Safety Data Sheet: SECTION 1: Identification of The Substance/mixture and of The Company/undertaking
Safety Data Sheet: SECTION 1: Identification of The Substance/mixture and of The Company/undertaking
This safety data sheet was created pursuant to the requirements of:
Safety data sheet according to Regulation (EC) 2020/878
1.2. Relevant identified uses of the substance or mixture and uses advised against
Manufacturer Supplier
Emergency Telephone POISON INFORMATION CENTRE (Beaumont Hospital, Republic of Ireland only) +353 (0)1
809 2166 (08:00 - 22:00)
Emergency Telephone - IN CASE OF EMERGENCY CALL: +44 1865 407333 (24hr, Provided by Carechem 24)
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Flammable liquids
Acute aquatic toxicity Category 1 - (H400)
Chronic aquatic toxicity Category 1 - (H410)
Signal word
Warning
Hazard statements
This mixture contains no substance considered to be persistent, bioaccumulating or toxic (PBT). This mixture contains no
substance considered to be very persistent nor very bioaccumulating (vPvB).
Endocrine Disruptor Information This product does not contain any known or suspected endocrine disruptors.
Not applicable
3.2 Mixtures
Chemical name Weight-% REACH registration EC No (EU Classification according Specific M-Factor M-Factor
number Index No) to Regulation (EC) No. concentration (long-term)
1272/2008 [CLP] limit (SCL)
2-Butoxyethanol 1-5 01-2119475108-36-00 203-905-0 Acute Tox. 4 (H332) - - -
111-76-2 00 Eye Irrit. 2 (H319)
Acute Tox. 4 (H302)
Skin Irrit. 2 (H315)
nitrate amine salt of 0.1-1 No data available 946-436-3 Aquatic Chronic 1 - 100 -
N-[3- (H410)
dimethylaminopropy Aquatic Acute 1 (H400)
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Chemical name Oral LD50 mg/kg Dermal LD50 Inhalation LC50 - 4 Inhalation LC50 - 4 Inhalation LC50 - 4
mg/kg hour - dust/mist - mg/L hour - vapour - mg/L hour - gas - ppm
2-Butoxyethanol 1200 + 435 No data available 3+ No data available
111-76-2 470 2.1749
2.3489
Propan-2-ol 1870 4059 No data available 30.1002 No data available
67-63-0
+ This value is the harmonised acute toxicity estimate (ATE) listed in CLP Annex VI, Part 3. This harmonised ATE value must be
used when calculating the acute toxicity estimate (ATEmix) for classifying a mixture containing the listed substance
This product does not contain candidate substances of very high concern at a concentration >=0.1% (Regulation (EC) No.
1907/2006 (REACH), Article 59)
Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep
eye wide open while rinsing. Do not rub affected area.
Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes
and shoes.
Self-protection of the first aider Remove all sources of ignition. Ensure that medical personnel are aware of the material(s)
involved, take precautions to protect themselves and prevent spread of contamination. Use
personal protective equipment as required. See section 8 for more information.
4.2. Most important symptoms and effects, both acute and delayed
4.3. Indication of any immediate medical attention and special treatment needed
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Suitable Extinguishing Media Dry chemical. Carbon dioxide (CO2). Water spray. Alcohol resistant foam.
Large Fire CAUTION: Use of water spray when fighting fire may be inefficient.
Unsuitable extinguishing media Do not scatter spilled material with high pressure water streams.
Specific hazards arising from the Risk of ignition. Keep product and empty container away from heat and sources of ignition.
chemical In the event of fire, cool tanks with water spray. Fire residues and contaminated fire
extinguishing water must be disposed of in accordance with local regulations.
Special protective equipment and Firefighters should wear self-contained breathing apparatus and full firefighting turnout gear.
precautions for fire-fighters Use personal protection equipment.
Personal precautions Evacuate personnel to safe areas. Use personal protective equipment as required. See
section 8 for more information. Avoid contact with skin, eyes or clothing. Ensure adequate
ventilation. Keep people away from and upwind of spill/leak. ELIMINATE all ignition sources
(no smoking, flares, sparks or flames in immediate area). Pay attention to flashback. Take
precautionary measures against static discharges. All equipment used when handling the
product must be grounded. Do not touch or walk through spilled material.
Environmental precautions Refer to protective measures listed in Sections 7 and 8. Prevent further leakage or spillage if
safe to do so. Prevent product from entering drains.
Methods for containment Stop leak if you can do it without risk. Do not touch or walk through spilled material. A
vapour suppressing foam may be used to reduce vapours. Dyke far ahead of spill to collect
run-off water. Keep out of drains, sewers, ditches and waterways. Absorb with earth, sand
or other non-combustible material and transfer to containers for later disposal.
Methods for cleaning up Take precautionary measures against static discharges. Dam up. Soak up with inert
absorbent material. Pick up and transfer to properly labelled containers.
Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.
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Reference to other sections See section 8 for more information. See section 13 for more information.
Advice on safe handling Use personal protection equipment. Avoid contact with skin and eyes. Avoid breathing
vapours or mists. Keep away from heat, hot surfaces, sparks, open flames and other
ignition sources. No smoking. Use grounding and bonding connection when transferring this
material to prevent static discharge, fire or explosion. Use with local exhaust ventilation. Use
spark-proof tools and explosion-proof equipment. Keep in an area equipped with sprinklers.
Use according to package label instructions.
General hygiene considerations Do not eat, drink or smoke when using this product. Contaminated work clothing should not
be allowed out of the workplace. Regular cleaning of equipment, work area and clothing is
recommended. Wash hands before breaks and immediately after handling the product.
Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from heat,
sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static
electricity). Keep in properly labelled containers. Do not store near combustible materials.
Keep in an area equipped with sprinklers. Store in accordance with the particular national
regulations. Store in accordance with local regulations.
Risk Management Methods (RMM) The information required is contained in this Safety Data Sheet.
Exposure Limits
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Propan-2-ol - TWA: 500 mg/m3 TWA: 200 ppm TWA: 150 ppm TWA: 200 ppm
67-63-0 Ceiling: 1000 mg/m3 TWA: 490 mg/m3 TWA: 350 mg/m3 TWA: 500 mg/m3
D* STEL: 400 ppm STEL: 250 ppm STEL: 250 ppm
STEL: 980 mg/m3 STEL: 600 mg/m3 STEL: 620 mg/m3
Chemical name France Germany TRGS Germany DFG Greece Hungary
2-Butoxyethanol TWA: 10 ppm TWA: 10 ppm TWA: 10 ppm TWA: 25 ppm TWA: 20 ppm
111-76-2 TWA: 49 mg/m3 TWA: 49 mg/m3 TWA: 49 mg/m3 TWA: 120 mg/m3 TWA: 98 mg/m3
STEL: 50 ppm H* Peak: 20 ppm * STEL: 50 ppm
STEL: 246 mg/m3 Peak: 98 mg/m3 STEL: 246 mg/m3
* * b*
Propan-2-ol STEL: 400 ppm TWA: 200 ppm TWA: 200 ppm TWA: 400 ppm TWA: 500 mg/m3
67-63-0 STEL: 980 mg/m3 TWA: 500 mg/m3 TWA: 500 mg/m3 TWA: 980 mg/m3 TWA: 200 ppm
Peak: 400 ppm STEL: 500 ppm STEL: 1000 mg/m3
Peak: 1000 mg/m3 STEL: 1225 mg/m3 STEL: 400 ppm
b*
Chemical name Ireland Italy MDLPS Italy AIDII Latvia Lithuania
2-Butoxyethanol TWA: 20 ppm TWA: 20 ppm TWA: 20 ppm TWA: 20 ppm STEL: 20 ppm
111-76-2 TWA: 98 mg/m3 TWA: 98 mg/m3 TWA: 97 mg/m3 TWA: 98 mg/m3 STEL: 100 mg/m3
STEL: 50 ppm STEL: 50 ppm STEL: 50 ppm TWA: 10 ppm
STEL: 246 mg/m3 STEL: 246 mg/m3 STEL: 246 mg/m3 TWA: 50 mg/m3
Sk* cute* Ada* O*
Propan-2-ol TWA: 200 ppm - TWA: 200 ppm TWA: 350 mg/m3 STEL: 250 ppm
67-63-0 STEL: 400 ppm TWA: 492 mg/m3 STEL: 600 mg/m3 STEL: 600 mg/m3
Sk* STEL: 400 ppm TWA: 150 ppm
STEL: 983 mg/m3 TWA: 350 mg/m3
Chemical name Luxembourg Malta Netherlands Norway Poland
2-Butoxyethanol STEL: 50 ppm STEL: 50 ppm TWA: 20.4 ppm TWA: 10 ppm STEL: 200 mg/m3
111-76-2 STEL: 246 mg/m3 STEL: 246 mg/m3 TWA: 100 mg/m3 TWA: 50 mg/m3 TWA: 98 mg/m3
TWA: 20 ppm skin* STEL: 50 ppm STEL: 20 ppm skóra*
TWA: 98 mg/m3 TWA: 20 ppm STEL: 246 mg/m3 STEL: 75 mg/m3
Peau* TWA: 98 mg/m3 H* H*
Propan-2-ol - - - TWA: 100 ppm STEL: 1200 mg/m3
67-63-0 TWA: 245 mg/m3 TWA: 900 mg/m3
STEL: 150 ppm skóra*
STEL: 306.25 mg/m3
Chemical name Portugal Romania Slovakia Slovenia Spain
2-Butoxyethanol TWA: 20 ppm TWA: 20 ppm TWA: 20 ppm TWA: 20 ppm TWA: 20 ppm
111-76-2 TWA: 98 mg/m3 TWA: 98 mg/m3 TWA: 98 mg/m3 TWA: 98 mg/m3 TWA: 98 mg/m3
STEL: 50 ppm STEL: 50 ppm K* STEL: 50 ppm STEL: 50 ppm
STEL: 246 mg/m3 STEL: 246 mg/m3 Ceiling: 246 mg/m3 STEL: 246 mg/m3 STEL: 245 mg/m3
Cutânea* P* K* vía dérmica*
Propan-2-ol TWA: 200 ppm TWA: 81 ppm TWA: 200 ppm TWA: 200 ppm TWA: 200 ppm
67-63-0 STEL: 400 ppm TWA: 200 mg/m3 TWA: 500 mg/m3 TWA: 500 mg/m3 TWA: 500 mg/m3
STEL: 203 ppm Ceiling: 1000 mg/m3 STEL: 400 ppm STEL: 400 ppm
STEL: 500 mg/m3 STEL: 1000 mg/m3 STEL: 1000 mg/m3
Chemical name Sweden Switzerland United Kingdom
2-Butoxyethanol Bindande KGV: 50 ppm TWA: 10 ppm TWA: 25 ppm
111-76-2 Bindande KGV: 246 mg/m3 TWA: 49 mg/m3 TWA: 123 mg/m3
NGV: 10 ppm STEL: 20 ppm STEL: 50 ppm
NGV: 50 mg/m3 STEL: 98 mg/m3 STEL: 246 mg/m3
H* H* Sk*
Propan-2-ol Vägledande KGV: 250 ppm TWA: 200 ppm TWA: 400 ppm
67-63-0 Vägledande KGV: 600 mg/m3 TWA: 500 mg/m3 TWA: 999 mg/m3
NGV: 150 ppm STEL: 400 ppm STEL: 500 ppm
NGV: 350 mg/m3 STEL: 1000 mg/m3 STEL: 1250 mg/m3
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workweek) workweek
Chemical name Latvia Luxembourg Romania Slovakia
Propan-2-ol - - 50 mg/L - urine (Acetone) -
67-63-0 - end of shift
Chemical name Slovenia Spain Switzerland United Kingdom
2-Butoxyethanol 150 mg/g Creatinine - 200 mg/g Creatinine 150 mg/g creatinine (urine 240 mmol/mol creatinine -
111-76-2 urine (Butoxyacetic acid (urine - Butoxyacetic acid - 2-Butoxyacetic acid urine (Butoxyacetic acid) -
(after hydrolysis)) - at the (with hydrolysis) end of (after hydrolysis) end of post shift
end of the work shift; for shift) shift, and after several
long-term exposure: at the shifts (for long-term
end of the work shift after exposures))
several consecutive
workdays
Propan-2-ol 25 mg/L - blood (Acetone) 40 mg/L (urine - Acetone 25 mg/L (urine - Acetone -
67-63-0 - at the end of the work end of workweek) end of shift)
shift 0.4 mmol/L (urine -
25 mg/L - urine (Acetone) Acetone end of shift)
- at the end of the work 25 mg/L (whole blood -
shift Acetone end of shift)
0.4 mmol/L (whole blood -
Acetone end of shift)
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Chemical name Freshwater Marine sediment Sewage treatment Soil Food chain
sediment
2-Butoxyethanol 34.6 mg/kg 3.46 mg/kg 463 mg/L 2.33 mg/kg soil dw 0.02 g/kg food
111-76-2 sediment dw sediment dw
Propan-2-ol 552 mg/kg sediment 552 mg/kg sediment 2251 mg/L 28 mg/kg soil dw 160 mg/kg food
67-63-0 dw dw
Skin and body protection Wear suitable protective clothing. Long sleeved clothing. Chemical resistant apron.
Antistatic boots.
Respiratory protection No protective equipment is needed under normal use conditions. If exposure limits are
exceeded or irritation is experienced, ventilation and evacuation may be required.
General hygiene considerations Do not eat, drink or smoke when using this product. Contaminated work clothing should not
be allowed out of the workplace. Regular cleaning of equipment, work area and clothing is
recommended. Wash hands before breaks and immediately after handling the product.
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Explosion data
Sensitivity to mechanical impact None.
Sensitivity to static discharge Yes.
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Product Information
Inhalation Specific test data for the substance or mixture is not available.
Eye contact Specific test data for the substance or mixture is not available.
Skin contact Specific test data for the substance or mixture is not available. Causes mild skin irritation.
Ingestion Specific test data for the substance or mixture is not available.
Acute toxicity
The following values are calculated based on chapter 3.1 of the GHS document
ATEmix (oral) 20,408.20 mg/kg
ATEmix (dermal) 99,999.00 mg/kg
ATEmix (inhalation-gas) 99,999.00 ppm
ATEmix (inhalation-vapour) 449.00 mg/l
ATEmix (inhalation-dust/mist) 99,999.00 mg/l
Component Information
Chemical name Oral LD50 Dermal LD50 Inhalation LC50
2-Butoxyethanol = 470 mg/kg ( Rat ) = 435 mg/kg ( Rabbit ) = 450 ppm ( Rat ) 4 h
= 486 ppm ( Rat ) 4 h
Propan-2-ol = 1870 mg/kg ( Rat ) = 4059 mg/kg ( Rabbit ) > 10000 ppm ( Rat ) 6 h
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Skin corrosion/irritation Based on available data, the classification criteria are not met.
Serious eye damage/eye irritation Based on available data, the classification criteria are not met.
Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
Germ cell mutagenicity Based on available data, the classification criteria are not met.
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Carcinogenicity Based on available data, the classification criteria are not met.
Reproductive toxicity Based on available data, the classification criteria are not met.
STOT - single exposure Based on available data, the classification criteria are not met.
STOT - repeated exposure Based on available data, the classification criteria are not met.
Aspiration hazard Based on available data, the classification criteria are not met.
Endocrine disrupting properties The substance/mixture does not contain components considered to have endocrine
disrupting properties according to REACH Article 57(f) or Commission Delegated regulation
(EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
Bioaccumulation
Component Information
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PBT and vPvB assessment The product does not contain any substance(s) classified as PBT or vPvB above the
threshold of declaration.
Endocrine disrupting properties The substance/mixture does not contain components considered to have endocrine
disrupting properties according to REACH Article 57(f) or Commission Delegated regulation
(EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
Waste from residues/unused Should not be released into the environment. Dispose of in accordance with local
products regulations. Dispose of waste in accordance with environmental legislation.
Contaminated packaging Empty containers pose a potential fire and explosion hazard. Do not cut, puncture or weld
containers.
IMDG
14.1 UN number or ID number UN3082
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14.2 UN proper shipping name Environmentally hazardous substances, liquid, n.o.s. (nitrate amine salt of N-[3-
dimethylaminopropyl]- C14-C20 amides, saturated, reaction products with ethylene oxide)
14.3 Transport hazard class(es) 9
14.4 Packing group III
Description UN3082, Environmentally hazardous substances, liquid, n.o.s. (nitrate amine salt of N-[3-
dimethylaminopropyl]- C14-C20 amides, saturated, reaction products with ethylene oxide),
9, III, (60°C c.c.), Marine pollutant
14.5 Environmental hazards Yes
14.6 Special precautions for user
Special Provisions 274, 335, 969
EmS-No F-A, S-F
14.7 Maritime transport in bulk No information available
according to IMO instruments
RID
14.1 UN number or ID number UN3082
14.2 UN proper shipping name Environmentally hazardous substances, liquid, n.o.s. (nitrate amine salt of N-[3-
dimethylaminopropyl]- C14-C20 amides, saturated, reaction products with ethylene oxide)
14.3 Transport hazard class(es) 9
14.4 Packing group III
Description UN3082, Environmentally hazardous substances, liquid, n.o.s. (nitrate amine salt of N-[3-
dimethylaminopropyl]- C14-C20 amides, saturated, reaction products with ethylene oxide),
9, III
14.5 Environmental hazards Yes
14.6 Special precautions for user
Special Provisions 274, 335, 375, 601
Classification code M6
ADR
14.1 UN number or ID number UN3082
14.2 UN proper shipping name Environmentally hazardous substances, liquid, n.o.s. (nitrate amine salt of N-[3-
dimethylaminopropyl]- C14-C20 amides, saturated, reaction products with ethylene oxide)
14.3 Transport hazard class(es) 9
14.4 Packing group III
Description UN3082, Environmentally hazardous substances, liquid, n.o.s. (nitrate amine salt of N-[3-
dimethylaminopropyl]- C14-C20 amides, saturated, reaction products with ethylene oxide),
9, III, (-)
14.5 Environmental hazards Yes
14.6 Special precautions for user
Special Provisions 274, 335, 601, 375
Classification code M6
Tunnel restriction code (-)
National regulations
France
Occupational Illnesses (R-463-3, France)
Chemical name French RG number
2-Butoxyethanol - 111-76-2 RG 84
Propan-2-ol - 67-63-0 RG 84
Germany
Water hazard class (WGK) slightly hazardous to water (WGK 1)
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European Union
Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents
at work.
International Inventories
TSCA Contact supplier for inventory compliance status
DSL/NDSL Contact supplier for inventory compliance status
EINECS/ELINCS Contact supplier for inventory compliance status
ENCS Contact supplier for inventory compliance status
IECSC Contact supplier for inventory compliance status
KECL Contact supplier for inventory compliance status
PICCS Contact supplier for inventory compliance status
AIIC Contact supplier for inventory compliance status
NZIoC Contact supplier for inventory compliance status
Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AIIC - Australian Inventory of Industrial Chemicals
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Legend
SVHC: Substances of Very High Concern for Authorisation:
Classification procedure
Classification according to Regulation (EC) No. 1272/2008 [CLP] Method Used
Acute oral toxicity Calculation method
Acute dermal toxicity Calculation method
Acute inhalation toxicity - gas Calculation method
Acute inhalation toxicity - vapour Calculation method
Acute inhalation toxicity - dust/mist Calculation method
Skin corrosion/irritation Calculation method
Serious eye damage/eye irritation Calculation method
Respiratory sensitisation Calculation method
Skin sensitisation Calculation method
Mutagenicity Calculation method
Carcinogenicity Calculation method
Reproductive toxicity Calculation method
STOT - single exposure Calculation method
STOT - repeated exposure Calculation method
Acute aquatic toxicity Calculation method
Chronic aquatic toxicity Calculation method
Aspiration hazard Calculation method
Ozone Calculation method
Key literature references and sources for data used to compile the SDS
Agency for Toxic Substances and Disease Registry (ATSDR)
U.S. Environmental Protection Agency ChemView Database
European Food Safety Authority (EFSA)
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