Scribd
Upload
44 views17 pages

Experiemnt 4 Redox Titration

Analytical Chemistry

Uploaded by

Khánh An Nguyễn
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
44 views17 pages

Experiemnt 4 Redox Titration

Analytical Chemistry

Uploaded by

Khánh An Nguyễn
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 17

ANALYTICAL CHEMISTRY

EXPERIMENT 4
Redox Titration

MSc. Bui Xuan Anh Dao


Redox Titration
• To determine concentration of a solution, based
on a redox reaction between the analyte and
titrant

• Can be used to analyze for any oxidizing or


reducing agent.

Redox reaction? Oxidizing/ reducing agent?


Redox Titration
• REDOX REACTION (Oxidation - Reduction Reaction)
A reaction in which electrons are transferred between
species or in which atoms change oxidation number

2KMnO4 + 5H2C2O4 + 3H2SO4  10CO2 + K2SO4 + 2MnSO4 + 8H2O

• Oxidation number of single ions is equal to the charge on


the ion
Redox Titration
• REDOX REACTION (Oxidation - Reduction Reaction)
A reaction in which electrons are transferred between
species or in which atoms change oxidation number

+7 +3 +4 +2
2KMnO4 + 5H2C2O4 + 3H2SO4  10CO2 + K2SO4 + 2MnSO4 + 8H2O

• Oxidation number of single ions is equal to the charge on


the ion
+7 +3 +4 +2
2KMnO4 + 5H2C2O4 + 3H2SO4  10CO2 + K2SO4 + 2MnSO4 + 8H2O

OXIDATION REDUCTION

reducing oxidizing
agent. agent.

REDUCING OXIDIZING
AGENT AGENT
+7 +3 +4 +2
2KMnO4 + 5H2C2O4 + 3H2SO4  10CO2 + K2SO4 + 2MnSO4 + 8H2O

OXIDATION REDUCTION
the loss of the gain of
electrons electrons
C+3  C+4 + e- Mn+7 + 5e-  Mn+2
reducing oxidizing
agent. agent. KMNO4

REDUCING OXIDIZING
AGENT AGENT
Compound that loses Compound that
electrons gains electrons
Redox Titration
• Many redox reactions are either slow or have
inconsistent stoichiometry. The stability of titrant
and analyte solutions can also be a problem .

• Back titration: instead of titrating the original


sample, a known excess of standard reagent is
added to the solution, and the excess is titrated
Experiment
• Determine the mass of ascorbic acid (C6H8O6) in a
vitamin C tablet by applying redox titration.

• In this titration, iodine plays a role as reducing agent,


so that the method is also called iodometric titration.

• As the low solubility of iodine, the experiment will be


performed by generation of known excess quantity
iodine by the reaction between iodide and iodate
Experiment – part 1
1. Prepare chemical

– 250ml 1M KI solution (1 groups do preparation)

– 250ml 0.01 M KIO3 solution (3 groups)

– KI and KIO3 need to store in brown Duran

2. Standardize with Na2S2O3 solution


10ml 0.01M KIO3
+ 5ml 1M KI
10ml 0.5M H2SO4

IO3- + 8I- + 6H+ -> 3I3- + H2O (1)


Reaction
Then titrate with Na2S2O3

2S2O32- + I3- -> S4O62- + 3I- (2)

Add 2ml starch as indicator -> titrate ->


Experiment – part 2
1. Prepare 250ml 0.3M H2SO4 from 0.5M H2SO4 (had
prepared) (1 groups)

2. Prepare sample solution from Vitamin C capsule


• Weigh 1 tablet
• 100mg powder of sample -> 100ml 0.3 M H2SO4 -> 250ml
solution (2 groups)
1 2
Weighing Add 100 mg of Vit.C
tablet of Vit. C powder

250-mL
Beaker
Grind into powder

+ 100 ml 0.3M
H2SO4

Add DI
water to
Weighing 100 mg of
250 ml
Vit.C powder
250-mL Volumetric flask
Experiment – part 2
3. Iodometric titration between ascorbic acid and iodine
solution

• 20ml sample solution + 5ml 1M KI + 20ml 0.01M KIO3


Then titrate with Na2S2O3 solution. Add 2ml starch indicator
before end point.

• Repeat 5 times
Reactions
• IO3- + 8I- + 6H+ -> 3I3- + H2O (1)

• C6H8O6 + I3- + H2O → C6H6O6 + 3I- + 2H+ (2)

• 2S2O32- + I3- -> S4O62- + 3I- (3)


Report

1. Determine the mass of Vitamin C per capsule and


percentage by mass of vitamin C per capsule.

2. Compare with information on label of tablet’s


container.

3. Provide reaction equators and full calculation

Note: Be carefull with calculation. Follow the procedure


carefully step by step for calculation.
Further question
1. What is reducing/ oxidizing agent/ oxidation / reduction
process/ redox reaction/iodometric titration?

2. When will we use back titration / redox titration?

3. Why is H2SO4 added for the titration?

4. What gives the blue color of the titration

5. Why do not add starch from the beginning of titration


process? Why do we have to add starch just before the
endpoint?

6. Why do we need to contain KI and KIO3 in the brown


Duran?
Video links

https://www.youtube.com/watch?v=RKR0XFFcbnk&ab_channel=
JeffreyMills

https://www.youtube.com/watch?v=lkJyP6OYmAY&ab_channel=
KEGSChemistry

https://www.youtube.com/watch?v=nO0eiMaUrSA&ab_channel=
ChrisAmbidge

You might also like

pFad - Phonifier reborn

Pfad - The Proxy pFad of © 2024 Garber Painting. All rights reserved.

Note: This service is not intended for secure transactions such as banking, social media, email, or purchasing. Use at your own risk. We assume no liability whatsoever for broken pages.


Alternative Proxies:

Alternative Proxy

pFad Proxy

pFad v3 Proxy

pFad v4 Proxy