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Solution

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Preksha T
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06-10-2024

1103CJA101021240014 JA

PHYSICS

SECTION-I

1) Magnitudes of angular magnifications of an astronomical telescope in normal vision & least


distance of distinct vision are x & y respectively. The least distance of distinct vision is D. The focal
length of objective lens will be :

(A) (y – x)D

(B)

(C)

(D)

2) A thin oil film of refractive index 1.2 floats on the surface of water (µ = ). When a light of
wavelength λ = 9.6 × 10–7 m falls normally on the film from air, then it appears dark when seen
normally. The minimum change in its thickness for which it will appear bright in normally reflected
light by the same light is :-

(A) 10–7 m
(B) 2 × 10–7 m
(C) 3 × 10–7 m
(D) 5 × 10–7 m

3) In a Young's double slit experiment D equals the distance of screen and d is the separation
between the slit. The distance of the nearest point to the central maximum where the intensity is
same as that due to a single slit, is equal to :-

(A)

(B)

(C)

(D)

4) In a Young's double slit experiment, slits are separated by 0.5 mm, and the screen is placed 150
cm away. A beam of light consisting of two wavelengths, 650 nm and 520 nm, is used to obtain
interference fringes on the screen. The least distance from the common central maximum to the
point where the bright fringes due to both the wavelengths coincide is :
(A) 9.75 mm
(B) 15.6 mm
(C) 1.56 mm
(D) 7.8 mm

5) A monochromatic beam of light falls on Young's double slit experiment apparatus as shown in
figure. A thin sheet of glass is inserted in front of lower slit S2. (λ = 600 nm is wavelength of light in
vacuum). If zeroth order bright fringe (corresponding to zero phase difference) is obtained on screen

at O, then

(A)
(B)
(C) μt = dθ

(D)

6) In a YDSE experiment λ = 540 nm, D = 1m, d = 1 mm. A thin film is pasted on upper slit and the
central maxima shifts to the point just in front of the upper slit. What is the path difference at the
centre of the screen ?

(A) 540 nm
(B) 270 nm
(C) 500 nm
(D) 810 nm

7) In telescope, if the powers of an objective and eye lens are + 1.25 D and + 20 D respectively, then
for relaxed vision, the length of tube and magnification will be :-

(A) 85 cm and 25
(B) 85 cm and 16
(C) 21.25 cm and 16
(D) 21.25 cm and 25

8) One slit of a double slit experiment is covered by a thin glass plate of refractive index 1.4 and the
other by a thin glass plate of refractive index 1.7. The point on the screen, where central bright
fringe was formed before the introduction of the glass sheets, is now occupied by the 5th bright
fringe. Assuming that both the glass plates have same thickness and wavelength of light used is
4800 Å, find their thickness.
(A) 6 µm
(B) 8 µm
(C) 4 µm
(D) 2 µm

9) In YDSE, intensity of light passes through both slit is equal. A 100% transparent thin film is
placed infront of one of the slits. Now the intensity on the centre becomes 25% of the previous
intensity. The wavelength of light is 4000 Å and refractive index 1.5. The minimum thickness of the
glass slab is :-

(A) 1.23 × 10–7 m


(B) 2.67 × 10–7 m
(C) 4 × 10–7 m
(D) None of these

10) White light is incident on a thin film of constant refractive index placed in vacuum. Thickness of
the film is gradually increased from zero. At a thickness t, wavelength of 4000Å is strongly visible in
reflected light for first time. When thickness is further increased by 0.05 μm wavelength of 6000Å is
strongly visible for first time at same angle in reflected light. Value of t will be:

(A) 0.4 μm
(B) 0.6 μm
(C) 0.1 μm
(D) 0.2 μm

11) In a Young's double slit experiment, the slits are placed 0.320 mm apart. Light of wavelength λ =
500 nm is incident on the slits. The total number of bright fringes that are observed in the angular
range –30°≤ q ≤ 30°is:

(A) 320
(B) 641
(C) 321
(D) 640

12) White light is used to illuminate the two slits in Young's double slit experiment. The separation
between the slits is d and the distance between the screen and the slits is D (>> d). At a point on the
screen directly in front of one of the slits, certain wavelengths are missing. The missing wavelengths
are (here m = 0, 1, 2, ... is an integer)

(A)

(B)

(C)
(D)

13) The path difference between two interfering waves at a point on the screen is . The ratio of
intensity at this point and that at the central bright fringe will be : (Assume that intensity due to
each slit in same)

(A) 0.853
(B) 8.53
(C) 0.75
(D) 7.5

14) A plane wavefront AB is incident on a concave mirror as shown. Then, the wavefront just after

reflection is :

(A)

(B)

(C)

(D) None of the above

15) In YDSE, if sources are incoherent, the intensity on screen is 3I0. When these sources are
coherent then minimum intensity on screen is I0. If maximum intensity produced by these coherent
sources on screen is nI0 then find n.

(A) 4
(B) 1.5
(C) 5
(D) 5.5

16) In an interference experiment as shown in the figure, the source plane and screen are separated

by a distance 1m. At a certain position of source, fringe width is and by moving the source

away from mirror along the line AB by 0.6 mm, the fringe width changed to :-
(A) Wavelength of light used is 5000 Å
(B) Wavelength of light used is 6000 Å
(C) Initial distance of source from A is 1.8 mm
(D) Initial distance of source from A is 0.6 mm

17) A compound microscope of tube length 200mm, magnifying power 400 has objective of focal
length 10mm. The focal length of eye-piece will be (under normal adjustment)

(A)

(B)

(C)

(D)

18) In a standard YDSE two slits A and B are covered by a wedge shaped thin film of refractive index
μ as shown in the figure. The thickness of film varies linearly from t to 3t from one end to the other
as shown in the figure. The distance between the two slits is d. The screen is at distance D from slits.
White light is used in experiment and consider d<<<D. Find the distance of central maxima from

the point O [centre of screen].

(A)
below point O

(B)
above point O

(C)
below point O

(D)
below point O
19) A ray of light of intensity I is incident on a parallel glass slab at a point A as shown in Fig, It
undergoes partial reflection and refraction. At each reflection 25% of incident energy is reflected.
The rays AB and A'B' undergo interference. The ratio is

(A) 4 : 1
(B) 8 : 1
(C) 7 : 1
(D) 49 : 1

20) An astronomical telescope has magnifying power 6 for distance objects. The separation between
objective and the eye piece is 42 cm and the final image is formed at infinity. The focal length f0 of
objective and focal length fe of eye-piece are (in cm) :-

(A) f0 = 36, fe = 6
(B) f0 = 50, fe = 8
(C) f0 = 20, fe = 10
(D) f0 = 40, fe = 8

SECTION-II

1) One slit of a Young's experiment is covered by a glass plate (μ1 = 1.4) and the other by another
glass plate (μ2 = 1.7) of the same thickness. The point of central maxima on the screen, before the
plates were introduced is now occupied by the third bright fringe. Find the thickness of the plates
(in µm), the wavelength of light used is 4000 Å.

2) A glass of refractive index 1.5 is coated with a thin layer of thickness t, of refractive index 1.8.
Light of wavelength λ travelling in air is incident normally on the layer. It is partly reflected at the
upper and at the lower surfaces of the layer. The two reflected rays interfere. If λ = 648 nm, obtain
the least value of t (in 10–8 m) for which the rays interfere constructively.

3) Figure shows two coherent microwave source S1 and S2 emitting waves of wavelength λ and
separated by a distance 3λ. For λ <<D and y ≠ 0, the minimum value of y for point P to be an

intensity maximum is . Determine the value of m + n, if m and n are coprime numbers.


4) In a compound microscope the focal length of objective lens is 1.2 cm and focal length of eye
piece is 3.0 cm. When object is kept at 1.25 cm in front of objective, final image is formed at infinity.
Magnifying power of the compound microscope should be :

5) A compound microscope consists of an objective lens of focal length 1cm and an eye piece of focal
length 5 cm with a separation of 10 cm. The distance between an object and the objective lens, at

which the strain on the eye is minimum is cm. The value of n is ___

6) The magnifying power of the telescope is found to be 9 and the separation between the lenses is
20 cm for relaxed eye. Then magnitude of difference of focal lengths (in cm) of component lenses is
:-

7) The objective of an astronomical telescope has a focal length of 80 cm. The telescope is focused
for normal vision of distant objects when the tube length is 1.0 m. If the focal length of eye piece is fe

(in cm) and magnifying power of telescope is m then the value of is :

8) The outer surface of a transparent glass slab of refractive index µ1 = 1.5 is coated by a thin layer
of transparent medium of refractive index µ2 = 1.6. Orange light of wave length 6400 Å fall normally
on the coat. The reflected light at the upper surface and at the lower surface of the coat interfere
destructively. If thickness of the coat is 5K × 10–8m, calculate the minimum value of K.

9) In a YDSE bi-chromatic light of wavelengths 400 nm and 560 nm are used. The distance between
the slits is 0.1 mm and the distance between the plane of the slits and the screen is 1 m. The
minimum distance (in mm) between two successive regions of complete darkness is :

10) The focal length of the lens is 20 cm and 0.03 is the dispersive power of the material of a lens.
Find the magnitude of difference in the focal length (in mm) of the lens for violet and red color.

CHEMISTRY

SECTION-I
1) (X) and (Y), (X) and (Y) respectively are :

(A)

(B)

(C)

(D) both (1) and (2)

2)
Product ‘B’ in the reaction is

(A)

(B)

(C) CH3 – NH2


(D) CH3 – CH2 – NH2

3) Which of the following undergoes esterification with acetic acid at the faster rate?

(A) (CH3)3COH
(B) C2H5OH
(C) (CH3)3CHOH
(D) CH3OH

4) The structure of product C, formed by the following sequence of reactions is :

CH3COOH + SOCl2 → A B C

(A)

(B)
(C)

(D)

5)

(A)

(B)

(C)

(D)

6) Which one of the following reactions will not yield propionic acid?

– +
(A) CH3CH2COCH3 + OI /H3O
– +
(B) CH3CH2CH2OH + KMnO4 (Heat),OH /H3O
– +
(C) CH3CH2CCl3 + OH /H3O
+
(D) CH3CH2CH2Br + Mg, CO2 dry ether/H3O

7) Statement I: The melting point of monocarboxylic acid with even number of carbon atoms is
higher than that of with odd number of carbon atoms acid immediately below and above it in the
series.
Statement II : The solubility of monocarboxylic acids in water decreases with increase in
molar mass.
Choose the most appropriate option:

(A) Both Statement I and Statement II are correct.


(B) Both Statement I and Statement II are incorrect.
(C) Statement I is correct but Statement II is incorrect
(D) Statement I is incorrect but Statement II is correct
8) A compound (X), C4H8O3, liberates CO2 on reaction with NaHCO3. When (X) is treated with
Pyridinium chlorochromate, it is converted into a new compound (Y), C4H6O3, which on heating
expels CO2 to form acetone. The compound (X) is :-

(A)

(B)

(C) CH3CHOHCH2CO2H
(D) CH3CH2CH(OH)CO2H

9) Which of the following reaction represents incorrect product ?

(A)

(B)

(C)

(D)

10) By which of the following sequence of steps can the alcohol RCH2CH2OH(X) be converted into
RCH2CH2COOH(Y) ?

(A)
(B)
(C)

(D)

11) Which of the following is likely to form white salts?

(A) Cu2+
(B) Sc3+
(C) Ti3+
(D) Fe2+
12) On addition of small amount of KMnO4 to concentrated H2SO4, a green oily compound is obtained
which is highly explosive in nature. Identify the compound from the following.

(A) Mn2O7
(B) MnO2
(C) MnSO4
(D) Mn2O3

13) Which of the following pairs of compound have nearly equal size :-
(a) Y and La (b) Zr and Hf
(c) Ti and Zr (d) Nb and Ta

(A) a and b
(B) b and c
(C) b and d
(D) a, b, c

14) Oxidation state of mercury in amalgam, calomel and corrosive sublimate is

(A) 0, +1, +2
(B) +1, +1, +2
(C) 1+, +2, +1
(D) 0, +1, +1

15) Which of the following combinations in an aqueous medium will give a red colour or precipitate?

2+ 3-
(A) Fe + [Fe (CN)6]
(B) Co2+ + SCN–
(C) Cu2+ + OH–
(D) Fe3+ + SCN–

16) The colour of light absorbed by an aqueous solution of CuSO4 is

(A) Orange red


(B) Blue green
(C) Yellow
(D) Violet

17) What would happen when a solution of potassium chromate is treated with an excess of dilute
nitric acid -

(A) Cr3+ and are formed


(B) and H2O are formed

(C) is reduced to +3 state of Cr


(D) is oxidised to +7 state of Cr

18) Among the following series of transition metal ions the ore where all metal ions have 3d2
electronic configuration is -

(A) Ti+3 , V2+ , Cr3+, Mn4+


(B) Ti+ , V4+ , Cr6+, Mn+7
(C) Ti4+ , V4+ , Cr2+, Mn3+
(D) Ti2+ , V3+ , Cr4+, Mn+5

19) The metallic bond strength in first transition series increases from -

(A) Sc to Mn
(B) Sc to Cr
(C) Cr to Zn
(D) Sc to Cu

20) The Eu2+ ion is a strong reducing agent in spite of its ground state electronic configuration
(outermost) : [Atomic number of Eu = 63]

(A) 4f 76s2
(B) 4f 6
(C) 4f 7
(D) 4f 66s2

SECTION-II

1) Write the number of CO2 molecule released only on heating following molecule.

2) Number of the following statements which are correct ?


(i) Formic acid is stronger acid than acetic acid
(ii) o-bromobenzoic acid is weaker than o-chlorbenzoic acid
(iii) Acetaldehyde does not respond to silver mirror test
(iv) benzaldehyde does not reduce fehling’s solution

3)

How many different condensation products would be formed by above reaction ? (excluding stereo
isomers)

4) How many oxygen atoms are present in cyclic product?

5) No. of carbon atoms be present for an acid to be optically active?

6) In 3d-series, the number of metals showing only one stable oxidation state is

7) The magnetic moment of a transition metal ion is found to be 3.87 Bohr Magneton (BM). The
number of unpaired electrons present in it is :

8) Among Co3⊕, Ti2⊕, V2⊕ and Cr2⊕ ions, one if used as a reagent cannot liberate H2 from dilute mineral
acid solution, its spin-only magnetic moment in gaseous state is ……B.M. (Nearest integer)

9) When mixture of NaCl and K2Cr2O7 is gently warmed with conc.H2SO4 then compound X is formed.
What is the oxidation state of central atom of X.

10) How many of the following ions have spin magnetic moment more than 4 B.M.?
Ti+3, Cu+, Cr+3, V+2, Ni+2, Co+2, Fe+3, Mn+2

MATHEMATICS

SECTION-I

1) The intercept made by the plane on the x-axis is-

(A)

(B)

(C)

(D)

2) A plane passes through the point P(4, 0, 0) and Q(0, 0, 4) and is parallel to the y-axis. The distance
of the
plane from the origin is -
(A) 2
(B) 4
(C)
(D)

3) The distance of the point (1, 3, –7) from the plane passing through the point (1, –1, –1), having
normal

perpendicular to both the lines and is :

(A)

(B)

(C)

(D)

4) The line intersects the curve xy = c2, z = 0 if c is equal to

(A)
(B)
(C)
(D) None of these

5) Equation of a line in the plane which is perpendicular to the line whose

equation is and which passes through the point of intersection of and is

(A)

(B)

(C)

(D)

6) If the lines and are coplanar, then the value of k is:

(A)

(B)
(C)

(D)

7) If and are unit vectors satisfying , then the angle between the vectors
and is:

(A)

(B)

(C)

(D)

8) A plane containing the point (3,2,0) and the line also contains the point :-

(A) (0, 3, 1)
(B) (0, 7, 10)
(C)
(D)

0 0
9) A vector is inclined to x-axis at 45 , to y–axis at 60 and at an acute angle to z-axis. If is a
normal

to a plane passing through the point , then the equation of the plane is :

(A)
(B)
(C)
(D)

10) Equation of the plane containing the straight line and perpendicular to the plane
containing

the straight lines and is

(A)
(B)
(C)
(D)

11) Let P be the image of the point (3, 1, 7) with respect to the plane x – y + z = 3. Then the
equation of the
plane passing through P and containing the straight line is

(A)
(B)
(C)
(D)

12) A plane passing through the points (0, –1, 0) and (0, 0, 1) and making an angle with the plane
y – z + 5 = 0, also passes through the point :

(A)

(B)

(C)

(D)

13) Given the points A (-2, 3, -4), B (3, 2, 5), C (1, -1, 2) and D (3, 2, -4). The projection of the vector
on the vector is-

(A)

(B)

(C)

(D)

14) The value of is-

(A)
(B)
(C)
(D)

15) If the volume of the parallelopiped whose conterminous edges are represented by
is 546, then equals-

(A) 3
(B) 2
(C)
(D)

16) If and are three non-coplanar vectors then


equals-

(A) 0

(B)

(C)

(D)

17) The non-zero vectors and are related and . Then the angle
between and is

(A) 0

(B)

(C)

(D)

18) If the vectors and are the sides of a triangle ABC, then the length
of the median through A is :

(A)
(B)
(C)
(D)

19) If the volume of parallelopiped formed by the vectors and is minimum,


then is equal to:

(A)

(B)

(C)

(D)

20) If and are unit vectors such that and ,


then:

(A) are non-coplanar


(B) are non-coplanar
(C) are non-parallel
(D) are parallel and are parallel

SECTION-II

1) If the foot of the perpendicular drawn from the point (1, 0, 3) on a line passing through

is , then α is equal to_____ .

2) If the distance between the plane, and the plane containing the lines

and is equal to , then k is equal to ______


.

3) Let p be a point in the first octant, whose image Q in the plane x + y = 3 (that is, the line segment
PQ is
perpendicular to the plane x + y = 3 and the mid-point of PQ lies in the plane x + y = 3) lies on the
z-axis.
Let the distance of P from the x-axis be 5. If R is the image of P in the xy-plane, then the length of PR
is_______ .

4) Three lines are given by and .


Let the lines cut the plane x + y + z = 1 at the points A, B and C respectively. If the area of the
triangle ABC is then the value of equals _________ .

5) Find the number of sphere of radius r touching the coordinate axes.

6) Find the radius of the circular section in which the sphere is cut by the plane

7) If and are any two unit vectors, then sum of maximum and minimum value of

is equal to

8) If and are vectors in space given by and , then the value of

is

9) Consider the cube in the first octant with sides OP, OQ and OR of length 1, along the x-axis, y-axis
and z-axis, respectively, where O(0, 0, 0) is the origin. Let be the centre of the cube
and T be the vertex of the cube opposite to the origin O such that S lies on the diagonal OT. If

and then the value of 6 is _________

10) Let and be two vectors. Consider a vector

. If the projection of on the vector is , then the

minimum value of is equal to-


ANSWER KEYS

PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A B C D A C B B B C B A C C C B A A D A

SECTION-II

Q. 21 22 23 24 25 26 27 28 29 30
A. 4.00 9.00 7.00 200 50.00 16 5.00 4.00 28 6

CHEMISTRY

SECTION-I

Q. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50
A. B A D A D D A C D A B A C A D A B D B C

SECTION-II

Q. 51 52 53 54 55 56 57 58 59 60
A. 4.00 3.00 4.00 1.00 5.00 2.00 3.00 5.00 6.00 2.00

MATHEMATICS

SECTION-I

Q. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80
A. A D D C B B C B B C C B C B C D D C C C

SECTION-II

Q. 81 82 83 84 85 86 87 88 89 90
A. 4 3 8 1 8 4 8 5 3 18
SOLUTIONS

PHYSICS

1)

For normal vision

For near point vision

f0 = (y – x)D

2) For normal incidence path difference between ray 1 and ray 2 is 2 µ1 t

For minimum thickness increment

3)

Inet = I1 + I2 +
I1 = I2 = I0
Let at a distance y. Resultant intersity = I0
I0 = 2I0 + 2I0 cosφ
1 = 2 [1 + cosφ]

Relation between phase difference and path difference is


y=

4) n1λ1 = n2λ2

4th bright fringe of 650 nm will coincide with 5th bright fringe of 520 nm.

x= = 7.8mm

5)

dsinθ = (µ – 1)t

6)

7) f0 = 80 cm
fe = 5 cm
ℓ = f0 + fe = 85 cm

8)

9)

I1 = I2 = I'
Maximum Intensity = 4I'
I = I1 + I2 +
I' = I' + I' +
I' = 2I' + 2I'cosϕ
1 = 2(1 + cosϕ)

cosϕ =

ϕ = 120º or

Δx =

= (μ – 1)t

= (1.5 – 1)t
t = 2.67 × 10–7 m

10)

(For Imax for first time)


⇒t∝λ


13)

At path difference , phase difference is

So the required ratio is

14)

Wave frent are ⊥ to rays

15)

16)

Let AS = h ...(i)
....(ii)

h = 1.2 mm

λ = 0.6 × 10–6 m
λ= 6000 Å

17)

For normal adjustment

For objective

fo very small,

18)

Shift in fringe pattern

= (constant) ;

=
19)

From figure and

By using

20) f0 + fe = 42

21)

(µ2 – µ1)t = 3λ

22)

Path difference between rays reflected from upper and lower faces of layer = 2μt cosr = 2 μt (for
normal incidence). But there is change in path of λ/2 of light at upper surface due to reflection from
denser medium. So actual path difference is 2 μt – λ/2.

For constructive interference

For least thickness n = 0.

∴ = 90 nm

23)
Δx = d cosθ = 3λ cosθ
for maximum Intersity ⇒ Δx = nλ
⇒ 3λ cosθ = nλ

⇒ cosθ =
maximum Intersity at n = 1 , 2, 3
for y minimum = n ⇒ 2

⇒ cosθ =

⇒ m+n=5+2=7

24)

from

26)

Magnification
Separation between lenses,

Given and
After solving

27) ℓ = f0 + fe = 1
fe = 20 cm

28)
2 µ2t –

t=
= 2 × 10–7m
= 5K × 10–8
K=4

30)

= (n – 1)

⇒– = dn
(differentiating both sides)

⇒– (n – 1) = dn

⇒ –df = f
but dn = nv – nR

∴ –df = f
⇒ df = –ωf
⇒ fv – fR = –ωf
= –0.03 × 20 = –0.6 cm

CHEMISTRY

31)

32)

33)

Alcohol with smaller alkyl group undergoes esterification at the faster rate.

34)
35)

36)

All gives propanoic acid as product but option 4 gives butanoic as product

37) Both Statement I and Statement II are correct.

38)
39)

40)

R–CH2–CH2–OH R–CH2–CH2–Br R – CH2 – CH2 – CN R – CH2–CH2–COOH

41)
0 0
Sc3+ = [Ar]4s 3d (It has zero unpaired e–)

42) KMnO4 Mn2O7


explosive

43)

Size of 4 d series 5 d series in group no 4 to 11

44)

In amalgam, mercury has 0 oxidation state


Calomel → Hg2Cl2 : +1
Corrosive sublimate (HgCl2) : +2

45)

Fe(SCN)3 is red colour

46)

Colour of CuSO4 is greenish blue hence, the colour of light absorbed by an aqueous solution is
orange-red.

47)

K2CrO4 + HNO3 → K2Cr2O7 + H2O


(Any acid)

48)

Ti+2 V+3 Cr+4 Mn+5


3d24s2 4s23d3 4s13d5 4s23d5
3d2 3d2 3d2 3d2

49)

Number of unpaired e– α metallic bond strength.

50)

Eu → [Xe]4f76s2

51) On same carbon 2 groups CO2 lost. β-keto acid on heating will loose CO2.

52)

Acetaldehyde give silver mirror test so statement (iii) incorrect and (i), (ii), (iv) are correct.

53) Claisen ester condensation


self = 2 crossed = 2

54)

β-keto acids on heating readily undergoes decarboxylation.

55)

56)

Sc and Zn show only one oxidation state.


58)

values are negative for Ti, V and Cr so their M2⊕ oxi. states are less stable than M3⊕

oxi. states but Co3⊕ is more stable due to positive value of for Co So,
Co can not liberate H2 by reaction with dilute mineral acid solution (H⊕) by reducing H⊕ ion.
3⊕

Co3⊕ has d6 configuration, So, Number of unpaired electrons = 4


Spin only magnetite moment B.M. ≈ 5 B.M.

59)

In this reaction CrO2Cl2 is formed in which Cr is +6.

60)

Only Fe+3 and Mn+2 have more than 4 unpaired electrons.

MATHEMATICS

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