Formglas Products Ltd.

SAFETY DATA SHEET

Section 1: Identification
Product Identifier Formglas® GFRC-L
Other means of identification
Synonyms Glass Fiber Reinforced Concrete, GFRC
SDS# GFRC-L
Recommended Use Architectural building products
Recommended Restrictions Not for use as load bearing components
Manufacturer Information Formglas Products Ltd.
181 Regina Road
Vaughan, ON Canada L4L 8M3
Tel: 866.635.8030
Emergency telephone number Chemtrec – Emergency 800.424.9300 (Customer # 851813)

Section 2: Hazard identification

Classification of the GFRC-L Glass Fiber Reinforced Concrete is a mixture of ingredients
Substance or Mixture molded into a solid manufactured “article” and not hazardous in its solid
form. However, exposure to dust from cutting, grinding or otherwise
altering these articles may irritate the eyes, skin, nose, throat or
respiratory tract. Hazards listed are associated with individual ingredients
used in the manufacture of these articles. See Sections 8 and 11 for
information concerning exposure and personal protection.
Physical Hazards Not classified
Health Hazards Serious eye damage / eye irritation Category 2B
Environmental Hazards Not Classified
Label Elements
Symbol None
Signal Word None
Hazard statement None
Precautionary statements
Prevention Wear protective gloves, eye and face protection, respiratory protection.
Response IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If eye
irritation persists: Get medical attention.
IF SWALLOWED: Rinse mouth. Call a doctor if you feel unwell.
Hazards not otherwise classified Exposure to dust from cutting, grinding or otherwise altering these
manufactured articles may irritate the respiratory tract. Wear respiratory
protection. See Section 8: Exposure controls/personal protection.

Section 3: Composition/information on ingredients

Mixture
Chemical name(s) CAS# Concentration (% wt.)
White Portland Cement – Calcium salts as listed 46.9
3CaO.SiO2 12168-85-3
2CaO.SiO2 10034-77-2

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3CaO.Al2O3 12042-78-3
4CaO.Al2O3.Fe2O3 12068-35-8
CaSO4.2H2O 13397-24-5
Sand, crystalline silica* 14808-60-7 42.1
Acrylic polymer n/a 6.4
Glass fiber 65997-17-3 4.0
Binder 919-30-2 0.4
Color pigments 13463-67-7 0.2 – 1.7
57455-37-5
1317-61-9
1308-38-9
Steel (reinforcement, if required) Not Assigned 0 – 5.0
Note: * The weight percent listed is for total silica and not the respirable fraction. All silica ingredients have been
bonded into these manufactured articles and are not respirable as provided. Cutting, grinding or otherwise altering
these manufactured articles may produce respirable crystalline silica dust. See Section 8 for exposure details.
The weight percent of the steel reinforcement, if any, could vary depending on structural or attachment
requirements.

Section 4: First-aid measures

Inhalation Particles or dust may cause irritation. Remove person to fresh air. Have affected
person blow nose or use soft tissues to remove particles or residues from
nostrils. If symptoms persist, get medical attention.
Skin contact For skin contact or irritation, wash immediately and thoroughly with soap and
water. Get medical attention if irritation develops or persists. For minor cuts or
abrasions, rinse away debris with water, clean with soap and water, disinfect and
bandage. Get medical attention as circumstances dictate.
Eye contact For dust in the eyes, flush eyes immediately and thoroughly with plenty of water,
also under the eyelids, for at least 15 minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Get medical attention if irritation persists or for
eye abrasions.
Ingestion Rinse mouth with water immediately. Do not induce vomiting without medical
advice. If symptoms persist, get medical attention.
Most important symptoms/ Eye irritation. Exposed individuals may experience eye tearing, redness and
effects, acute and delayed discomfort. Inhalation may cause respiratory tract irritation. Symptoms may be
delayed.

Section 5: Fire-fighting measures

Suitable extinguishing media Use water or other extinguishing measures that are appropriate to the local
circumstances and environment. There is no unsuitable extinguishing media
known.
Specific hazards arising During a fire, toxic gases and particulates (such as oxides of sulfur) may be
from the chemical released by the decomposition of calcium sulfate. No unusual fire or explosion
hazards noted.
Special protective actions Fire-fighters should use standard fire-fighting procedures appropriate for the
for fire-fighters local circumstances and environment.

Section 6: Accidental release measures

Personal precautions, These solid manufactured articles do not represent a spill, leak or release
protective equipment and hazard. Avoid actions that cause dust from damaged articles from becoming
emergency procedures airborne. Avoid inhalation of dust. Wear gloves and other personal protective
equipment. Refer to Section 8: Exposure controls/personal protection.
Environmental precautions Avoid discharge into drains, sewers and other waterways.
Methods and materials for Follow federal, state or provincial, and/or local regulations for solid waste

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containment and cleaning up disposal.

Section 7: Handling and storage

Precautions for safe handling These manufactured articles can be heavy and awkward to lift and install posing
risks such as sprains to the back, arms and legs. Use proper lifting and handling
techniques. Wear clean gloves to protect hands from rough edges and glass
fibers.
Conditions for safe storage, Protect products from weather and store indoors in a cool, dry, ventilated area
including incompatibilities away from moisture. Incompatible with: acids, phosphorus, diazomethane,
and aluminum (at high temperatures).

Section 8: Exposure controls/personal protection

Control parameters
Occupational exposure limits
Chemical name(s) CAS# ACGIH - TLV OSHA
(mg/m3) (mg/m3)
White portland cement 65997-15-1 1 10 (T) / 5 (R) PEL
Sand, crystalline silica, 14808-60-7 0.025 4.3(T) / 3.3 (R) TWA
Acrylic polymer n/a 5 10 (T)
Glass fiber 65997-17-3 10 15 (T) / 5 (R) PEL
Binder 919-30-2 n/a n/a
Color pigments 13463-67-7 10 15 (T) / 5 (R) PEL
57455-37-5 n/a 10 (T) / 3 (R)
1317-61-9 10 15 (T) / 5 (R)
1308-38-9 10 15 (T) / 5 (R) PEL
Steel (reinforcement, if required) Not Assigned 0.5 15 (T) / 5 (R) PEL
OSHA - Occupational Health and Safety Administration; PEL – Permissible Exposure limit
TWA – Time Weighted Average; (T) – Total dust; (R) - Respirable fraction
ACGIH – American Conference of Governmental Hygienists; TLV – Threshold Limit Value
Note: These manufactured articles contain crystalline silica but not in a respirable form. Cutting, grinding or similar
alterations to these articles that produce dust may contain respirable crystalline silica dust which is a known lung
carcinogen, and is listed in California Proposition 65 as being known to cause cancer. Take precautions to
prevent and/or control dust levels, if any, to within approved limits.
Appropriate engineering controls
Normal handling and use of the manufactured articles as supplied do not create a risk of exposure beyond
personal exposure limits. If cutting, grinding or other modifications are made to the manufactured articles that
generate dust, take precautions to keep dust levels below permissible exposure limits through the use of portable
dust collectors and/or ventilation, as needed. If necessary, use a process enclosure with adequate ventilation to
contain, extract and/or collect dust.
Individual protection measures, such as personal protection equipment
Respiratory Protection When dust is present wear a NIOSH approved respirator that is properly fitted.
Eye/face protection Wear appropriate safety glasses, goggles or face shields as the nature of the
work dictates.
Skin Protection Wear clean gloves when handling parts. Wear protective clothing to prevent
repeated or prolonged skin contact. Remove clothing and protective equipment
that becomes dusty and clean before reusing.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practices.

Section 9: Physical and chemical properties

Appearance: Solid; range of colors Explosive limits: Not applicable
Odour: Little or none Vapour pressure: Not applicable
Odour threshold: Not applicable Vapour density: Not applicable

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pH: Not applicable Relative Density: 6.5-7.5 lb/ft² (32-37 kg/m²)
Melting point: Not applicable Solubility: Not applicable
Freezing point: Not applicable Partition coefficient: Not applicable
Initial boiling point: Not applicable Auto-ignition temperature: Not applicable
Flash point: Not applicable Decomposition temperature: Not available
Evaporation rate: Not applicable Viscosity: Not applicable
Flammability: Noncombustible

Section 10: Stability and reactivity

Reactivity Not available
Chemical stability Stable at normal conditions
Possibility of hazardous No dangerous reaction known under normal conditions of use.
Reactions
Conditions to avoid Incompatibilities – see below.
Incompatible materials Some ingredients have incompatibilities. Silica sand dissolves in hydrofluoric acid
producing corrosive silicon tetrafluoride gas. Silicates also react with powerful
oxidizers such as fluorine and chlorine trifluoride. Iron Oxide pigments are
incompatible with hydrazine, calcium hypochlorite, performic acid and bromine
pentafluoride.
Hazardous decomposition Toxic gases and particulates, calcium oxides, sulfur dioxides.
Products

Section 11: Toxicological information

Acute Exposure to dust may cause irritation to the eyes, skin and respiratory tract.
Skin corrosion/irritation Dust in contact with skin can cause irritation or dry skin
Serious eye damage/eye Dust in the eyes will cause eye irritation
Irritation
Skin sensitization Not classified
Respiratory sensitization Not classified
Germ cell mutagenicity Not classified
Carcinogenicity Not expected to be hazardous by OSHA criteria
Note: Exposure to airborne respirable crystalline silica dust is listed by IARC, NTP and California Proposition 65
as a lung carcinogen known to cause cancer. Prolonged exposure to respirable crystalline silica has been known
to cause silicosis, a lung disease. While there may be a factor of individual susceptibility to a given exposure to
respirable silica dust, the risk of contracting silicosis and the severity of the disease is clearly related to the
amount exposure and the length of time (usually years) of exposure.
IARC Monographs. Overall Evaluation of Carcinogenicity
Crystalline Silica (Quartz) CAS# 14808-60-7 1 (Carcinogenic to humans)
Reproductive toxicity Not classified
STOT single exposure Not classified
STOT repeated exposure Not classified
Aspiration hazard Not classified
Chronic effects Not hazardous under normal conditions of use

Section 12: Ecological information

These solid manufactured articles do not represent a spill, leak or accidental release hazard and not known to
produce an adverse effect on ecology.
Toxicity No data available

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Persistence and degradability No data available
Mobility in soil No data available
Other adverse effects Not expected to produce an adverse effect on ecology

Section 13: Disposal considerations

Disposal methods For the safety of persons conducting disposal, recycling or reclamation activities,
please refer to Section 8: Exposure controls/personal protection. Treat these
materials as solid waste. Do not dispose of in sewers, drainage systems or
waterways. Dispose of material in accordance with federal, state or provincial,
and local regulations.

Section 14: Transport information

DOT Not regulated as dangerous goods
IATA Not regulated as dangerous goods
IMDG Not regulated as dangerous goods
TDG Not regulated as dangerous goods
Transport in bulk according Not applicable
to Annex II of Marpol 73/78
and the IBC code

Section 15: Regulatory information

The items that are the subject of this Safety Data Sheet fall within the scope of the definition of “manufactured
articles” by United States and Canadian regulations concerning hazardous materials. The information provided
pertains to the individual ingredients used to make these manufactured articles.
These manufactured articles are not subject to the Montreal protocol, Stockholm convention or the Rotterdam
convention.
US California proposition 65
Note: Silica, crystalline (airborne particles of a respirable size) is listed as a chemical known to the state of
California to cause cancer. The manufactured articles that are the subject of this SDS may contain crystalline
silica but not in a respirable form. Performing cutting, grinding or other operations that create dust could produce
airborne particles of respirable size. See Section 8: Exposure controls/personal protection

Section 16: Other information

HMIS Ratings Health: 1; Flammability: 0; Physical hazard: 0 Personal Protection: E
NFPA Ratings Health: 1; Fire: 0; Reactivity: 0
HMIS/NFPA hazard legend 0 = Minimal; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe
E = Safety glasses, gloves and dust respirator
Abbreviations legend
HMIS - Hazardous Materials Identification System NFPA - National Fire Protection Association
CAS - Chemical Abstracts Service DOT - Department of Transportation (US)
IARC - International Agency for Research on cancer OSHA - Occupational Health and Safety Administration
NTP-– National Toxicology Program TDG – Transportation of Dangerous Goods (Cdn.)
NIOSH - National Institute of Occupational Safety and Health
SDS Issue date May, 2015
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge as of the date issued
and is typical of the articles manufactured. Some variations could be expected with custom made articles due to
part size and its structural requirements, finish and support embedments etc. The information given is provided as
a guideline for safe handling, use, storage, transportation, disposal and not to be considered a warranty or quality
specification. The user assumes full responsibility for applying the appropriate safety measures when these
products are used.

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