108. A transition metal ‘X’ has a configuration [Ar] 3d4 in its +3 111.

111. Which of the following element is represented by electronic

oxidation state, its atomic number is: configuration 1s 2 2s 2 2p1x 2p1y 2p1z ?
(1) 25 (2) 26 (3) 22 (4) 19 (1) N (2) O (3) P (4) S
109. An element has 2 electrons in K shell, 8 electrons in L shell, 112. The total number of electrons present in all the p– orbital of
bromine are: (Given: Atomic no. of Br = 35)
13 electrons in M shell and one electron in N shell. The
(1) 5 (2) 15 (3) 17 (4) 35
element is:
113. Which of the following statement in relation to the hydrogen
(1) Cr (2) Fe (3) V (4) Ti atom is correct?
110. Sum of electronic spins of all electrons with the configuration (1) 3s, 3p and 3d orbital all have the same energy
3d7 is: (2) 3s and 3p orbital are of lower energy than 3d orbital
(1) + 3/2 (2) + 5/2 (3) Both of these
(3) + 7/2 (4) 9/2 (4) None of these

PRABAL EXERCISE-2 (LEARNING PLUS)

1. Which of the following conclusions could not be derived 7. Charge of the species with 17 protons, 18 neutrons and 18
from Rutherford’s α-particle scattering experiment? electrons is:
(1) Most of the space in the atom is empty (1) + 1 (2) – 1
(2) The radius of the atom is about 10–10 m while that of (3) – 2 (4) None of these
nucleus is 10–15 m 8. Calculate the de-Broglie wavelength of the electron in the
(3) Electrons move in a circular path of fixed energy called ground state of hydrogen atom, given that its kinetic energy
orbits is 13.6 eV. (1eV = 1.602 × 10– 19J)
(4) Electrons and the nucleus are held together by (1) 3.328 × 10–10 m (2) 2.338 × 10–10 m
(3) 3.328 × 10 m10 (4) 2.338 × 10–18 m
electrostatic forces of attraction
2. How much energy is required to ionise a H-atom if the 9. In a photoelectric effect, the energy of the photon striking a
electron occupies n = 5 orbit? metallic surface is 5.6 × 10–19 J. The kinetic energy of the
(1) 5.44 eV (2) 10.8 eV ejected electrons is 12.0 × 10–20 J. The work function is:
(3) 0.544 eV (4) 1.08 eV (1) 6.4 × 10–19 J (2) 6.8 × 10–19 J
–19
(3) 4.4 × 10 J (4) 6.4 × 10–20 J
3. The hydride ion is isoelectronic with:
10. The probability density plots of 1s and 2s orbitals are given
(1) H+ (2) He+
in figure:
(3) He (4) Be
4. The momentum of radiation of wavelength 0.33 nm is
_____ kg m sec–1
(1) 2 × 10–24 (2) 2 × 10–12
(3) 2 × 10–6 (4) 2 × 10–48
5. Which of the following options does not represent ground
state electronic configuration of an atom? The density of dots in a region represents the probability
density of finding electrons in the region.
(1) 1s2 2s2 2p6 3s2 3p6 3d8 4s2
On the basis of above diagram, which of the following
(2) 1s2 2s2 2p6 3s2 3p6 3d9 4s2
statements is incorrect?
(3) 1s2 2s2 2p6 3s2 3p6 3d10 4s1 (1) 1s and 2s orbitals are spherical in shape.
(4) 1s2 2s2 2p6 3s2 3p6 3d5 4s1 (2) The probability of finding the electron is maximum
6. Nitrogen laser produces a radiation at a wavelength of near the nucleus.
337.1 nm. If the number of photons emitted is 5.6 × 1024 (3) The probability of finding the electron at a given
per/sec, calculate the power of this laser. distance is equal in all directions.
(1) 3.33 × 106 J/s (2) 3.33 × 105 J/s (4) The probability density of electrons for 2s orbital
(3) 1.56 × 106 J/s (4) 15.6 × 108 J/s decreases uniformly as distance from the nucleus
increases.

Structure of Atom 83
 11. The work function of a photoelectric material is 3.3 eV. It 21. Which among the following pair of species are isosters.
threshold frequency will be: (1) CO2 and N2 (2) O3 and N2O
(1) 7.96 × 1014 Hz (2) 7.96 × 1010 Hz (3) F2 and H2O (4) SO2 and CO
(3) 5 × 1033 Hz (4) 4 × 1011 Hz
22. The pair of ions having same electronic configuration is:
12. Which of the following statement is not correct about the
(1) Cr3+, Fe3+ (2) Fe3+, Mn2+
characteristics of cathode rays?
(3) Fe3+, Co3+ (4) Sc3+, Cr3+
(1) They start from the cathode and move towards the
anode. 23. The transition of electron in H-atom that will emit maximum
(2) They travel in straight line in the absence of an external energy is:
electrical or magnetic field. (1) n3 → n2 (2) n4 → n3
(3) Characteristics of cathode rays do not depend upon the (3) n5 → n4 (4) All have same energy
material of electrodes in cathode ray tube.
24. A ball of mass 200 gm is moving with velocity of
(4) Characteristics of cathode rays depend upon the nature
10 m.s–1. If the error in measurement of velocity is 0.1%,
of gas present in the cathode ray tube.
the uncertainity in its position is:
13. Which of the following statements about the electron is
(1) 3.3. × 10–31 m (2) 3.3 × 10–27 m
incorrect?
(3) 5.3 × 10–25 m (4) 2.64 × 10–32 m
(1) It is a negatively charged particle
(2) The mass of electron is equal to the mass of neutron 25. If waves travelling at same speeds, which of the following
(3) It is a basic constituent of all atoms matter waves have the shortest wavelength?
(4) It is a constituent of cathode rays (1) Electron (2) Alpha particle (He2+)
14. Two atoms are said to be isobars if: (3) Neutron (4) Proton
(1) They have same atomic number but different mass 26. An ion with mass number 56 and atomic number 26
number. contains 3 units of positive charge. Number of proton and
(2) They have same number of electrons but different electrons.
number of neutrons. (1) 23, 26 (2) 26, 26
(3) They have same number of neutrons but different (3) 26, 23 (4) None of these
number of electrons.
(4) Sum of the number of protons and neutrons is same but 27. A quantum of light having energy E has wavelength equal
the number of protons is different. to 7200Å. The frequency of light which corresponds to
energy equal to 3E, is:
15. A gas of monoatomic hydrogen is excited by an energy of
12.75 eV/atom. Which spectral lines of the following are (1) 1.25 × 1014 s–1 (2) 1.25 × 1015s–1
formed in Lyman, Balmer and Paschen series respectively. (3) 1.25 × 1013s–1 (4) 1.25 × 1014 s–1
(1) 3, 2, 1 (2) 2, 3, 1 (3) 1, 3, 2 (4) 1, 2, 3 28. Bond dissociation energy of AB molecules is 300 kJ/mole.
16. The number of radial nodes for 3p orbital is: The number of moles of photons of wavelength 6625Å
(1) 3 (2) 4 (3) 2 (4) 1 requires to dissociate 3 moles of AB molecules is:
(1) 1 (2) 2 (3) 4 (4) 5
17. Number of angular nodes for 4d orbital:
(1) 4 (2) 3 (3) 2 (4) 1 29. Ultraviolet light of 6.2 eV falls on Cesium surface (work
function = 1.2 eV). The kinetic energy (in electron volts) of
18. Which of the following is responsible to rule out the the fastest electron emitted is approximately:
existence of definite paths or trajectories of electrons? (1) 5 eV (2) 4 eV (3) 3 eV (4) 2 eV
(1) Pauli’s exclusion principle 30. The ionization potential of hydrogen atom is 13.6 eV.
(2) Heisenberg’s uncertainty principle The wavelength of the energy radiation required for the
(3) Hund’s rule of maximum multiplicity ionization of H-atom is:
(4) Aufbau principle (1) 1911 nm (2) 912 nm
(3) 68 nm (4) 91.2 nm
19. Total number of orbitals associated with third shell will be:
(1) 2 (2) 4 (3) 9 (4) 3 31. Each hydrogen atom is excited by giving 10.2eV. The
maximum number of spectral lines in the emission is
20. Orbital angular momentum depends on:
equal to
(1) l (2) n and l (3) n and m (4) m and s
(1) 1 (2) 2 (3) 3 (4) 4

84 P NEET Dropper Module-1 CHEMISTRY

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