REPORT

DRRR-Proficiency Proficiency testing scheme accredited by A2LA

according to ISO/IEC 17043:2010.

Testing

RVEP 222031 Proficiency testing scheme accredited by DAkkS

according to DIN EN ISO/IEC 17043:2010.
The accreditation is valid only for the scope listed
in the annex of the accreditation certificate [D-EP-
17063-01-00].
The Deutsche Akkreditierungsstelle GmbH is a
skimmed milk powder signatory of the multilateral arrangements of EA,
ILAC and IAF for mutual recognition.

chemical-physical
Deutsches Referenzbüro für Ringversuche und
Referenzmaterialien GmbH
Reinhartser Straße 31 D-87437 Kempten
Moritz Hebestreit Regina Wörz fon: +49 (0)8 31/960 878-0
fax: +49 (0)8 31/960 878-99
Inspector* PT-Assistant e-Mail: info@DRRR.de
website: www.DRRR.de

accounting details:
VAT-no DE254613132
Raiffeisenbank im Allgäuer Land
BIC-Code: GENO DEF1DTA
IBAN: DE94 7336 9264 0000 1023 50

place of business: Kempten

commercial registry: HRB 9496
local court: Kempten
managing director:
Dr. rer. nat. Ulrich Leist
Thorsten Helbig M.Eng.

date: 13.10.2022

The copying, distribution and external utilization

* responsible for planning, organization and evaluation of the present of this document and the corresponding
certificates as well as the communication of its
proficiency testing scheme contents to others without expressed
authorization by the DRRR GmbH is prohibited.

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index of contents

1. timetable page 3

2. participants page 3

3. subcontracting services page 3

4. test items page 4

5. requested test parameters page 4

6. homogeneity and stability of the test items page 5

7. demonstration of the results page 5

8. recommendations page 5

9. determination of assigned value and SDPA page 6

10. remarks and comments page 7

11. results, tables and graphics

fat page 8

moisture content page 22

protein (Nx6,38) page 36

lactose (monohydrate) page 50

ash page 62

titratable acid page 76

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1. timetable

announcement of the proficiency testing: 17.08.2022

shipment of samples: 31.08.2022

final date for results: 30.09.2022

preparation and dispatch of report: 13.10.2022

2. participants

national (Germany) 4

international 21

thereof from the EU 4

participants total 25

3. subcontracting services

For this proficiency test the following work was subcontracted

Sample production Homogeneity test Stability test

sample 1 x x

sample 2 x x

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4. test items

sample 1: Skimmed milk powder; RM CP L MP MP 15

- Manufacturing process: Industrially manufactured goods

- Dimension: 80,0 g in foil-laminated, heat sealed sachet

- Material: typical skimmed milk powder

sample 2: Skimmed milk powder; RM CP L MP MP 16

- Manufacturing process: Industrially manufactured goods

- Dimension: 80,0 g in foil-laminated, heat sealed sachet

- Material: typical skimmed milk powder

5. requested test parameters

1) fat

2) moisture content

3) protein (Nx6,38)

4) lactose (monohydrate)

5) ash

6) titratable acid

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6. homogeneity and stability of the test items

In this proficiency testing a third party homogene reference material of an accredited PT

provider was used. So the material complies with the international standard DIN EN
ISO/IEC 17043:2010.

For additional information (e.g. calculation equations and evaluation criteria) we recommend
our statistical protocol.

7. demonstration of the results

All individual results of the laboratories are shown in tables and diagrams and can include
the following elements:
- Measurement results and average of the participants for each parameter
- Applied testing methods of the participants
- Performance evaluation of the participants by using the z'-score
- Precision data
- Graphic illustration (with the individual results in ascending order)
- If applicable, graphic illustration of further test methods
- Youden-Plot
- Graphic illustration of the z'-score of all participants

Interpretation possibilities of the graphics and additional information on the graphic

illustrations can be found in our statistical protocol.

8. recommendations

In addition to the long-term monitoring of the own quality by means of reference material,
control charts and proficiency testing, we have included a number of general
recommendations in our statistical protocol.

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9. determination of assigned value and SDPA

General information:

In principle the proficiency testings are evaluated by different statistical methods. This
statistical methods can be adapted exactly to the available data or the available data set.
The statistics used for the respective parameter to calculate the assigned value (xpt) and the
standard deviation for proficiency assessment (SDPA) can be found in the following table:

remark for the SDPA:

Usually the SDPA is calculated as the "Consensus value sbest" from the data of the
participants. If this calculated value falls below or exceeds the defined minimum SDPA
(SDPAmin) or maximum SDPA (SDPAmax) for the respective parameter, sbest is replaced by
the defined SDPAmin or SDPAmax.

Statistical background information (e.g. selection criteria for the different statistical
methods, treatment of outliers, specialities of certain types of distributions and
measurement of laboratory performance can be found in our statistical protocol.

sample Parameter Selection of SDPA Applied statistic

sample 1 fat Consensus value s best Robust statistic (Hampel estimator, Q-method)

sample 2 fat Consensus value s best Robust statistic (Hampel estimator, Q-method)

sample 1 moisture content Consensus value s best Conventional statistics (no outliers)

sample 2 moisture content Consensus value s best Conventional statistics (all values)

sample 1 protein (Nx6,38) Consensus value s best Conventional statistics (all values)

sample 2 protein (Nx6,38) Consensus value s best Conventional statistics (no outliers)

sample 1 lactose (monohydrate) Consensus value s best Conventional statistics (all values)

sample 2 lactose (monohydrate) Consensus value s best Conventional statistics (all values)

sample 1 ash Consensus value s best Robust statistic (Hampel estimator, Q-method)

sample 2 ash Consensus value s best Robust statistic (Hampel estimator, Q-method)

sample 1 titratable acid Consensus value s best Robust statistic (Hampel estimator, Q-method)

sample 2 titratable acid Consensus value s best Robust statistic (Hampel estimator, Q-method)

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10. remarks and comments

This proficiency testing was carried out for the 12th time. 25 laboratories participated in this
proficiency testing. All parameters in this proficiency testing could be evaluated.
The results achieved in the proficiency testing were in accordance with our expectations.

For the laboratories 8 / 10 / 11 / 12 / 13 / 14 / 15 / 16 / 17 / 18 / 19 / 20 / 21 / 22 / 23 / 24 and

25, only two results (of the available results) were used for the calculation of the assigned
value and the SDPA, as otherwise the influence of a single laboratory on the reference
value would have been too great. Nevertheless, all results of these laboratories were
evaluated as usual and graphically presented in the report.

For the parameter titratable acid, for sample 1 and 2, laboratory 9 was defined as technical
outlier, since the measured values are obvious decimal point errors.

The relative standard deviations / MADs in the proficiency testing were in the range of our
expectation and, compared to our empirical value for the mean relative standard deviation,
were as follows:
fat, sample 1: 10.99 % (empirical value: 11.17 %)
fat, sample 2: 8.82 % (experience value: 11.17 %)
moisture content, sample 1: 3.58 % (empirical value: 3.48 %)
moisture content, sample 2: 4.56 % (empirical value: 3.48 %)
protein, sample 1: 0.51 % (empirical value: 0.66 %)
protein, sample 2: 0.39 % (empirical value: 0.66 %)
lactose monohydrate, sample 1: 1.30 % (empirical value: 1.73 %)
lactose monohydrate, sample 2: 1.68 % (empirical value: 1.73 %)
ash, sample 1: 1.40 % (empirical value: 1.15 %)
ash, sample 2: 1.37 % (empirical value: 1.15 %)
titratable acid, sample 1: 9.80 % (empirical value: 11.16 %)
titratable acid, sample 2: 9.48 % (empirical value: 11.16 %)

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results
fat sample 1

assigned value xpt [g/100 g] - Röse-Gottlieb 0,64

± expanded uncertainty (k=t) of the assigned value U(x pt) 0,03

customer data performance

x x x x x̅
lab
single single single single lab method description / com-
code z-score z'-score CRD-value
value 1 value 2 value 3 value 4 mean standard ments
no.
[g/100 g]
1 0,37 0,37 0,37 NMR -3,78 -3,81 -2,02

Mojonni
er-type
Gravimetric method fat-
2 < 1.01 > 0.99 (reference method) - ISO extractio
1736 IDF 9 n flacks
were
used

Röse Gottlieb VDLUFA C

3 0,65 0,63 0,64 0,04 0,04 0,02
15.2.1
Röse-Gottlieb LFGB Person
4,1 0,58 0,60 0,59 -0,67 -0,67 -0,36
L02.07-15 1
Röse-Gottlieb LFGB Person
4,2 0,61 0,59 0,60 -0,52 -0,53 -0,28
L02.07-15 2
5 0,79 0,76 0,78 IDF 123:2008 1,95 1,97 1,04
6 0,63 0,63 0,63 ISO 1736 -0,10 -0,10 -0,05
7 n/a n/a - -
8,1 n/a n/a
8,2 n/a n/a
8,3 n/a n/a
8,4 n/a n/a

<2 <2
g/100g g/100g
AOAC Official method
2000.18 fat content of raw LOQ=2
9 2
and pasteurized whole milk g/100g
2 g/ g/ 100
(Gerber method by weight)
100 g= g=
LOQ LOQ

10,1 0,66 n/a 0,66 ISO 1736/IDF 9 0,32 0,33 0,17

10,2 0,60 n/a 0,60 ISO 1736/IDF 9 -0,52 -0,53 -0,28
10,3 0,69 n/a 0,69 GB5009.6 (Method III) 0,75 0,76 0,40
10,4 0,63 n/a 0,63 GB5009.6 (Method III) -0,10 -0,10 -0,05
11,1 0,60 n/a 0,60 Foss InfraXact -0,52 -0,53 -0,28
11,2 0,61 n/a 0,61 Foss InfraXact -0,38 -0,39 -0,20
11,3 0,60 n/a 0,60 Foss InfraXact -0,52 -0,53 -0,28
11,4 0,62 n/a 0,62 Foss InfraXact -0,24 -0,24 -0,13
12,1 0,47 n/a 0,47 NZTM3.6.3 -2,36 -2,38 -1,26
12,2 0,66 n/a 0,66 NZTM3.6.3 0,32 0,33 0,17
12,3 0,50 n/a 0,50 NMR -1,94 -1,96 -1,04
12,4 0,46 n/a 0,46 NMR -2,51 -2,53 -1,34
13,1 0,62 n/a 0,62 ISO 1211/IDF 1 -0,24 -0,24 -0,13
13,2 0,55 n/a 0,55 ISO 1211/IDF 1 -1,23 -1,24 -0,66

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results
fat sample 1

assigned value xpt [g/100 g] - Röse-Gottlieb 0,64

± expanded uncertainty (k=t) of the assigned value U(x pt) 0,03

customer data performance

x x x x x̅
lab
single single single single lab method description / com-
code z-score z'-score CRD-value
value 1 value 2 value 3 value 4 mean standard ments
no.
[g/100 g]
13,3 n/a n/a
13,4 n/a n/a
14,1 0,58 n/a 0,58 AOAC 932.06 -0,81 -0,81 -0,43
14,2 0,64 n/a 0,64 AOAC 932.06 0,04 0,04 0,02
14,3 n/a n/a
14,4 n/a n/a
15,1 0,59 n/a 0,59 ISO 1736/IDF 9 -0,67 -0,67 -0,36
15,2 0,60 n/a 0,60 ISO 1736/IDF 9 -0,52 -0,53 -0,28
15,3 n/a n/a
15,4 n/a n/a
16,1 0,69 n/a 0,69 AS2300.1.3 0,75 0,76 0,40
16,2 0,69 n/a 0,69 AS2300.1.3 0,75 0,76 0,40
16,3 n/a n/a
16,4 n/a n/a
17,1 0,53 n/a 0,53 ISO 1736/IDF 9 (Mod) -1,51 -1,53 -0,81
17,2 0,58 n/a 0,58 ISO 1736/IDF 9 (Mod) -0,81 -0,81 -0,43
17,3 0,56 n/a 0,56 Not Specified -1,09 -1,10 -0,58
17,4 0,65 n/a 0,65 Not Specified 0,18 0,18 0,10
18,1 0,70 n/a 0,70 ISO 1736/IDF 9 0,89 0,90 0,48
18,2 0,65 n/a 0,65 ISO 1736/IDF 9 0,18 0,18 0,10
18,3 n/a n/a
18,4 n/a n/a
19,1 0,70 n/a 0,70 NZTM3.6.3 0,89 0,90 0,48
19,2 0,69 n/a 0,69 NZTM3.6.3 0,75 0,76 0,40
19,3 0,70 n/a 0,70 NZTM3.6.3 0,89 0,90 0,48
19,4 0,69 n/a 0,69 NZTM3.6.3 0,75 0,76 0,40
20,1 n/a n/a
20,2 n/a n/a
20,3 n/a n/a
20,4 n/a n/a
21,1 0,76 n/a 0,76 NMR 1,74 1,75 0,93
21,2 0,59 n/a 0,59 NMR -0,67 -0,67 -0,36
21,3 n/a n/a
21,4 n/a n/a
22,1 0,62 n/a 0,62 NZTM3.6.3 -0,24 -0,24 -0,13
22,2 0,62 n/a 0,62 NZTM3.6.3 -0,24 -0,24 -0,13
22,3 n/a n/a
22,4 n/a n/a
23,1 0,72 n/a 0,72 NZTM3.6.3 1,17 1,18 0,63
23,2 0,72 n/a 0,72 NZTM3.6.3 1,17 1,18 0,63

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results
fat sample 1

assigned value xpt [g/100 g] - Röse-Gottlieb 0,64

± expanded uncertainty (k=t) of the assigned value U(x pt) 0,03

customer data performance

x x x x x̅
lab
single single single single lab method description / com-
code z-score z'-score CRD-value
value 1 value 2 value 3 value 4 mean standard ments
no.
[g/100 g]
23,3 n/a n/a
23,4 n/a n/a
24,1 n/a n/a
24,2 n/a n/a
24,3 n/a n/a
24,4 n/a n/a
25,1 0,70 n/a 0,70 Food Scan 0,89 0,90 0,48
25,2 0,69 n/a 0,69 Food Scan 0,75 0,76 0,40
25,3 n/a n/a
25,4 n/a n/a

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summarized evaluation
fat sample 1

assigned value xpt [g/100 g] - Röse-Gottlieb 0,64

± expanded uncertainty (k=t) of the assigned value U(x pt) 0,03
standard deviation for proficiency assessment (SDPA) 0,07
no. of datasets excluding outlier 25
no. of outlier 0

performance rating of laboratory datasets: precision data of the used DRRR-

standard-method:
§ 64 LFGB L 02.07-15

repeatability
z-score r 0,10
r rel (%) 15,70
x − xpt
z=
z≤2 2<z<3 z≥3 sR reproducibility
41 2 1 R 0,20
R rel (%) 31,39

z'-score repeatability standard deviation

sr
x − xpt 0,04
z′ =
z' ≤ 2 2 < z' < 3 z' ≥ 3 SDPA2 + s2
M
41 2 1 reproducibility standard deviation
sR 0,07

critical difference
CRD-value CD 0,13
x − xpt
CRD =
CD
material standard deviation:
This value is calculated on the basis
CRD < 1 CRD > 1 of previous studies and/or experience
39 5 values.
sM 0,01

x̅ = your lab mean value

Further information you will find in our statistical Protocol. xpt
As a registered customer you can download the statistical protocol on your personal assigned value
home page in our Online-Data-Information-Network (ODIN). U(xpt) expanded uncertainty
Alternatively, we also provide you with the statistical protocol on request. (k=t0.975, n-1) of the
assigned value

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paricipants total (independent of methods)

fat sample 1 (informative)

conventional statistics excluding outlier

mean [g/100 g] 0,63

standard deviation [g/100 g] 0,07
no. of datasets excluding outlier 43
no. of outlier 1

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results sorted according to means

fat sample 1
(error indicator = laboratory range)
1,10

1,00

0,90

0,80

0,70
Fett / fat [g/100 g]

0,60

0,50

0,40

0,30

0,20 Grubbs-Ausreißer /
Grubbs-outlier: 1
0,10
1
12,4
12,1
12,3
17,1
13,2
17,3
14,1
17,2
4,1
15,1
21,2
4,2
10,2
11,1
11,3
15,2
11,2
11,4
13,1
22,1
22,2
6
10,4
3
14,2
17,4
18,2
10,1
12,2
10,3
16,1
16,2
19,2
19,4
25,2
18,1
19,1
19,3
25,1
23,1
23,2
21,1
5
Labor-Code Nr. / lab code no.

Laborspannweite / lab range

Labormittelwert / lab mean value

Mittelwert nach Ausreißereliminierung / mean excluding outlier: 0,63

Zugwiesener Wert / assigned value (Röse-Gottlieb) ± U(xpt): 0,64 ± 0,03

results sorted according to methods

fat sample 1
(error indicator = laboratory range)
1,10

1,00 Röse-Gottlieb sonstige Methoden/

other methods
0,90

0,80

0,70
Fett / fat [g/100 g]

0,60

0,50

0,40

0,30

0,20

0,10
12,1
17,1
13,2
17,2
4,1
15,1
4,2
10,2
15,2
13,1
22,1
22,2
6
3
18,2
10,1
12,2
16,1
16,2
19,2
18,1
19,1
23,1
23,2
5
1
12,4
12,3
17,3
14,1
21,2
11,1
11,3
11,2
11,4
10,4
14,2
17,4
10,3
19,4
25,2
19,3
25,1
21,1

Labor-Code Nr. / lab code no.

Laborspannweite / lab range

Labormittelwert / lab mean value

Zugwiesener Wert / assigned value (Röse-Gottlieb) ± U(xpt): 0,64 ± 0,03

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results
fat sample 2

assigned value xpt [g/100 g] - Röse-Gottlieb 0,54

± expanded uncertainty (k=t) of the assigned value U(x pt) 0,02

customer data performance

x x x x x̅
lab
single single single single lab method description / com-
code z-score z'-score CRD-value
value 1 value 2 value 3 value 4 mean standard ments
no.
[g/100 g]
1 0,22 0,22 0,22 NMR -4,58 -6,74 -2,45

Mojonni
er-type
Gravimetric method fat-
2 < 0.62 > 0.62 (reference method) - ISO extractio
1736 IDF 9 n flacks
were
used

Röse Gottlieb VDLUFA C

3 0,59 0,60 0,60 0,72 1,07 0,39
15.2.1
Röse-Gottlieb LFGB Person
4,1 0,54 0,49 0,52 -0,41 -0,60 -0,22
L02.07-15 1
Röse-Gottlieb LFGB Person
4,2 0,45 0,46 0,46 -1,26 -1,85 -0,67
L02.07-15 2
5 0,60 0,65 0,63 IDF 123:2008 1,15 1,69 0,61
6 0,44 0,46 0,45 ISO 1736 -1,33 -1,95 -0,71
7 n/a n/a - -
8,1 n/a n/a
8,2 n/a n/a
8,3 n/a n/a
8,4 n/a n/a

<2 <2
g/100g g/100g AOAC Official method
2000.18 fat content of raw LOQ=2
9
2 2 and pasteurized whole milk g/100g
g/100 g/100 g (Gerber method by weight)
g= LOQ = LOQ

10,1 0,52 n/a 0,52 ISO 1736/IDF 9 -0,34 -0,50 -0,18

10,2 0,51 n/a 0,51 ISO 1736/IDF 9 -0,48 -0,70 -0,26
10,3 0,54 n/a 0,54 GB5009.6 (Method III) -0,05 -0,08 -0,03
10,4 0,49 n/a 0,49 GB5009.6 (Method III) -0,76 -1,12 -0,41
11,1 0,49 n/a 0,49 Foss InfraXact -0,76 -1,12 -0,41
11,2 0,48 n/a 0,48 Foss InfraXact -0,90 -1,33 -0,48
11,3 0,49 n/a 0,49 Foss InfraXact -0,76 -1,12 -0,41
11,4 0,48 n/a 0,48 Foss InfraXact -0,90 -1,33 -0,48
12,1 n/a n/a
12,2 n/a n/a
12,3 n/a n/a
12,4 n/a n/a
13,1 0,47 n/a 0,47 ISO 1211/IDF 1 -1,04 -1,54 -0,56

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results
fat sample 2

assigned value xpt [g/100 g] - Röse-Gottlieb 0,54

± expanded uncertainty (k=t) of the assigned value U(x pt) 0,02

customer data performance

x x x x x̅
lab
single single single single lab method description / com-
code z-score z'-score CRD-value
value 1 value 2 value 3 value 4 mean standard ments
no.
[g/100 g]
13,2 0,52 n/a 0,52 ISO 1211/IDF 1 -0,34 -0,50 -0,18
13,3 n/a n/a
13,4 n/a n/a
14,1 0,55 n/a 0,55 AOAC 932.06 0,09 0,13 0,05
14,2 0,55 n/a 0,55 AOAC 932.06 0,09 0,13 0,05
14,3 n/a n/a
14,4 n/a n/a
15,1 0,57 n/a 0,57 ISO 1736/IDF 9 0,37 0,55 0,20
15,2 0,54 n/a 0,54 ISO 1736/IDF 9 -0,05 -0,08 -0,03
15,3 n/a n/a
15,4 n/a n/a
16,1 0,59 n/a 0,59 AS2300.1.3 0,65 0,96 0,35
16,2 0,62 n/a 0,62 AS2300.1.3 1,08 1,59 0,58
16,3 n/a n/a
16,4 n/a n/a
17,1 0,52 n/a 0,52 ISO 1736/IDF 9 (Mod) -0,34 -0,50 -0,18
17,2 0,51 n/a 0,51 ISO 1736/IDF 9 (Mod) -0,48 -0,70 -0,26
17,3 0,41 n/a 0,41 Not Specified -1,89 -2,79 -1,01
17,4 0,40 n/a 0,40 Not Specified -2,03 -2,99 -1,09
18,1 0,58 n/a 0,58 ISO 1736/IDF 9 0,51 0,75 0,27
18,2 0,61 n/a 0,61 ISO 1736/IDF 9 0,94 1,38 0,50
18,3 n/a n/a
18,4 n/a n/a
19,1 0,57 n/a 0,57 NZTM3.6.3 0,37 0,55 0,20
19,2 0,58 n/a 0,58 NZTM3.6.3 0,51 0,75 0,27
19,3 0,57 n/a 0,57 NZTM3.6.3 0,37 0,55 0,20
19,4 0,58 n/a 0,58 NZTM3.6.3 0,51 0,75 0,27
20,1 n/a n/a
20,2 n/a n/a
20,3 n/a n/a
20,4 n/a n/a
21,1 0,57 n/a 0,57 NMR 0,37 0,55 0,20
21,2 0,42 n/a 0,42 NMR -1,75 -2,58 -0,94
21,3 n/a n/a
21,4 n/a n/a
22,1 0,53 n/a 0,53 NZTM3.6.3 -0,20 -0,29 -0,10
22,2 0,53 n/a 0,53 NZTM3.6.3 -0,20 -0,29 -0,10
22,3 n/a n/a
22,4 n/a n/a
23,1 0,54 n/a 0,54 NZTM3.6.3 -0,05 -0,08 -0,03

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results
fat sample 2

assigned value xpt [g/100 g] - Röse-Gottlieb 0,54

± expanded uncertainty (k=t) of the assigned value U(x pt) 0,02

customer data performance

x x x x x̅
lab
single single single single lab method description / com-
code z-score z'-score CRD-value
value 1 value 2 value 3 value 4 mean standard ments
no.
[g/100 g]
23,2 0,53 n/a 0,53 NZTM3.6.3 -0,20 -0,29 -0,10
23,3 n/a n/a
23,4 n/a n/a
24,1 n/a n/a
24,2 n/a n/a
24,3 n/a n/a
24,4 n/a n/a
25,1 0,58 n/a 0,58 Food Scan 0,51 0,75 0,27
25,2 0,59 n/a 0,59 Food Scan 0,65 0,96 0,35
25,3 n/a n/a
25,4 n/a n/a

RVEP 222031 / Art.-No.: 2010001 ©DRRR

 17/89

summarized evaluation
fat sample 2

assigned value xpt [g/100 g] - Röse-Gottlieb 0,54

± expanded uncertainty (k=t) of the assigned value U(x pt) 0,02
standard deviation for proficiency assessment (SDPA) 0,05
no. of datasets excluding outlier 23
no. of outlier 0

performance rating of laboratory datasets: precision data of the used DRRR-

standard-method:
§ 64 LFGB L 02.07-15

repeatability
z-score r 0,10
r rel (%) 18,39
x − xpt
z=
z≤2 2<z<3 z≥3 sR reproducibility
38 1 1 R 0,20
R rel (%) 36,78

z'-score repeatability standard deviation

sr
x − xpt 0,04
z′ =
z' ≤ 2 2 < z' < 3 z' ≥ 3 SDPA2 + s2
M
36 3 1 reproducibility standard deviation
sR 0,07

critical difference
CRD-value CD 0,13
x − xpt
CRD =
CD
material standard deviation:
This value is calculated on the basis
CRD < 1 CRD > 1 of previous studies and/or experience
37 3 values.
sM 0,01

x̅ = your lab mean value

Further information you will find in our statistical Protocol. xpt
As a registered customer you can download the statistical protocol on your personal assigned value
home page in our Online-Data-Information-Network (ODIN). U(xpt) expanded uncertainty
Alternatively, we also provide you with the statistical protocol on request. (k=t0.975, n-1) of the
assigned value

RVEP 222031 / Art.-No.: 2010001 ©DRRR

 18/89

paricipants total (independent of methods)

fat sample 2 (informative)

conventional statistics excluding outlier

mean [g/100 g] 0,53

standard deviation [g/100 g] 0,06
no. of datasets excluding outlier 39
no. of outlier 1

RVEP 222031 / Art.-No.: 2010001 ©DRRR

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results sorted according to means

fat sample 2
(error indicator = laboratory range)
1,10

1,00

0,90

0,80
Fett / fat [g/100 g]

0,70

0,60

0,50

0,40

0,30

0,20 Grubbs-Ausreißer /
Grubbs-outlier: 1
0,10
1
17,4
17,3
21,2
6
4,2
13,1
11,2
11,4
10,4
11,1
11,3
10,2
17,2
4,1
10,1
13,2
17,1
22,1
22,2
23,2
10,3
15,2
23,1
14,1
14,2
15,1
19,1
19,3
21,1
18,1
19,2
19,4
25,1
16,1
25,2
3
18,2
16,2
5
Labor-Code Nr. / lab code no.

Laborspannweite / lab range

Labormittelwert / lab mean value

Mittelwert nach Ausreißereliminierung / mean excluding outlier: 0,53

Zugwiesener Wert / assigned value (Röse-Gottlieb) ± U(xpt): 0,54 ± 0,02

results sorted according to methods

fat sample 2
(error indicator = laboratory range)
1,10

1,00
sonstige Methoden/
Röse-Gottlieb
other methods
0,90

0,80

0,70
Fett / fat [g/100 g]

0,60

0,50

0,40

0,30

0,20

0,10
6
4,2
13,1
10,2
17,2
4,1
10,1
13,2
17,1
22,1
22,2
23,2
15,2
23,1
15,1
19,1
18,1
19,2
16,1
3
18,2
16,2
5
1
17,4
17,3
21,2
11,2
11,4
10,4
11,1
11,3
10,3
14,1
14,2
19,3
21,1
19,4
25,1
25,2

Labor-Code Nr. / lab code no.

Laborspannweite / lab range

Labormittelwert / lab mean value

Zugwiesener Wert / assigned value (Röse-Gottlieb) ± U(xpt): 0,54 ± 0,02

RVEP 222031 / Art.-No.: 2010001 ©DRRR

 20/89

Youdenplot

zufällige Abweichung / systematisch zu hoch /

random deviation systematically to high

1,10

1,00

0,90

0,80
fat sample 2 [g/100 g]
Fett Probe 2 /

0,70

16,2 5
18,2
0,60 3 16,1
25,2
19,2
19,4
18,1
25,1
15,1 19,1
19,3 21,1
14,1 14,2
15,2 10,3 23,1
22,2
22,1 23,2
17,113,2 4,1 10,1
17,210,2
0,50 11,1 10,4
11,3
11,2
11,4
13,1
4,2 6

21,2
17,3
0,40 17,4

0,30

1
0,20

0,10
0,10 0,20 0,30 0,40 0,50 0,60 0,70 0,80 0,90 1,00 1,10

systematisch zu niedrig / Fett Probe 1 / zufällige Abweichung /

systematically to low fat sample 1 [g/100 g] random deviation

xpt ± 2 * SDPA xpt

95-%-Vertrauensellipse / 95 % confidence ellipse 99-%-Vertrauensellipse / 99 % confidence ellipse

Linear (Trendlinie / trend line)

RVEP 222031 / Art.-No.: 2010001 ©DRRR

21/89

©DRRR
5 5
21,1 16,2
23,2 18,2
23,1 3
25,1 25,2
19,3 16,1
19,1
18,1 25,1
25,2 19,4
19,4 19,2
19,2 18,1
16,2 21,1
16,1 19,3
10,3 19,1
12,2 15,1
Labor-Code Nr. / lab code no.
10,1 14,2

Labor-Code Nr. / lab code no.

18,2 14,1
17,4
14,2 23,1
3 15,2
10,4 10,3
6 23,2
z'-score

22,2 22,2

z'-score
22,1 22,1
13,1 17,1
11,4 13,2
11,2 10,1
15,2
11,3 4,1
11,1 17,2
10,2 10,2
4,2 11,3
21,2 11,1
15,1 10,4
4,1 11,4

RVEP 222031 / Art.-No.: 2010001

17,2 11,2
14,1 13,1
17,3 4,2
13,2
17,1 6
12,3 21,2
summary z'-score

summary z'-score
12,1 17,3
12,4 17,4
1 1
fat sample 1

fat sample 2
5,00

4,00

3,00

2,00

1,00

0,00

-1,00

-2,00

-3,00

-4,00

-5,00

-1,00

-2,00

-3,00

-4,00

-5,00
5,00

4,00

3,00

2,00

1,00

0,00
z'-score z'-score
 22/89

results
moisture content sample 1

assigned value xpt [g/100 g] - 102°C+/-2°C 3,77

± expanded uncertainty (k=t) of the assigned value U(x pt) 0,05

customer data performance

x x x x x̅
lab
single single single single lab method description / com-
code z-score z'-score CRD-value
value 1 value 2 value 3 value 4 mean standard ments
no.
[g/100 g]
1 3,80 3,85 3,83 Trockenschrank 0,72 0,37 0,42

Determination of moisture
2 > 3.95 < 3.97 content (Reference
method) ISO 5537 IDF 26

102°C Trockenschrank
3 3,78 3,85 3,82 0,58 0,30 0,34
VDLUFA C 35.6
VDLUFA C35.6 Verf A Person
4,1 3,92 3,91 3,92 1,99 1,04 1,17
102°C 1
VDLUFA C35.6 Verf A Person
4,2 4,04 4,02 4,03 3,62 1,89 2,13
102°C 2
5 3,75 3,66 3,71 IDF 26A:1993 -0,98 -0,51 -0,58
6 3,83 3,79 3,81 @ 102°C 0,51 0,26 0,30
7 3,32 3,31 3,32 PN-A-86364 / 102°C - -6,50 -3,39 -3,83
8,1 3,84 3,88 3,86 VDLUFAC35.6 102 °C 1,21 0,63 0,72
8,2 3,69 3,65 3,67 VDLUFAC35.6 102 °C -1,48 -0,77 -0,87
8,3 3,88 3,83 3,86 VDLUFAC35.6 102 °C 1,14 0,60 0,67
8,4 3,77 3,75 3,76 VDLUFAC35.6 102 °C -0,20 -0,11 -0,12
9 n/a n/a
10,1 3,54 n/a 3,54 IDF 26A -3,31 -1,73 -1,95
10,2 3,45 n/a 3,45 IDF 26A -4,59 -2,39 -2,70
10,3 3,54 n/a 3,54 GB5009.3 (Method I) -3,31 -1,73 -1,95
10,4 3,45 n/a 3,45 GB5009.3 (Method I) -4,59 -2,39 -2,70
11,1 4,04 n/a 4,04 Foss InfraXact 3,76 1,96 2,22
11,2 4,06 n/a 4,06 Foss InfraXact 4,04 2,11 2,38
11,3 4,13 n/a 4,13 Foss InfraXact 5,03 2,63 2,97
11,4 4,29 n/a 4,29 Foss InfraXact 7,30 3,81 4,30
12,1 3,83 n/a 3,83 NZTM3.12.8 0,79 0,41 0,46
12,2 3,84 n/a 3,84 NZTM3.12.8 0,93 0,49 0,55
12,3 n/a n/a
12,4 n/a n/a
13,1 3,65 n/a 3,65 ISO 5537/IDF 26 -1,76 -0,92 -1,04
13,2 3,60 n/a 3,60 ISO 5537/IDF 26 -2,47 -1,29 -1,45
13,3 n/a n/a
13,4 n/a n/a
14,1 3,87 n/a 3,87 NIRO A1b 1,35 0,71 0,80
14,2 3,72 n/a 3,72 NIRO A1b -0,77 -0,40 -0,45
14,3 n/a n/a
14,4 n/a n/a
15,1 4,00 n/a 4,00 Not Specified 3,19 1,67 1,88
15,2 3,88 n/a 3,88 Not Specified 1,50 0,78 0,88
15,3 n/a n/a

RVEP 222031 / Art.-No.: 2010001 ©DRRR

 23/89

results
moisture content sample 1

assigned value xpt [g/100 g] - 102°C+/-2°C 3,77

± expanded uncertainty (k=t) of the assigned value U(x pt) 0,05

customer data performance

x x x x x̅
lab
single single single single lab method description / com-
code z-score z'-score CRD-value
value 1 value 2 value 3 value 4 mean standard ments
no.
[g/100 g]
15,4 n/a n/a
16,1 3,94 n/a 3,94 AS2300.1.1 2,35 1,22 1,38
16,2 3,99 n/a 3,99 AS2300.1.1 3,05 1,59 1,80
16,3 n/a n/a
16,4 n/a n/a
17,1 3,74 n/a 3,74 IDF 26A -0,48 -0,25 -0,29
17,2 3,68 n/a 3,68 IDF 26A -1,33 -0,70 -0,79
17,3 n/a n/a
17,4 n/a n/a
18,1 3,91 n/a 3,91 IDF 26A 1,92 1,00 1,13
18,2 3,91 n/a 3,91 IDF 26A 1,92 1,00 1,13
18,3 n/a n/a
18,4 n/a n/a
19,1 3,62 n/a 3,62 NZTM3.12.8 -2,18 -1,14 -1,29
19,2 3,76 n/a 3,76 NZTM3.12.8 -0,20 -0,11 -0,12
19,3 3,62 n/a 3,62 NZTM3.12.8 -2,18 -1,14 -1,29
19,4 3,76 n/a 3,76 NZTM3.12.8 -0,20 -0,11 -0,12
20,1 n/a n/a
20,2 n/a n/a
20,3 n/a n/a
20,4 n/a n/a
21,1 3,76 n/a 3,76 NZTM3.12.8 -0,20 -0,11 -0,12
21,2 3,73 n/a 3,73 NZTM3.12.8 -0,63 -0,33 -0,37
21,3 n/a n/a
21,4 n/a n/a
22,1 3,81 n/a 3,81 NZTM3.12.8 0,51 0,26 0,30
22,2 3,80 n/a 3,80 NZTM3.12.8 0,36 0,19 0,21
22,3 n/a n/a
22,4 n/a n/a
23,1 3,79 n/a 3,79 NZTM3.12.8 0,22 0,12 0,13
23,2 3,75 n/a 3,75 NZTM3.12.8 -0,34 -0,18 -0,20
23,3 n/a n/a
23,4 n/a n/a
24,1 n/a n/a
24,2 n/a n/a
24,3 n/a n/a
24,4 n/a n/a
25,1 n/a n/a
25,2 n/a n/a
25,3 n/a n/a

RVEP 222031 / Art.-No.: 2010001 ©DRRR

 24/89

results
moisture content sample 1

assigned value xpt [g/100 g] - 102°C+/-2°C 3,77

± expanded uncertainty (k=t) of the assigned value U(x pt) 0,05

customer data performance

x x x x x̅
lab
single single single single lab method description / com-
code z-score z'-score CRD-value
value 1 value 2 value 3 value 4 mean standard ments
no.
[g/100 g]
25,4 n/a n/a

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summarized evaluation
moisture content sample 1

assigned value xpt [g/100 g] - 102°C+/-2°C 3,77

± expanded uncertainty (k=t) of the assigned value U(x pt) 0,05
standard deviation for proficiency assessment (SDPA) 0,14
no. of datasets excluding outlier 27
no. of outlier 1

performance rating of laboratory datasets: precision data of the used DRRR-

standard-method:
ISO 5537/IDF 26

repeatability
z-score r 0,15
r rel (%) 3,97
x − xpt
z=
z≤2 2<z<3 z≥3 sR reproducibility
27 4 12 R 0,20
R rel (%) 5,30

z'-score repeatability standard deviation

sr
x − xpt 0,05
z′ =
z' ≤ 2 2 < z' < 3 z' ≥ 3 SDPA2 + s2
M
37 4 2 reproducibility standard deviation
sR 0,07

critical difference
CRD-value CD 0,12
x − xpt
CRD =
CD
material standard deviation:
This value is calculated on the basis
CRD < 1 CRD > 1 of previous studies and/or experience
23 20 values.
sM 0,01

x̅ = your lab mean value

Further information you will find in our statistical Protocol. xpt
As a registered customer you can download the statistical protocol on your personal assigned value
home page in our Online-Data-Information-Network (ODIN). U(xpt) expanded uncertainty
Alternatively, we also provide you with the statistical protocol on request. (k=t0.975, n-1) of the
assigned value

RVEP 222031 / Art.-No.: 2010001 ©DRRR

 26/89

paricipants total (independent of methods)

moisture content sample 1 (informative)

conventional statistics excluding outlier

mean [g/100 g] 3,79

standard deviation [g/100 g] 0,19
no. of datasets excluding outlier 43
no. of outlier 0

RVEP 222031 / Art.-No.: 2010001 ©DRRR

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results sorted according to means

moisture content sample 1
(error indicator = laboratory range)
5,00

4,80
Wassergehalt / moisture content [g/100 g]

4,60

4,40

4,20

4,00

3,80

3,60

3,40

3,20

3,00
7
10,2
10,4
10,1
10,3
13,2
19,1
19,3
13,1
8,2
17,2
5
14,2
21,2
17,1
23,2
8,4
19,2
19,4
21,1
23,1
22,2
6
22,1
3
1
12,1
12,2
8,3
8,1
14,1
15,2
18,1
18,2
4,1
16,1
16,2
15,1
4,2
11,1
11,2
11,3
11,4
Labor-Code Nr. / lab code no.

Laborspannweite / lab range

Labormittelwert / lab mean value

Mittelwert nach Ausreißereliminierung / mean excluding outlier: 3,79

Zugwiesener Wert / assigned value (102°C+/-2°C) ± U(xpt): 3,77 ± 0,05

results sorted according to methods

moisture content sample 1
(error indicator = laboratory range)
5,00

4,80 102°C+/-2°C sonstige Methoden/

other methods
Wassergehalt / moisture content [g/100 g]

4,60

4,40

4,20

4,00

3,80

3,60

3,40

3,20 Grubbs-Ausreißer /
Grubbs-outlier: 7
3,00
7
10,2
10,1
13,2
19,1
13,1
8,2
17,2
5
21,2
17,1
23,2
19,2
21,1
23,1
22,2
6
22,1
3
12,1
12,2
8,1
18,1
18,2
4,1
16,1
16,2
4,2
10,4
10,3
19,3
14,2
8,4
19,4
1
8,3
14,1
15,2
15,1
11,1
11,2
11,3
11,4

Labor-Code Nr. / lab code no.

Laborspannweite / lab range

Labormittelwert / lab mean value

Zugwiesener Wert / assigned value (102°C+/-2°C) ± U(xpt): 3,77 ± 0,05

RVEP 222031 / Art.-No.: 2010001 ©DRRR

 28/89

results
moisture content sample 2

assigned value xpt [g/100 g] - 102°C+/-2°C 3,66

± expanded uncertainty (k=t) of the assigned value U(x pt) 0,07

customer data performance

x x x x x̅
lab
single single single single lab method description / com-
code z-score z'-score CRD-value
value 1 value 2 value 3 value 4 mean standard ments
no.
[g/100 g]
1 3,66 3,64 3,65 Trockenschrank -0,13 -0,05 -0,08

Determination of moisture
2 > 3.91 < 4.04 content (Reference
method) ISO 5537 IDF 26

102°C Trockenschrank
3 3,75 3,80 3,78 1,64 0,69 0,97
VDLUFA C 35.6
VDLUFA C35.6 Verf A Person
4,1 3,83 3,83 3,83 2,42 1,02 1,43
102°C 1
VDLUFA C35.6 Verf A Person
4,2 3,98 3,98 3,98 4,54 1,92 2,68
102°C 2
5 3,84 3,72 3,78 IDF 26A:1993 1,71 0,72 1,01
6 3,77 3,76 3,77 @ 102°C 1,50 0,63 0,88
7 3,23 3,23 3,23 PN-A-86364 / 102°C - -6,07 -2,56 -3,58
8,1 3,87 3,84 3,86 VDLUFAC35.6 102 °C 2,77 1,17 1,63
8,2 3,65 3,67 3,66 VDLUFAC35.6 102 °C 0,01 0,01 0,01
8,3 3,80 3,79 3,80 VDLUFAC35.6 102 °C 1,92 0,81 1,13
8,4 3,61 3,62 3,62 VDLUFAC35.6 102 °C -0,62 -0,26 -0,37
9 n/a n/a
10,1 3,32 n/a 3,32 IDF 26A -4,80 -2,02 -2,83
10,2 3,50 n/a 3,50 IDF 26A -2,25 -0,95 -1,33
10,3 3,32 n/a 3,32 GB5009.3 (Method I) -4,80 -2,02 -2,83
10,4 3,50 n/a 3,50 GB5009.3 (Method I) -2,25 -0,95 -1,33
11,1 4,02 n/a 4,02 Foss InfraXact 5,11 2,15 3,01
11,2 4,03 n/a 4,03 Foss InfraXact 5,25 2,21 3,09
11,3 4,03 n/a 4,03 Foss InfraXact 5,25 2,21 3,09
11,4 4,03 n/a 4,03 Foss InfraXact 5,25 2,21 3,09
12,1 n/a n/a NZTM3.12.8
12,2 n/a n/a NZTM3.12.8
12,3 n/a n/a
12,4 n/a n/a
13,1 3,60 n/a 3,60 ISO 5537/IDF 26 -0,84 -0,35 -0,49
13,2 3,57 n/a 3,57 ISO 5537/IDF 26 -1,26 -0,53 -0,74
13,3 n/a n/a
13,4 n/a n/a
14,1 3,80 n/a 3,80 NIRO A1b 1,99 0,84 1,18
14,2 3,85 n/a 3,85 NIRO A1b 2,70 1,14 1,59
14,3 n/a n/a
14,4 n/a n/a
15,1 3,96 n/a 3,96 Not Specified 4,26 1,80 2,51
15,2 3,87 n/a 3,87 Not Specified 2,99 1,26 1,76
15,3 n/a n/a

RVEP 222031 / Art.-No.: 2010001 ©DRRR

 29/89

results
moisture content sample 2

assigned value xpt [g/100 g] - 102°C+/-2°C 3,66

± expanded uncertainty (k=t) of the assigned value U(x pt) 0,07

customer data performance

x x x x x̅
lab
single single single single lab method description / com-
code z-score z'-score CRD-value
value 1 value 2 value 3 value 4 mean standard ments
no.
[g/100 g]
15,4 n/a n/a
16,1 3,92 n/a 3,92 AS2300.1.1 3,69 1,56 2,18
16,2 3,80 n/a 3,80 AS2300.1.1 1,99 0,84 1,18
16,3 n/a n/a
16,4 n/a n/a
17,1 3,61 n/a 3,61 IDF 26A -0,69 -0,29 -0,41
17,2 3,58 n/a 3,58 IDF 26A -1,12 -0,47 -0,66
17,3 n/a n/a
17,4 n/a n/a
18,1 3,71 n/a 3,71 IDF 26A 0,72 0,30 0,43
18,2 3,73 n/a 3,73 IDF 26A 1,00 0,42 0,59
18,3 n/a n/a
18,4 n/a n/a
19,1 3,66 n/a 3,66 NZTM3.12.8 0,01 0,01 0,01
19,2 3,48 n/a 3,48 NZTM3.12.8 -2,53 -1,07 -1,49
19,3 3,66 n/a 3,66 NZTM3.12.8 0,01 0,01 0,01
19,4 3,48 n/a 3,48 NZTM3.12.8 -2,53 -1,07 -1,49
20,1 n/a n/a
20,2 n/a n/a
20,3 n/a n/a
20,4 n/a n/a
21,1 3,65 n/a 3,65 NZTM3.12.8 -0,13 -0,05 -0,08
21,2 3,64 n/a 3,64 NZTM3.12.8 -0,27 -0,11 -0,16
21,3 n/a n/a
21,4 n/a n/a
22,1 3,69 n/a 3,69 NZTM3.12.8 0,44 0,18 0,26
22,2 3,66 n/a 3,66 NZTM3.12.8 0,01 0,01 0,01
22,3 n/a n/a
22,4 n/a n/a
23,1 3,58 n/a 3,58 NZTM3.12.8 -1,12 -0,47 -0,66
23,2 3,56 n/a 3,56 NZTM3.12.8 -1,40 -0,59 -0,83
23,3 n/a n/a
23,4 n/a n/a
24,1 n/a n/a
24,2 n/a n/a
24,3 n/a n/a
24,4 n/a n/a
25,1 n/a n/a
25,2 n/a n/a
25,3 n/a n/a

RVEP 222031 / Art.-No.: 2010001 ©DRRR

 30/89

results
moisture content sample 2

assigned value xpt [g/100 g] - 102°C+/-2°C 3,66

± expanded uncertainty (k=t) of the assigned value U(x pt) 0,07

customer data performance

x x x x x̅
lab
single single single single lab method description / com-
code z-score z'-score CRD-value
value 1 value 2 value 3 value 4 mean standard ments
no.
[g/100 g]
25,4 n/a n/a

RVEP 222031 / Art.-No.: 2010001 ©DRRR

 31/89

summarized evaluation
moisture content sample 2

assigned value xpt [g/100 g] - 102°C+/-2°C 3,66

± expanded uncertainty (k=t) of the assigned value U(x pt) 0,07
standard deviation for proficiency assessment (SDPA) 0,17
no. of datasets excluding outlier 26
no. of outlier 0

performance rating of laboratory datasets: precision data of the used DRRR-

standard-method:
ISO 5537/IDF 26

repeatability
z-score r 0,15
r rel (%) 4,10
x − xpt
z=
z≤2 2<z<3 z≥3 sR reproducibility
23 8 10 R 0,20
R rel (%) 5,47

z'-score repeatability standard deviation

sr
x − xpt 0,05
z′ =
z' ≤ 2 2 < z' < 3 z' ≥ 3 SDPA2 + s2
M
34 7 0 reproducibility standard deviation
sR 0,07

critical difference
CRD-value CD 0,12
x − xpt
CRD =
CD
material standard deviation:
This value is calculated on the basis
CRD < 1 CRD > 1 of previous studies and/or experience
19 22 values.
sM 0,01

x̅ = your lab mean value

Further information you will find in our statistical Protocol. xpt
As a registered customer you can download the statistical protocol on your personal assigned value
home page in our Online-Data-Information-Network (ODIN). U(xpt) expanded uncertainty
Alternatively, we also provide you with the statistical protocol on request. (k=t0.975, n-1) of the
assigned value

RVEP 222031 / Art.-No.: 2010001 ©DRRR

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paricipants total (independent of methods)

moisture content sample 2 (informative)

conventional statistics excluding outlier

mean [g/100 g] 3,70

standard deviation [g/100 g] 0,20
no. of datasets excluding outlier 41
no. of outlier 0

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results sorted according to means

moisture content sample 2
(error indicator = laboratory range)
5,00

4,80
Wassergehalt / moisture content [g/100 g]

4,60

4,40

4,20

4,00

3,80

3,60

3,40

3,20

3,00
7
10,1
10,3
19,2
19,4
10,2
10,4
23,2
13,2
17,2
23,1
13,1
17,1
8,4
21,2
21,1
1
8,2
19,1
19,3
22,2
22,1
18,1
18,2
6
3
5
8,3
14,1
16,2
4,1
14,2
8,1
15,2
16,1
15,1
4,2
11,1
11,2
11,3
11,4
Labor-Code Nr. / lab code no.

Laborspannweite / lab range

Labormittelwert / lab mean value

Mittelwert nach Ausreißereliminierung / mean excluding outlier: 3,70

Zugwiesener Wert / assigned value (102°C+/-2°C) ± U(xpt): 3,66 ± 0,07

results sorted according to methods

moisture content sample 2
(error indicator = laboratory range)
5,00

4,80 102°C+/-2°C sonstige Methoden/

other methods
Wassergehalt / moisture content [g/100 g]

4,60

4,40

4,20

4,00

3,80

3,60

3,40

3,20

3,00
7
10,1
19,2
10,2
23,2
13,2
17,2
23,1
13,1
17,1
21,2
21,1
8,2
19,1
22,2
22,1
18,1
18,2
6
3
5
16,2
4,1
8,1
16,1
4,2
10,3
19,4
10,4
8,4
1
19,3
8,3
14,1
14,2
15,2
15,1
11,1
11,2
11,3
11,4

Labor-Code Nr. / lab code no.

Laborspannweite / lab range

Labormittelwert / lab mean value

Zugwiesener Wert / assigned value (102°C+/-2°C) ± U(xpt): 3,66 ± 0,07

RVEP 222031 / Art.-No.: 2010001 ©DRRR

 34/89

Youdenplot

zufällige Abweichung / systematisch zu hoch /

random deviation systematically to high

5,00

4,80

4,60

4,40
moisture content sample 2 [g/100 g]
Wassergehalt Probe 2 /

4,20

11,2 11,3
11,1 11,4
4,00 4,2
15,1
16,1
15,2
14,2 8,1
4,1
3,80 5
14,1
8,3 16,2
63
18,2
18,1
22,1
19,1 8,2
19,3 21,122,21
21,2
8,4
17,1
3,60 13,1
13,2 17,2 23,223,1

10,2
10,4
19,2
19,4

3,40
10,1
10,3

7
3,20

3,00
3,00 3,20 3,40 3,60 3,80 4,00 4,20 4,40 4,60 4,80 5,00

systematisch zu niedrig / Wassergehalt Probe 1 / zufällige Abweichung /

systematically to low moisture content sample 1 [g/100 g] random deviation

xpt ± 2 * SDPA xpt

95-%-Vertrauensellipse / 95 % confidence ellipse 99-%-Vertrauensellipse / 99 % confidence ellipse

Linear (Trendlinie / trend line)

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summary z'-score
moisture content sample 1

z'-score
5,00

4,00

3,00

2,00

1,00
z'-score

0,00

-1,00

-2,00

-3,00

-4,00

-5,00
7
10,2
10,4
10,1
10,3
13,2
19,1
19,3
13,1
8,2
17,2
5
14,2
21,2
17,1
23,2
8,4
19,2
19,4
21,1
23,1
22,2
6
22,1
3
1
12,1
12,2
8,3
8,1
14,1
15,2
18,1
18,2
4,1
16,1
16,2
15,1
4,2
11,1
11,2
11,3
11,4
Labor-Code Nr. / lab code no.

summary z'-score
moisture content sample 2

z'-score
5,00

4,00

3,00

2,00

1,00
z'-score

0,00

-1,00

-2,00

-3,00

-4,00

-5,00
7
10,1
10,3
19,2
19,4
10,2
10,4
23,2
13,2
17,2
23,1
13,1
17,1
8,4
21,2
21,1
1
8,2
19,1
19,3
22,2
22,1
18,1
18,2
6
3
5
8,3
14,1
16,2
4,1
14,2
8,1
15,2
16,1
15,1
4,2
11,1
11,2
11,3
11,4

Labor-Code Nr. / lab code no.

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results
protein (Nx6,38) sample 1

assigned value xpt [g/100 g] - Kjeldahl 32,82

± expanded uncertainty (k=t) of the assigned value U(x pt) 0,06

customer data performance

x x x x x̅
lab
single single single single lab method description / com-
code z-score z'-score CRD-value
value 1 value 2 value 3 value 4 mean standard ments
no.
[g/100 g]
1 32,88 33,44 33,16 Dumas 2,26 2,04 1,22

Kjeldahl
principle
Determination of nitrogen and
2 < 32.95 > 32.91 content-Part 1 - SR EN crude
ISO 8968-1:2014 protein
calculati
on

3 32,95 32,90 32,93 Kjeldahl VDLUFA C 30.2 0,70 0,63 0,38

Person
4,1 32,65 32,60 32,63 Kjeldahl LFGB L01.00-10/1 -1,29 -1,17 -0,70
1
Person
4,2 32,64 32,68 32,66 Kjeldahl LFGB L01.00-10/1 -1,06 -0,96 -0,57
2
5 32,51 32,83 32,67 IDF 20-3:2004 -0,99 -0,90 -0,53
6 32,92 32,75 32,84 ISO 8968-1 0,10 0,09 0,06
7 32,56 32,55 32,56 PN-ENISO 8968-2:2004 - -1,75 -1,59 -0,95

8,1 32,75 32,69 32,72 VDLUFAC30.2 Kjeldahl -0,66 -0,60 -0,36

8,2 32,79 32,82 32,81 VDLUFAC30.2 Kjeldahl -0,09 -0,09 -0,05

8,3 32,61 32,67 32,64 VDLUFAC30.2 Kjeldahl -1,19 -1,08 -0,64

8,4 32,68 32,60 32,64 VDLUFAC30.2 Kjeldahl -1,19 -1,08 -0,64

9 n/a n/a
10,1 33,17 n/a 33,17 ISO 8968-1/IDF 20-1 2,33 2,10 1,26
10,2 33,08 n/a 33,08 ISO 8968-1/IDF 20-1 1,73 1,56 0,93
GB5009.5 (Method I
10,3 33,18 n/a 33,18 2,39 2,16 1,29
Kjeldahl)
GB5009.5 (Method I
10,4 32,93 n/a 32,93 0,73 0,66 0,40
Kjeldahl)
11,1 32,25 n/a 32,25 Foss InfraXact -3,78 -3,41 -2,04
11,2 32,23 n/a 32,23 Foss InfraXact -3,91 -3,53 -2,11
11,3 32,99 n/a 32,99 Foss InfraXact 1,13 1,02 0,61
11,4 32,97 n/a 32,97 Foss InfraXact 1,00 0,90 0,54
12,1 32,60 n/a 32,60 ISO 8968-1/IDF 20-1 -1,45 -1,32 -0,79
12,2 32,73 n/a 32,73 ISO 8968-1/IDF 20-1 -0,59 -0,54 -0,32
12,3 n/a n/a
12,4 n/a n/a
13,1 32,77 n/a 32,77 ISO 8968-1/IDF 20-1 -0,33 -0,30 -0,18
13,2 32,83 n/a 32,83 ISO 8968-1/IDF 20-1 0,07 0,06 0,04
13,3 n/a n/a

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results
protein (Nx6,38) sample 1

assigned value xpt [g/100 g] - Kjeldahl 32,82

± expanded uncertainty (k=t) of the assigned value U(x pt) 0,06

customer data performance

x x x x x̅
lab
single single single single lab method description / com-
code z-score z'-score CRD-value
value 1 value 2 value 3 value 4 mean standard ments
no.
[g/100 g]
13,4 n/a n/a
14,1 33,11 n/a 33,11 AOAC 930.29 1,93 1,74 1,04
14,2 32,87 n/a 32,87 AOAC 930.29 0,34 0,30 0,18
14,3 n/a n/a
14,4 n/a n/a
15,1 32,71 n/a 32,71 ISO 8968-1/IDF 20-1 -0,72 -0,66 -0,39
15,2 32,68 n/a 32,68 ISO 8968-1/IDF 20-1 -0,92 -0,84 -0,50
15,3 n/a n/a
15,4 n/a n/a
16,1 32,86 n/a 32,86 AS2300.1.2.1 0,27 0,24 0,15
16,2 32,87 n/a 32,87 AS2300.1.2.1 0,34 0,30 0,18
16,3 n/a n/a
16,4 n/a n/a

17,1 32,66 n/a 32,66 ISO 8968-2/IDF 20-2 (Mod) -1,06 -0,96 -0,57

17,2 32,84 n/a 32,84 ISO 8968-2/IDF 20-2 (Mod) 0,14 0,12 0,07

17,3 32,86 n/a 32,86 Not Specified 0,27 0,24 0,15

17,4 32,74 n/a 32,74 Not Specified -0,53 -0,48 -0,28
18,1 32,41 n/a 32,41 ISO 8968-1/IDF 20-1 -2,71 -2,46 -1,47
18,2 32,91 n/a 32,91 ISO 8968-1/IDF 20-1 0,60 0,54 0,33
18,3 n/a n/a
18,4 n/a n/a
19,1 33,00 n/a 33,00 ISO 8968-1/IDF 20-1 1,20 1,08 0,65
19,2 33,00 n/a 33,00 ISO 8968-1/IDF 20-1 1,20 1,08 0,65
19,3 33,00 n/a 33,00 ISO 8968-1/IDF 20-1 1,20 1,08 0,65
19,4 33,00 n/a 33,00 ISO 8968-1/IDF 20-1 1,20 1,08 0,65
20,1 n/a n/a
20,2 n/a n/a
20,3 n/a n/a
20,4 n/a n/a
21,1 32,89 n/a 32,89 ISO 8968-1/IDF 20-1 0,47 0,42 0,25
21,2 32,90 n/a 32,90 ISO 8968-1/IDF 20-1 0,54 0,48 0,29
21,3 n/a n/a
21,4 n/a n/a
22,1 32,89 n/a 32,89 ISO 8968-1/IDF 20-1 0,47 0,42 0,25
22,2 32,89 n/a 32,89 ISO 8968-1/IDF 20-1 0,47 0,42 0,25
22,3 n/a n/a
22,4 n/a n/a
23,1 32,82 n/a 32,82 ISO 8968-1/IDF 20-1 0,01 0,00 0,00
23,2 32,93 n/a 32,93 ISO 8968-1/IDF 20-1 0,73 0,66 0,40

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results
protein (Nx6,38) sample 1

assigned value xpt [g/100 g] - Kjeldahl 32,82

± expanded uncertainty (k=t) of the assigned value U(x pt) 0,06

customer data performance

x x x x x̅
lab
single single single single lab method description / com-
code z-score z'-score CRD-value
value 1 value 2 value 3 value 4 mean standard ments
no.
[g/100 g]
23,3 n/a n/a
23,4 n/a n/a
24,1 n/a n/a
24,2 n/a n/a
24,3 n/a n/a
24,4 n/a n/a
25,1 32,78 n/a 32,78 Food Scan -0,26 -0,24 -0,14
25,2 32,80 n/a 32,80 Food Scan -0,13 -0,12 -0,07
25,3 n/a n/a
25,4 n/a n/a

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 39/89

summarized evaluation
protein (Nx6,38) sample 1

assigned value xpt [g/100 g] - Kjeldahl 32,82

± expanded uncertainty (k=t) of the assigned value U(x pt) 0,06
standard deviation for proficiency assessment (SDPA) 0,17
no. of datasets excluding outlier 32
no. of outlier 0

performance rating of laboratory datasets: precision data of the used DRRR-

standard-method:
§ 64 LFGB L 01.00-10/1

repeatability
z-score r 0,23
r rel (%) 0,70
x − xpt xpt * 0,007
z=
z≤2 2<z<3 z≥3 sR reproducibility
41 4 2 R 0,43
R rel (%) 1,30
xpt * 0,013

z'-score repeatability standard deviation

sr
x − xpt 0,08
z′ =
z' ≤ 2 2 < z' < 3 z' ≥ 3 SDPA2 + s2
M
41 4 2 reproducibility standard deviation
sR 0,15

critical difference
CRD-value CD 0,28
x − xpt
CRD =
CD
material standard deviation:
This value is calculated on the basis
CRD < 1 CRD > 1 of previous studies and/or experience
40 7 values.
sM 0,02

x̅ = your lab mean value

Further information you will find in our statistical Protocol. xpt
As a registered customer you can download the statistical protocol on your personal assigned value
home page in our Online-Data-Information-Network (ODIN). U(xpt) expanded uncertainty
Alternatively, we also provide you with the statistical protocol on request. (k=t0.975, n-1) of the
assigned value

RVEP 222031 / Art.-No.: 2010001 ©DRRR

 40/89

paricipants total (independent of methods)

protein (Nx6,38) sample 1 (informative)

conventional statistics excluding outlier

mean [g/100 g] 32,82

standard deviation [g/100 g] 0,21
no. of datasets excluding outlier 47
no. of outlier 0

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results sorted according to means

protein (Nx6,38) sample 1
(error indicator = laboratory range)
33,80

33,60
Protein (Nx6,38) / protein (Nx6,38) [g/100 g]

33,40

33,20

33,00

32,80

32,60

32,40

32,20

32,00

31,80
11,2
11,1
18,1
7
12,1
4,1
8,3
8,4
4,2
17,1
5
15,2
15,1
8,1
12,2
17,4
13,1
25,1
25,2
8,2
23,1
13,2
6
17,2
16,1
17,3
14,2
16,2
21,1
22,1
22,2
21,2
18,2
3
10,4
23,2
11,4
11,3
19,1
19,2
19,3
19,4
10,2
14,1
1
10,1
10,3
Labor-Code Nr. / lab code no.

Laborspannweite / lab range

Labormittelwert / lab mean value

Mittelwert nach Ausreißereliminierung / mean excluding outlier: 32,82

Zugwiesener Wert / assigned value (Kjeldahl) ± U(xpt): 32,82 ± 0,06

results sorted according to methods

protein (Nx6,38) sample 1
(error indicator = laboratory range)
33,80

33,60 Kjeldahl
sonstige Methoden/
other methods
Protein (Nx6,38) / protein (Nx6,38) [g/100 g]

33,40

33,20

33,00

32,80

32,60

32,40

32,20

32,00

31,80
18,1
7
12,1
4,1
4,2
17,1
5
15,2
15,1
8,1
12,2
13,1
8,2
23,1
13,2
6
17,2
16,1
14,2
16,2
21,1
22,1
22,2
21,2
18,2
3
23,2
19,1
19,2
10,2
14,1
10,1
11,2
11,1
8,3
8,4
17,4
25,1
25,2
17,3
10,4
11,4
11,3
19,3
19,4
1
10,3

Labor-Code Nr. / lab code no.

Laborspannweite / lab range

Labormittelwert / lab mean value

Zugwiesener Wert / assigned value (Kjeldahl) ± U(xpt): 32,82 ± 0,06

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results
protein (Nx6,38) sample 2

assigned value xpt [g/100 g] - Kjeldahl 38,87

± expanded uncertainty (k=t) of the assigned value U(x pt) 0,06

customer data performance

x x x x x̅
lab
single single single single lab method description / com-
code z-score z'-score CRD-value
value 1 value 2 value 3 value 4 mean standard ments
no.
[g/100 g]
1 38,79 39,11 38,95 Dumas 0,47 0,54 0,25

Kjeldahl
principle
Determination of nitrogen and
2 38,84 38,89 38,87 content-Part 1 - SR EN crude -0,01 -0,01 0,00
ISO 8968-1:2014 protein
calculati
on

3 38,85 38,81 38,83 Kjeldahl VDLUFA C 30.2 -0,20 -0,24 -0,11

Person
4,1 38,51 38,76 38,64 Kjeldahl LFGB L01.00-10/1 -1,30 -1,49 -0,70
1
Person
4,2 38,74 38,68 38,71 Kjeldahl LFGB L01.00-10/1 -0,88 -1,01 -0,47
2
5 38,82 38,85 38,84 IDF 20-3:2004 -0,18 -0,20 -0,10
6 38,88 38,92 38,90 ISO 8968-1 0,19 0,22 0,10
7 38,85 38,86 38,86 PN-ENISO 8968-2:2004 - -0,06 -0,07 -0,03

8,1 38,71 38,73 38,72 VDLUFAC30.2 Kjeldahl -0,82 -0,94 -0,44

8,2 38,89 38,90 38,90 VDLUFAC30.2 Kjeldahl 0,16 0,18 0,09

8,3 38,57 38,65 38,61 VDLUFAC30.2 Kjeldahl -1,44 -1,65 -0,78

8,4 38,73 38,74 38,74 VDLUFAC30.2 Kjeldahl -0,74 -0,85 -0,40

9 n/a n/a
10,1 39,15 n/a 39,15 ISO 8968-1/IDF 20-1 1,59 1,83 0,86
10,2 39,20 n/a 39,20 ISO 8968-1/IDF 20-1 1,87 2,15 1,01
GB5009.5 (Method I
10,3 39,20 n/a 39,20 1,87 2,15 1,01
Kjeldahl)
GB5009.5 (Method I
10,4 39,15 n/a 39,15 1,59 1,83 0,86
Kjeldahl)
11,1 38,77 n/a 38,77 Foss InfraXact -0,54 -0,62 -0,29
11,2 38,87 n/a 38,87 Foss InfraXact 0,02 0,02 0,01
11,3 38,83 n/a 38,83 Foss InfraXact -0,20 -0,24 -0,11
11,4 38,69 n/a 38,69 Foss InfraXact -0,99 -1,14 -0,53
12,1 n/a n/a ISO 8968-1/IDF 20-1
12,2 n/a n/a ISO 8968-1/IDF 20-1
12,3 n/a n/a
12,4 n/a n/a
13,1 38,77 n/a 38,77 ISO 8968-1/IDF 20-1 -0,54 -0,62 -0,29
13,2 38,77 n/a 38,77 ISO 8968-1/IDF 20-1 -0,54 -0,62 -0,29
13,3 n/a n/a

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results
protein (Nx6,38) sample 2

assigned value xpt [g/100 g] - Kjeldahl 38,87

± expanded uncertainty (k=t) of the assigned value U(x pt) 0,06

customer data performance

x x x x x̅
lab
single single single single lab method description / com-
code z-score z'-score CRD-value
value 1 value 2 value 3 value 4 mean standard ments
no.
[g/100 g]
13,4 n/a n/a
14,1 38,97 n/a 38,97 AOAC 930.29 0,58 0,67 0,31
14,2 39,04 n/a 39,04 AOAC 930.29 0,97 1,12 0,53
14,3 n/a n/a
14,4 n/a n/a
15,1 38,65 n/a 38,65 ISO 8968-1/IDF 20-1 -1,21 -1,40 -0,66
15,2 38,67 n/a 38,67 ISO 8968-1/IDF 20-1 -1,10 -1,27 -0,59
15,3 n/a n/a
15,4 n/a n/a
16,1 38,95 n/a 38,95 AS2300.1.2.1 0,47 0,54 0,25
16,2 38,89 n/a 38,89 AS2300.1.2.1 0,13 0,15 0,07
16,3 n/a n/a
16,4 n/a n/a

17,1 38,65 n/a 38,65 ISO 8968-2/IDF 20-2 (Mod) -1,21 -1,40 -0,66

17,2 38,67 n/a 38,67 ISO 8968-2/IDF 20-2 (Mod) -1,10 -1,27 -0,59

17,3 38,74 n/a 38,74 Not Specified -0,71 -0,82 -0,38

17,4 n/a n/a Not Specified
18,1 38,31 n/a 38,31 ISO 8968-1/IDF 20-1 -3,12 -3,59 -1,68
18,2 38,66 n/a 38,66 ISO 8968-1/IDF 20-1 -1,16 -1,33 -0,63
18,3 n/a n/a
18,4 n/a n/a
19,1 39,09 n/a 39,09 ISO 8968-1/IDF 20-1 1,25 1,44 0,68
19,2 38,98 n/a 38,98 ISO 8968-1/IDF 20-1 0,64 0,73 0,34
19,3 39,09 n/a 39,09 ISO 8968-1/IDF 20-1 1,25 1,44 0,68
19,4 38,98 n/a 38,98 ISO 8968-1/IDF 20-1 0,64 0,73 0,34
20,1 n/a n/a
20,2 n/a n/a
20,3 n/a n/a
20,4 n/a n/a
21,1 38,94 n/a 38,94 ISO 8968-1/IDF 20-1 0,41 0,47 0,22
21,2 38,99 n/a 38,99 ISO 8968-1/IDF 20-1 0,69 0,80 0,37
21,3 n/a n/a
21,4 n/a n/a
22,1 38,86 n/a 38,86 ISO 8968-1/IDF 20-1 -0,04 -0,04 -0,02
22,2 38,96 n/a 38,96 ISO 8968-1/IDF 20-1 0,52 0,60 0,28
22,3 n/a n/a
22,4 n/a n/a
23,1 38,92 n/a 38,92 ISO 8968-1/IDF 20-1 0,30 0,35 0,16
23,2 38,97 n/a 38,97 ISO 8968-1/IDF 20-1 0,58 0,67 0,31

RVEP 222031 / Art.-No.: 2010001 ©DRRR

 44/89

results
protein (Nx6,38) sample 2

assigned value xpt [g/100 g] - Kjeldahl 38,87

± expanded uncertainty (k=t) of the assigned value U(x pt) 0,06

customer data performance

x x x x x̅
lab
single single single single lab method description / com-
code z-score z'-score CRD-value
value 1 value 2 value 3 value 4 mean standard ments
no.
[g/100 g]
23,3 n/a n/a
23,4 n/a n/a
24,1 n/a n/a
24,2 n/a n/a
24,3 n/a n/a
24,4 n/a n/a
25,1 38,47 n/a 38,47 Food Scan -2,22 -2,56 -1,20
25,2 38,63 n/a 38,63 Food Scan -1,32 -1,53 -0,72
25,3 n/a n/a
25,4 n/a n/a

RVEP 222031 / Art.-No.: 2010001 ©DRRR

 45/89

summarized evaluation
protein (Nx6,38) sample 2

assigned value xpt [g/100 g] - Kjeldahl 38,87

± expanded uncertainty (k=t) of the assigned value U(x pt) 0,06
standard deviation for proficiency assessment (SDPA) 0,15
no. of datasets excluding outlier 30
no. of outlier 1

performance rating of laboratory datasets: precision data of the used DRRR-

standard-method:
§ 64 LFGB L 01.00-10/1

repeatability
z-score r 0,27
r rel (%) 0,70
x − xpt xpt * 0,007
z=
z≤2 2<z<3 z≥3 sR reproducibility
43 1 1 R 0,51
R rel (%) 1,30
xpt * 0,013

z'-score repeatability standard deviation

sr
x − xpt 0,10
z′ =
z' ≤ 2 2 < z' < 3 z' ≥ 3 SDPA2 + s2
M
41 3 1 reproducibility standard deviation
sR 0,18

critical difference
CRD-value CD 0,33
x − xpt
CRD =
CD
material standard deviation:
This value is calculated on the basis
CRD < 1 CRD > 1 of previous studies and/or experience
41 4 values.
sM 0,02

x̅ = your lab mean value

Further information you will find in our statistical Protocol. xpt
As a registered customer you can download the statistical protocol on your personal assigned value
home page in our Online-Data-Information-Network (ODIN). U(xpt) expanded uncertainty
Alternatively, we also provide you with the statistical protocol on request. (k=t0.975, n-1) of the
assigned value

RVEP 222031 / Art.-No.: 2010001 ©DRRR

 46/89

paricipants total (independent of methods)

protein (Nx6,38) sample 2 (informative)

conventional statistics excluding outlier

mean [g/100 g] 38,84

standard deviation [g/100 g] 0,19
no. of datasets excluding outlier 45
no. of outlier 0

RVEP 222031 / Art.-No.: 2010001 ©DRRR

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results sorted according to means

protein (Nx6,38) sample 2
(error indicator = laboratory range)
39,80

39,60
Protein (Nx6,38) / protein (Nx6,38) [g/100 g]

39,40

39,20

39,00

38,80

38,60

38,40

38,20

38,00

37,80
18,1
25,1
8,3
25,2
4,1
15,1
17,1
18,2
15,2
17,2
11,4
4,2
8,1
8,4
17,3
11,1
13,1
13,2
3
11,3
5
7
22,1
2
11,2
16,2
8,2
6
23,1
21,1
1
16,1
22,2
14,1
23,2
19,2
19,4
21,2
14,2
19,1
19,3
10,1
10,4
10,2
10,3
Labor-Code Nr. / lab code no.

Laborspannweite / lab range

Labormittelwert / lab mean value

Mittelwert nach Ausreißereliminierung / mean excluding outlier: 38,84

Zugwiesener Wert / assigned value (Kjeldahl) ± U(xpt): 38,87 ± 0,06

results sorted according to methods

protein (Nx6,38) sample 2
(error indicator = laboratory range)
39,80

39,60
Kjeldahl sonstige Methoden/
Protein (Nx6,38) / protein (Nx6,38) [g/100 g]

39,40 other methods

39,20

39,00

38,80

38,60

38,40

38,20

38,00 Grubbs-Ausreißer /
Grubbs-outlier: 18,1
37,80
18,1
4,1
15,1
17,1
18,2
15,2
17,2
4,2
8,1
13,1
13,2
3
5
7
22,1
2
16,2
8,2
6
23,1
21,1
16,1
22,2
14,1
23,2
19,2
21,2
14,2
19,1
10,1
10,2
25,1
8,3
25,2
11,4
8,4
17,3
11,1
11,3
11,2
1
19,4
19,3
10,4
10,3

Labor-Code Nr. / lab code no.

Laborspannweite / lab range

Labormittelwert / lab mean value

Zugwiesener Wert / assigned value (Kjeldahl) ± U(xpt): 38,87 ± 0,06

RVEP 222031 / Art.-No.: 2010001 ©DRRR

 48/89

Youdenplot

zufällige Abweichung / systematisch zu hoch /

random deviation systematically to high

39,80

39,60

39,40

39,20 10,2 10,3

protein (Nx6,38) sample 2 [g/100 g]

10,4 10,1

19,1
19,3
Protein (Nx6,38) Probe 2 /

14,2
39,00 21,2 19,2
19,4
22,223,2
16,1
14,1
1
21,1
23,1
8,2 6 16,2
11,2 22,1
7
5 3 11,3
38,80
11,1 13,1 13,2
8,4 17,3
4,2 8,1
11,4
15,2 17,2 18,2
17,115,1
4,1 25,2
8,3
38,60

25,1

38,40
18,1

38,20

38,00

37,80
31,80 32,00 32,20 32,40 32,60 32,80 33,00 33,20 33,40 33,60 33,80

systematisch zu niedrig / Protein (Nx6,38) Probe 1 / zufällige Abweichung /

systematically to low protein (Nx6,38) sample 1 [g/100 g] random deviation

xpt ± 2 * SDPA xpt

95-%-Vertrauensellipse / 95 % confidence ellipse 99-%-Vertrauensellipse / 99 % confidence ellipse

Linear (Trendlinie / trend line)

RVEP 222031 / Art.-No.: 2010001 ©DRRR

49/89

©DRRR
10,3 10,3
10,1 10,2
1 10,4
14,1 10,1
10,2 19,3
19,4 19,1
19,3 14,2
19,2 21,2
19,1 19,4
11,3 19,2
11,4 23,2
23,2 14,1
10,4 22,2
3 16,1
18,2 1
21,2
21,1
Labor-Code Nr. / lab code no.
22,2

Labor-Code Nr. / lab code no.

22,1 23,1
21,1 6
16,2 8,2
14,2 16,2
17,3 11,2
16,1 2
z'-score

17,2 22,1
6 7

z'-score
13,2 5
23,1 11,3
8,2 3
25,2 13,2
25,1 13,1
13,1 11,1
17,4 17,3
12,2 8,4
8,1 8,1
15,1 4,2
15,2 11,4
5
17,2

RVEP 222031 / Art.-No.: 2010001

17,1
4,2 15,2
18,2
protein (Nx6,38) sample 1

protein (Nx6,38) sample 2

8,4
8,3 17,1
4,1 15,1
12,1 4,1
7 25,2
summary z'-score

summary z'-score
18,1 8,3
11,1 25,1
11,2 18,1
5,00

4,00

3,00

2,00

1,00

0,00

-1,00

-2,00

-3,00

-4,00

-5,00

-1,00

-2,00

-3,00

-4,00

-5,00
5,00

4,00

3,00

2,00

1,00

0,00
z'-score z'-score
 50/89

results
lactose (monohydrate) sample 1

assigned value xpt [g/100 g] - enzym. 56,66

± expanded uncertainty (k=t) of the assigned value U(x pt) 1,17

customer data performance

x x x x x̅
lab
single single single single lab method description / com-
code z-score z'-score CRD-value
value 1 value 2 value 3 value 4 mean standard ments
no.
[g/100 g]
1 58,06 56,59 57,33 enzymatisch 0,55 0,89 0,34
2 n/a n/a

3 55,85 55,79 55,82 Enzym VDLUFA C 20.2.3 -0,70 -1,12 -0,43

Person
4,1 56,33 56,19 56,26 enzym. LFGB L01.00-17 -0,33 -0,53 -0,21
1
Person
4,2 56,28 56,50 56,39 enzym. LFGB L01.00-17 -0,22 -0,36 -0,14
2
5 57,06 57,40 57,23 IDF 79-2:2002 0,48 0,77 0,29
6 56,10 56,20 56,15 HPAEC-PAD -0,42 -0,68 -0,26
7 n/a n/a - -
8,1 n/a n/a
8,2 n/a n/a
8,3 n/a n/a
8,4 n/a n/a
9 n/a n/a
10,1 n/a n/a
10,2 n/a n/a
10,3 n/a n/a
10,4 n/a n/a
11,1 n/a n/a
11,2 n/a n/a
11,3 n/a n/a
11,4 n/a n/a
12,1 n/a n/a
12,2 n/a n/a
12,3 n/a n/a
12,4 n/a n/a
13,1 n/a n/a
13,2 n/a n/a
13,3 n/a n/a
13,4 n/a n/a
14,1 n/a n/a
14,2 n/a n/a
14,3 n/a n/a
14,4 n/a n/a
15,1 n/a n/a
15,2 n/a n/a
15,3 n/a n/a
15,4 n/a n/a
16,1 n/a n/a

RVEP 222031 / Art.-No.: 2010001 ©DRRR

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results
lactose (monohydrate) sample 1

assigned value xpt [g/100 g] - enzym. 56,66

± expanded uncertainty (k=t) of the assigned value U(x pt) 1,17

customer data performance

x x x x x̅
lab
single single single single lab method description / com-
code z-score z'-score CRD-value
value 1 value 2 value 3 value 4 mean standard ments
no.
[g/100 g]
16,2 n/a n/a
16,3 n/a n/a
16,4 n/a n/a
17,1 n/a n/a
17,2 n/a n/a
17,3 n/a n/a
17,4 n/a n/a
18,1 n/a n/a
18,2 n/a n/a
18,3 n/a n/a
18,4 n/a n/a
19,1 n/a n/a
19,2 n/a n/a
19,3 n/a n/a
19,4 n/a n/a
20,1 n/a n/a
20,2 n/a n/a
20,3 n/a n/a
20,4 n/a n/a
21,1 n/a n/a
21,2 n/a n/a
21,3 n/a n/a
21,4 n/a n/a
22,1 n/a n/a
22,2 n/a n/a
22,3 n/a n/a
22,4 n/a n/a
23,1 n/a n/a
23,2 n/a n/a
23,3 n/a n/a
23,4 n/a n/a
24,1 n/a n/a
24,2 n/a n/a
24,3 n/a n/a
24,4 n/a n/a
25,1 n/a n/a
25,2 n/a n/a
25,3 n/a n/a
25,4 n/a n/a

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summarized evaluation
lactose (monohydrate) sample 1

assigned value xpt [g/100 g] - enzym. 56,66

± expanded uncertainty (k=t) of the assigned value U(x pt) 1,17
standard deviation for proficiency assessment (SDPA) 0,74
no. of datasets excluding outlier 4
no. of outlier 0

performance rating of laboratory datasets: precision data of the used DRRR-

standard-method:
§ 64 LFGB L 01.00-17

repeatability
z-score r 2,83
r rel (%) 5,00
x − xpt xpt * 0,05
z=
z≤2 2<z<3 z≥3 sR reproducibility
6 0 0 R 3,40
R rel (%) 6,00
xpt * 0,06

z'-score repeatability standard deviation

sr
x − xpt 1,00
z′ =
z' ≤ 2 2 < z' < 3 z' ≥ 3 SDPA2 + s2
M
6 0 0 reproducibility standard deviation
sR 1,20

critical difference
CRD-value CD 1,94
x − xpt
CRD =
CD
material standard deviation:
This value is calculated on the basis
CRD < 1 CRD > 1 of previous studies and/or experience
6 0 values.
sM 0,11

x̅ = your lab mean value

Further information you will find in our statistical Protocol. xpt
As a registered customer you can download the statistical protocol on your personal assigned value
home page in our Online-Data-Information-Network (ODIN). U(xpt) expanded uncertainty
Alternatively, we also provide you with the statistical protocol on request. (k=t0.975, n-1) of the
assigned value

RVEP 222031 / Art.-No.: 2010001 ©DRRR

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paricipants total (independent of methods)

lactose (monohydrate) sample 1 (informative)

conventional statistics excluding outlier

mean [g/100 g] 56,53

standard deviation [g/100 g] 0,61
no. of datasets excluding outlier 6
no. of outlier 0

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results sorted according to means

lactose (monohydrate) sample 1
(error indicator = laboratory range)
63,00
Lactose (Monohydrat) / lactose (monohydrate) [g/100 g]

62,00

61,00

60,00

59,00

58,00

57,00

56,00

55,00

54,00

53,00
3

4,1

4,2

1
Labor-Code Nr. / lab code no.

Laborspannweite / lab range

Labormittelwert / lab mean value

Mittelwert nach Ausreißereliminierung / mean excluding outlier: 56,53

Zugwiesener Wert / assigned value (enzym.) ± U(xpt): 56,66 ± 1,17

results sorted according to methods

lactose (monohydrate) sample 1
(error indicator = laboratory range)
63,00
Lactose (Monohydrat) / lactose (monohydrate) [g/100 g]

62,00
sonstige Methoden/
61,00 enzym.
other methods
60,00

59,00

58,00

57,00

56,00

55,00

54,00

53,00
3

4,1

4,2

Labor-Code Nr. / lab code no.

Laborspannweite / lab range

Labormittelwert / lab mean value

Zugwiesener Wert / assigned value (enzym.) ± U(xpt): 56,66 ± 1,17

RVEP 222031 / Art.-No.: 2010001 ©DRRR

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results
lactose (monohydrate) sample 2

assigned value xpt [g/100 g] - enzym. 49,33

± expanded uncertainty (k=t) of the assigned value U(x pt) 1,32

customer data performance

x x x x x̅
lab
single single single single lab method description / com-
code z-score z'-score CRD-value
value 1 value 2 value 3 value 4 mean standard ments
no.
[g/100 g]
1 50,73 49,45 50,09 enzymatisch 0,73 0,91 0,45
2 n/a n/a

3 48,85 48,90 48,88 Enzym VDLUFA C 20.2.3 -0,43 -0,54 -0,27

Person
4,1 48,52 48,26 48,39 enzym. LFGB L01.00-17 -0,90 -1,12 -0,56
1
Person
4,2 48,34 48,21 48,28 enzym. LFGB L01.00-17 -1,01 -1,26 -0,62
2
5 50,16 49,76 49,96 IDF 79-2:2002 0,60 0,76 0,37
6 47,80 45,70 46,75 HPAEC-PAD -2,47 -3,09 -1,53
7 n/a n/a - -
8,1 n/a n/a
8,2 n/a n/a
8,3 n/a n/a
8,4 n/a n/a
9 n/a n/a
10,1 n/a n/a
10,2 n/a n/a
10,3 n/a n/a
10,4 n/a n/a
11,1 n/a n/a
11,2 n/a n/a
11,3 n/a n/a
11,4 n/a n/a
12,1 n/a n/a
12,2 n/a n/a
12,3 n/a n/a
12,4 n/a n/a
13,1 n/a n/a
13,2 n/a n/a
13,3 n/a n/a
13,4 n/a n/a
14,1 n/a n/a
14,2 n/a n/a
14,3 n/a n/a
14,4 n/a n/a
15,1 n/a n/a
15,2 n/a n/a
15,3 n/a n/a
15,4 n/a n/a
16,1 n/a n/a

RVEP 222031 / Art.-No.: 2010001 ©DRRR

 56/89

results
lactose (monohydrate) sample 2

assigned value xpt [g/100 g] - enzym. 49,33

± expanded uncertainty (k=t) of the assigned value U(x pt) 1,32

customer data performance

x x x x x̅
lab
single single single single lab method description / com-
code z-score z'-score CRD-value
value 1 value 2 value 3 value 4 mean standard ments
no.
[g/100 g]
16,2 n/a n/a
16,3 n/a n/a
16,4 n/a n/a
17,1 n/a n/a
17,2 n/a n/a
17,3 n/a n/a
17,4 n/a n/a
18,1 n/a n/a
18,2 n/a n/a
18,3 n/a n/a
18,4 n/a n/a
19,1 n/a n/a
19,2 n/a n/a
19,3 n/a n/a
19,4 n/a n/a
20,1 n/a n/a
20,2 n/a n/a
20,3 n/a n/a
20,4 n/a n/a
21,1 n/a n/a
21,2 n/a n/a
21,3 n/a n/a
21,4 n/a n/a
22,1 n/a n/a
22,2 n/a n/a
22,3 n/a n/a
22,4 n/a n/a
23,1 n/a n/a
23,2 n/a n/a
23,3 n/a n/a
23,4 n/a n/a
24,1 n/a n/a
24,2 n/a n/a
24,3 n/a n/a
24,4 n/a n/a
25,1 n/a n/a
25,2 n/a n/a
25,3 n/a n/a
25,4 n/a n/a

RVEP 222031 / Art.-No.: 2010001 ©DRRR

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summarized evaluation
lactose (monohydrate) sample 2

assigned value xpt [g/100 g] - enzym. 49,33

± expanded uncertainty (k=t) of the assigned value U(x pt) 1,32
standard deviation for proficiency assessment (SDPA) 0,83
no. of datasets excluding outlier 4
no. of outlier 0

performance rating of laboratory datasets: precision data of the used DRRR-

standard-method:
§ 64 LFGB L 01.00-17

repeatability
z-score r 2,47
r rel (%) 5,00
x − xpt xpt * 0,05
z=
z≤2 2<z<3 z≥3 sR reproducibility
5 1 0 R 2,96
R rel (%) 6,00
xpt * 0,06

z'-score repeatability standard deviation

sr
x − xpt 0,87
z′ =
z' ≤ 2 2 < z' < 3 z' ≥ 3 SDPA2 + s2
M
5 0 1 reproducibility standard deviation
sR 1,05

critical difference
CRD-value CD 1,69
x − xpt
CRD =
CD
material standard deviation:
This value is calculated on the basis
CRD < 1 CRD > 1 of previous studies and/or experience
5 1 values.
sM 0,10

x̅ = your lab mean value

Further information you will find in our statistical Protocol. xpt
As a registered customer you can download the statistical protocol on your personal assigned value
home page in our Online-Data-Information-Network (ODIN). U(xpt) expanded uncertainty
Alternatively, we also provide you with the statistical protocol on request. (k=t0.975, n-1) of the
assigned value

RVEP 222031 / Art.-No.: 2010001 ©DRRR

 58/89

paricipants total (independent of methods)

lactose (monohydrate) sample 2 (informative)

conventional statistics excluding outlier

mean [g/100 g] 48,72

standard deviation [g/100 g] 1,24
no. of datasets excluding outlier 6
no. of outlier 0

RVEP 222031 / Art.-No.: 2010001 ©DRRR

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results sorted according to means

lactose (monohydrate) sample 2
(error indicator = laboratory range)
55,00
Lactose (Monohydrat) / lactose (monohydrate) [g/100 g]

54,00

53,00

52,00

51,00

50,00

49,00

48,00

47,00

46,00

45,00
6

4,2

4,1

1
Labor-Code Nr. / lab code no.

Laborspannweite / lab range

Labormittelwert / lab mean value

Mittelwert nach Ausreißereliminierung / mean excluding outlier: 48,72

Zugwiesener Wert / assigned value (enzym.) ± U(xpt): 49,33 ± 1,32

results sorted according to methods

lactose (monohydrate) sample 2
(error indicator = laboratory range)
55,00
Lactose (Monohydrat) / lactose (monohydrate) [g/100 g]

54,00

enzym. sonstige Methoden/

53,00
other methods
52,00

51,00

50,00

49,00

48,00

47,00

46,00

45,00
4,1

4,2

Labor-Code Nr. / lab code no.

Laborspannweite / lab range

Labormittelwert / lab mean value

Zugwiesener Wert / assigned value (enzym.) ± U(xpt): 49,33 ± 1,32

RVEP 222031 / Art.-No.: 2010001 ©DRRR

 60/89

Youdenplot

zufällige Abweichung / systematisch zu hoch /

random deviation systematically to high

55,00

54,00

53,00

52,00
lactose (monohydrate) sample 2 [g/100 g]
Lactose (Monohydrat) Probe 2 /

51,00

1
50,00 5

49,00 3

4,1
4,2

48,00

47,00
6

46,00

45,00
53,00 54,00 55,00 56,00 57,00 58,00 59,00 60,00 61,00 62,00 63,00

systematisch zu niedrig / Lactose (Monohydrat) Probe 1 / zufällige Abweichung /

systematically to low lactose (monohydrate) sample 1 [g/100 g] random deviation

xpt ± 2 * SDPA xpt

95-%-Vertrauensellipse / 95 % confidence ellipse 99-%-Vertrauensellipse / 99 % confidence ellipse

Linear (Trendlinie / trend line)

RVEP 222031 / Art.-No.: 2010001 ©DRRR

 61/89

summary z'-score
lactose (monohydrate) sample 1

z'-score
5,00

4,00

3,00

2,00

1,00
z'-score

0,00

-1,00

-2,00

-3,00

-4,00

-5,00
3

4,1

4,2

1
Labor-Code Nr. / lab code no.

summary z'-score
lactose (monohydrate) sample 2

z'-score
5,00

4,00

3,00

2,00

1,00
z'-score

0,00

-1,00

-2,00

-3,00

-4,00

-5,00
6

4,2

4,1

Labor-Code Nr. / lab code no.

RVEP 222031 / Art.-No.: 2010001 ©DRRR

 62/89

results
ash sample 1

assigned value xpt [g/100 g] - 500-550°C 6,70

± expanded uncertainty (k=t) of the assigned value U(x pt) 0,08

customer data performance

x x x x x̅
lab
single single single single lab method description / com-
code z-score z'-score CRD-value
value 1 value 2 value 3 value 4 mean standard ments
no.
[g/100 g]
1 n/a n/a
2 n/a n/a
3 6,68 6,65 6,67 550°C VDLUFA C 10.2 -0,34
Person
4,1 6,68 6,72 6,70 VDLUFA C10.2 0,03
1
Person
4,2 6,71 6,70 6,71 VDLUFA C10.2 0,09
2
5 6,69 6,69 6,69 AOAC 930.30 -0,07
Gravimetric method at
6 6,81 6,86 6,84 1,46
538°C
7 6,78 6,78 6,78 PN-A-86364 / 550°C - 0,88
500-550
8,1 6,63 6,66 6,65 VDLUFAC10.2 -0,55
°C
500-550
8,2 6,78 3,79 5,29 VDLUFAC10.2 -14,93
°C
500-550
8,3 6,49 6,51 6,50 VDLUFAC10.2 -2,08
°C
500-550
8,4 6,56 6,65 6,61 VDLUFAC10.2 -0,97
°C
9 n/a n/a
10,1 n/a n/a
10,2 n/a n/a
10,3 n/a n/a
10,4 n/a n/a
11,1 n/a n/a
11,2 n/a n/a
11,3 n/a n/a
11,4 n/a n/a
12,1 n/a n/a
12,2 n/a n/a
12,3 n/a n/a
12,4 n/a n/a
13,1 n/a n/a
13,2 n/a n/a
13,3 n/a n/a
13,4 n/a n/a
14,1 n/a n/a
14,2 n/a n/a
14,3 n/a n/a
14,4 n/a n/a
15,1 n/a n/a
15,2 n/a n/a

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results
ash sample 1

assigned value xpt [g/100 g] - 500-550°C 6,70

± expanded uncertainty (k=t) of the assigned value U(x pt) 0,08

customer data performance

x x x x x̅
lab
single single single single lab method description / com-
code z-score z'-score CRD-value
value 1 value 2 value 3 value 4 mean standard ments
no.
[g/100 g]
15,3 n/a n/a
15,4 n/a n/a
16,1 n/a n/a
16,2 n/a n/a
16,3 n/a n/a
16,4 n/a n/a
17,1 n/a n/a
17,2 n/a n/a
17,3 n/a n/a
17,4 n/a n/a
18,1 n/a n/a
18,2 n/a n/a
18,3 n/a n/a
18,4 n/a n/a
19,1 n/a n/a
19,2 n/a n/a
19,3 n/a n/a
19,4 n/a n/a
20,1 n/a n/a
20,2 n/a n/a
20,3 n/a n/a
20,4 n/a n/a
21,1 n/a n/a
21,2 n/a n/a
21,3 n/a n/a
21,4 n/a n/a
22,1 n/a n/a
22,2 n/a n/a
22,3 n/a n/a
22,4 n/a n/a
23,1 n/a n/a
23,2 n/a n/a
23,3 n/a n/a
23,4 n/a n/a
24,1 n/a n/a
24,2 n/a n/a
24,3 n/a n/a
24,4 n/a n/a
25,1 n/a n/a
25,2 n/a n/a

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results
ash sample 1

assigned value xpt [g/100 g] - 500-550°C 6,70

± expanded uncertainty (k=t) of the assigned value U(x pt) 0,08

customer data performance

x x x x x̅
lab
single single single single lab method description / com-
code z-score z'-score CRD-value
value 1 value 2 value 3 value 4 mean standard ments
no.
[g/100 g]
25,3 n/a n/a
25,4 n/a n/a

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summarized evaluation
ash sample 1

assigned value xpt [g/100 g] - 500-550°C 6,70

± expanded uncertainty (k=t) of the assigned value U(x pt) 0,08
standard deviation for proficiency assessment (SDPA) 0,09
no. of datasets excluding outlier 8
no. of outlier 0

performance rating of laboratory datasets: precision data of the used DRRR-

standard-method:
none standard method defined

repeatability
z-score r -
r rel (%) -
For this parameter no z-score calculation is x − xpt
performed. The reasons for this can be z=
found in our statistical protocol. sR reproducibility
R -
R rel (%) -

z'-score repeatability standard deviation

sr
x − xpt -
z′ =
z' ≤ 2 2 < z' < 3 z' ≥ 3 SDPA2 + s2
M
8 1 1 reproducibility standard deviation
sR -

critical difference
CRD-value CD -
x − xpt
For this parameter no CRD calculation is CRD =
performed. The reasons for this can be
CD
material standard deviation:
found in our statistical protocol.
This value is calculated on the basis
of previous studies and/or experience
values.
sM 0,01

x̅ = your lab mean value

Further information you will find in our statistical Protocol. xpt
As a registered customer you can download the statistical protocol on your personal assigned value
home page in our Online-Data-Information-Network (ODIN). U(xpt) expanded uncertainty
Alternatively, we also provide you with the statistical protocol on request. (k=t0.975, n-1) of the
assigned value

RVEP 222031 / Art.-No.: 2010001 ©DRRR

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paricipants total (independent of methods)

ash sample 1 (informative)

conventional statistics excluding outlier

mean [g/100 g] 6,68

standard deviation [g/100 g] 0,10
no. of datasets excluding outlier 9
no. of outlier 1

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results sorted according to means

ash sample 1
(error indicator = laboratory range)
7,20

7,10

7,00

6,90
Asche / ash [g/100 g]

6,80

6,70

6,60

6,50

6,40

5,28 Grubbs-Ausreißer /
6,30
Grubbs-outlier: 8,2
6,20
8,2

8,3

8,4

8,1

4,1

4,2

6
Labor-Code Nr. / lab code no.

Laborspannweite / lab range

Labormittelwert / lab mean value

Mittelwert nach Ausreißereliminierung / mean excluding outlier: 6,68

Zugwiesener Wert / assigned value (500-550°C) ± U(xpt): 6,70 ± 0,08

results sorted according to methods

ash sample 1
(error indicator = laboratory range)
7,20

7,10 sonstige
Methoden/
500-550°C other
7,00
methods
6,90
Asche / ash [g/100 g]

6,80

6,70

6,60

6,50

6,40
5,28
6,30

6,20
8,3

8,1

4,1

4,2

8,2

8,4

Labor-Code Nr. / lab code no.

Laborspannweite / lab range

Labormittelwert / lab mean value

Zugwiesener Wert / assigned value (500-550°C) ± U(xpt): 6,70 ± 0,08

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results
ash sample 2

assigned value xpt [g/100 g] - 500-550°C 7,80

± expanded uncertainty (k=t) of the assigned value U(x pt) 0,09

customer data performance

x x x x x̅
lab
single single single single lab method description / com-
code z-score z'-score CRD-value
value 1 value 2 value 3 value 4 mean standard ments
no.
[g/100 g]
1 n/a n/a
2 n/a n/a
3 7,84 7,86 7,85 550°C VDLUFA C 10.2 0,44
Person
4,1 7,71 7,73 7,72 VDLUFA C10.2 -0,77
1
Person
4,2 7,72 7,74 7,73 VDLUFA C10.2 -0,68
2
5 7,74 7,76 7,75 AOAC 930.30 -0,49
Gravimetric method at
6 7,93 7,92 7,93 1,13
538°C
7 7,88 7,88 7,88 PN-A-86364 / 550°C - 0,71
500-550
8,1 7,67 7,66 7,67 VDLUFAC10.2 -1,28
°C
500-550
8,2 7,87 7,94 7,91 VDLUFAC10.2 0,95
°C
500-550
8,3 7,68 7,64 7,66 VDLUFAC10.2 -1,33
°C
500-550
8,4 7,59 7,63 7,61 VDLUFAC10.2 -1,80
°C
9 n/a n/a
10,1 n/a n/a
10,2 n/a n/a
10,3 n/a n/a
10,4 n/a n/a
11,1 n/a n/a
11,2 n/a n/a
11,3 n/a n/a
11,4 n/a n/a
12,1 n/a n/a
12,2 n/a n/a
12,3 n/a n/a
12,4 n/a n/a
13,1 n/a n/a
13,2 n/a n/a
13,3 n/a n/a
13,4 n/a n/a
14,1 n/a n/a
14,2 n/a n/a
14,3 n/a n/a
14,4 n/a n/a
15,1 n/a n/a
15,2 n/a n/a

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results
ash sample 2

assigned value xpt [g/100 g] - 500-550°C 7,80

± expanded uncertainty (k=t) of the assigned value U(x pt) 0,09

customer data performance

x x x x x̅
lab
single single single single lab method description / com-
code z-score z'-score CRD-value
value 1 value 2 value 3 value 4 mean standard ments
no.
[g/100 g]
15,3 n/a n/a
15,4 n/a n/a
16,1 n/a n/a
16,2 n/a n/a
16,3 n/a n/a
16,4 n/a n/a
17,1 n/a n/a
17,2 n/a n/a
17,3 n/a n/a
17,4 n/a n/a
18,1 n/a n/a
18,2 n/a n/a
18,3 n/a n/a
18,4 n/a n/a
19,1 n/a n/a
19,2 n/a n/a
19,3 n/a n/a
19,4 n/a n/a
20,1 n/a n/a
20,2 n/a n/a
20,3 n/a n/a
20,4 n/a n/a
21,1 n/a n/a
21,2 n/a n/a
21,3 n/a n/a
21,4 n/a n/a
22,1 n/a n/a
22,2 n/a n/a
22,3 n/a n/a
22,4 n/a n/a
23,1 n/a n/a
23,2 n/a n/a
23,3 n/a n/a
23,4 n/a n/a
24,1 n/a n/a
24,2 n/a n/a
24,3 n/a n/a
24,4 n/a n/a
25,1 n/a n/a
25,2 n/a n/a

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results
ash sample 2

assigned value xpt [g/100 g] - 500-550°C 7,80

± expanded uncertainty (k=t) of the assigned value U(x pt) 0,09

customer data performance

x x x x x̅
lab
single single single single lab method description / com-
code z-score z'-score CRD-value
value 1 value 2 value 3 value 4 mean standard ments
no.
[g/100 g]
25,3 n/a n/a
25,4 n/a n/a

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summarized evaluation
ash sample 2

assigned value xpt [g/100 g] - 500-550°C 7,80

± expanded uncertainty (k=t) of the assigned value U(x pt) 0,09
standard deviation for proficiency assessment (SDPA) 0,11
no. of datasets excluding outlier 8
no. of outlier 0

performance rating of laboratory datasets: precision data of the used DRRR-

standard-method:
none standard method defined

repeatability
z-score r -
r rel (%) -
For this parameter no z-score calculation is x − xpt
performed. The reasons for this can be z=
found in our statistical protocol. sR reproducibility
R -
R rel (%) -

z'-score repeatability standard deviation

sr
x − xpt -
z′ =
z' ≤ 2 2 < z' < 3 z' ≥ 3 SDPA2 + s2
M
10 0 0 reproducibility standard deviation
sR -

critical difference
CRD-value CD -
x − xpt
For this parameter no CRD calculation is CRD =
performed. The reasons for this can be
CD
material standard deviation:
found in our statistical protocol.
This value is calculated on the basis
of previous studies and/or experience
values.
sM 0,01

x̅ = your lab mean value

Further information you will find in our statistical Protocol. xpt
As a registered customer you can download the statistical protocol on your personal assigned value
home page in our Online-Data-Information-Network (ODIN). U(xpt) expanded uncertainty
Alternatively, we also provide you with the statistical protocol on request. (k=t0.975, n-1) of the
assigned value

RVEP 222031 / Art.-No.: 2010001 ©DRRR

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paricipants total (independent of methods)

ash sample 2 (informative)

conventional statistics excluding outlier

mean [g/100 g] 7,77

standard deviation [g/100 g] 0,11
no. of datasets excluding outlier 10
no. of outlier 0

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results sorted according to means

ash sample 2
(error indicator = laboratory range)
8,20

8,10

8,00

7,90
Asche / ash [g/100 g]

7,80

7,70

7,60

7,50

7,40

7,30

7,20
8,4

8,3

8,1

4,1

4,2

8,2

6
Labor-Code Nr. / lab code no.

Laborspannweite / lab range

Labormittelwert / lab mean value

Mittelwert nach Ausreißereliminierung / mean excluding outlier: 7,77

Zugwiesener Wert / assigned value (500-550°C) ± U(xpt): 7,80 ± 0,09

results sorted according to methods

ash sample 2
(error indicator = laboratory range)
8,20

8,10 sonstige
500-550°C Methoden/
8,00 other
methods
7,90
Asche / ash [g/100 g]

7,80

7,70

7,60

7,50

7,40

7,30

7,20
8,1

4,1

4,2

8,2

8,4

8,3

Labor-Code Nr. / lab code no.

Laborspannweite / lab range

Labormittelwert / lab mean value

Zugwiesener Wert / assigned value (500-550°C) ± U(xpt): 7,80 ± 0,09

RVEP 222031 / Art.-No.: 2010001 ©DRRR

 74/89

Youdenplot

zufällige Abweichung / systematisch zu hoch /

random deviation systematically to high

8,20

8,10

8,00

7,90
ash sample 2 [g/100 g]

3
Asche Probe 2 /

7,80
5
4,2
4,1
7,70
8,3 8,1

8,4
7,60

7,50

7,40

7,30

7,20
6,20 6,30 6,40 6,50 6,60 6,70 6,80 6,90 7,00 7,10 7,20

systematisch zu niedrig / Asche Probe 1 / zufällige Abweichung /

systematically to low ash sample 1 [g/100 g] random deviation

xpt ± 2 * SDPA xpt

95-%-Vertrauensellipse / 95 % confidence ellipse 99-%-Vertrauensellipse / 99 % confidence ellipse

Linear (Trendlinie / trend line)

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summary z'-score
ash sample 1

z'-score
5,00

4,00

3,00

2,00

1,00
z'-score

0,00

-1,00

-2,00

-3,00

-4,00

-5,00
8,2

8,3

8,4

8,1

4,1

4,2

6
Labor-Code Nr. / lab code no.

summary z'-score
ash sample 2

z'-score
5,00

4,00

3,00

2,00

1,00
z'-score

0,00

-1,00

-2,00

-3,00

-4,00

-5,00
8,4

8,3

8,1

4,1

4,2

8,2

Labor-Code Nr. / lab code no.

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results
titratable acid sample 1

assigned value xpt [g/100 g] - titrim. 0,10

± expanded uncertainty (k=t) of the assigned value U(x pt) 0,00

customer data performance

x x x x x̅
lab
single single single single lab method description / com-
code z-score z'-score CRD-value
value 1 value 2 value 3 value 4 mean standard ments
no.
[g/100 g]
1 n/a n/a

accordin
g to
method
results
were
obtained
as °T
(value
Dried milk - Determination 1: 14.2,
of titratable acidity value 2:
2 0,13 0,13 0,13 2,79
(Routine method) - SR ISO 14.4)
6092:2008 that
were
transfor
med in
g/100g
by
multiplyi
ng with
0.009

3 0,14 0,13 0,14 titrim. VDLUFA C 8.4 3,29

4,1 0,11 0,11 0,11 VDLUFA C8.4 AP TR 0,78
4,2 n/a n/a
5 0,13 0,13 0,13 ADPI Bulletin 916:2009 2,79
6 0,83 0,86 0,85 at pH 8,3,in lactic acid 74,58
7 n/a n/a - -
Bulletin
8,1 0,11 0,11 0,11 ADPI1190 0,78
916
Bulletin
8,2 0,11 0,11 0,11 ADPI1190 0,78
916
Bulletin
8,3 0,10 0,40 0,25 ADPI1190 14,84
916
Bulletin
8,4 0,11 0,11 0,11 ADPI1190 0,78
916
AOAC Official method
9 1,20 1,21 1,21 947.05 Acidity of milk 110,73
(Titrimetric method)
10,1 0,10 n/a 0,10 AOAC 947.05 -0,73
10,2 0,10 n/a 0,10 AOAC 947.05 -0,73
10,3 n/a n/a
10,4 n/a n/a

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results
titratable acid sample 1

assigned value xpt [g/100 g] - titrim. 0,10

± expanded uncertainty (k=t) of the assigned value U(x pt) 0,00

customer data performance

x x x x x̅
lab
single single single single lab method description / com-
code z-score z'-score CRD-value
value 1 value 2 value 3 value 4 mean standard ments
no.
[g/100 g]
11,1 n/a n/a
11,2 n/a n/a
11,3 n/a n/a
11,4 n/a n/a
12,1 0,10 n/a 0,10 NZTM3.2.3 -0,23
12,2 0,10 n/a 0,10 NZTM3.2.3 -0,23
12,3 n/a n/a
12,4 n/a n/a
13,1 0,10 n/a 0,10 APHA 15.023 Chptr 15 -0,23
13,2 0,10 n/a 0,10 APHA 15.023 Chptr 15 -0,23
13,3 0,10 n/a 0,10 APHA 15.023 Chptr 15 -0,13
13,4 0,10 n/a 0,10 APHA 15.023 Chptr 15 -0,13
14,1 0,10 n/a 0,10 SMEDP 15.023 -0,23
14,2 0,09 n/a 0,09 SMEDP 15.023 -1,23
14,3 n/a n/a
14,4 n/a n/a
SMEDP 15.021 17th Ed
15,1 0,09 n/a 0,09 -1,33
(Mod)
SMEDP 15.021 17th Ed
15,2 0,09 n/a 0,09 -1,63
(Mod)
15,3 n/a n/a
15,4 n/a n/a
16,1 0,11 n/a 0,11 AS2300.2.10 1,08
16,2 0,11 n/a 0,11 AS2300.2.10 1,08
16,3 n/a n/a
16,4 n/a n/a
17,1 0,11 n/a 0,11 SMEDP 15.023 0,28
17,2 0,11 n/a 0,11 SMEDP 15.023 0,28
17,3 n/a n/a
17,4 n/a n/a
18,1 0,09 n/a 0,09 APHA 15.021 -1,13
18,2 0,09 n/a 0,09 APHA 15.021 -1,13
18,3 n/a n/a
18,4 n/a n/a
19,1 0,09 n/a 0,09 NZTM3.2.3 -1,03
19,2 0,09 n/a 0,09 NZTM3.2.3 -0,83
19,3 0,09 n/a 0,09 NZTM3.2.3 -1,03
19,4 0,09 n/a 0,09 NZTM3.2.3 -0,83
20,1 0,11 n/a 0,11 NZTM3.2.3 0,78
20,2 0,11 n/a 0,11 NZTM3.2.3 0,78
20,3 n/a n/a

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results
titratable acid sample 1

assigned value xpt [g/100 g] - titrim. 0,10

± expanded uncertainty (k=t) of the assigned value U(x pt) 0,00

customer data performance

x x x x x̅
lab
single single single single lab method description / com-
code z-score z'-score CRD-value
value 1 value 2 value 3 value 4 mean standard ments
no.
[g/100 g]
20,4 n/a n/a
21,1 0,10 n/a 0,10 NZTM3.2.3 -0,63
21,2 0,10 n/a 0,10 NZTM3.2.3 -0,63
21,3 n/a n/a
21,4 n/a n/a
22,1 0,11 n/a 0,11 NZTM3.2.3 0,78
22,2 0,11 n/a 0,11 NZTM3.2.3 0,78
22,3 n/a n/a
22,4 n/a n/a
23,1 0,09 n/a 0,09 NZTM3.2.3 -0,93
23,2 0,09 n/a 0,09 NZTM3.2.3 -0,93
23,3 0,09 n/a 0,09 NZTM3.2.3 -1,43
23,4 0,09 n/a 0,09 NZTM3.2.3 -1,23
24,1 0,11 n/a 0,11 AS2300.2.10 0,78
24,2 0,11 n/a 0,11 AS2300.2.10 0,78
24,3 n/a n/a
24,4 n/a n/a
25,1 n/a n/a
25,2 n/a n/a
25,3 n/a n/a
25,4 n/a n/a

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summarized evaluation
titratable acid sample 1

assigned value xpt [g/100 g] - titrim. 0,10

± expanded uncertainty (k=t) of the assigned value U(x pt) 0,00
standard deviation for proficiency assessment (SDPA) 0,01
no. of datasets excluding outlier 34
no. of outlier 0

performance rating of laboratory datasets: precision data of the used DRRR-

standard-method:
none standard method defined

repeatability
z-score r -
r rel (%) -
For this parameter no z-score calculation is x − xpt
performed. The reasons for this can be z=
found in our statistical protocol. sR reproducibility
R -
R rel (%) -

z'-score repeatability standard deviation

sr
x − xpt -
z′ =
z' ≤ 2 2 < z' < 3 z' ≥ 3 SDPA2 + s2
M
38 2 4 reproducibility standard deviation
sR -

critical difference
CRD-value CD -
x − xpt
For this parameter no CRD calculation is CRD =
performed. The reasons for this can be
CD
material standard deviation:
found in our statistical protocol.
This value is calculated on the basis
of previous studies and/or experience
values.
sM 0,00

x̅ = your lab mean value

Further information you will find in our statistical Protocol. xpt
As a registered customer you can download the statistical protocol on your personal assigned value
home page in our Online-Data-Information-Network (ODIN). U(xpt) expanded uncertainty
Alternatively, we also provide you with the statistical protocol on request. (k=t0.975, n-1) of the
assigned value

RVEP 222031 / Art.-No.: 2010001 ©DRRR

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paricipants total (independent of methods)

titratable acid sample 1 (informative)

conventional statistics excluding outlier

mean [g/100 g] 0,10

standard deviation [g/100 g] 0,01
no. of datasets excluding outlier 41
no. of outlier 3

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results sorted according to means

titratable acid sample 1
(error indicator = laboratory range)
0,26

0,24 0,84
1,20
titrierbare Säure / titratable acid [g/100 g]

0,22

0,20

0,18

0,16

0,14

0,12

0,10

0,08 Grubbs-Ausreißer / Technischer-Ausreißer /

Grubbs-outlier: 6 / 8,3 technical-outlier: 9
0,06
15,2
23,3
15,1
14,2
23,4
18,1
18,2
19,1
19,3
23,1
23,2
19,2
19,4
10,1
10,2
21,1
21,2
12,1
12,2
13,1
13,2
14,1
13,3
13,4
17,1
17,2
4,1
8,1
8,2
8,4
20,1
20,2
22,1
22,2
24,1
24,2
16,1
16,2
2
5
3
8,3
6
9
Labor-Code Nr. / lab code no.

Laborspannweite / lab range

Labormittelwert / lab mean value

Mittelwert nach Ausreißereliminierung / mean excluding outlier: 0,10

Zugwiesener Wert / assigned value (titrim.) ± U(xpt): 0,10 ± 0,00

results sorted according to methods

titratable acid sample 1
(error indicator = laboratory range)
0,26

0,24
0,84

0,22 titrim. 1,20

titrierbare Säure / titratable acid [g/100 g]

0,20 sonstige
Methoden/
0,18
other
methods
0,16

0,14

0,12

0,10

0,08 Technischer-Ausreißer /
technical-outlier: 9
0,06
15,2
15,1
14,2
18,1
18,2
19,1
23,1
23,2
19,2
10,1
10,2
21,1
21,2
12,1
12,2
13,1
13,2
14,1
17,1
17,2
4,1
8,1
8,2
20,1
20,2
22,1
22,2
24,1
24,2
16,1
16,2
2
5
3
23,3
23,4
19,3
19,4
13,3
13,4
8,4
8,3
6
9

Labor-Code Nr. / lab code no.

Laborspannweite / lab range

Labormittelwert / lab mean value

Zugwiesener Wert / assigned value (titrim.) ± U(xpt): 0,10 ± 0,00

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results
titratable acid sample 2

assigned value xpt [g/100 g] - titrim. 0,12

± expanded uncertainty (k=t) of the assigned value U(x pt) 0,00

customer data performance

x x x x x̅
lab
single single single single lab method description / com-
code z-score z'-score CRD-value
value 1 value 2 value 3 value 4 mean standard ments
no.
[g/100 g]
1 n/a n/a

accordin
g to
method
results
were
obtained
as °T
(value
Dried milk - Determination 1: 16.4,
of titratable acidity value 2:
2 < 0.15 > 0.15
(Routine method) - SR ISO 16.2)
6092:2008 that
were
transfor
med in
g/100g
by
multiplyi
ng with
0.009

3 0,12 0,13 0,13 titrim. VDLUFA C 8.4 0,83

4,1 0,13 0,13 0,13 VDLUFA C8.4 AP TR 1,29
4,2 n/a n/a
5 0,15 0,15 0,15 ADPI Bulletin 916:2009 3,11
6 0,99 1,01 1,00 at pH 8,3,in lactic acid 80,47
7 n/a n/a - -
Bulletin
8,1 0,13 0,13 0,13 ADPI1190 1,29
916
Bulletin
8,2 0,13 0,12 0,13 ADPI1190 0,83
916
Bulletin
8,3 0,12 0,12 0,12 ADPI1190 0,38
916
Bulletin
8,4 0,12 0,12 0,12 ADPI1190 0,38
916
AOAC Official method
9 1,36 1,39 1,38 947.05 Acidity of milk 114,61
(Titrimetric method)
10,1 0,11 n/a 0,11 AOAC 947.05 -0,53
10,2 0,11 n/a 0,11 AOAC 947.05 -0,53
10,3 n/a n/a

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results
titratable acid sample 2

assigned value xpt [g/100 g] - titrim. 0,12

± expanded uncertainty (k=t) of the assigned value U(x pt) 0,00

customer data performance

x x x x x̅
lab
single single single single lab method description / com-
code z-score z'-score CRD-value
value 1 value 2 value 3 value 4 mean standard ments
no.
[g/100 g]
10,4 n/a n/a
11,1 n/a n/a
11,2 n/a n/a
11,3 n/a n/a
11,4 n/a n/a
12,1 n/a n/a NZTM3.2.3
12,2 n/a n/a NZTM3.2.3
12,3 n/a n/a
12,4 n/a n/a
13,1 0,11 n/a 0,11 APHA 15.023 Chptr 15 -0,26
13,2 0,12 n/a 0,12 APHA 15.023 Chptr 15 -0,08
13,3 0,12 n/a 0,12 APHA 15.023 Chptr 15 0,11
13,4 0,12 n/a 0,12 APHA 15.023 Chptr 15 0,20
14,1 0,10 n/a 0,10 SMEDP 15.023 -1,44
14,2 0,11 n/a 0,11 SMEDP 15.023 -0,53
14,3 n/a n/a
14,4 n/a n/a
SMEDP 15.021 17th Ed
15,1 0,10 n/a 0,10 -1,08
(Mod)
SMEDP 15.021 17th Ed
15,2 0,10 n/a 0,10 -1,17
(Mod)
15,3 n/a n/a
15,4 n/a n/a
16,1 0,13 n/a 0,13 AS2300.2.10 1,11
16,2 0,13 n/a 0,13 AS2300.2.10 0,83
16,3 n/a n/a
16,4 n/a n/a
17,1 0,12 n/a 0,12 SMEDP 15.023 0,47
17,2 0,12 n/a 0,12 SMEDP 15.023 0,38
17,3 n/a n/a
17,4 n/a n/a
18,1 0,10 n/a 0,10 APHA 15.021 -1,08
18,2 0,11 n/a 0,11 APHA 15.021 -0,90
18,3 n/a n/a
18,4 n/a n/a
19,1 0,11 n/a 0,11 NZTM3.2.3 -0,53
19,2 0,11 n/a 0,11 NZTM3.2.3 -0,44
19,3 0,11 n/a 0,11 NZTM3.2.3 -0,53
19,4 0,11 n/a 0,11 NZTM3.2.3 -0,44
20,1 0,12 n/a 0,12 NZTM3.2.3 0,38
20,2 0,12 n/a 0,12 NZTM3.2.3 0,38

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results
titratable acid sample 2

assigned value xpt [g/100 g] - titrim. 0,12

± expanded uncertainty (k=t) of the assigned value U(x pt) 0,00

customer data performance

x x x x x̅
lab
single single single single lab method description / com-
code z-score z'-score CRD-value
value 1 value 2 value 3 value 4 mean standard ments
no.
[g/100 g]
20,3 n/a n/a
20,4 n/a n/a
21,1 0,11 n/a 0,11 NZTM3.2.3 -0,62
21,2 0,10 n/a 0,10 NZTM3.2.3 -1,26
21,3 n/a n/a
21,4 n/a n/a
22,1 0,12 n/a 0,12 NZTM3.2.3 0,38
22,2 0,12 n/a 0,12 NZTM3.2.3 0,38
22,3 n/a n/a
22,4 n/a n/a
23,1 0,11 n/a 0,11 NZTM3.2.3 -0,71
23,2 0,11 n/a 0,11 NZTM3.2.3 -0,62
23,3 0,11 n/a 0,11 NZTM3.2.3 -0,90
23,4 0,11 n/a 0,11 NZTM3.2.3 -0,99
24,1 0,14 n/a 0,14 AS2300.2.10 2,20
24,2 0,12 n/a 0,12 AS2300.2.10 0,38
24,3 n/a n/a
24,4 n/a n/a
25,1 n/a n/a
25,2 n/a n/a
25,3 n/a n/a
25,4 n/a n/a

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summarized evaluation
titratable acid sample 2

assigned value xpt [g/100 g] - titrim. 0,12

± expanded uncertainty (k=t) of the assigned value U(x pt) 0,00
standard deviation for proficiency assessment (SDPA) 0,01
no. of datasets excluding outlier 31
no. of outlier 0

performance rating of laboratory datasets: precision data of the used DRRR-

standard-method:
none standard method defined

repeatability
z-score r -
r rel (%) -
For this parameter no z-score calculation is x − xpt
performed. The reasons for this can be z=
found in our statistical protocol. sR reproducibility
R -
R rel (%) -

z'-score repeatability standard deviation

sr
x − xpt -
z′ =
z' ≤ 2 2 < z' < 3 z' ≥ 3 SDPA2 + s2
M
37 1 3 reproducibility standard deviation
sR -

critical difference
CRD-value CD -
x − xpt
For this parameter no CRD calculation is CRD =
performed. The reasons for this can be
CD
material standard deviation:
found in our statistical protocol.
This value is calculated on the basis
of previous studies and/or experience
values.
sM 0,00

x̅ = your lab mean value

Further information you will find in our statistical Protocol. xpt
As a registered customer you can download the statistical protocol on your personal assigned value
home page in our Online-Data-Information-Network (ODIN). U(xpt) expanded uncertainty
Alternatively, we also provide you with the statistical protocol on request. (k=t0.975, n-1) of the
assigned value

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paricipants total (independent of methods)

titratable acid sample 2 (informative)

conventional statistics excluding outlier

mean [g/100 g] 0,12

standard deviation [g/100 g] 0,01
no. of datasets excluding outlier 38
no. of outlier 3

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results sorted according to means

titratable acid sample 2
(error indicator = laboratory range)
0,26

0,24
1,00
titrierbare Säure / titratable acid [g/100 g]

0,22 1,37

0,20

0,18

0,16

0,14

0,12

0,10

0,08 Grubbs-Ausreißer / Technischer-Ausreißer /

Grubbs-outlier: 5 / 6 technical-outlier: 9
0,06
14,1
21,2
15,2
15,1
18,1
23,4
18,2
23,3
23,1
21,1
23,2
10,1
10,2
14,2
19,1
19,3
19,2
19,4
13,1
13,2
13,3
13,4
8,3
8,4
17,2
20,1
20,2
22,1
22,2
24,2
17,1
3
8,2
16,2
16,1
4,1
8,1
24,1
5
6
9
Labor-Code Nr. / lab code no.

Laborspannweite / lab range

Labormittelwert / lab mean value

Mittelwert nach Ausreißereliminierung / mean excluding outlier: 0,12

Zugwiesener Wert / assigned value (titrim.) ± U(xpt): 0,12 ± 0,00

results sorted according to methods

titratable acid sample 2
(error indicator = laboratory range)
0,26

0,24 1,00
1,37
titrierbare Säure / titratable acid [g/100 g]

0,22 titrim.
0,20
sonstige
0,18 Methoden/
other
0,16 methods

0,14

0,12

0,10

0,08 Technischer-Ausreißer /
technical-outlier: 9
0,06
14,1
21,2
15,2
15,1
18,1
18,2
23,1
21,1
23,2
10,1
10,2
14,2
19,1
19,2
13,1
13,2
17,2
20,1
20,2
22,1
22,2
24,2
17,1
3
8,2
16,2
16,1
4,1
8,1
24,1
5
23,4
23,3
19,3
19,4
13,3
13,4
8,3
8,4
6
9

Labor-Code Nr. / lab code no.

Laborspannweite / lab range

Labormittelwert / lab mean value

Zugwiesener Wert / assigned value (titrim.) ± U(xpt): 0,12 ± 0,00

RVEP 222031 / Art.-No.: 2010001 ©DRRR

 88/89

Youdenplot

zufällige Abweichung / systematisch zu hoch /

random deviation systematically to high

0,26

0,24

0,22

0,20
titratable acid sample 2 [g/100 g]
titrierbare Säure Probe 2 /

0,18

0,16
5

0,14 24,1

8,1
4,1
16,1
8,216,2 3
17,1
0,12 13,4
17,2 24,2
20,2
20,1
22,2
22,1
8,4 8,3
13,3
13,2
13,1
14,2 19,2
19,4
19,1
19,3
10,2
10,1
23,2
21,1
23,1
23,318,2
23,4
15,1
15,2 18,1
21,2
0,10 14,1

0,08

0,06
0,06 0,08 0,10 0,12 0,14 0,16 0,18 0,20 0,22 0,24 0,26

systematisch zu niedrig / titrierbare Säure Probe 1 / zufällige Abweichung /

systematically to low titratable acid sample 1 [g/100 g] random deviation

xpt ± 2 * SDPA xpt

95-%-Vertrauensellipse / 95 % confidence ellipse 99-%-Vertrauensellipse / 99 % confidence ellipse

Linear (Trendlinie / trend line)

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©DRRR
9 9
6 6
8,3 5
3 24,1
5 8,1
2 4,1
16,2 16,1
16,1 16,2
24,2 8,2
24,1
22,2 3
22,1 17,1
20,2 24,2
20,1 22,2
8,4 22,1
Labor-Code Nr. / lab code no.
8,2 20,2

Labor-Code Nr. / lab code no.

8,1 20,1
4,1 17,2
17,2 8,4
17,1 8,3
13,4 13,4
13,3
z'-score

13,3
14,1

z'-score
13,2 13,2
13,1 13,1
12,2 19,4
12,1 19,2
21,2 19,3
21,1 19,1
10,2 14,2
10,1 10,2
19,4 10,1
19,2 23,2
23,2 21,1
23,1

RVEP 222031 / Art.-No.: 2010001

23,1
19,3 23,3
19,1
18,2 18,2
titratable acid sample 1

titratable acid sample 2

18,1 23,4
23,4 18,1
14,2 15,1
summary z'-score

summary z'-score
15,1 15,2
23,3 21,2
15,2 14,1
5,00

4,00

3,00

2,00

1,00

0,00

-1,00

-2,00

-3,00

-4,00

-5,00

-1,00

-2,00

-3,00

-4,00

-5,00
5,00

4,00

3,00

2,00

1,00

0,00
z'-score z'-score