Safety Data Sheet GHS – United States

Section 1. Product and Company Identification

Product Names EPK Kaolin

Synonym Edgar Clay, China Clay, EPK, Edgar Pulverized Kaolin
Supplier/ Edgar Minerals, Inc.
Manufacturer 651 Keuka Rd.
Hawthorne, FL 32640
352-481-2421 phone
352-481-2334 fax
Emergency Phone Number 352-317-1617

Product Use Ceramics, Sanitary Ware, Agriculture, Paint filler, China clay, various industrial applications
Restrictions on use Not applicable

Section 2. Hazards Identification

OSHA/HCS status This material is considered hazardous by the
OSHA Hazard Communication Standard (29 CFR 1910.1200)
Classification of the OSHA - CARCINOGENICITY (Inhalation) - Category 1A
substance or mixture (See section 16 for OSHA, IARC, and NTP carcinogen listings)
OSHA - SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure)
(respiratory tract) (inhalation) - Category 1
Signal Word Danger
Hazard Statement EPK Kaolin is a naturally occurring mineral, which may contain amounts of crystalline silica
typically 0.1-1.0%, may cause damage to respiratory system through prolonged or repeated
exposure.
• • CARCINOGENICITY: This product contains crystalline silica. Repeated,
prolonged inhalation of dust may cause delayed lung injury which may result in
silicosis or pneumoconiosis. The International Agency For Research On Cancer
in its publication, “IARC Monographs On the Evaluation Of The Carcinogenic Risk
To Humans – Silica, Some Silicates, Coal Dust and Para-aramid Fibrils” - Volume
68, 1997, has concluded that there is sufficient evidence of the carcinogenicity of
crystalline silica in humans, and has, therefore, classified crystalline silica in, Group
1, Carcinogenic to Humans. The National Toxicology Program’s (“NTP’s”) Ninth
Annual Report on Carcinogens 2000, lists crystalline silica (respirable) as a
substance which is known to be a human carcinogen. In humans, a number of studies
have found an association between lung cancer and exposure to dust containing
respirable crystalline silica. In many of these studies, though not all, lung cancer
risks were elevated and could not be explained by confounding factors such as
cigarette smoking or arsenic or random inhalation. While the IARC working group
concluded there was sufficient evidence in humans for the carcinogenicity of inhaled
crystalline silica in the form of quartz or crystobalite, it noted that carcinogenicity in
humans was not detected in all circumstances studied.
ACGIH states that it is a suspected cause of cancer. Other forms of respirable
crystalline silica (e.g. tridymite and cristobalite) may also be present or formed
under certain industrial processes.

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GHS label elements /
Hazard pictograms

Health Hazard Irritant

(carcinogen) (skin,eye & respiratory tract)
Precautionary Statements
Avoid generating dust.
Do not breath dust.
Wear approved respiratory protection if exposure is greater
than suggested exposure limits.
Unclassified Hazards
Slippery when wet.

% of ingredients with
unknown acute toxicity
None Known

Section 3. Composition / Information on Ingredients

Substances:
Chemical Formula CAS & ICSC Numbers Percentage
2 3 2 2
Kaolinite Al O .2SiO .2H O CAS # 1332-58-7 ICSC # 1144 99.0% - 99.9%
2
Quartz (Crystaline Silica) SiO CAS # 14808-60-7 ICSC # 0808 0.1% - 1.0%

Section 4. First-Aid Measures

Description of first-aid Measures:

First-aid measures general Never give anything by mouth to an unconscious person.
If you feel unwell, seek medical attention.
First-aid measures after inhalation Move victim to well ventilated area.
If mechanical discomfort persists, seek medical attention.
First-aid measures after skin contact Remove contaminated clothing. Wash affected area with soap and warm water.
Obtain medical attention if irritation persists.
First-aid measures after eye contact Flush the eyes immediately with large amounts of running water, lifting the upper and lower lids
occasionally. Remove contact lenses if present and easy to do. If irritation persists or for imbedded
foreign body, get immediate medical attention.
First-aid measures after ingestion Rinse mouth. Do NOT induce vomiting. Unlikely to be toxic by ingestion.
If discomfort persists, seek medical attention.
Most Important Symptoms and Effects, Both Acute and Delayed:
Symptoms/injuries Causes damage to organs through prolonged or repeated exposure (inhalation).
Symptoms/injuries after inhalation May cause cancer by inhalation. Dust from this product may cause irritation to the respiratory tract.
Symptoms/injuries after skin contact Prolonged contact with large amounts of dust may cause mechanical irritation.
Symptoms/injuries after eye contact Prolonged contact with large amounts of dust may cause mechanical irritation.
Symptoms/injuries after ingestion If a large quantity has been ingested: intestinal blockage. Gastrointestinal irritation.
Chronic symptoms Repeated or prolonged exposure to respirable crystalline silica dust will cause lung damage in the form
of silicosis. Symptoms will include progressively more difficult breathing, cough, fever, and weight loss.
Acute silicosis can be fatal.
If exposed or concerned, get medical advice and attention.

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Section 5. Fire-Fighting Measures

NFPA

National Fire Protection Association (U.S.A.)

Suitable extinguishing media This product is not combustible.
Use extinguishing media appropriate for surrounding fire.
Unsuitable extinguishing media No restrictions on extinguishing media for this material.
Special hazards arising from the substance or This material is not flammable and does not support fire. The paper
mixture bags and bulk bags containing the material are flammable.
Hazardous thermal decomposition products This material does not contain hazardous decomposition products.
Special protective actions Product can become slippery when wet.
for fire-fighters
Special protective equipment Fire-fighters should wear appropriate protective equipment.
for fire-fighters

Section 6. Accidental Release Measures

Use of personal precautions Avoid inhalation of dry clay dust. Wear appropriate personal
protective clothing and respiratory protection when cleaning up dry
clay dust.
Emergency procedures There are no emergency procedures required for this material. Avoid
release to the environment, including sewers, surface or ground
water.

Methods and Materials

For containment Kaolin waste is not reactive, flammable or biodegradable. Use
conventional means; e.g. sweeping, vacuum, etc. Use caution on
wet floor, as it may be slippery.

Clean up procedures Clean up residue with high-efficiency particulate filter vacuum. Scoop
spilled material into appropriate containers for disposal. Use
methods to minimize dust. Avoid sweeping spilled dry material. If
sweeping of a contaminated area is necessary, use a dust
suppressant agent.

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Section 7. Handling & Storage

Precautions for safe handling Paper bags weigh 50 lbs. Use proper lifting techniques to avoid
physical injury. Bulk bags weigh 2000 lbs. Use proper equipment to
lift. Do not breath dust. Do not eat, drink or smoke when using this
product. Use methods to minimize dust. Routine housekeeping
should be instituted to ensure that dusts do not accumulate on
surfaces. Wear protective gloves/clothing and eye/face protection.
Was thoroughly after handling.
Recommendations on the No special storage considerations, but keep in a dry location.
conditions for safe storage

Section 8. Exposure Controls / Personal Protection

Chemical Name CAS Numbers Occupational Exposure Limits
3
Quartz,(Crystalline Silica)SiO2 CAS#14808-60-7 ACGIH TLV: TWA 0.025 mg/ m (respirable)
3
OSHA PEL: TWA 10 mg/m / divided by the value “%SiO2” + 2
(respirable)
3
OSHA PEL: TWA 30 mg/m / divided by the value “%SiO2” + 2 (total
dust)
3
CAL OSHA PEL: TWA .1 mg/ m (respirable)
3
CAL OSHA PEL: TWA .3 mg/ m (total)
3
NIOSH REL: .05 mg/m TWA (respirable dust)
3
Kaolinite Al2O3.2SiO2.2H2O CAS#1332-58-7 ACGIH TLV: TWA 2 mg/ m (respirable) / particulate matter
containing no asbestos and <1% crystalline silica (respirable)
3
OSHA PEL: TWA 5 mg/m (respirable)
3
OSHA PEL: TWA 15 mg/m (total)
3
CAL OSHA PEL: TWA 2 mg/ m (respirable)
3 3
NIOSH REL: 10 mg/m TWA (total dust); 5 mg/m TWA (respirable dust)

Appropriate engineering Clay in moist form poses no health risk and no inhalation risk .
Controls In the event that dust is generated, use local exhaust ventilation or other
engineering controls as required to maintain exposures below applicable
occupational exposure limits (TLV).
Ensure that dust handling systems are designed in a manner to prevent the escape of
dust into the work area. Ensure compliance with applicable exposure limits.
Recommendations for personal protective measures
Local Exhaust: When mixing, dry sanding or grinding clay products, use sufficient local exhaust to reduce the level of
respirable dust to the applicable standards set forth in Section III. See ACGIH “Industrial Ventilation, A Manual of
Recommended Practice,” latest edition.

Respiratory Protection: Dust is generated when working with dry kaolin. To minimize exposure to dust and/or crystalline
silica, the mixing of dry kaolin products should be conducted with sufficient ventilation.
Respirable dust and quartz levels should be monitored regularly. Dust and quartz levels in excess of appropriate exposure
limits should be reduced by feasible engineering controls, including (but not limited to) wet suppression, ventilation, and
process enclosure. When such controls are not feasible, NIOSH/MSHA approved respirators must be worn in accordance
with a respiratory protection program which meets OSHA/MSHA requirements as set forth at 29 CFR1910.134 and ANSI
Z88.2-2015”Practices for Respiratory Protection”.

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Eye Protection: Use safety glasses with side shields that are compliant with ANSI Z87.1-1989. Face shields can also be
used when mixing dry kaolin. Wear tight fitting dust goggles when excessively (visible) dusty conditions are present or
are anticipated. NIOSH recommends that contact lenses not be worn when working with material containing crystalline
silica dust.

Skin Protection: Use gloves and/or protective clothing if abrasion or allergic reactions are experienced.

Work/Hygienic Practices: Avoid creating and breathing dust. Always observe good personal hygiene measures, such as
washing after handling material and before eating, drinking and/or smoking. Routinely wash work clothes and protective
equipment to remove contaminates.

Protective Clothing Pictograms

Section 9. Physical & Chemical Properties

Physical State Powder or prill
Appearance Buff color in dry form
Odor Earthy odor when wet
Odor Threshold Not Applicable
pH 5.5-6.5
Solubility in Water None
o
Melting Point 1740-1785 C
Freezing Point < 0 °C (<32°F)
Specific Gravity / Relative Density 2.65 g/cc
Evaporation Rate No data available
Flash Point Not Applicable
Auto-Ignition Temperature Not Applicable
Decomposition Temperature Not Applicable
Flammability Not Applicable
Vapor Pressure Not Applicable
Vapor Density Not Applicable
Explosive Limits Not Applicable
Viscosity Not Applicable
Partition Coefficient: n-octanol/water Not Applicable
Initial Boiling Point & Boiling Range Not Applicable

Section 10. Stability & Reactivity

Reactivity Hazardous reactions will not occur under normal conditions.
Chemical stability Stable at standard temperature and pressure.
Possibility of hazardous reactions Hazardous polymerization will not occur.
Conditions to avoid Avoid generating dust
Incompatible materials None known
Hazardous decomposition products None known

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Section 11. Toxicological Information

Routes of Exposure Inhalation of dry clay dust, Ingestion
Acute Effects
Inhalation Aspiration of high concentrations of dry clay dust may cause
mechanical irritation and discomfort. Long term exposure may
cause chronic effects.
Eye Contact Not a primary eye irritant. May cause mechanical irritation.
Skin Contact/Irritation Not a skin irritant. Not absorbed through skin.
Sensitization Not a sensitizer
Ingestion Ingestion may cause gastrointestinal irritation

Section 11. Toxicological Information

Chronic Effects
OSHA Carcinogen Lung cancer – Silica has been classified by OSHA as a human
lung carcinogen.
Mutagenic Effects None Known
Teratogenic Effects None Known
Developmental Toxicity None Known
Effects of Silicosis Symptoms of Silicosis
Bronchitis/Chronic Obstructive Pulmonary Shortness of breath; possible fever.
Disorder. Fatigue; loss of appetite.
Tuberculosis – Silicosis makes an individual Chest pain; dry, nonproductive cough.
more susceptible to TB. Respiratory failure, which may eventually lead to death.
Scleroderma – a disease affecting skin,
blood vessels, joints and skeletal muscles.
Possible renal disease.
Remarks
Carcinogenicity “Calcined kaolin is not listed as a carcinogen by the
International Agency for Research on Cancer (IARC), the
National Toxicology Program (NTP), or the Occupational Safety
and Health Administration (OSHA). The American Conference of
Governmental Industrial Hygienists (ACGIH) lists kaolin as Not
Classifiable as a Human Carcinogen: Inadequate data on which
to classify the agent in terms of its carcinogenicity in humans
and/or animals.”
“The International Agency for Research on Cancer has
determined that crystalline silica (quartz) is carcinogenic to
humans (Group 1). Refer to IARC Monograph 100C (2011). The
National Toxicology Program classifies respirable crystalline
silica as “known to be a human carcinogen” (12th Report on
Carcinogens, 2011). The ACGIH classifies crystalline silica,
quartz, as a suspected human carcinogen (A2).”

Numerical Measures of toxicity None Known

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OSHA, IARC, and NTP Carcinogen Classifications

Chemical with Carcinogen Potential CAS# OSHA IARC NTP
Quartz, (Crystalline Silica) SiO2 CAS # 14808-60-7 Yes Yes - Group 1 Yes

Section 12. Ecological Information (non-mandatory)

Ecotoxicity None Known
Biochemical oxygen demand (BOD5) None Known
Chemical oxygen demand(COD) None Known
Products of Biodegradation None Known
Toxicity of the products of Biodegradation None Known
Bioaccumulation Potential None Known
Potential to move from soil to groundwater None Known
Other adverse effects None Known

13. Disposal Considerations

Personal Protection Refer to Section 8: “Recommendations for Personal Protective Measures”
when disposing of ceramic waste.
Appropriate disposal containers Standard waste disposal containers – no specials requirements.
Appropriate disposal methods Disposal of this product should comply with the requirements of
environmental protection and waste disposal legislation and any regional
local authority requirements. In most cases, this is normal waste disposal.
The generation of waste should be avoided or minimized. Dispose of non-
recyclable products via a licensed waste disposal contractor. Waste
packaging should be recycled. Avoid dispersal of spilled material and runoff
and contact with soil, waterways, drains, and sewers.
Physical and chemical properties Dry clay dust should be placed in a sealed container
that may affect disposal or in a manner that reduces or eliminates the release of the product.
Packaging should be recycled before disposal.
Sewage disposal Do not dispose of into sinks or toilets. They will clog. Never dispose of this
product into a sewer system.
Special precautions for landfills There are no special precautions for disposal in a landfill.
or incineration activities This product is non-combustible and is not suitable for incineration.

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Section 14. Transportation Information

Regulatory UN UN Proper Transport Packing Bulk Transport Special
Information Number Shipping Name Hazard Class Group Number Guidance Precautions
DOT Not regulated - - - - -
Classification
TDG Not regulated - - - - -
Classification
ADR/RID Class Not regulated - - - - -
IMDG Class Not regulated - - - - -
IATA-DGR Not regulated - - - - -
Class

Section 15. Regulatory Information

TSCA – Toxic Substances Control Act - EPA Quartz and other chemicals are listed in the
TSCA Chemical Substance Inventory
California Prop. 65 WARNING: This product contains a chemical known to the State
of California to cause cancer. (Prop. 65 - Calif. Health & Safety
Code Section 2549 Et Seq.)
SARA/Title lll This material contains no substances at or above the reporting
(Emergency Planning & Community threshold under Section 313,
Right-to-Know Act) Based on available data.

Section 16. Other Information

Definitions
ASTM means American Society for Testing and Materials
IARC means International Agency for Research on Cancer
NTP means National Toxicology Program
HCS means Hazard Communication Standard
CAS means Chemical Abstract Service
ACGIH means American Conference of Governmental Industrial Hygienists
CAL-OSHA means California OSHA, most CAL-OSHA standards defer to the federal OSHA standards
OSHA means Occupational Safety & Health Administration
OSHA PEL means OSHA Permissible Exposure Limit
OSHA STEL means short term exposure limit. Limit exposure to a duration of 15 minutes, that cannot be
repeated more than 4 times per day, with at least 60 minutes between exposure periods
TWA means Time Weighted Average (average exposure on the basis of an 8h/day, 40h/week work schedule)
TLV means Threshold Limit Value - American Conference of Governmental Industrial Hygienists (ACGIH)
NFPA Hazard Rating: Health 1 Fire 0 Reactivity: 0
Three types of TLVs for chemical substances as defined by the ACGIH are:
1. TLV-TWA - Time weighted average - average exposure on the basis of an 8h/day, 40h/week work
schedule.
2. TLV-STEL - Short-term exposure limit - spot exposure for a duration of 15 minutes, that cannot be
repeated more than 4 times per day, with at least 60 minutes between exposure periods.
3. TLV-C - Ceiling limit - absolute exposure limit that should not be exceeded at any time.

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This SDS is in compliance with The Globally Harmonized System of Classification and Labeling of Chemicals
(GHS) – June 1, 2015. This data sheet is subject to change without notice.

Information presented herein has been compiled from sources considered to be dependable and is accurate
and reliable to the best of our knowledge and belief but is not guaranteed to be so. Nothing herein is to be
construed as recommending any practice or any product in violation of any patent or in violation of any law or
regulation. It is the user’s responsibility to determine for himself the suitability of any material for a specific
purpose and to adopt such safety precautions as may be necessary. We make no warranty as to the results to
be obtained in using any material and, since conditions of use are not under our control, we must necessarily
disclaim all liability with respect to the use of any material supplied by us.

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