29-09-2024

9610ZJM801447240006 JM

PART 1 : PHYSICS

SACTION-A

1) A block of mass m is taken from A to B on an irregular shaped rough inclined slowly by applying a
needed tangential force (F) to the block. If WF is work done by applied force then (friction coefficient

= µ) :

(A) WF = mgH + µmgH

(B) WF = µmgD + mgH
(C) WF = mgH – µmgD
(D) W = –mgH – µmgD

2) A block of mass 2kg is moving with 10 m/s velocity on smooth fixed horizontal plane, what will the

maximum compression in spring?

(A) 1 cm
(B) 10 cm
(C) 1m
(D) 0.1 cm

3) The force acting on a body moving along x axis varies with the position of the particle as shown in
the fig. The body is in stable equilibrium at

(A)
(B)
(C) Both and
(D) Neither nor

4) Assume the aerodynamic drag force on a car is proportional to its speed. If the power output from
the engine is doubled, then the maximum speed of the car.
(A) is unchanged
increases by a factor of
(B)

(C) is also doubled

(D) increases by a factor of four

5) A circular smooth arc wire of radius 20 m is situated as shown in figure whose centre is at origin.
A small bead is released from A with zero speed and move on the wire to reach point B. Normal
contact force on the bead changes it's direction at point on C. OC makes angle θ with x-axis then :-

(A)

(B)

(C)

(D)

6) A stone tied to a string of length L is whirled in a vertical circle with the other end of the string at
the centre. At a certain instant of time, the stone is at its lowest position and has a speed u. The
magnitude of the change in its velocity as it reaches a position where the string is horizontal is-

(A)

(B)

(C)

(D)

7) Power supplied to a particle of mass 2 kg varies with time as P = watt. Here t is time in
second. If velocity of particle at t = 0 s is v = 0 m/s. The velocity of particle at time t = 2 s will be :-

(A) 1 m/s
(B) 4 m/s
(C) 2 m/s
(D) m/s

8) The potential energy function for a conservative force and its corresponding force curves are
shown. Which of the following is correct ?
(A)

(B)

(C)

(D)

9) A block of mass 2kg having 64 J kinetic energy initially moves on rough (µ = 0.8) horizontal
surface, what will be distance covered by block before it stops ?

(A) 8 m
(B) 4 m
(C) 6 m
(D) 10 m

10) A block of mass M kg is kept on a platform which starts accelerating upwards from rest with a
constant acceleration a m/s2. During the time interval T the work done by contact force on mass M is

(A)

(B) zero

(C)

(D)
11) Block 'm' is released from rest at natural length position of spring. For what minimum value of
m, 5kg block will lose the contact with ground.

(A) 5kg
(B) 10kg
(C) 2.5 kg
(D) Can't be determined

12) A small ball starts motion on a smooth inclined track which becomes loop of radius R in vertical

plane, When ball rises again.

(A) speed of the ball at highest point is zero but highest point is 2R above the ground.
(B) speed of the ball at highest point is non zero but highest point is 2R above the ground
speed of the ball is along horizontal at highest point and highest point is less than the 2R above
(C)
the ground.
speed of the ball is along horizontal at highest point but height of highest point above the
(D)
ground can not be calculated.

13) Velocity time graph of a particle is shown in the diagram. Choose the INCORRECT option.

(A) Work done by net force for part AB is positive.

(B) Work done by net force for part BC is zero.
(C) Work done by net force for part DE is negative.
(D) Work done by net force for part CD is negative

14) A body of mass 100 gm is rotating in a circular path of radius r with constant speed. The work
done in one complete revolution is

(A) 100 rJ

(B)
J

(C)
J
(D) zero

15) Block is taken toward left so that spring is compressed. Now the block is released from rest.
Block move on smooth horizontal surface after leaving spring, then on circular path of radius R. By
how much distance spring should be compressed so that block can complete circular motion:-

(A)
(B)
(C) 5R

(D)

16) A chain of mass M and length L is held on a frictionless table in such a way that its part is
hanging below the edge of table. The work done to pull the hanging part of chain is :-

(A)

(B) Zero

(C)

(D)

17) The work done by a force on a body moving from (1, 4)m to (3, 8) m is 44 J. The force can be :

(A)

(B)

(C)

(D)

18) A block of mass m is suspended by a light thread from an elevator. The elevator is accelerating
upward with uniform acceleration a. The work done by tension on the block during t seconds is (u =

0) :
(A)
(g + a) at2

(B)
(g – a)at2

(C)
gat2
(D) 0

19) A particle of mass m is bound by the linear potential U = kr, where k is a constant and r > 0 . It
is moving in a circular orbit of radius r0 about the origin :-

(A)
Its mechanical energy is .
(B) The speed is independent of value of radius
(C) The angular speed is independent of value of radius

(D)
Its mechanical energy is

20) A point object of mass 2 kg is moved from point A to point B very slowly on a curved path by
applying a tangential force on a curved path as shown in figure. Then find the work done by external
force in moving the body. Given that μs = 0.3, μk = 0.1 [g = 10 m/s2]

(A) 100 J
(B) 200 J
(C) 300 J
(D) 400 J

SECTION-B

1) The two blocks shown here are connected by an elastic string of force constant 100 N/m. The
block of mass 1 kg is released with string just taut. If the normal force on the 10 kg block is N

newton when 1 kg block has a speed of 1 m/sec; then find the value of .

2) A ball is projected with horizontal velocity at the bottom most point attached with
inextensible string of length R and fixed at O as shown. Tension in the string in horizontal position is
N × mg. The value of N is :-

3) A particle of mass 2 kg moves on a smooth horizontal plane under the action of a single force

. Under this force it is displaced from (0,0) to (1m, 1m). The initial speed of the
particle is m/s and final is m/s. Find the value of k.

4) One end of a spring of natural length ℓ and spring constant k is fixed at the ground and the other
is fitted with a smooth ring of mass m which is allowed to slide on a horizontal rod fixed at a height
ℓ (figure). Initially, the spring makes an angle of θ with the vertical when the system is released from

rest. If the speed of the ring when the spring becomes vertical is (2ℓ/3) m/s then the value tan

θ is find x.:

5)

A point mass of 0.5 kg is moving along x-axis as x = t2 + 2t, where, x is in meters and t is in seconds.
Find the work done (in J) by all the forces acting on the body during the time interval [ 0, 2s].

6) A block of mass 45 kg resting on a horizontal surface is acted upon by a force F which varies as
shown in the figure. If the coefficient of friction between the block and surface is 0.2, find the

displacement (in m) when the block will come to rest.

7) A single conservative force F(x) acts on 1 kg particle that moves along x–axis. The potential
energy U(x) is given by U(x) = (x–2)2 – 20. Where x is in meters and U(x) in joules. If particle has a
kinetic energy of 20 J at x = 5m, find mechanical energy (in joules) at x = 2m.
8) A mass m slides from rest at height h down a smooth curved surface which becomes horizontal at
zero height (see figure). A spring is fixed horizontally on the level part of the surface. The spring
constant is k N/m. When the mass encounters the spring it compresses it by an amount x = h/10.

If m = 1 kg, h = 5 m then find k /100.

9) Consider a force . The work done by this force in moving a particle from point A(1, 0)
to B(0, 1) along the line segment is (all quantities are in SI units):

10) A small block of mass 1 kg is placed at a distance 4m from open end on a truck starting from rest
with constant acceleration of 4 m/s2, if μs = 0.3 and μk = 0.2 between truck & block. Find KE of block
(in joule) w.r.t truck when it is about to fall.

PART 2 : CHEMISTRY

SECTION-A

1) If work done by the system is 300 joule when 100 cal. heat is supplied to it. The change in internal
energy during the process is :-

(A) – 200 Joule

(B) 400 Joule
(C) 720 Joule
(D) 120 Joule

2) The heat change for the following reaction at 298 K at constant pressure is A2B(s) → 2A(s) +
1/2B2(g), ΔH = +7.3 kcal The heat change at constant volume would be :

(A) 7.3 kcal

(B) More than 7.3kcal
(C) Zero
(D) Less than 7.3kcal

3) If 100 mole of H2O2 decompose at 1 bar and 300 K, the work done (kJ) by O2(g) as it expands
against 1 bar pressure is :
2H2O2(ℓ) 2H2O(ℓ) + O2(g)
(R = 8.3 J K mol–1)
–1

(A) -498.00
(B) -249.00
(C) -124.50
(D) -62.25

4) 10 moles of an ideal gas expand isothermally and reversibly from a pressure of 10 atm to one atm
pressure at 300 Kelvin. What is the largest mass which can be lifted through a height of 100 metres?

(A) 31842 kg
(B) 58.55 kg
(C) 342.58 kg
(D) 116.11 kg

5) Heat absorbed by a system in going through a cyclic process shown in figure is :

(A) 107 π J
(B) 106 π J
(C) 102 π J
(D) 104 π J

6) For a reversible adiabatic ideal gas expansion is equal to :

(A)

(B)

(C)

(D)
7) Select the correct statement:

Magnitude of work done by the system in case of infinite stage expansion is less than single
(A)
stage expansion in case of ideal gas subjected to isothermal process.
(B) Irreversible work is greater than reversible work in isothermal compression of ideal gas.
For an ideal gas in case of single stage isothermal expansion and compression system as well as
(C)
surrounding are restored back to their original states.
If ideal gas in thermodynamic equilibrium is taken from state A to state B, by four successive
(D)
single stage expansions. Then we can plot 4 points on the P-V indicator diagram.

8) One mole of an ideal gas is allowed to expand reversibly and adiabatically from a temperature of
27°C. If the work done by the gas in the process is 3 kJ, the final temperature will be equal to (CV =
20 J/K mol):-

(A) 100 K
(B) 450 K
(C) 150 K
(D) 400 K

9) The piece of zinc at a temperature of 20.0°C weighing 65.38 g is dropped into 180 g of boiling
water (T = 100°C). The specific heat of zinc is 0.400 J g–1 °C–1 and that of water is 4.20 J g–1°C–1. What
is the final common temperature reached by both the zinc and water :-

(A) 97.3°C
(B) 33.4°C
(C) 80.1°C
(D) 60.0°C

10) An ideal gas is taken around the cycle ABCA as shown in P-V diagram. The net work done by the
gas during the cycle is equal to :

(A) 12P1V1
(B) 6P1V1
(C) 5P1V1
(D) P1V1

11) At 27 °C latent heat of fusion of a compound is 2930 J/mol. Entropy change is -

(A) 9.77 J/mol –K

(B) 10.77 J/mol –K
(C) 9.07 J/mol –K
(D) 0.977 J/mol –K

12) One mole of an ideal gas is expanded isothermally and reversibly to half its initial pressure. ΔS
for the process in JK–1 mol–1 is : [ln 2 = .693 and R = 8.314 J/mol.K]

(A) 10.76
(B) 6.76
(C) 8.03
(D) 5.76

13) Calculate the equilibrium constant for the reaction PCl5(g) PCl3(g) + Cl2(g) at 400K is ΔH°=
69418.86J/mol and ΔS°= 154.4JK–1 mol–1 :

(A) 1
(B) 10
(C) 100
(D) 1000

14) Calculate the entropy change involved in the isothermal reversible expansion of 5 mol of ideal
gas from a volume of 10L to 100L at 300K :

(A) 191.47 JK–1

(B) 95.7 JK–1
(C) 41.57 JK–1
(D) 83.14 JK–1

15) For a perfectly crystalline solid Cp,m = aT3, where a is constant. If Cp,m is 0.42 J/K-mol at 10 K,
molar entropy at 10 K is

(A) 0.42 J/K-mol

(B) 0.14 J/K-mol
(C) 4.2 J/K-mol
(D) Zero

16) A process has ΔH = 200 Jmol–1 and ΔS = 40 JK–1mol–1. Out of the values given below, choose the
minimum temperature above which the process will be spontaneous :

(A) 5 K
(B) 4 K
(C) 20 K
(D) 12 K

17) For the chemical reaction , the standard reaction Gibbs energy depends on temperature
T (in K) as :

ΔrGo (in kJ mol–1) = 120 – T

The major component of the reaction mixture at T is :

(A) X if T = 315 K
(B) X if T = 350 K
(C) Y if T = 300 K
(D) Y if T = 280 K

18) At 320 K, a gas A2 is 20% dissociated to A(g). The standard free energy change at 320 K and 1
atm in J mol–1 is approximately : (R = 8.314 JK–1 mol–1; ℓn 2 = 0.693; ℓn 3 = 1.098)

(A) 4281
(B) 4763
(C) 2068
(D) 1844

19) ΔfG° at 500 K for substance 'S' in liquid state and gaseous state are + 100.7 kcal mol–1 and + 103
kcal mol–1, respectively. Vapour pressure of liquid 'S' at 500 K is approximately equal to : (R = 2 cal
K–1 mol–1) -

(A) 0.1 atm

(B) 10 atm
(C) 100 atm
(D) 1 atm

20) Oxygen gas weighing 64 gm is expanded from

1 atm to 0.25 atm at 30°C. Calculate entropy change, assuming the gas to be ideal :-

(A) 11.04 cal mol–1 K–1

(B) 22.02 cal mol–1 K–1
(C) 15.24 cal mol–1 K–1
(D) 5.55 cal mol–1 K–1

SECTION-B

1) Find magnitude of difference in standard Gibb's energy of formation of H2O(g) & H2O(l) at 300K in
kJ/mol if Vapour pressure of H2O at 300 K is 30 torr. [Use : 1 bar = 75 cm Hg]
[Give your answer as nearest integer]

2) Identify the number of processes with ΔG = 0 :

(a) H2O( , 0°C, 1atm) → H2O(g,0°C, 1 atm)
(b) H2O( , 100°C, 1 atm) → H2O(g, 100°C, 1 atm)
(c) H2O( , 27°C, 0.04 atm) → H2O(g, 27°C, 0.04 atm)
(d) H2O(s, –10°C, 0.01 atm) → H2O(g, –10°C, 0.01 atm)
(e) H2O( , 0°C, 1atm) → H2O(s,0°C, 1 atm)
(f) H2O( , 100°C, 1atm) → H2O(g, 100°C, 0.1 atm)
(g) H2O( , 0°C, 1atm) → H2O(s, 0°C, 5 atm)
(Vapour pressure of ice at –10°C = 0.01 atm
Vapour pressure of water at 27°C = 0.04 atm)

3) The efficiency of a carnot cycle is 1/6. On decreasing the temperature of the sink by 65°C,
the efficiency increases to 1/3. Calculate the temperature of sink (in °C).

4) Calculate ΔG (in bar-L) when a definite mass of a monoatomic ideal gas at 1 bar & 27°C is
expanded adiabatically against vacuum from 10 L to 20 L (ln2 = 0.7)

5) For the reaction 2NO2(g) N2O4(g), when

ΔS = –176.0 JK–1 and ΔH = –57.8 kJ mol-1, the magnitude of ΔG at 298 K for the reaction is_____ kJ
mol–1. (Nearest integer).

6) The heat of vaporization of a liquid at 500 K and 1 atm pressure is 10 Kcal/mol. What will be the
change in internal energy (ΔU in Kcal) of 3 moles of the liquid at the same temperature and pressure
?

7) What is the total number of intensive properties in the given list:

(i) Internal energy (ii) Pressure
(iii) Molar entropy (iv) Volume
(v) Density (vi) Boiling point
(vii) Molality (viii) heat capacity

8) Two moles of He gas (γ= 5/3) are initially at temp 27°C and occupy a volume of 20 litres. The gas
is first expanded at constant pressure until its volume is doubled. Then it undergoes reversible
adiabatic change, until the volume become 110 lit, then predict the value of T/100 (where T is the

final temperature, = )

9)

In a cyclic process ABCA consist of three processes. if , , and

, , then find magnitude of work done by system in process CA.
Fill your answer as sum of digits (excluding decimal places) till you get the single digit answer

10) The magnitude of work done (in Joule) by a gas that undergoes a reversible expansion along the

path ABC shown in the figure is ________

 PART 3 : MATHEMATICS

SECTION-A

1)

The number of ways in which 8 non-identical apples can be distributed among 3 boys such that every
boy should get atleast 1 apple and atmost 4 apples is K. 7P3 where K has the value equal to :

(A) 88
(B) 66
(C) 44
(D) 22

2) The number of ways selecting three numbers from 1 to 30, so as to exclude every selection of
three consecutive number is

(A) 4030
(B) 4031
(C) 4032
(D) 4035

3) Two variants of a test paper are distributed among 12 students. Number of ways of seating of the
students in two rows so that the students sitting side by side do not have identical papers & those
sitting in the same column have the same paper is:

(A)

(B)

(C)
(D)

4) Find the number of positive integral solution of the equation x.y.z=120.

(A) 70
(B) 75
(C) 80
(D) 90

5) Find the number of positive integral solutions of the inequation x + y + z ≥ 150, where
0 < x ≤ 60, 0 < y ≤ 60, 0 < z ≤ 60.

33
(A) C3
34
(B) C3
 35
(C) C5
36
(D) C6

6) In how many ways can 12 identical apples be distributed among four children if each gets atleast
1 apple and not more than 4 apples.

(A) 25
(B) 27
(C) 29
(D) 31

7) If r, s, t are prime numbers and p, q are the positive integers such that their HCF is rs2t and their
LCM is r2s3t, then the numbers of ordered pair of (p, q) is -

(A) 4
(B) 18
(C) 36
(D) 72

8) In a high school, a committee has to be formed from a group of 6 boys M1, M2, M3, M4, M5, M6 and
5 girls G1, G2, G3, G4, G5.
(i) Let α1 be the total number of ways in which the committee can be formed such that the committee
has 5 members, having exactly 3 boy and 2 girls.
(ii) Let α2 be the total number of ways in which the committe can be formed such that the committee
has at least 2 members, and having an equal number of boys and girls.
(iii) Let α3 be the total number of ways in which the committe can be formed such that the committee
has 5 members, at least 2 of them being girls.
(iv) Let α4 be the total number of ways in which the committee can be formed such that the
commitee has 4 members, having at least 2 girls and such that both M1 and G1 are NOT in the
committee together.

List-I List-II

P. The value of α1 is 1. 136

Q. The value of α2 is 2. 189

R. The value of α3 is 3. 192

S. The value of α4 is 4. 200

5. 381

6. 461
The correct option is :-
(A) P → 4; Q → 6, R → 2; S → 1
(B) P → 1; Q → 4; R → 2; S → 3
(C) P → 4; Q → 6, R → 5; S → 2
(D) P → 4; Q → 2; R → 3; S → 1
9) Let P1, P2, …, P15 be 15 points on a circle. The number of distinct triangles formed by points Pi, Pj,
Pk such that i + j + k ≠ 15, is :

(A) 12
(B) 419
(C) 443
(D) 455

10) 5 boys and 3 girls are sitting in a row of 8 seats. Number of ways in which they can be seated so
that not all the girls sit side by side, is:

(A) 36000
(B) 9080
(C) 3960
(D) 11600

11) A person writes a letter each to six friends and addresses the corresponding envelopes. The
number of ways in which the letters can be placed in the envelops so that atleast two of them are in
the wrong envelopes is

(A) 710
(B) 720
(C) 730
(D) 719

12) The number of ways in which a person can go from point A to point B if he can travel only to the
right or upward along the lines (as shown in GRID) is

(A) 15
(B) 20
(C) 25
(D) 30

13) Permutation of a eight digit number is called ALLENITE if every two consecutive numbers in the
permutation are relatively prime. If the digits of number belongs to set S={2,3,4,5,6,7,8,9}. Then
the number of ALLENITE permutations are (repetition of digit is not allowed). (For example
65232327 is ALLENITE but 27635792 is NOT)

(A) 480
(B) 540
(C) 720
(D) 810

14) In a certain test ai students gave wrong answers to at least i questions

where . No student gave more than k wrong answers. The total numbers of wrong answers given is

(A)
(B)
(C) Zero
(D) None of these

15) How many hexagons can be constructed by joining the vertices of a quindecagon (15 sides) if
none of the sides of the hexagon is also the side of the 15-gon.

(A) 140
(B) 160
(C) 130
(D) 180

16) The sum of all natural numbers 'n' such that 100 < n < 200 and H.C.F (91, n) > 1 is:

(A) 3221
(B) 3121
(C) 3203
(D) 3303

17) There are three coplanar parallel lines. If any p points are taken on each of the lines, the
maximum number of triangles with vertices at these points is:

(A)
(B)
(C)
(D) None of these

18) From a set of 30 multiple choice questions, having exactly one answer correct from four given
options, the number of ways in which a student can attempt odd number of questions is-

(A)

(B)

(C)

(D)

19) If and be two three digit numbers, then the number of pairs of α and β
that can be formed so that α can be subtracted from β without borrowing.

(A) 55 . (45)2
(B) 45 . (55)2
(C) 36 . (45)2
(D) 553

20) Consider a set X which consist of all 4-digit integers in interval [2022, 4482] formed by using the
digits 0, 2, 3, 4, 6, 7. Consider another set S which also consist 4-digits integers formed by digits 0,
2, 3, 4, 6, 7 in interval [2022, 4482] but only those which satisfy the following conditions-
(i) If number start with 2, it must contain all digits 2, 4, 6, 7 and 4 should not be at tens place.
(ii) If number start with 3 then it should not have more than 2 different digits.
(iii) If number start with 4 then it should not be divisible by 5.
Then number of elements in set S is

(A) 130
(B) 134
(C) 265
(D) 160

SECTION-B

1) Four horses compete in a race. Let N be the total number of different orders in which the horses
can cross the finish line. Assume that all four horses finish the race and two or more horses can

cross the finishing line together. The value of is (where [.] denotes greatest integer function)

2) There are 4,5 and 6 points lying on 3 parallel lines L1,L2 and L3 respectively such that no three
points lying on different lines are collinear, then maximum K number of triangles can be formed by
joining given points. Sum of digits of K is equal to

3) If 2λ is the number of ways of selecting 3 member subset of {1, 2, 3, ......, 29}, so that the
numbers form a GP with integer common ratio, then the value of λ is

4) Let number of non negative integral solutions of the inequality x + y + z ≤ 6 be m and number

of natural solutions of the inequality x + y + z + t < 10 be n, then find the value of .

5) The number of three digit numbers of the form xyz with x < y, z < y, x ≠ 0 is α then find the value

of .

6) Let A = {1, 2, 3, ....., 40}, then total number of ways of selecting 3 distinct integers from set A. If
their product is divisible by 27 is.
7) Consider a 20 sided convex polygon k, with vertices A1, A2 .... A20. in that order. Find the number
of ways in which three sides of k can be choosen such that every pair among them has atleast two
sides of ‘k' between them

8) The number of permutations which can be formed out of the letters of the word "SERIES" taking
three letters together is

9) Let X be the set of all five digit numbers formed using 1,2,2,2,4,4,0. For example, 22240 is in X
while 02244 and 44422 are not in X. Suppose that each element of X has an equal chance of being
chosen. Let p be the conditional probability that an element chosen at random is a multiple of 20
given that it is a multiple of 5. Then the value of 38p is equal to

10) In how many ways can 8 different books be distributed among 3 students if each receives at
least 2 books?
 ANSWER KEYS

PART 1 : PHYSICS

SACTION-A

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B B B B D D C C B C A C C D B D D A A D

SECTION-B

Q. 21 22 23 24 25 26 27 28 29 30
A. 9 7 2 2 8 4 9 4 1 8

PART 2 : CHEMISTRY

SECTION-A

Q. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50
A. D D C B C B B C A C A D B B B A A A B D

SECTION-B

Q. 51 52 53 54 55 56 57 58 59 60
A. 8 4 52 7 5 27 5 3 3 48

PART 3 : MATHEMATICS

SECTION-A

Q. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80
A. D C D D A D A C C A D B C B A B C D B D

SECTION-B

Q. 81 82 83 84 85 86 87 88 89 90
A. 7 7 6 3 4 1771 520 42 31 2940
 SOLUTIONS

PART 1 : PHYSICS

1) WF – µmgD – mgH = 0 – 0

WF = µmgD + mgH

2)

20000 x2 = 2 × (10)2

x= = 10 cm

3)

Body will be in equilibrium at both as at these points force will be zero.

At on increasing x force becomes -ve & on decreasing x force becomes +ve. So force &
displacement have opposite signs. So it a pt. of stable equation.

4)

F∝v
P = F · v ∝ v2
⇒

5) Work energy theorem

... (i)
at point C

... (ii)
From equation (i) & (ii)

6)

In this case motion of stone is in vertical circle of radius L and centre at O The change in
velocity is
 According to work-energy theorem,

or ...(i)
WT= work done by the force of tension = 0

Wg= work done by the fore of gravity

=mgL (path independent)

From eq.(i),

7) Appyling work energy theorem

Kf = Ki + work done

mv2 = 0 +

solving we get v = 2 m/s.

8)

9)

Work energy theorem

–µmgx = 0 – 64

x=

10)

For block
N – Mg = Ma
i.e. N = Mg + Ma

Displacement, S =
So work due to N = N.S

W = M(g + a) .

W=

11)

Maximum elongation in spring =

Maximum tension force → 2mgsinθ ≥ 5g
m≥5

12) At bottom point velocity will be

v< so it will not reach at top most point and after leaving surface it will do projectile
motion.
So, velocity will be horizontal at highest point.

13) Slope = Negative

Velocity = Negative
Acceleration = Negative

14)

θ = 90°
w=0

15)

16)
Required work done = change in potential energy of chain
Now let Potential energy (U) = 0 at table level so potential energies of chain

17)

only (D) option satisfies this.

18)

T = mg + ma, S = at2

WT = T × S

19)

F=

0
E = U + K = kr +

20)

ΔK.E = Wfr + Wg + Wext

= – (0.1 × 20 × 200) + 0 + Wext = 400 J

21)

Applying WET

100x2 –20x + 1 = 0

Now for block of 10 kg

⇒ 100 = N + kx
so N = 90

22)

23)

W = ∆KE =
Here W =

m/ s

24)

mv2 = kx2

m = kx2

⇒x= = –

cos θ = ⇒ θ = 53°
 25)

26)

The block will come to rest when total area will become zero
⇒s = 4m

27)

Mechanical energy E = K + U = constant

At x = 5m, E= K + U = 20 + (5–2)2 – 20 = 9 J
⇒ At x = 2m, E = 9J

28) mgh =

29)

30)
 using work-energy theorem-

W = 1 × 4 × 4 – 0.2 × 10 × 4 = 8 J

PART 2 : CHEMISTRY

31)

ΔE = q + W
ΔE = 100 × 4.2 J + (–300J) ( q = 100 Cal)
ΔE = 120J

32)

ΔH = ΔE + ΔnRT or ΔE = ΔH – ΔnRT

∴ ΔE = +7.3 – × 0.002 × 298

= 7.3 – 0.298 = 7 kcal

33)

w = – Δng.RT
= – (50 × 8.3 × 300)/1000
= – 124.50 kJ

34)

w = – 57441.4 J
w = –mgh
∴ m = 58.55 kg

35)

Magnitude of work done = Area under P – V curve

 = 100π (KPa – L)

= 100π × = 102 π J
ΔU = 0 (for cyclic process) ΔU = q = W
|q| = 102 π J Ans. C

36)

= constant,
P.γV .dV + Vγ.dP = 0
γ–1

37)

In expansion |wrev| > |wirr|

In compression |wrev| < |wirr|
For 4 stage expansion 5 points will be obtained.

38) q = 0

39)

Heat gain by zinc = Heat lost by water

MZn SZn (Tf – Ti) = (100 – Tf)

(65.38 gm) (Tf – 20°C) = (180 gm) (4.20J/g°C) (100°C - Tf)

Tf =
Tf = 97.3°C

40)

Work done by the gas in the cyclic process = Area bounded (ABCA) = 5P1V1

41)

ΔS = = 9.77

42)

ΔS = 2.303 nR log
= 2.303 × 1 × 8.314 × log
= 8.314 × ln 2 = 8.314 × 0.693 = 5.76 Jk–1 mol–1

43)

ΔH° = ΔG° + ΔST

69418.86 = ΔG° + 154.4 × 400
2.303 RT log K = 7658.86 = ΔG°
log K = 1 = log10. , K = 10.

44)

ΔS = 2.303 nR log
= 2.303 × 5 × 8.314 log 100/10 = 95.7Jk–1

45)

Cp,m = aT3
0.42 = a (10)3
⇒ a = 0.42 × 10–3

ΔS = S10K – S0K, S0K = 0

46)

ΔG = ΔH – TΔS = 0
TΔS = ΔH

T= =5K
So, above 5K, ΔG = –ve
Process will be spontaneous.

47)

ΔrGo = 120 – T=0

T = 120
T = 320 K
So, above 320 K; ΔG = –ve & below 320 K; ΔG = +ve
Reactant X is major at 315 K.
 48)

Given that, A2 ⇌ 2A
Initially, suppose [A2] = 1M and [A] = 0M
After 20% dissociation, 80% of A2 will remain
[A2] = 0.8 M
The equilibrium constant

K= = 0.2
ΔG° = –RTlnK = –8.314 × 320 × ln0.2 = 4281 J/mol

49)

As we know that, at equilibrium,

ΔG° = –2.303 RT log Kp ......… (1)
S(l) ⇌ S(g)
From the above reaction,
ΔG° = 103 – 100.7 = 2.3 kcal/mol = 2.3 × 103 cal/mol
From equation (1), we have
2.3 × 103 = –2.303 × 2 × 500 × log Kp
Kp = 10–1 atm

Kp =
PS(l) = 10 atm

50)

ΔS = 2.303 × n × R × log10

= 2.303×
= 5.55 cal mol–1 K–1

51)

H2O(l) ⇌ H2O(g)
ΔrG° =
= – RTlnK

= –RTln = –2.303 ×
= +8 kJ (nearest integer)

52)

b, c, d and e are equilibrium condition.

53)

η=1–

… (1)

… (2)

TH = 6 × 65 = 390 K = 117°C

TL = = 325K = 52°C

54)

q = 0; w = 0; ΔU = 0 ; T → constant

ΔG = nRT ln

= P1V1 ln

= 1 × 10 ln
= 10 × 0.7 = 7 bar.L

55)

ΔG = ΔH – TΔS = (– 57.8) – 298(– 0.176) = – 57.8 + 52.448 = – 5.352

|ΔG| = 5 KJ/moL

56) ΔH for 3 moles of liquid

= 3 × 10 = 30 Kcal
ΔH = ΔU + Δ(PV)
ΔU = ΔH – nRT

= 30
= 27 Kcal

57)
Fact, (ii), (iii), (v), (vi), (vii) are intensive properties.

58)

Ist process is isobaric

volume become double so, T also gets doubled
So Ti = 2 × 300 = 600
Tf = ?, Vf = 110 lit
P1V1γ = constant = TVγ–1 = constant
TiVi5/3–1 = TfVf2/3
600 × (40)2/3 = Tf × (110)2/3
Tf = 300 K

Ans. =3

59)

ΔU = 0
Wtotal = – qtotal
80 + 40 + WCA = –(–20 – 40 – 30)
WCA = – 30 J

60)

Magnitude of work done = Area enclosed by curve

PART 3 : MATHEMATICS

61) Ways of distribution

B1 B2 B3
(i) 1 3 4
(ii) 2 2 4
(iii) 3 3 2

∴ Total no. of ways =

Solving K = 22

62)

The numbers of ways of selecting 3 number out of 30 is 30C3. But this include 28 ways of selecting 3
consecutive numbers [viz (1, 2, 3), (2, 3, 4), (3, 4, 5), ..., (28, 29, 30)]
Thus, required number of ways is 30C3 - 28 = 4032.

63)
 = total number of required possible ways is

12
C6 × 6 ! × 6! × 2! = × 6 ! × 6 ! × 2! = 2 × 12!

64)

x.y.z = (2)3 (3)1 (5)1

x.y.z

∴ Total solutions = 10 × 3 × 3 = 90

65)

Let x = 60 – t1, y = 60–t2, z = 60–t3 (where 0 ≤ t1 ≤ 59, 0 ≤ t2 ≤ 59, 0 ≤ t3 ≤ 59)

Given x + y + z ≥ 150
or x + y + z – w =150 (where 0 ≤ w ≤ 147) …(i)
Putting values of x, y, z in equation (i)
60 – t1 + 60–t2 + 60–t3– w =150
30 = t1 + t2 + t3 + w
Total solutions = 33C3

66)

Let x, y, z & w be the number of apples given to the children.

⇒ x + y + z + w =12
Giving one-one apple to each
Now, x + y + z + w = 8 ...(i)
Here, 0 ≤ x ≤ 3, 0 ≤ y ≤ 3, 0 ≤ z ≤ 3, 0 ≤ w ≤ 3
x = 3–t1, y = 3–t2, z = 3–t3, w = 3–t4.
Putting value of x, y, z, w in equation (i)
Put 12–8 = t1 + t2 + t3 + t4
⇒ t1 + t2 + t3 + t4 =4
(Here max. value that t1, t2, t3 & t4 can attain is 3, so we have to remove those cases when any of
ti getting value 4)
= 7C3 – (all cases when atleast one is 4)
= 7C3 – 4 = 35 – 4 = 31

67)
 68)

(1)
So P → 4

(2) = = 461
So Q → 6

(3) = 381
So R → 5

(4)
So S → 2

69)

i + j + k = 15 (Given)

Number of Possible triangles using the vertices Pi, Pj, Pk such that i + j + k ≠ 15 is equal to
15
C3 – 12 = 443 Option (3)

70) Total no. of arrangement if all the girls do not sit

side by side is = [all arrangement – girls seat side by side]
= 8! – (6! × 3!) = 6! (56 – 6) = 6! × 50 = 720 × 50 = 36000

71)

Required number of ways = D2+D3+D4+D5+D6

 Required number of ways = 719

72)

To reach the point B from point A, a person has to travel along 3 horizontal and 3 vertical strips.
we have to arrange 3H and 3V in a row

Number of ways
=20

73)

2,4,8 2's
3,9 3's
{5, 7} can go anywhere and 6 can go only next to 5 or 7.
Case-1: 6 is at begining or end. The next number can be 5 or 7. Then 6 numbers can be 232327,
232372, 323272, 232723,232732, 237232, 327232, 272323, 273232, 723232. That's 10 choice times
2(switch 5 or 7) and 2 for putting 6 (beg or end) times 6 for {2, 4, 8} times 2 for {3, 9}. Total =480
This case
Case-2: 6 is in middle. Then 5 and 7 must be next
(1) 6 in 2nd position 56723232
(2) 6 in 3rd 25672323, 25673232
(3) 6 in 4th 23567232, 32567232
Total =5×2×2×6×2
Total =240
Final total =480+240=720

74)

Total number of wrong answers

75)

76) H.C.F (91, n) >1

SA = Sum of number between 100 and 200 which one divisible by 7

= 105 + 112 + ... + 196

SB = Sum of number between 100 and 200 which one divisible by 13

SC = Sum of number which one divisible by 7 and 13 = 182

 77)

The number of triangles with vertices on different lines

The number of triangles with two vertices on one line and the third vertex on any one of the other

two lines
So, the required number of triangles

78) The number of ways of attempting a question with four alternatives = 4.

The number of ways of attempting odd number of questions =

79)

β–α

__________
Number of pairs = (10 + 9 + 8 +….. + 1)2 . (9 + 8 +……. + 1) = (55)2 .45

80)

Element in set S :
(i)
2×2=4
(ii) =1
Number can be formed,
3, 0 __ __ __
3, 2
3, 4 0 , 3 , 3 =3
3, 6 0 , 0 , 3 =3
3, 7 0 , 0 , 0 =1
__
7
iii) 4 __ __ __
4 × 6 × 5 = 120
Total numbers in set S = 4 + 36 + 120 = 160

81)

H1 – H2 – H3 – H4 =
H1H2H3H4 = 1 ⇒ 75

82)

No of Δ's formed
= 4+5+6C3 – 4C3 – 5C3 – 6C3
= 421
∴ sum of digits = 4 + 2 + 1 = 7

83)

84)

x + y + z + F1 ≤ 6
∴ 6 + 3C3 = m = 9C3
x+y+z+t≤9
x + y + z + t + F2 ≤ 5 (give one to each x, y, z, t for natural solution)
5+4 9
∴ n = C4 = C4

∴ = = = 3. Ans.

85)

We must have x ≥ 1 and y ≥ 2, since x is less than y. That is, y = j with 2 ≤ j ≤ 9, then x can take the
j – 1 values from 1 to j – 1 and z can take the j values from 0 to j – 1. For each value y = j, therefore,
xyz can take j(j – 1) values. We can now get the answer by summing over all values of y :

= 285 – 45 = 240

86) {3, 6, 9, 12, 15, 18, 21, 24, 27, 30, 33, 36, 39}

No of ways = = 1771

87)
 88)

SERIES
S - 2, E - 2 , R, I
case-I when all letter distinct is
4
C3 × 3! = 4 × 6 = 24
case-II when 2 letters are same the

2
C1 . 3C1 × = 2 . 3 . 3 = 18
total number is 24 + 18 = 42

89)

No. of elements in X which are multiple of 5

Among these 38 elements, let us calculate when element is not divisible by 20

∴
∴ 38p = 31

90)
If each receives at least two books, then the division three would be as shown below:

The number of ways of division for tree in figure (i) is

The number of ways of division for tree in figure (ii) is

The total number of ways of distribution of these groups among 3 students is