TARGET : JEE (Main + Advanced)

ENTHUSIAST COURSE
(SESSION : 2021-22)

RACE # 01 to 10_(BOOKLET)
(PHYSICAL)

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Important Notes
 JEE (Main + Advanced) 2022
JEE (Main + Advanced) 2022
ENTHUSIAST COURSE
ENTHUSIAST COURSE
RACE # 01 PHYSICAL CHEMISTRY
M.M. : 30 TIME : 35 Min.

Only One Correct Answer :

1. A quantity of hydrogen gas occupies a volume of 30.0 mL at a certain temperature and pressure. What
volume would half this mass of hydrogen occupy at triple the absolute temperature if the pressure
were one-ninth that of the original gas? [3]
(A) 270 mL (B) 90 mL (C) 405 mL (D) 135 mL
2. A metal carbonate decomposes according to following reaction [3]
M2CO3(s) ¾¾
® M2O(s) + CO2(g)
Percentage loss in mass on complete decomposition of M2CO3(s)
(Atomic mass of M = 102)
100 50 25
(A) % (B) % (C) % (D) 15%
3 3 3
3. How many litres of oxygen at 1atm & 273K will be required to burn completely 2.2 g of propane (C3H8)
(A) 11.2 L (B) 22.4 L (C) 5.6 L (D) 44.8 L [3]
4. 'P' v/s 'V' graph is plotted for 1 mole of hypothetical gas. Range of a/b for this gas in (atm-L/mole).
[R = 0.08 atm- litre / mole-K]

300K
200K
V

æaö æaö
(A) 54 < ç ÷ < 81 (B) 27 < ç ÷ < 42
èbø èbø

æaö æaö
(C) 40 < ç ÷ < 65 (D) 13.5 < ç ÷ < 40.5 [3]
èbø èbø
5. In the given isobaric process shown by graph between T & V. [3]

T C
A
(0, 0)
V

(A) Moles decreases throughout (B) Moles first increases then decreases
(C) Moles first decreases then increases (D) Moles cannot be predicted form given data

Physical/Race # 01-10_(Book) E-1/16

 JEE (Main + Advanced) 2022

ENTHUSIAST COURSE

6. The equation for the reaction in the figure below is: [3]
 2HI(g).
H2(g) + I2(g) + Heat 
0.8

Conc.(mmol/L)
HI
At the instant 3 min, what change was imposed into the 0.6
equilibrium? 0.4 H2
(A) Pressure was increased 0.2 I2
0
(B) Temperature was increased 0 1 2 3
Time(min)
(C) Iodine was added to the system
(D) Hydrogen was added to the system
7. A hydrogen atom in an excited state emits a photon which has the longest wavelength of the Paschen
series. Further emissions from the atom cannot include the [3]
(A) longest wavelength of the Lyman series (B) second longest wavelength of the Lyman series
(C) longest wavelength of the Balmer series (D) second longest wavelength of the Balmer series
8. 0.8 M FeSO4 solution requires 160ml, 0.2M Al2(Cr2O7)3 in acidic medium, Calculate volume of FeSO4
consumed -
(A) 480 ml (B) 240 ml (C) 720 ml (D) 40 ml [3]
Multiple correct :
9. At equilibrium 5 moles of Ne is added in a 10L rigid container at 300K. In which of given reaction
equilibrium is not disturbed -

 2NO(g)
(A) N2(g) + O2(g)   2NH3(g)
(B) N2(g) + 3H2(g)  [3]

 2NH3(g)+CO2(g)
(C) NH2COONH4(s)   H2S(g)
(D) H2(g) + S(s) 

10. The graph below shows the distribution of molecular speed of two ideal gases X and Y at 200K.
on the basis of the below graph identify the correct statements - [3]
Fraction of gas particle

Y
X
250 500 750 1000 1250 speed(m/s)

(A) If gas X is methane, then gas Y can be CO2

(B) Fraction of molecules of X must be greater than Y in a particular range of speed at 200K
(C) Under identical conditions, rate of effusion of Y is greater than that of X
(D) The molar kinetic energy of gas X at 200K is equal to the molar kinetic energy of Y at 200K

E-2/16 Physical/Race # 01-10_(Book)

 JEE (Main + Advanced) 2022
JEE (Main + Advanced) 2022
ENTHUSIAST COURSE
ENTHUSIAST COURSE
RACE # 02 PHYSICAL CHEMISTRY
M.M. : 30 TIME : 35 Min.

Single correct :
1. Consider the following reaction [3]
2Na + 2NH3 ¾¾ ® 2NaNH2 + H2(g)

2NaNH2 + C ¾¾
® Na2CN2 + 2H2 (g)

Na2CN2 + C ¾¾
® 2NaCN
51gm dry ammonia gas is passed over excess heated sodium to form sodamide (NaNH2) which is further
reacted with carbon (excess) to finally form NaCN. Find the total volume of H2(g) evolved at 0.5 atm,
273K [3]
(A) 201.6 L (B) 100.8 L (C) 403.2 L (D) 50.4 L
2. If KP for a reaction is 1/9 × 10–2 atm–2 at 500 K. Magnitude of KC will be [Take R = 0.08] [3]

(A) 3 × 10–1 (B) 1/9 × 10–2 (C) 16/9 (D) Data insufficient
3. A container of volume 2 litre contains H2 gas at 300K as shown (Patm= 76 cm of Hg)

4cm 3
Liquid A (density = 27.2 gm/cm )
H2 2cm 3
Gas Liquid B (density = 6.8 gm/cm )
3
Hg(l) (density = 13.6g m/cm )

The pressure (in cm Hg) of H2 in the container is -

(A) 82 cm (B) 85 cm (C) 80 cm (D) 81 cm
4. Let the most probable velocity of hydrogen molecules at a temperature t0C is V0. Suppose all the molecules
dissociate into atoms when temperature is raised to (2t + 273)0C then the new r.m.s velocity is

[3]
(A) 2 / 3 V0 (B) 3(2 + 273 / t ) V0 (C) 2 3 V0 (D) 6 V0
Multiple correct :
5. Whenever a hydrogen atom emits a photon in the Balmer series [3]
(A) it may emit another photon in the Balemr series
(B) it may emit another photon in the Lyman series
(C) the second photon, if emitted will have a wavelength of about 122 nm
(D) it may emit a second photon, but the wavelength of this photon cannot be predicted
6. H2C2O4 and NaHC2O4behave as acids as well as reducing agents. Which are the correct statements?
(A) equivalent weight of H2C2O4 and NaHC2O4 are equal to their molecular weights when behaving as
reducing agents. [3]
(B) 100 ml of 1N solution of each is neutralised by same volume of 1 N Ca(OH)2
(C) 100 ml of 1N solution of each is neutralised by same volumes of 1M Ca(OH)2
(D) 100 ml of 1M solution of each is oxidised by same volume of 1 M KMnO4 solution in acidic
medium

Physical/Race # 01-10_(Book) E-3/16

 JEE (Main + Advanced) 2022

ENTHUSIAST COURSE

INTEGER :
7. 280 g of a mixture containing CH4 and C2H6 in 5 : 2 molar ratio is burnt in presence of excess of oxygen.
Calculate total moles of CO2 produced. [3]
8. 5.00 moles of hydrogen gas, 3 moles of white phosphorus {P4(s)} and 12 moles of oxygen gas are taken
in a sealed flask and allowed to react as follows : [3]
H2(g) + P4(s) + O2(g)  H3PO4
Determine the moles of ortho-phosphoric acid that can be produced, considering that the reaction occurs
in 90% yield.
9. In the following reaction : 3A (g) + B (g) 2C (g) + D (g), initial mol of B is double of A. At
equilibrium, mol of A and C are equal. Hence % dissociation of B is : [3]
10. In the ionic reaction, [3]
xBrO3– + yCr3+ + zH2O  pBr2 + qHCrO4– + rH+
{x, y, z, p, q, r, are in simplest whole number ratio}
Find the value of (z – x – y).

E-4/16 Physical/Race # 01-10_(Book)

 JEE (Main + Advanced) 2022
JEE (Main + Advanced) 2022
ENTHUSIAST COURSE
ENTHUSIAST COURSE
RACE # 03 PHYSICAL CHEMISTRY
M.M. : 30 TIME : 35 Min.

Single correct :
1. Which of the following is not a crystalline solid ? [3]
(A) Common salt (B) Sugar (C) Iron (D) Rubber
2. a  b  c, 900 represents [3]
(A) tetragonal system (B) orthorhombic system
(C) monoclinic system (D) triclinic system
3. The most unsymmetrical crystal system is : [3]
(A) Cubic (B) Hexagonal (C) Triclinic (D) Orthorhombic
4. In a face centred cubic cell, an atom at the face contributes to the unit cell,
(A) 1 part (B) 1/2 part (C) 1/4 part (D) 1/8 part
5. A compund having bcc geometry has atomic mass 54. Calculate the density of the unit cell, if its edge length
is 300 pm. (NA = 6 × 1023)
(A) 6.67 g cm–3 (B) 3.33 g cm–3 (C) 13.33 g cm–3 (D) 4.67 g cm–3
6. Volume of dil. HNO3 (d = 1.1 gm/ml, 20% w/w) that can be prepared by diluting, 50 ml of concentrated HNO3
(d = 1.4 gm/ml, 70% w/w) with water is nearest to - [3]
(A) 150 ml (B) 223 ml (C) 178 ml (D) 333 ml
7. If a pure compound is composed of X2Y3 molecules and consists of 60 % X by weight what is the atomic
weight of Y in term of atomic weight of X (Atomic mass of X = Mx) ? [3]

 4 2 3
(A) M (B) M (C) M (D) M
4 x 9 x 3 x 2 x
8. Calculate the volume of Cl2 gas (in ml) liberated at 1 atm & 273 K when 1.74gm MnO2 reacts with 2.19gm
HCl according to the following reaction with % yield 40. (Mn = 55) [3]

MnO2 + HCl 
 MnCl2 + Cl2 + H2O

(A) 336 ml (B) 112 ml (C) 134.4 ml (D) 44.8 ml

9. The volume (in ml) of 0.5 M NaOH required for the complete reaction with 150 ml of 1.5M H3PO3 solutions
is - [3]
(A) 1350 (B) 900 (C) 1250 (D) 1150
Subjective :
10. A mixture of butane C4H10, with a gaseous hydrocarbon of the Alkene series occupied 20 mm. To burn the
mixture completely, 125 mm of oxygen were required and after combustion 80 mm CO2 were formed. All
pressure were measured at the same temperature and volume.
Calculate : [3]
(a) The formula of Alkene
(b) the composition (% by mole) of mixture by pressure

Physical/Race # 01-10_(Book) E-5/16

 JEE (Main + Advanced) 2022
JEE (Main + Advanced) 2022
ENTHUSIAST COURSE
ENTHUSIAST COURSE
RACE # 04 PHYSICAL CHEMISTRY
M.M. : 32 TIME : 35 Min.
Single correct :
1. Which of the following is not a characteristic of crystalline solids ? [3]
(A) They have a regular geometry (B) They have sharp melting points
(C) They are isotropic (D) They undergo a clean cleavage
2. Bravais lattices are of [3]
(A) 10 types (B) 8 types (C) 7 types (D) 14 types
3. An element crystallizes in both fcc & bcc lattices. Then ratio of edge length of fcc unit cell to bcc unit
cell will be -
(1) 1 : 2 2 (2) 3 : 2 (3) 2 : 3 (4) 6 :1 [3]
4. The number of atoms per unit cell in a simple cubic, face-centred cubic and body-centered cubic structure
respectively are - [3]
(A) 1, 4, 2 (B) 1, 2, 4 (C) 8, 14, 9 (D) 8, 4, 2
5. If the coordination number of an element in its crystal lattice is 8, then packing is : [3]
(A) fcc (B) hcp (C) bcc (D) sc
6. Sodium metal crystallises in bcc lattice with the cell edge, a = 42.29 Å. What is the radius of sodium
atom ? [3]
(A) 1.86 Å (B) 16.2 Å (C) 18.3 Å (D) 1.12 Å

7. 500 mL of a gaseous hydrocarbon when burnt in excess of O2 gave 2.5 L of CO2 and 3 L of water
vapour under the same conditions. The formula of the hydrocarbon is [3]
(A) C4H8 (B) C4H10 (C) C5H6 (D) C5H12
8. Fraction of edge length covered by atoms in BCC structure is - [3]
3 1 3
(A) 1 (B) (C) (D)
8 2 2
9. Match the column- [5]
Column-I Column-II
(Concentration of aqueous solution) (Density of given solutions is 1.2 g/ml)
(A) 2M NaOH solution (P) 16gm solute in 240gm solution

w
(B) 8%   KOH solution (Q) 60gm solute in 240 gm solution
V

w
(C) 45%   C H O solution (R) 8gm solute in 100 ml solution
 W  6 12 6

1
(D) X C3H7OH  (S) 30 gm solute in 100 ml solution
11
(T) 1 mole solute in 400 gm solution
Subjective :
10. 500 ml of 2M CH3COOH solution is mixed with 600 ml 12% w/v CH3COOH solution, then calculate
the final molarity of solution. [3]
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 JEE (Main + Advanced) 2022
JEE (Main + Advanced) 2022
ENTHUSIAST COURSE
ENTHUSIAST COURSE
RACE # 05 PHYSICAL CHEMISTRY
M.M. : 30 TIME : 35 Min.
Single correct :
1. Which of the following is a non-crystalline solid ? [3]
(A) CsCl (B) NaCl (C) CaF2 (D) Glass
2. A solid has structure in which W atoms are located at the corners of a cubic lattice, O atoms at the centre
of edges and Na atom at centre of the cube. The formula of the compound is, [3]
(A) NaWO2 (B) NaWO3 (C) Na2WO3 (D) NaWO4
3. The coordination number of a cation occupying a tetrahedral hole is : [3]
(A) 4 (B) 6 (C) 8 (D) 12
4. A metallic crystal crystallizes into a lattice containing a sequence of layers AB AB AB....Any packing of
spheres leaves out voids in the lattice. What percentage of volume of this lattice is empty space,
(A) 74% (B) 26% (C) 32% (D) 48 % [3]
5. If the radius of an atom of an element is 75 pm and the lattice is body-centred cubic, the edge of the unit cell
will be ,
(A) 32.475 pm (B) 173.2 pm (C) 37.5 pm (D) 212.1 pm [3]
6. A compound formed by elements A and B has cubic structure in which A atoms are at the corners of the cube
and B atoms are at the face centres. The formula of the compound will be ,
(A) A4B3 (B) A2B (C) AB3 (D) A2B3 [3]
7. On heating 60 ml mixture containing equal volume of chlorine gas and it's gaseous oxide, volume becomes
75 ml due to complete decomposition of oxide. On treatment with KOH volume becomes
15 ml. What is the formula of oxide of chlorine
(A) ClO2 (B) Cl2O3 (C) Cl2O (D) Cl2O7 [3]
More than one correct :
8. 10 mole of A2B3 contains 100gm of A atom & 60 gm of B atoms. Choose the correct statements -
(A) Molecular weight of A2B3 is equal to 16 [3]
(B) Atomic weight of A is equal to 5
(C) Weight of one atom of B is equal to 2
(D) Atomic weight of B is equal to 6
9. Select the incorrect statement(s) [3]
(A) During a reaction, moles and mass of atoms remain constant

 C + 3D, for maximum product formation per gram of reactant mixture,

(B) For reaction 2A + 3B 
mass ratio of A & B must be 2 : 3
(C) Both molarity and mole fraction are temperature dependent
(D) 22.7 litre of water at S.T.P. conditions contains 6 × 1024 protons.

Physical/Race # 01-10_(Book) E-7/16

 JEE (Main + Advanced) 2022

ENTHUSIAST COURSE

10. Which of the following atoms touch each other in a fcc unit cell (diagram given) - [3]

Atom 4 is at the centre of side face

5 4 Atom 5 is at the centre of back face
Atom 3 is at the centre of bottom face
1 2
3

(A) 1 & 2 (B) 1 & 3 (C) 3 & 5 (D) 3 & 4

E-8/16 Physical/Race # 01-10_(Book)

 JEE (Main + Advanced) 2022
JEE (Main + Advanced) 2022
ENTHUSIAST COURSE
ENTHUSIAST COURSE
RACE # 06 PHYSICAL CHEMISTRY
M.M. : 30 TIME : 35 Min.
Single correct :
1. The co-ordination number of sodium oxide (Na2O) type structure is - [3]
(A) 1 : 2 (B) 4 : 4 (C) 4 : 8 (D) 8 : 4
2. An element has bcc structure having unit cells 12.08 × 1023. The number of atoms in these cells is -
(A) 12.08 × 1023 (B) 24.16 × 1023 (C) 48.38 × 1023 (D) 6.09 × 1023 [3]
3. A metal has bcc structure and the edge length of its unit cell is 3.04 Å. The volume of the unit cell in cm3
will be -
(A) 1.6 × 10–21 cm3 (B) 2.81 × 10–23 cm3 (C) 6.02 × 10—23 cm3 (D) 6.6 × 10–24 cm3 [3]
4. The compound CuCl has ZnS (ccp) structure. Its density is 3.4 g cm–3. What is the length of the edge of
the unit cell ? [Cu = 63.5, Cl = 35.5, NA = 6 × 1023 , (2.924)3 = 25] [3]
(A) 5.84 cm (B) 584.8 pm (C) 292.4 m (D) 193.3 × 10–24 cm
5. The density of KBr is 3.33 g cm–3. The length of the unit cell is 619.7 pm. Then the solid is [3]
(K = 39, Br = 80, , (6.197)3 = 238, NA = 6 × 1023)
(A) Face centred cubic (B) Simple cubic system
(C) Body centred cubic system (D) None of these
6. An atomic solid crystallizes in bcc lattice if circumference (surface) of atoms at the adjacent corners are
seperated by 54 pm then edge length of bcc unit cell is ( 3 = 1.7) [3]
(A) 450 pm (B) 108 pm (C) 216 pm (D) 360 pm
7. Packing fraction in fcc lattice is - [3]

 2  3
(A) (B) (C) (D)
6 6 2 3 8
8. Find type of crystallization of Ag(At. wt. = 108 amu) atom with cubical side length 5Å, if density of
crystall lattice is 2.88 gram/cm3. (NA = 6 × 1023) [3]
(A) SC (B) FCC (C) BCC (D) HCP
9. If r+ = 200 pm & r– = 500 pm in ionic crystal then cation will be present in - [3]
(A) triangular void (B) tetrahedral void (C) octahedral void (D) cubical void
Multiple correct :
10. Which of the following are correct - [3]
(A) In NaCl type crystal coordination number of cation and anion are 6
(B) In CaF2 type crystal the coordination number of cation is 4 and anion is 8
(C) In zinc blende type crystal (ZnS) the coordination number of cation and anion is 6
(D) In CsCl type crystal the coordination number of cation is 8

Physical/Race # 01-10_(Book) E-9/16

 JEE (Main + Advanced) 2022
JEE (Main + Advanced) 2022
ENTHUSIAST COURSE
ENTHUSIAST COURSE
RACE # 07 PHYSICAL CHEMISTRY
M.M. : 30 TIME : 35 Min.
Single correct :
1. A pseudo solid is : [3]
(A) Glass (B) Pitch (C) KCl (D) Glass and pitch both
2. An alloy of copper, silver and gold is found to have copper constituting the fcc lattice. If silver atoms
occupy the edge centres and gold is present at body centre, the alloy has a formula , [3]
(A) Cu4Ag2Au (B) Cu4Ag4Au (C) Cu4Ag3Au (D) CuAgAu
3. A compound contains P and Q elements. Atoms Q are in ccp arrangement while P occupy all tetrahedral
sites. Formula of compound is : [3]
(A) PQ (B) PQ2 (C) P2Q (D) P3Q
4. The ionic radii of Rb+ and I– are 1.46 and 2.16 Å respectively. The most probable type of structure
exhibited by it is : [3]
(A) CsCI type (B) NaCl type (C) ZnS type (D) CaF2 type
5. Shortest interionic distance in zinc blende structure is (a is edge length of unit cell) [3]
a a a a
(A) (B) 3 (C) (D) 3
2 2 2 4
6. Crystal AB shows ZnS (zinc blende) type structure if the radius of B– is 50 pm then the radius of A+
will be, if edge length of unit cell is 160 pm. ( 3  1.73) [3]
(A) 11.25 pm (B) 27.9 pm (C) 15.25pm (D) 19.2 pm
7. An ionic crystalline solid AB having cubic unit cell, may have following arrangement(s) - [3]
(A) B– in FCC and A+ occupies all tetrahedral voids.
(B) B– in CCP and A+ in alternate tetrahedral voids.
(C) B– at each corner and A+ at all face centres.
(D) B– at each corner and A+ at each edge center.
8. A gaseous mixture of C3H8 and CH4 exerts a pressure of 320 mm Hg at temperature TK in a V lt. flask.
On complete combustion of mixture, flask containing only CO2 exerts a pressure of 448 mm Hg under
identical condition. The mole fraction of C3H8 in the given mixture is
(A) 0.35 (B) 0.5 (C) 0.2 (D) 0.4 [3]
Multiple correct
9. The hcp and ccp structure of a given element
(A) have same density [3]
(B) have same distance between two consecutive layers (A & B)
(C) have same co-ordination number
(D) have same fraction of unoccupied space.
10. Select the correct statement - [3]
(A) Atom present at the corner of HCP prism is shared by 6 such prisms
(B) hcp is more close packing than fcc
(C) Size of octahedral void is bigger than tetrahedral void
r
(D) If = 0.5 then most probable co-ordination number of cation will be 6
r
E-10/16 Physical/Race # 01-10_(Book)
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RACE # 08 PHYSICAL CHEMISTRY
M.M. : 30 TIME : 35 Min.

MULTIPLE CORRECT :
1. At 273K Pd vs P is plotted for various gases 1,2,3,4. Assuming ideal behaviour four gases N2, He, CO2
& H2. The correct combination is [P denotes pressure in atmosphere & d denotes density in gm/L]

1 2 3 4
Pd

(A) 2 - N2, 1 – He, 3 – CO2, 4 – H2 (B) 4 - N2, 1 – He, 2 – CO2, 3 – H2 [3]

(C) 4 - N2, 3 – He, 2 – CO2, 1 – H2 (D) 2 - N2, 3 – He, 1 – CO2, 4 – H2
2. The correct statement(a) regarding F-centre is/are :
(A) Electrons are held in the voids of crystals
(B) F-centre imparts colour to the crystal
(C) Conductivity of the crystal increases due to F-centre
(D) Due to F-centre there is no effect on conductivity of crystal
Assertion & Reason :
3. Statement-1: In diamond carbon atoms occupy alternate tetrahedral voids in the FCC lattice formed
by the carbon atoms. [3]
Statement-2: In diamond, packing fraction is more than 74%.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for
statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.
4. PA = (235 y – 125 xy) mm of Hg. PA is partial pressure of A, x is mole fraction of B in liquid phase in the
mixture of two liquids A and B and y is the mole fraction of A in vapour phase, then P°B in mm of Hg is
(A) 235 (B) 0 (C) 110 (D) 125
5. The vapour pressure of pure benzene at 50°C is 268 torr. How many mol of non-volatile solute per mol
of benzene is required to prepare a solution of benzene having a vapour pressure of 167 torr at 50°C:
(A) 0.377 (B) 0.605 (C) 0.623 (D) 0.395
6. The vapour pressure of a dilute solution of a solute is not influenced by :
(A) temperature of solution (B) melting point of solute
(C) mole fraction of solute (D) degree of dissociation of solute
7. Vapour pressure of an aqueous solution of a non-volatile and non electrolyte solute at certain temperature
T was found to be 39.964 torr. If the vapour pressure of pure solvent at same temperature is 40 torr,
find the molality of aqueous solution :
(A) 0.1 m (B) 0.005 m (C) 0.05 m (D) 0.04 m [3]

Physical/Race # 01-10_(Book) E-11/16

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ENTHUSIAST COURSE

SUBJECTIVE :
8. Two completely miscible liquids A & B form an ideal solution. What is the vapour pressure (in torr)
of solution containing 2 moles of A and 3 moles of B at 300K? [3]
[Given: At 300 K, Vapour pr. of pure liquid A(PAo) = 100 torr
Vapour pr. of pure liquid B (PBo) = 300 torr]
9. A compound formed by elements X & Y, Crystallizes in a cubic structure, where X is at the corners of
the cube and Y is at six face centers. What is the formula of the compound? If side length is 5Å,
estimate the density of the solid in gm /cm3 assuming atomic weight of X and Y as 60 amu and 90 amu
respectively. [3]
–1
10. A flask has 10 molecules out of which four molecules are moving at 7ms and the remaining ones are
moving at same speeed of X ms–1. If rms of the gas is 5ms–1, what is 'X' ? [3]

E-12/16 Physical/Race # 01-10_(Book)

 JEE (Main + Advanced) 2022
JEE (Main + Advanced) 2022
ENTHUSIAST COURSE
ENTHUSIAST COURSE
RACE # 09 PHYSICAL CHEMISTRY
M.M. : 30 TIME : 35 Min.
Single correct :
1. Choose the correct statement : [3]
(A) Rate of effusion of gas is inversly proportional to the molecular weight of gas
(B) Mean free path of gases decreases with increase in temperature at constant volume
(C) Partial pressure of gas do not changes on addition of another non-reactive gas in the same container
at constant volume and temperature
(D) Compressibility of real gases are always more than ideal gases
2. A 150 ml mixutre of CO and CO2 is passed through a tube containing excess of red hot charcoal. The
volume become 200 ml due to reaction. [3]
CO2(g) + C(s) 
 2CO(g)
Select the correct statement(s).
(A) mole percent of CO2 in the original mixture is 50
(B) mole fraction of CO in the original mixture is 0.66
(C) the original mixture contains 50 ml of CO2
(D) the orginal mixture contain 50 ml of CO.
3. Solutions having the same osmotic pressure are called : [3]
(A) isotonic solution (B) molar solutions (C) hypotonic solutions (D) ideal solutions

Semipermeable
membrane

Solution-1 Solution-2

4.
pH1 pH2

If water particles move from solution-1 to solution-2 when both the aqueous solution contain same base
at same temperature then [3]
(A) pH1 > pH2 (B) pH1 < pH2 (C) pH1 = pH2 (D) pH1  pH2
5. The density of a pure substance 'A' whose atoms pack in cubic close pack arrangement is 1 gm/cc. If B
atoms can occupy tetrahedral void and if all the tetrahedral voids are occupied by 'B' atom. What is the
density of resulting solid in gm/cc. [Atomic mass (A) = 30 gm/mol & Atomic mass (B) = 50 gm/mol]
(A) 3.33 (B) 4.33 (C) 2.33 (D) 5.33 [3]
6. Diamond structure can be considered as ZnS (Zinc blend) structure in which each Zn2+ in alternate
tetrahedral void and S2- in cubic close pack arrangement is replaced by one carbon atom. If C–C covalent
bond length in diamond is 1.5Å , what is the edge length of diamond unit cell (z = 8).
(A) 3.46 Å (B) 6.92 Å (C) 1.73 Å (D) 3 Å [3]

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 JEE (Main + Advanced) 2022

ENTHUSIAST COURSE

7. A solid is formed and it has three types of atoms X, Y, Z. X forms a FCC lattice with Y atoms occupying all
the tetrahedral voids and Z atoms occupying half the octrahedral voids. The formula of the solid is :-
(A) X2Y4Z (B) XY2Z4 (C) X4Y2Z (D) X4YZ2 [3]
Multiple correct :
8. Select the correct statement about FCC (ABCAB...) structure. [3]
3a
(A) Distance between nearest octahedral void and tetrahedral void is
4
a
(B) Distance between two nearest octahedral void is
2
3a
(C) Distance between two nearest tetrahedral void is
2
2
(D) Distance between layer A and B is 2r
3
9. The co-ordination number of FCC structure for metals is 12, since [3]
(A) each atom touches 4 others in same layer, 3 in layer above and 3 in layer below.
(B) each atom touches 4 others in same layer, 4 in layer above and 4 in layer below.
(C) each atom touches 6 others in same layer, 3 in layer above and 3 in layer below.
(D) each atom touches 3 others in same layer, 6 in layer above and 6 in layer below.
10. In a solid AB having NaCl type structure A atoms occupy the corner of the cubic unit cell and the face
centered positions. If all the face-centered atom along one of the axes are removed, choose the correct
options: [3]
(Atomic weight of A = 40),
Atomic weight of B = 60, rA = 1.4 Å, rB = 2.8 Å
(A) the packing fraction is 0.579
(B) The density of the resultant solid is 1.008 g/cc
(C) The packing faction is 0.679
(D) The density of the resultant solid is 2.008 g/cc

E-14/16 Physical/Race # 01-10_(Book)

 JEE (Main + Advanced) 2022
JEE (Main + Advanced) 2022
ENTHUSIAST COURSE
ENTHUSIAST COURSE
RACE # 10 PHYSICAL CHEMISTRY
M.M. : 30 TIME : 35 Min.

SINGLE CORRECT :
1. 1.0 molal aqueous solution of an electrolyte A2B3 is 60% ionised. The boiling point of the solution at
1 atm is ( K b H2 O  = 0.52 K kg mol-1 )

(A) 274.76 K (B) 377 K (C) 376.4 K (D) 374.76 K [3]

2. What will be the molecular weight of CaCl2 determined in its aq. solution experimentally from depression
of freezing point ?
(A) 111 (B) <111 (C) > 111 (D) data insufficient [3]
3. Statement-1 : The freezing of water is an endothermic process. [3]
Statement-2 : Heat must be removed from the water to make it freeze.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.
4. A 2% (w/v) solution of glucose has the same elevation in B.P. as that of 5% (w/v) solution of a non-
volatile solute the molar mass of the solute is - [3]
(A) 180 (B) 450 (C) 72 (D) 18
5. The root mean square velocity of a gas molecule at 100 K and 0.5 atm pressure is 106.4 m s–1. If the
temperature is raised to 400 K and the pressure is raised to 2 atm, the root mean square velocity becomes
(A) 106.4 m s–1 (B) 425.6 m s–1 (C) 212.8 m s–1 (D) 851.2 m s–1
6. An ionic solid has some point defect but its experimental density is equal to its theoretical density.
The type of defect is [3]
(A) Schottky defect (B) Frenkel defect
(C) Metal excess defect (D) Metal deficient defect
7. A solution prepared by dissolving a 2.50 g sample of an unknown compound dissolved in 34.0 g of benzene, C6H6
boils at 1.38°C higher than pure benzene. Which expression gives the molar mass of the unknown compound ?

Compound Kb [3]

C 6H 6 2.53°C.m–1

2.50 34.0
(A) 2.53 × (B) 1.38 ×  2.50
1.38 2.53

2.53 1 1.38
(C) 2.50 × 103 ×  (D) 2.50 × 103 × × 2.53
34.0 1.38 34.0

Physical/Race # 01-10_(Book) E-15/16

 JEE (Main + Advanced) 2022

ENTHUSIAST COURSE

8. When 1.20 g of sulphur is melted with 15.00 g of naphthalene, the solution freezes at 77.2° C. What is the
molar mass of this from of sulphur. Data for Napthalene [3]

Melting point, m.p 80°C

Freezing point depression constant, kf = 6.80°C m–1

(A) 180 g mol–1 (B) 194 g mol–1 (C) 260 g mol–1 (D) 450 g mol–1

9. The Van't Hoff factor 0.1 M La (NO3)3 solution is found to be 2.74 the percentage dissociation of the salt is :

(A) 85 % (B) 58 % (C) 65.8% (D) 56.8% [3]

10. Maximum freezing point will be for 1 molal solution of (assuming equal ionisation in each case) :

(A) [Fe(H2O)3 Cl3] (B) [Fe(H2O)5Cl] Cl2.H2O [3]

(C) [Fe(H2O)4Cl2]Cl.2H2O (D) [Fe(H2O)3Cl3].3H2O

E-16/16 Physical/Race # 01-10_(Book)

Important Notes