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TASK 4 0711 Edit 1

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9 views4 pages

TASK 4 0711 Edit 1

Uploaded by

kardianahkaling
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© © All Rights Reserved
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TASK 4 0711

OBJECTIVES

1. When 10 cm3 of a gaseous hydrocarbon was completely burnt in 70 cm3 of oxygen (excess),

30 cm3 of carbon dioxide was produced and 20 cm3 of oxygen remain unreacted, all volumes
being

measured at the same temperature and pressure. What is the formula of the hydrocarbon?

A CH4 B CH3CH3 C CH3CH2CH3 D CH3CH2CH2CH3

2. Tetramethyl-lead(lV) increases the rate of the reaction of methane with chlorine.

CH4(g) + Cl2(g) → CH3Cl(g) + HCl(g)

Why can tetramethyl-lead(IV) behave in this way?

A It is a source of methyl radicals.

B It releases CH3+(g).

C It reacts with chloromethane and prevents equilibrium being established.

D Metal ions catalyse the reaction.

3. 2-Butanol → 2-Butene → 2- Chlorobutane


What are the chemical needed for the conversion of I and II ?

I II
A Concentrated H2SO4 Chlorine gas
B Concentrated H2SO4 Hydrogen chloride gas
C Aqueous HNO3 Hydrogen chloride
D Acidified KMnO4 Aqueous HCl

4. CH3CH2Br reacts with an aqueous solution of potassium hydroxide forming CH3CH2OH, whereas

(CH3)3Br reacts with an ethanolic solution of potassium hydroxide forming CH2 = C(CH3)2 as the
major product. Which statement is true about the two reactions ?

A The reactions occur at room temperature.


B The reactions occur through the formation of carbocation.
C The reactions are nucleophilic substitution and elimination respectively.

D The rate of each reaction is independent of the concentration of OH– ions.


5. Nitrobenzene may be made by reacting benzene with a mixture of concentrated sulphuric and

nitric acids.

Which of the following best explains the role of the sulphuric acid?

A removing the water produced

B forming an unstable complex with benzene .

C acting as a solvent

D protonating nitric acid

6. Which reagent could detect the presence of added alcohol in a petrol consisting mainly of a

mixture of akanes and alkenes?

A Na B Br2 (in CCl4)

C KMnO4(aq) D 2,4-dinitrophenylhydrazine

7. Which of the following combination of reactants is the most suitable to produce the organic

structure given below.

A C6H5COCI and C6H5OH B C6H5COOH and C6H5OH

C C6H5NH2 and C6H5NO2 D C6H5COH and C6H5OH

8. An organic compound has the following properties.

* It decolourises bromine water.

* 1.0 mol of the organic compound reacts with excess PCl5 to produce 2 mol of HCl.

* It loses water readily when heated.

The compound could be

A B

C D
9. An organic compound with the following structure, dissolved in
aqueous

sodium hydroxide. The sodium salt produced is

A B

C D

10. A compound has the following chemical properties.


(i) It gives a positive iodoform test.

(ii) It decolourises acidified aqueous potassium manganate (VII).

(iii) It reacts with phosphorus pentachloride to produce hydrogen chloride gas.


The compound is
A CH3COCH3 B CH3CH2OH
C (CH3)3COH D (CH3CH2)2CHOH

11. The sex hormones progesterone and testosterone have the following structures.

Progesterone Testosterone

Which reagents could be used to distinguish between them?


A Hydrogen cyanide B 2,4-Dinitrophenylhydrazine

C Hydrazine D Iodine and aqueous sodium hydroxide

STRUCTURES

QUESTION 1

2- bromobutane reacts with aqueous hydroxide ions to give 2-butanol


(a) State what type of reaction mechanism this is. [1 mark]
(b) State the reagent needed to convert 2-bromobutane to CH3CH2CH(CH3)CH(OH)CH3 in 2 steps.
[2 marks]
(c) Write the displayed formula of the product when 2-methyl-2-propanol is heated with an
excess of concentrated sulphuric acid and name the reaction that occurred. [2 marks]
(d) The structural formula for menthol is as follows.

Menthol is a derivative of cyclohexane that is used in the skin lotion industry to prevent skin
itchiness.
Circle all the chiral carbon centres in the structural formula of menthol. [2 marks]

QUESTION 2

Butanenitrile, CH3CH2CH2CN, is hydrolysed in acidic conditions to yield compound A.


When compound A is reacted with phosphorus pentachloride, a compound B is produced.
Compound B reacts with ethanol to produce a liquid C which has a sweet smell.
(i) Determine the structural formulae for compound A. [1 mark]

(ii) Give the IUPAC name for the compound B. [1 mark]


(iii) Write the chemical equation for the formation of compound C. [1 mark]

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