004
26 Molar Entropy (kJ/kgmole-C) 214.8 214.8 214.8
27 Heat Flow (kJ/h) -3.963e+007 -3.963e+007 0.0000
28 Liq Vol Flow @Std Cond (m3/h) 110.9 * 110.9 0.0000
29
30
PROPERTIES
31 Overall Vapour Phase Liquid Phase
32 Molecular Weight 61.86 61.86 61.86
33 Molar Density (kgmole/m3) 0.3873 0.3873 0.3873
34 Mass Density (kg/m3) 23.96 23.96 23.96
35 Act. Volume Flow (m3/h) 4903 4903 0.0000
36 Mass Enthalpy (kJ/kg) -337.4 -337.4 -337.4
37 Mass Entropy (kJ/kg-C) 3.473 3.473 3.473
38 Heat Capacity (kJ/kgmole-C) 81.85 81.85 81.85
39 Mass Heat Capacity (kJ/kg-C) 1.323 1.323 1.323
40 LHV Molar Basis (Std) (kJ/kgmole) 7.194e+005 7.194e+005 7.194e+005
41 HHV Molar Basis (Std) (kJ/kgmole) 7.633e+005 7.633e+005 7.633e+005
42 HHV Mass Basis (Std) (kJ/kg) 1.234e+004 1.234e+004 1.234e+004
43 CO2 Loading --- --- ---
44 CO2 Apparent Mole Conc. (kgmole/m3) --- --- ---
45 CO2 Apparent Wt. Conc. (kgmol/kg) --- --- ---
46 LHV Mass Basis (Std) (kJ/kg) 1.163e+004 1.163e+004 1.163e+004
47 Phase Fraction [Vol. Basis] 1.000 1.000 ---
48 Phase Fraction [Mass Basis] 1.000 1.000 0.0000
49 Phase Fraction [Act. Vol. Basis] 1.000 1.000 0.0000
50 Mass Exergy (kJ/kg) 387.3 --- ---
51 Partial Pressure of CO2 (kPa) 0.0000 --- ---
52 Cost Based on Flow (Cost/s) 0.0000 0.0000 0.0000
53 Act. Gas Flow (ACT_m3/h) 4903 4903 ---
54 Avg. Liq. Density (kgmole/m3) 16.44 16.44 16.44
55 Specific Heat (kJ/kgmole-C) 81.85 81.85 81.85
56 Std. Gas Flow (STD_m3/h) 4.490e+004 4.490e+004 0.0000
57 Std. Ideal Liq. Mass Density (kg/m3) 1017 1017 1017
58 Act. Liq. Flow (m3/s) --- --- ---
59 Z Factor --- 0.9939 0.9939
60 Watson K 7.653 7.653 7.653
61 User Property --- --- ---
62 Partial Pressure of H2S (kPa) 0.0000 --- ---
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 58 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 18 (continued) Property Package: SRK
8
9
10
PROPERTIES
11 Overall Vapour Phase Liquid Phase
12 Cp/(Cp - R) 1.113 1.113 1.113
13 Cp/Cv 1.130 1.130 1.130
14 Ideal Gas Cp/Cv 1.115 1.115 1.115
15 Ideal Gas Cp (kJ/kgmole-C) 80.38 80.38 80.38
16 Mass Ideal Gas Cp (kJ/kg-C) 1.299 1.299 1.299
17 Heat of Vap. (kJ/kgmole) 2.465e+004 --- ---
18 Kinematic Viscosity (cSt) 1.277 1.277 0.3297
19 Liq. Mass Density (Std. Cond) (kg/m3) 1059 1059 1059
20 Liq. Vol. Flow (Std. Cond) (m3/h) 110.9 110.9 0.0000
21 Liquid Fraction 0.0000 0.0000 1.000
22 Molar Volume (m3/kgmole) 2.582 2.582 2.582
23 Mass Heat of Vap. (kJ/kg) 398.5 --- ---
24 Phase Fraction [Molar Basis] 1.0000 1.0000 0.0000
25 Surface Tension (dyne/cm) --- --- 0.0000
26 Thermal Conductivity (W/m-K) 4.428e-002 4.428e-002 3.282e-002
27 Bubble Point Pressure (kPa) --- --- ---
28 Viscosity (cP) 3.058e-002 3.058e-002 7.899e-003
29 Cv (Semi-Ideal) (kJ/kgmole-C) 73.54 73.54 73.54
30 Mass Cv (Semi-Ideal) (kJ/kg-C) 1.189 1.189 1.189
31 Cv (kJ/kgmole-C) 72.44 72.44 72.44
32 Mass Cv (kJ/kg-C) 1.171 1.171 1.171
33 Cv (Ent. Method) (kJ/kgmole-C) --- --- ---
34 Mass Cv (Ent. Method) (kJ/kg-C) --- --- ---
35 Cp/Cv (Ent. Method) --- --- ---
36 Reid VP at 37.8 C (kPa) 1669 1669 1669
37 True VP at 37.8 C (kPa) 2089 2089 2089
38 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 110.9 110.9 0.0000
39 Viscosity Index -19.61 --- ---
40
41
COMPOSITION
42
43
Overall Phase Vapour Fraction 1.0000

44 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
45 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
46 Ethylene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
47 Cl2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
48 12-ClC2 483.9969 0.2549 47896.2335 0.4077 38.3170 0.3316
49 HCl 700.5639 0.3689 25543.1219 0.2174 29.3488 0.2540
50 VinylCl 700.5639 0.3689 43779.6423 0.3727 47.6250 0.4122
51 H2O 13.8483 0.0073 249.4776 0.0021 0.2500 0.0022
52 Oxygen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
53 Nitrogen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
54 Total 1898.9730 1.0000 117468.4753 1.0000 115.5408 1.0000
55
56
Vapour Phase Phase Fraction 1.000

57 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
58 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
59 Ethylene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
60 Cl2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
61 12-ClC2 483.9969 0.2549 47896.2335 0.4077 38.3170 0.3316
62 HCl 700.5639 0.3689 25543.1219 0.2174 29.3488 0.2540
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 59 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 18 (continued) Property Package: SRK
8
9
10
COMPOSITION
11
12
Vapour Phase (continued) Phase Fraction 1.000

13 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
14 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
15 VinylCl 700.5639 0.3689 43779.6423 0.3727 47.6250 0.4122
16 H2O 13.8483 0.0073 249.4776 0.0021 0.2500 0.0022
17 Oxygen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 Nitrogen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 1898.9730 1.0000 117468.4753 1.0000 115.5408 1.0000
20
21
Liquid Phase Phase Fraction 0.0000

22 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
23 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
24 Ethylene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
25 Cl2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
26 12-ClC2 0.0000 0.2549 0.0000 0.4078 0.0000 0.3317
27 HCl 0.0000 0.3689 0.0000 0.2174 0.0000 0.2540
28 VinylCl 0.0000 0.3689 0.0000 0.3727 0.0000 0.4122
29 H2O 0.0000 0.0073 0.0000 0.0021 0.0000 0.0022
30 Oxygen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
31 Nitrogen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
32 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
33
34
K VALUE
35 COMPONENTS MIXED LIGHT HEAVY
36 Ethylene 0.0000 0.0000 ---
37 Cl2 0.0000 0.0000 ---
38 12-ClC2 0.9999 0.9999 ---
39 HCl 1.000 1.000 ---
40 VinylCl 1.000 1.000 ---
41 H2O 1.000 1.000 ---
42 Oxygen 0.0000 0.0000 ---
43 Nitrogen 0.0000 0.0000 ---
44
45
UNIT OPERATIONS
46 FEED TO PRODUCT FROM LOGICAL CONNECTION
47 Cooler: Quench Plug Flow Reactor: Reactor 3 Set: SET-3
48
49
UTILITIES
50 ( No utilities reference this stream )
51
52
PROCESS UTILITY
53
54
55
DYNAMICS
56 Pressure Specification (Inactive): 2634 kPa
57 Flow Specification (Inactive) Molar: 1899 kgmole/h Mass: 1.175e+005 kg/h Std Ideal Liq Volume: 115.5 m3/h
58
59
User Variables
60
61
NOTES
62
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 60 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 18 (continued) Property Package: SRK
8
9
10
Description
11
12
Fluid Package: Basis-1
13 Material Stream: 19 Property Package: SRK
14
15
16
CONDITIONS
17 Overall Vapour Phase
18 Vapour / Phase Fraction 1.0000 1.0000
19 Temperature: (C) 186.0 * 186.0
20 Pressure: (kPa) 2634 2634
21 Molar Flow (kgmole/h) 1899 1899
22 Mass Flow (kg/h) 1.175e+005 1.175e+005
23 Std Ideal Liq Vol Flow (m3/h) 115.5 115.5
24 Molar Enthalpy (kJ/kgmole) -4.849e+004 -4.849e+004
25 Molar Entropy (kJ/kgmole-C) 170.9 170.9
26 Heat Flow (kJ/h) -9.208e+007 -9.208e+007
27 Liq Vol Flow @Std Cond (m3/h) 110.9 * 110.9
28
29
PROPERTIES
30 Overall Vapour Phase
31 Molecular Weight 61.86 61.86
32 Molar Density (kgmole/m3) 0.7959 0.7959
33 Mass Density (kg/m3) 49.23 49.23
34 Act. Volume Flow (m3/h) 2386 2386
35 Mass Enthalpy (kJ/kg) -783.8 -783.8
36 Mass Entropy (kJ/kg-C) 2.762 2.762
37 Heat Capacity (kJ/kgmole-C) 71.00 71.00
38 Mass Heat Capacity (kJ/kg-C) 1.148 1.148
39 LHV Molar Basis (Std) (kJ/kgmole) 7.194e+005 7.194e+005
40 HHV Molar Basis (Std) (kJ/kgmole) 7.633e+005 7.633e+005
41 HHV Mass Basis (Std) (kJ/kg) 1.234e+004 1.234e+004
42 CO2 Loading --- ---
43 CO2 Apparent Mole Conc. (kgmole/m3) --- ---
44 CO2 Apparent Wt. Conc. (kgmol/kg) --- ---
45 LHV Mass Basis (Std) (kJ/kg) 1.163e+004 1.163e+004
46 Phase Fraction [Vol. Basis] 1.000 1.000
47 Phase Fraction [Mass Basis] 1.000 1.000
48 Phase Fraction [Act. Vol. Basis] 1.000 1.000
49 Mass Exergy (kJ/kg) 152.8 ---
50 Partial Pressure of CO2 (kPa) 0.0000 ---
51 Cost Based on Flow (Cost/s) 0.0000 0.0000
52 Act. Gas Flow (ACT_m3/h) 2386 2386
53 Avg. Liq. Density (kgmole/m3) 16.44 16.44
54 Specific Heat (kJ/kgmole-C) 71.00 71.00
55 Std. Gas Flow (STD_m3/h) 4.490e+004 4.490e+004
56 Std. Ideal Liq. Mass Density (kg/m3) 1017 1017
57 Act. Liq. Flow (m3/s) --- ---
58 Z Factor 0.8671 0.8671
59 Watson K 7.653 7.653
60 User Property --- ---
61 Partial Pressure of H2S (kPa) 0.0000 ---
62 Cp/(Cp - R) 1.133 1.133
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 61 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 19 (continued) Property Package: SRK
8
9
10
PROPERTIES
11 Overall Vapour Phase
12 Cp/Cv 1.281 1.281
13 Ideal Gas Cp/Cv 1.153 1.153
14 Ideal Gas Cp (kJ/kgmole-C) 62.74 62.74
15 Mass Ideal Gas Cp (kJ/kg-C) 1.014 1.014
16 Heat of Vap. (kJ/kgmole) 2.465e+004 ---
17 Kinematic Viscosity (cSt) 0.3601 0.3601
18 Liq. Mass Density (Std. Cond) (kg/m3) 1059 1059
19 Liq. Vol. Flow (Std. Cond) (m3/h) 110.9 110.9
20 Liquid Fraction 0.0000 0.0000
21 Molar Volume (m3/kgmole) 1.256 1.256
22 Mass Heat of Vap. (kJ/kg) 398.5 ---
23 Phase Fraction [Molar Basis] 1.0000 1.0000
24 Surface Tension (dyne/cm) --- ---
25 Thermal Conductivity (W/m-K) 2.338e-002 2.338e-002
26 Bubble Point Pressure (kPa) 9652 ---
27 Viscosity (cP) 1.773e-002 1.773e-002
28 Cv (Semi-Ideal) (kJ/kgmole-C) 62.69 62.69
29 Mass Cv (Semi-Ideal) (kJ/kg-C) 1.013 1.013
30 Cv (kJ/kgmole-C) 55.44 55.44
31 Mass Cv (kJ/kg-C) 0.8963 0.8963
32 Cv (Ent. Method) (kJ/kgmole-C) --- ---
33 Mass Cv (Ent. Method) (kJ/kg-C) --- ---
34 Cp/Cv (Ent. Method) --- ---
35 Reid VP at 37.8 C (kPa) 1669 1669
36 True VP at 37.8 C (kPa) 2089 2089
37 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 110.9 110.9
38 Viscosity Index --- ---
39
40
COMPOSITION
41
42
Overall Phase Vapour Fraction 1.0000

43 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
44 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
45 Ethylene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
46 Cl2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
47 12-ClC2 483.9969 0.2549 47896.2335 0.4077 38.3170 0.3316
48 HCl 700.5639 0.3689 25543.1219 0.2174 29.3488 0.2540
49 VinylCl 700.5639 0.3689 43779.6423 0.3727 47.6250 0.4122
50 H2O 13.8483 0.0073 249.4776 0.0021 0.2500 0.0022
51 Oxygen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
52 Nitrogen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
53 Total 1898.9730 1.0000 117468.4753 1.0000 115.5408 1.0000
54
55
Vapour Phase Phase Fraction 1.000

56 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
57 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
58 Ethylene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
59 Cl2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
60 12-ClC2 483.9969 0.2549 47896.2335 0.4077 38.3170 0.3316
61 HCl 700.5639 0.3689 25543.1219 0.2174 29.3488 0.2540
62 VinylCl 700.5639 0.3689 43779.6423 0.3727 47.6250 0.4122
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 62 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 19 (continued) Property Package: SRK
8
9
10
COMPOSITION
11
12
Vapour Phase (continued) Phase Fraction 1.000

13 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
14 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
15 H2O 13.8483 0.0073 249.4776 0.0021 0.2500 0.0022
16 Oxygen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
17 Nitrogen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 Total 1898.9730 1.0000 117468.4753 1.0000 115.5408 1.0000
19
20
K VALUE
21 COMPONENTS MIXED LIGHT HEAVY
22 Ethylene --- --- ---
23 Cl2 --- --- ---
24 12-ClC2 --- --- ---
25 HCl --- --- ---
26 VinylCl --- --- ---
27 H2O --- --- ---
28 Oxygen --- --- ---
29 Nitrogen --- --- ---
30
31
UNIT OPERATIONS
32 FEED TO PRODUCT FROM LOGICAL CONNECTION
33 Cooler: Condenser Cooler: Quench
34
35
UTILITIES
36 ( No utilities reference this stream )
37
38
PROCESS UTILITY
39
40
41
DYNAMICS
42 Pressure Specification (Inactive): 2634 kPa
43 Flow Specification (Inactive) Molar: 1899 kgmole/h Mass: 1.175e+005 kg/h Std Ideal Liq Volume: 115.5 m3/h
44
45
User Variables
46
47
NOTES
48
49
50
Description
51
52
Fluid Package: Basis-1
53 Material Stream: 20 Property Package: SRK
54
55
56
CONDITIONS
57 Overall Liquid Phase
58 Vapour / Phase Fraction 0.0000 1.0000
59 Temperature: (C) 50.00 * 50.00
60 Pressure: (kPa) 2634 2634
61 Molar Flow (kgmole/h) 1899 1899
62 Mass Flow (kg/h) 1.175e+005 1.175e+005
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 63 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 20 (continued) Property Package: SRK
8
9
10
CONDITIONS
11 Overall Liquid Phase
12 Std Ideal Liq Vol Flow (m3/h) 115.5 115.5
13 Molar Enthalpy (kJ/kgmole) -7.514e+004 -7.514e+004
14 Molar Entropy (kJ/kgmole-C) 101.0 101.0
15 Heat Flow (kJ/h) -1.427e+008 -1.427e+008
16 Liq Vol Flow @Std Cond (m3/h) 110.9 * 110.9
17
18
PROPERTIES
19 Overall Liquid Phase
20 Molecular Weight 61.86 61.86
21 Molar Density (kgmole/m3) 15.94 15.94
22 Mass Density (kg/m3) 986.2 986.2
23 Act. Volume Flow (m3/h) 119.1 119.1
24 Mass Enthalpy (kJ/kg) -1215 -1215
25 Mass Entropy (kJ/kg-C) 1.633 1.633
26 Heat Capacity (kJ/kgmole-C) 98.35 98.35
27 Mass Heat Capacity (kJ/kg-C) 1.590 1.590
28 LHV Molar Basis (Std) (kJ/kgmole) 7.194e+005 7.194e+005
29 HHV Molar Basis (Std) (kJ/kgmole) 7.633e+005 7.633e+005
30 HHV Mass Basis (Std) (kJ/kg) 1.234e+004 1.234e+004
31 CO2 Loading --- ---
32 CO2 Apparent Mole Conc. (kgmole/m3) --- ---
33 CO2 Apparent Wt. Conc. (kgmol/kg) --- ---
34 LHV Mass Basis (Std) (kJ/kg) 1.163e+004 1.163e+004
35 Phase Fraction [Vol. Basis] 0.0000 1.000
36 Phase Fraction [Mass Basis] 0.0000 1.000
37 Phase Fraction [Act. Vol. Basis] 0.0000 1.000
38 Mass Exergy (kJ/kg) 58.70 ---
39 Partial Pressure of CO2 (kPa) 0.0000 ---
40 Cost Based on Flow (Cost/s) 0.0000 0.0000
41 Act. Gas Flow (ACT_m3/h) --- ---
42 Avg. Liq. Density (kgmole/m3) 16.44 16.44
43 Specific Heat (kJ/kgmole-C) 98.35 98.35
44 Std. Gas Flow (STD_m3/h) 4.490e+004 4.490e+004
45 Std. Ideal Liq. Mass Density (kg/m3) 1017 1017
46 Act. Liq. Flow (m3/s) 3.309e-002 3.309e-002
47 Z Factor 6.150e-002 6.150e-002
48 Watson K 7.653 7.653
49 User Property --- ---
50 Partial Pressure of H2S (kPa) 0.0000 ---
51 Cp/(Cp - R) 1.092 1.092
52 Cp/Cv 1.092 1.092
53 Ideal Gas Cp/Cv 1.187 1.187
54 Ideal Gas Cp (kJ/kgmole-C) 52.82 52.82
55 Mass Ideal Gas Cp (kJ/kg-C) 0.8539 0.8539
56 Heat of Vap. (kJ/kgmole) 2.465e+004 ---
57 Kinematic Viscosity (cSt) 0.2107 0.2107
58 Liq. Mass Density (Std. Cond) (kg/m3) 1059 1059
59 Liq. Vol. Flow (Std. Cond) (m3/h) 110.9 110.9
60 Liquid Fraction 1.000 1.000
61 Molar Volume (m3/kgmole) 6.272e-002 6.272e-002
62 Mass Heat of Vap. (kJ/kg) 398.5 ---
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 64 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 20 (continued) Property Package: SRK
8
9
10
PROPERTIES
11 Overall Liquid Phase
12 Phase Fraction [Molar Basis] 0.0000 1.0000
13 Surface Tension (dyne/cm) 11.90 11.90
14 Thermal Conductivity (W/m-K) 8.562e-002 8.562e-002
15 Bubble Point Pressure (kPa) 2591 ---
16 Viscosity (cP) 0.2078 0.2078
17 Cv (Semi-Ideal) (kJ/kgmole-C) 90.04 90.04
18 Mass Cv (Semi-Ideal) (kJ/kg-C) 1.456 1.456
19 Cv (kJ/kgmole-C) 90.04 90.04
20 Mass Cv (kJ/kg-C) 1.456 1.456
21 Cv (Ent. Method) (kJ/kgmole-C) --- ---
22 Mass Cv (Ent. Method) (kJ/kg-C) --- ---
23 Cp/Cv (Ent. Method) --- ---
24 Reid VP at 37.8 C (kPa) 1669 1669
25 True VP at 37.8 C (kPa) 2089 2089
26 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 110.9 110.9
27 Viscosity Index -55.09 ---
28
29
COMPOSITION
30
31
Overall Phase Vapour Fraction 0.0000

32 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
33 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
34 Ethylene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
35 Cl2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
36 12-ClC2 483.9969 0.2549 47896.2335 0.4077 38.3170 0.3316
37 HCl 700.5639 0.3689 25543.1219 0.2174 29.3488 0.2540
38 VinylCl 700.5639 0.3689 43779.6423 0.3727 47.6250 0.4122
39 H2O 13.8483 0.0073 249.4776 0.0021 0.2500 0.0022
40 Oxygen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
41 Nitrogen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
42 Total 1898.9730 1.0000 117468.4753 1.0000 115.5408 1.0000
43
44
Liquid Phase Phase Fraction 1.000

45 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
46 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
47 Ethylene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
48 Cl2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
49 12-ClC2 483.9969 0.2549 47896.2335 0.4077 38.3170 0.3316
50 HCl 700.5639 0.3689 25543.1219 0.2174 29.3488 0.2540
51 VinylCl 700.5639 0.3689 43779.6423 0.3727 47.6250 0.4122
52 H2O 13.8483 0.0073 249.4776 0.0021 0.2500 0.0022
53 Oxygen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
54 Nitrogen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
55 Total 1898.9730 1.0000 117468.4753 1.0000 115.5408 1.0000
56
57
K VALUE
58 COMPONENTS MIXED LIGHT HEAVY
59 Ethylene 0.0000 0.0000 ---
60 Cl2 0.0000 0.0000 ---
61 12-ClC2 0.0000 0.0000 ---
62 HCl 0.0000 0.0000 ---
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 65 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 20 (continued) Property Package: SRK
8
9
10
K VALUE
11 COMPONENTS MIXED LIGHT HEAVY
12 VinylCl 0.0000 0.0000 ---
13 H2O 0.0000 0.0000 ---
14 Oxygen 0.0000 0.0000 ---
15 Nitrogen 0.0000 0.0000 ---
16
17
UNIT OPERATIONS
18 FEED TO PRODUCT FROM LOGICAL CONNECTION
19 Valve: VLV-100 Cooler: Condenser
20
21
UTILITIES
22 ( No utilities reference this stream )
23
24
PROCESS UTILITY
25
26
27
DYNAMICS
28 Pressure Specification (Inactive): 2634 kPa
29 Flow Specification (Inactive) Molar: 1899 kgmole/h Mass: 1.175e+005 kg/h Std Ideal Liq Volume: 115.5 m3/h
30
31
User Variables
32
33
NOTES
34
35
36
Description
37
38
Fluid Package: Basis-1
39 Material Stream: 21 Property Package: SRK
40
41
42
CONDITIONS
43 Overall Vapour Phase Liquid Phase
44 Vapour / Phase Fraction 0.1239 0.1239 0.8761
45 Temperature: (C) 33.75 33.75 33.75
46 Pressure: (kPa) 1621 * 1621 1621
47 Molar Flow (kgmole/h) 1899 235.3 1664
48 Mass Flow (kg/h) 1.175e+005 9611 1.079e+005
49 Std Ideal Liq Vol Flow (m3/h) 115.5 10.87 104.7
50 Molar Enthalpy (kJ/kgmole) -7.514e+004 -7.300e+004 -7.544e+004
51 Molar Entropy (kJ/kgmole-C) 101.5 142.1 95.70
52 Heat Flow (kJ/h) -1.427e+008 -1.718e+007 -1.255e+008
53 Liq Vol Flow @Std Cond (m3/h) 110.9 * 10.58 101.0
54
55
PROPERTIES
56 Overall Vapour Phase Liquid Phase
57 Molecular Weight 61.86 40.84 64.83
58 Molar Density (kgmole/m3) 4.384 0.7161 15.92
59 Mass Density (kg/m3) 271.2 29.25 1032
60 Act. Volume Flow (m3/h) 433.1 328.6 104.5
61 Mass Enthalpy (kJ/kg) -1215 -1787 -1164
62 Mass Entropy (kJ/kg-C) 1.640 3.479 1.476
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 66 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 21 (continued) Property Package: SRK
8
9
10
PROPERTIES
11 Overall Vapour Phase Liquid Phase
12 Heat Capacity (kJ/kgmole-C) 89.19 39.17 96.27
13 Mass Heat Capacity (kJ/kg-C) 1.442 0.9591 1.485
14 LHV Molar Basis (Std) (kJ/kgmole) 7.194e+005 2.121e+005 7.911e+005
15 HHV Molar Basis (Std) (kJ/kgmole) 7.633e+005 2.222e+005 8.398e+005
16 HHV Mass Basis (Std) (kJ/kg) 1.234e+004 5440 1.295e+004
17 CO2 Loading --- --- ---
18 CO2 Apparent Mole Conc. (kgmole/m3) --- --- ---
19 CO2 Apparent Wt. Conc. (kgmol/kg) --- --- ---
20 LHV Mass Basis (Std) (kJ/kg) 1.163e+004 5192 1.220e+004
21 Phase Fraction [Vol. Basis] 9.404e-002 9.404e-002 0.9060
22 Phase Fraction [Mass Basis] 8.182e-002 8.182e-002 0.9182
23 Phase Fraction [Act. Vol. Basis] 0.7587 0.7587 0.2413
24 Mass Exergy (kJ/kg) 56.55 --- ---
25 Partial Pressure of CO2 (kPa) 0.0000 --- ---
26 Cost Based on Flow (Cost/s) 0.0000 0.0000 0.0000
27 Act. Gas Flow (ACT_m3/h) 328.6 328.6 ---
28 Avg. Liq. Density (kgmole/m3) 16.44 21.66 15.89
29 Specific Heat (kJ/kgmole-C) 89.19 39.17 96.27
30 Std. Gas Flow (STD_m3/h) 4.490e+004 5564 3.934e+004
31 Std. Ideal Liq. Mass Density (kg/m3) 1017 884.6 1030
32 Act. Liq. Flow (m3/s) 2.903e-002 --- 2.903e-002
33 Z Factor --- 0.8872 3.991e-002
34 Watson K 7.653 8.057 7.624
35 User Property --- --- ---
36 Partial Pressure of H2S (kPa) 0.0000 --- ---
37 Cp/(Cp - R) 1.103 1.269 1.095
38 Cp/Cv 1.024 1.505 1.095
39 Ideal Gas Cp/Cv 1.193 1.327 1.182
40 Ideal Gas Cp (kJ/kgmole-C) 51.48 33.76 53.99
41 Mass Ideal Gas Cp (kJ/kg-C) 0.8322 0.8266 0.8328
42 Heat of Vap. (kJ/kgmole) 2.667e+004 --- ---
43 Kinematic Viscosity (cSt) --- 0.4734 0.2574
44 Liq. Mass Density (Std. Cond) (kg/m3) 1059 908.8 1068
45 Liq. Vol. Flow (Std. Cond) (m3/h) 110.9 10.58 101.0
46 Liquid Fraction 0.8761 0.0000 1.000
47 Molar Volume (m3/kgmole) 0.2281 1.396 6.282e-002
48 Mass Heat of Vap. (kJ/kg) 431.1 --- ---
49 Phase Fraction [Molar Basis] 0.1239 0.1239 0.8761
50 Surface Tension (dyne/cm) 15.57 --- 15.57
51 Thermal Conductivity (W/m-K) --- 1.767e-002 0.1075
52 Bubble Point Pressure (kPa) 1937 --- ---
53 Viscosity (cP) --- 1.385e-002 0.2656
54 Cv (Semi-Ideal) (kJ/kgmole-C) 80.88 30.86 87.95
55 Mass Cv (Semi-Ideal) (kJ/kg-C) 1.307 0.7555 1.357
56 Cv (kJ/kgmole-C) 87.11 26.02 87.95
57 Mass Cv (kJ/kg-C) 1.408 0.6372 1.357
58 Cv (Ent. Method) (kJ/kgmole-C) --- --- ---
59 Mass Cv (Ent. Method) (kJ/kg-C) --- --- ---
60 Cp/Cv (Ent. Method) --- --- ---
61 Reid VP at 37.8 C (kPa) 1669 4553 1385
62 True VP at 37.8 C (kPa) 2089 4930 1749
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 67 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 21 (continued) Property Package: SRK
8
9
10
PROPERTIES
11 Overall Vapour Phase Liquid Phase
12 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 111.6 10.58 101.0
13 Viscosity Index -35.36 --- ---
14
15
COMPOSITION
16
17
Overall Phase Vapour Fraction 0.1239

18 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
19 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
20 Ethylene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
21 Cl2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
22 12-ClC2 483.9969 0.2549 47896.2335 0.4077 38.3170 0.3316
23 HCl 700.5639 0.3689 25543.1219 0.2174 29.3488 0.2540
24 VinylCl 700.5639 0.3689 43779.6423 0.3727 47.6250 0.4122
25 H2O 13.8483 0.0073 249.4776 0.0021 0.2500 0.0022
26 Oxygen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
27 Nitrogen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
28 Total 1898.9730 1.0000 117468.4753 1.0000 115.5408 1.0000
29
30
Vapour Phase Phase Fraction 0.1239

31 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
32 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
33 Ethylene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
34 Cl2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
35 12-ClC2 1.0288 0.0044 101.8097 0.0106 0.0814 0.0075
36 HCl 196.8871 0.8366 7178.6624 0.7469 8.2482 0.7592
37 VinylCl 37.2522 0.1583 2327.9676 0.2422 2.5324 0.2331
38 H2O 0.1619 0.0007 2.9168 0.0003 0.0029 0.0003
39 Oxygen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 Nitrogen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
41 Total 235.3301 1.0000 9611.3565 1.0000 10.8650 1.0000
42
43
Liquid Phase Phase Fraction 0.8761

44 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
45 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
46 Ethylene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
47 Cl2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
48 12-ClC2 482.9681 0.2903 47794.4237 0.4431 38.2355 0.3653
49 HCl 503.6768 0.3028 18364.4595 0.1703 21.1006 0.2016
50 VinylCl 663.3117 0.3987 41451.6747 0.3843 45.0926 0.4308
51 H2O 13.6863 0.0082 246.5608 0.0023 0.2471 0.0024
52 Oxygen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
53 Nitrogen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
54 Total 1663.6429 1.0000 107857.1188 1.0000 104.6758 1.0000
55
56
K VALUE
57 COMPONENTS MIXED LIGHT HEAVY
58 Ethylene 0.0000 0.0000 ---
59 Cl2 0.0000 0.0000 ---
60 12-ClC2 1.506e-002 1.506e-002 ---
61 HCl 2.763 2.763 ---
62 VinylCl 0.3970 0.3970 ---
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 68 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 21 (continued) Property Package: SRK
8
9
10
K VALUE
11 COMPONENTS MIXED LIGHT HEAVY
12 H2O 8.363e-002 8.363e-002 ---
13 Oxygen 0.0000 0.0000 ---
14 Nitrogen 0.0000 0.0000 ---
15
16
UNIT OPERATIONS
17 FEED TO PRODUCT FROM LOGICAL CONNECTION
18 Distillation: column 1 Valve: VLV-100
19
20
UTILITIES
21 ( No utilities reference this stream )
22
23
PROCESS UTILITY
24
25
26
DYNAMICS
27 Pressure Specification (Active): 1621 kPa *
28 Flow Specification (Inactive) Molar: 1899 kgmole/h Mass: 1.175e+005 kg/h Std Ideal Liq Volume: 115.5 m3/h
29
30
User Variables
31
32
NOTES
33
34
35
Description
36
37
Fluid Package: Basis-1
38 Material Stream: 22 Property Package: SRK
39
40
41
CONDITIONS
42 Overall Liquid Phase
43 Vapour / Phase Fraction 0.0000 1.0000
44 Temperature: (C) 90.00 * 90.00
45 Pressure: (kPa) 486.4 486.4
46 Molar Flow (kgmole/h) 494.0 494.0
47 Mass Flow (kg/h) 4.808e+004 4.808e+004
48 Std Ideal Liq Vol Flow (m3/h) 38.50 38.50
49 Molar Enthalpy (kJ/kgmole) -1.599e+005 -1.599e+005
50 Molar Entropy (kJ/kgmole-C) 163.4 163.4
51 Heat Flow (kJ/h) -7.902e+007 -7.902e+007
52 Liq Vol Flow @Std Cond (m3/h) 38.47 * 38.47
53
54
PROPERTIES
55 Overall Liquid Phase
56 Molecular Weight 97.32 97.32
57 Molar Density (kgmole/m3) 11.71 11.71
58 Mass Density (kg/m3) 1139 1139
59 Act. Volume Flow (m3/h) 42.20 42.20
60 Mass Enthalpy (kJ/kg) -1643 -1643
61 Mass Entropy (kJ/kg-C) 1.679 1.679
62 Heat Capacity (kJ/kgmole-C) 135.3 135.3
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 69 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 22 (continued) Property Package: SRK
8
9
10
PROPERTIES
11 Overall Liquid Phase
12 Mass Heat Capacity (kJ/kg-C) 1.391 1.391
13 LHV Molar Basis (Std) (kJ/kgmole) 1.083e+006 1.083e+006
14 HHV Molar Basis (Std) (kJ/kgmole) 1.164e+006 1.164e+006
15 HHV Mass Basis (Std) (kJ/kg) 1.196e+004 1.196e+004
16 CO2 Loading --- ---
17 CO2 Apparent Mole Conc. (kgmole/m3) --- ---
18 CO2 Apparent Wt. Conc. (kgmol/kg) --- ---
19 LHV Mass Basis (Std) (kJ/kg) 1.112e+004 1.112e+004
20 Phase Fraction [Vol. Basis] 0.0000 1.000
21 Phase Fraction [Mass Basis] 0.0000 1.000
22 Phase Fraction [Act. Vol. Basis] 0.0000 1.000
23 Mass Exergy (kJ/kg) 8.684 ---
24 Partial Pressure of CO2 (kPa) 0.0000 ---
25 Cost Based on Flow (Cost/s) 0.0000 0.0000
26 Act. Gas Flow (ACT_m3/h) --- ---
27 Avg. Liq. Density (kgmole/m3) 12.83 12.83
28 Specific Heat (kJ/kgmole-C) 135.3 135.3
29 Std. Gas Flow (STD_m3/h) 1.168e+004 1.168e+004
30 Std. Ideal Liq. Mass Density (kg/m3) 1249 1249
31 Act. Liq. Flow (m3/s) 1.172e-002 1.172e-002
32 Z Factor 1.376e-002 1.376e-002
33 Watson K 6.888 6.888
34 User Property --- ---
35 Partial Pressure of H2S (kPa) 0.0000 ---
36 Cp/(Cp - R) 1.065 1.065
37 Cp/Cv 1.472 1.472
38 Ideal Gas Cp/Cv 1.107 1.107
39 Ideal Gas Cp (kJ/kgmole-C) 86.02 86.02
40 Mass Ideal Gas Cp (kJ/kg-C) 0.8839 0.8839
41 Heat of Vap. (kJ/kgmole) 2.965e+004 ---
42 Kinematic Viscosity (cSt) 0.3283 0.3283
43 Liq. Mass Density (Std. Cond) (kg/m3) 1250 1250
44 Liq. Vol. Flow (Std. Cond) (m3/h) 38.47 38.47
45 Liquid Fraction 1.000 1.000
46 Molar Volume (m3/kgmole) 8.541e-002 8.541e-002
47 Mass Heat of Vap. (kJ/kg) 304.6 ---
48 Phase Fraction [Molar Basis] 0.0000 1.0000
49 Surface Tension (dyne/cm) 23.07 23.07
50 Thermal Conductivity (W/m-K) 0.1150 0.1150
51 Bubble Point Pressure (kPa) 117.7 ---
52 Viscosity (cP) 0.3740 0.3740
53 Cv (Semi-Ideal) (kJ/kgmole-C) 127.0 127.0
54 Mass Cv (Semi-Ideal) (kJ/kg-C) 1.305 1.305
55 Cv (kJ/kgmole-C) 91.91 91.91
56 Mass Cv (kJ/kg-C) 0.9444 0.9444
57 Cv (Ent. Method) (kJ/kgmole-C) 86.42 86.42
58 Mass Cv (Ent. Method) (kJ/kg-C) 0.8880 0.8880
59 Cp/Cv (Ent. Method) 1.566 1.566
60 Reid VP at 37.8 C (kPa) 15.94 15.94
61 True VP at 37.8 C (kPa) 17.07 17.07
62 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 38.47 38.47
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 70 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 22 (continued) Property Package: SRK
8
9
10
PROPERTIES
11 Overall Liquid Phase
12 Viscosity Index -19.76 ---
13
14
COMPOSITION
15
16
Overall Phase Vapour Fraction 0.0000

17 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
18 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
19 Ethylene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
20 Cl2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
21 12-ClC2 483.9966 0.9797 47896.2100 0.9962 38.3170 0.9952
22 HCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
23 VinylCl 0.0694 0.0001 4.3384 0.0001 0.0047 0.0001
24 H2O 9.9751 0.0202 179.7030 0.0037 0.1801 0.0047
25 Oxygen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
26 Nitrogen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
27 Total 494.0412 1.0000 48080.2513 1.0000 38.5018 1.0000
28
29
Liquid Phase Phase Fraction 1.000

30 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
31 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
32 Ethylene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
33 Cl2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
34 12-ClC2 483.9966 0.9797 47896.2100 0.9962 38.3170 0.9952
35 HCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
36 VinylCl 0.0694 0.0001 4.3384 0.0001 0.0047 0.0001
37 H2O 9.9751 0.0202 179.7030 0.0037 0.1801 0.0047
38 Oxygen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 Nitrogen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 Total 494.0412 1.0000 48080.2513 1.0000 38.5018 1.0000
41
42
K VALUE
43 COMPONENTS MIXED LIGHT HEAVY
44 Ethylene 0.0000 0.0000 ---
45 Cl2 0.0000 0.0000 ---
46 12-ClC2 0.0000 0.0000 ---
47 HCl 0.0000 0.0000 ---
48 VinylCl 0.0000 0.0000 ---
49 H2O 0.0000 0.0000 ---
50 Oxygen 0.0000 0.0000 ---
51 Nitrogen 0.0000 0.0000 ---
52
53
UNIT OPERATIONS
54 FEED TO PRODUCT FROM LOGICAL CONNECTION
55 Recycle: RCY-2 Cooler: E-105
56
57
UTILITIES
58 ( No utilities reference this stream )
59
60
PROCESS UTILITY
61
62
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 71 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 22 (continued) Property Package: SRK
8
9
10
DYNAMICS
11 Pressure Specification (Inactive): 486.4 kPa
12 Flow Specification (Inactive) Molar: 494.0 kgmole/h Mass: 4.808e+004 kg/h Std Ideal Liq Volume: 38.50 m3/h
13
14
User Variables
15
16
NOTES
17
18
19
Description
20
21
Fluid Package: Basis-1
22 Material Stream: 23 Property Package: SRK
23
24
25
CONDITIONS
26 Overall Vapour Phase
27 Vapour / Phase Fraction 1.0000 1.0000
28 Temperature: (C) 90.00 * 90.00
29 Pressure: (kPa) 1621 1621
30 Molar Flow (kgmole/h) 707.0 707.0
31 Mass Flow (kg/h) 2.595e+004 2.595e+004
32 Std Ideal Liq Vol Flow (m3/h) 29.79 29.79
33 Molar Enthalpy (kJ/kgmole) -8.975e+004 -8.975e+004
34 Molar Entropy (kJ/kgmole-C) 153.0 153.0
35 Heat Flow (kJ/h) -6.345e+007 -6.345e+007
36 Liq Vol Flow @Std Cond (m3/h) 29.63 * 29.63
37
38
PROPERTIES
39 Overall Vapour Phase
40 Molecular Weight 36.70 36.70
41 Molar Density (kgmole/m3) 0.5642 0.5642
42 Mass Density (kg/m3) 20.71 20.71
43 Act. Volume Flow (m3/h) 1253 1253
44 Mass Enthalpy (kJ/kg) -2445 -2445
45 Mass Entropy (kJ/kg-C) 4.169 4.169
46 Heat Capacity (kJ/kgmole-C) 32.28 32.28
47 Mass Heat Capacity (kJ/kg-C) 0.8796 0.8796
48 LHV Molar Basis (Std) (kJ/kgmole) 3.895e+004 3.895e+004
49 HHV Molar Basis (Std) (kJ/kgmole) 3.952e+004 3.952e+004
50 HHV Mass Basis (Std) (kJ/kg) 1077 1077
51 CO2 Loading --- ---
52 CO2 Apparent Mole Conc. (kgmole/m3) --- ---
53 CO2 Apparent Wt. Conc. (kgmol/kg) --- ---
54 LHV Mass Basis (Std) (kJ/kg) 1061 1061
55 Phase Fraction [Vol. Basis] 1.000 1.000
56 Phase Fraction [Mass Basis] 1.000 1.000
57 Phase Fraction [Act. Vol. Basis] 1.000 1.000
58 Mass Exergy (kJ/kg) 187.1 ---
59 Partial Pressure of CO2 (kPa) 0.0000 ---
60 Cost Based on Flow (Cost/s) 0.0000 0.0000
61 Act. Gas Flow (ACT_m3/h) 1253 1253
62 Avg. Liq. Density (kgmole/m3) 23.73 23.73
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 72 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 23 (continued) Property Package: SRK
8
9
10
PROPERTIES
11 Overall Vapour Phase
12 Specific Heat (kJ/kgmole-C) 32.28 32.28
13 Std. Gas Flow (STD_m3/h) 1.672e+004 1.672e+004
14 Std. Ideal Liq. Mass Density (kg/m3) 871.1 871.1
15 Act. Liq. Flow (m3/s) --- ---
16 Z Factor 0.9517 0.9517
17 Watson K 7.997 7.997
18 User Property --- ---
19 Partial Pressure of H2S (kPa) 0.0000 ---
20 Cp/(Cp - R) 1.347 1.347
21 Cp/Cv 1.477 1.477
22 Ideal Gas Cp/Cv 1.387 1.387
23 Ideal Gas Cp (kJ/kgmole-C) 29.82 29.82
24 Mass Ideal Gas Cp (kJ/kg-C) 0.8124 0.8124
25 Heat of Vap. (kJ/kgmole) 1.348e+004 ---
26 Kinematic Viscosity (cSt) 0.8215 0.8215
27 Liq. Mass Density (Std. Cond) (kg/m3) 875.7 875.7
28 Liq. Vol. Flow (Std. Cond) (m3/h) 29.63 29.63
29 Liquid Fraction 0.0000 0.0000
30 Molar Volume (m3/kgmole) 1.772 1.772
31 Mass Heat of Vap. (kJ/kg) 367.4 ---
32 Phase Fraction [Molar Basis] 1.0000 1.0000
33 Surface Tension (dyne/cm) --- ---
34 Thermal Conductivity (W/m-K) 2.141e-002 2.141e-002
35 Bubble Point Pressure (kPa) --- ---
36 Viscosity (cP) 1.701e-002 1.701e-002
37 Cv (Semi-Ideal) (kJ/kgmole-C) 23.97 23.97
38 Mass Cv (Semi-Ideal) (kJ/kg-C) 0.6531 0.6531
39 Cv (kJ/kgmole-C) 21.86 21.86
40 Mass Cv (kJ/kg-C) 0.5956 0.5956
41 Cv (Ent. Method) (kJ/kgmole-C) --- ---
42 Mass Cv (Ent. Method) (kJ/kg-C) --- ---
43 Cp/Cv (Ent. Method) --- ---
44 Reid VP at 37.8 C (kPa) 6194 6194
45 True VP at 37.8 C (kPa) 6234 6234
46 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 29.63 29.63
47 Viscosity Index -34.05 ---
48
49
COMPOSITION
50
51
Overall Phase Vapour Fraction 1.0000

52 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
53 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
54 Ethylene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
55 Cl2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
56 12-ClC2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
57 HCl 700.4939 0.9908 25540.5671 0.9844 29.3458 0.9852
58 VinylCl 6.4793 0.0092 404.9015 0.0156 0.4405 0.0148
59 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
60 Oxygen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
61 Nitrogen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
62 Total 706.9731 1.0000 25945.4686 1.0000 29.7863 1.0000
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 73 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
Fluid Package: Basis-1
7 Material Stream: 23 (continued) Property Package: SRK
8
9
10
COMPOSITION
11
12
Vapour Phase Phase Fraction 1.000

13 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
14 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
15 Ethylene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
16 Cl2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
17 12-ClC2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 HCl 700.4939 0.9908 25540.5671 0.9844 29.3458 0.9852
19 VinylCl 6.4793 0.0092 404.9015 0.0156 0.4405 0.0148
20 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
21 Oxygen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
22 Nitrogen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
23 Total 706.9731 1.0000 25945.4686 1.0000 29.7863 1.0000
24
25
K VALUE
26 COMPONENTS MIXED LIGHT HEAVY
27 Ethylene --- --- ---
28 Cl2 --- --- ---
29 12-ClC2 --- --- ---
30 HCl --- --- ---
31 VinylCl --- --- ---
32 H2O --- --- ---
33 Oxygen --- --- ---
34 Nitrogen --- --- ---
35
36
UNIT OPERATIONS
37 FEED TO PRODUCT FROM LOGICAL CONNECTION
38 Recycle: RCY-3 Heater: E-106
39
40
UTILITIES
41 ( No utilities reference this stream )
42
43
PROCESS UTILITY
44
45
46
DYNAMICS
47 Pressure Specification (Inactive): 1621 kPa
48 Flow Specification (Inactive) Molar: 707.0 kgmole/h Mass: 2.595e+004 kg/h Std Ideal Liq Volume: 29.79 m3/h
49
50
User Variables
51
52
NOTES
53
54
55
Description
56
57
58 Adjust: ADJ-1
59
60
61
Adjusted Variable Measured Variable
62 OBJECT VARIABLE OBJECT VARIABLE
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 74 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.
1
Case Name: Aspen finally done.hsc
2 INDIAN INSTITUTE OF TECH
3 Bedford, MA Unit Set: SI10
4 USA
Date/Time: Mon Apr 29 19:26:23 2024
5
6
7 Adjust: ADJ-1 (continued)
8
9 Reactor-1 Tank Volume R1-SS B3: Residence Time
10
11
Solving Parameters
12 Source for Target Value: User Supplied Target Value: 1.800e-002 *
13 Solving Method: Secant Tolerance: 1.000e-003 * Maximum Iterations: 30 *
14 Step Size: 100.0 m3 Minimum: --- Maximum: ---
15
16
User Variables
17
18 Adjust: ADJ-2
19
20
21
Adjusted Variable Measured Variable
22 OBJECT VARIABLE OBJECT VARIABLE
23 Reactor-2 Reactor Volume R2-SS B3: Residence Time (h)
24
25
Solving Parameters
26 Source for Target Value: User Supplied Target Value: 5.000e-002 *
27 Solving Method: Secant Tolerance: 1.000e-003 * Maximum Iterations: 30 *
28 Step Size: 40.00 m3 * Minimum: --- Maximum: ---
29
30
User Variables
31
32 Adjust: ADJ-3
33
34
35
Adjusted Variable Measured Variable
36 OBJECT VARIABLE OBJECT VARIABLE
37 Reactor-2 Tube Length R2-SS B7: L/D
38
39
Solving Parameters
40 Source for Target Value: User Supplied Target Value: 1.500 *
41 Solving Method: Secant Tolerance: 1.000e-003 * Maximum Iterations: 10
42 Step Size: 12.50 m * Minimum: --- Maximum: ---
43
44
User Variables
45
46 Adjust: ADJ-4
47
48
49
Adjusted Variable Measured Variable
50 OBJECT VARIABLE OBJECT VARIABLE
51 Reactor 3 Reactor Volume R3-SS B3: Residence time
52
53
Solving Parameters
54 Source for Target Value: User Supplied Target Value: 8.300e-003 *
55 Solving Method: Secant Tolerance: 1.000e-003 * Maximum Iterations: 30 *
56 Step Size: 100.0 m3 Minimum: --- Maximum: ---
57
58
User Variables
59
60
61
62
63 Aspen Technology Inc. Aspen HYSYS Version 12.1 Page 75 of 75
Licensed to: INDIAN INSTITUTE OF TECH * Specified by user.