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2020 NEET CHEMISTRY PAPER Rationalized & Non Rationalized B

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50 views5 pages

2020 NEET CHEMISTRY PAPER Rationalized & Non Rationalized B

Uploaded by

Aanya Punatar
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Ace Chemistry Private Tuitions

Prof Santosh Yadav’s


ACE CHEMISTRY PRIVATE TUITIONS
NEET 2020 Chemistry Paper
Note: Bold Marked Questions Are Non-Rationalised

46] Identify compound X in the following 51] The number of protons neutrons and
sequence reactions. electrons in 175 , respectively, are
71 Lu
CH3 CHO
1) 71,71 and 104
Cl2/hv H2O
X 2) 175, 104 and 71
373 K
3) 71, 104 and 71
CHCl2 CCl3 4) 104, 71 and 71

1) 2) 52] The calculated spin only magnetic moment


of Cr2+ ion is:
Cl CH2Cl
1) 5.92 BM
2) 2.84 BM
3) 4)
3) 3.87 BM
4) 4.90 BM
47] Identify a molecule which does NOT exist
1) C2 2) O2 p-block Elements
3) He2 4) Li2 53] Match the following
Polymers Oxide Nature
48] Which of the following is a natural a) CO i) Basic
polymer? b) BaO ii) Neutral
1) polybutadiene c) Al2O3 iii) Acidic
2) poly (Butadiene-acrylonitrile) d) Cl2O7 iv) Amphoteric
3) cis-1, 4-polyisoprene Which of the following is CORRECT
4) poly (Butadiene-styrene) option?
(a) (b) (c) (d)
49] An increase in the concentration of the
reactant of a reaction leads to change in: 1) (iii) (iv) (i) (ii)
1) threshold energy 2) (iv) (iii) (ii) (i)
2) collision frequency 3) (i) (ii) (iii) (iv)
3) activation energy 4) (ii) (i) (iv) (iii)
4) heat of reaction
54] Urea reacts with water to form A which will
50] Anisole on cleavage with HI gives: decompose to form B. B when passed
OH I 2+
through Cu (aq) , deep blue colour solution C
1) 2) is formed. What is the formula of C form the
+ C2H5I + C2H5OH
following?
OH I 1) Cu(OH)2
Beyond NCERT
2) CuCO3.Cu(OH)2
3) 4)
+ CH3I + CH3OH 3) CuSO4
4) [Cu(NH3)4]2+

Ace Chemistry Private Tuitions Prof. Santosh Yadav 23


Ace Chemistry Private Tuitions
s-block Elments 59] A tertiary butyl carbonation is more stable than
55] Match the following and identify the secondary butyl carbocation because of which
CORRECT option. of the following?
a) CO(g) + H2(g) i) Mg(HCO3)2+ 1) –R effect of – CH3 groups
Ca(HCO3)2 2) Hyperconjugation
b) Temporary ii) An electron 3) –I effect of – CH3 groups
hardness of deficient 4) +R effect of – CH3 groups
water hydride
c) B2H6 iii) Synthesis gas 60] Find out the solubility of Ni(OH)2 in 0.1 M
d) H2O2 iv) Non-planar NaOH Given that the ionic product of Ni(OH)2
structure is 2 ×10–15.
(a) (b) (c) (d) 1) 1 × 10–13 M 2) 1 × 108 M
1) (iii) (iv) (ii) (i) 3) 2 × 10–13 M 4) 2 × 10–8 M
2) (i) (iii) (ii) (iv)
3) (iii) (i) (ii) (iv) 61] Reaction between acetone and
4) (iii) (ii) (i) (iv) methyl magnesium chloride followed by
hydrolysis will give:
56] The mixture which shows positive deviation 1) Tert. Butyl alcohol 2) Isobutyl alcohol
form Raoult’s law is: 3) Isopropyl alcohol 4) Sec. butyl alcohol
1) Acetone + Chloroform
2) Chloroethane + Bromoethane 62] Which of the following amine will give the
3) Ethanol + Acetone carbylamines test?
4) Benzene + Toluene N(CH3)2 NHC2H5

57] The freezing point depression constant (Kf) of 1) 2)


benzene is 5.12 K kg mol–1. The freezing point
depression for the solution of molality 0.078 m
NH2 NHCH3
containing a non-electrolyte solute in benzene
is (rounded of upto two decimal places):
3) 4)
1) 0.40 K 2) 0.60 K
3) 0.20 K 4) 0.80 K

58] Which of the following set of molecules will 63] An Alkene on ozonolysis gives methanol as
have zero dipole moment? one of the products. Its structure is:
1) Nitrogen trifluoride, beryllium difluoride, H2C CH CH2 CH2CH2CH3
water, 1,3-dichlorobenzene
2) Boron trifluoride, beryllium difluoride, 1) 2)
carbon dioxide, 1,4-dichlorobenzene
3) Ammonia, beryllium difluoride, water, CH CH CH3 CH2 CH2 CH3
1,4-dichlorobenzene
4) Boron trifluoride, hydrogen fluoride, carbon 3) 4)
dioxide, 1,3-dichlorobenzene .

Ace Chemistry Private Tuitions Prof. Santosh Yadav 24


Ace Chemistry Private Tuitions
States of Matter p-block Elements
64] A mixture of N2 and Ar gases in a cylinder 70] Which of the following is NOT CORRECT
contains 7g of N2 and 8g of Ar. If the total about carbon monoxide?
pressure of the mixture of the gases in the 1) The carboxyhaemoglobin (haemoglobin
bound to CO) is less stable than
cylinder is 27 bar, the partial pressure of N2
oxyhaemoglobin
is 2) It is produced due to incomplete
[Use atomic masses (in g mol–1): N = 14, combustion
Ar = 40] 3) It forms carboxyhaemoglobin
1) 15 bar 2) 18 bar 4) It reduces oxygen carrying ability of
3) 9 bar 4) 12 bar blood
71] Hydrolysis of sucrose is given by the
65] Which of the following is the CORRECT
following reaction.
order of increasing field strength of ligands
to form coordination compounds? Sucrose + H2O Glucose + Fructose
If the equilibrium constant (Kc) is 2 × 1013 at
1) F– < SCN– < C 2 O 24 − < CN–
300K, the value of rGo at the same
2) CN– < C 2 O 24 − < SCN– < F– temperature will be:
1) 8.314 J mol–1 K–1 × 300 K × ln(3 × 1013)
3) SCN– < F– < C 2 O 24 − < CN–
2) –8.314 J mol–1 K–1 × 300 K × ln(4 × 1013)
4) SCN– < F– < CN– < C 2 O 24 − 3) –8.314 J mol–1 K–1 × 300 K ×ln(2 × 1013)
4) 8.314 J mol–1 K–1 × 300 K × ln(2 × 1013)
66] Paper chromatography is an example of:
1) Thin layer chromatography 72] HCl was passed through a solution of CaCl2,
2) Column chromatography MgCl2 and NaCl. Which of the following
3) Adsorption chromatography compound (s) crystallise(s)?
4) Partition chromatography 1) Only MgCl2
2) NaCl, MgCl2 and CaCl2
67] Sucrose on hydrolysis gives: 3) Both MgCl2 and CaCl2
1) -D-Glucose + -D-Fructose 4) Only NaCl
2) -D-Fructose + -D-Fructose
3) -D-Glucose + -D-Fructose Solid States
4) -D-Glucose + -D-Glucose 73] An element has a body centered cubic
(bcc)structure with a cell edge of 288 pm.
68] The rate constant for a first order reaction is The atomic radius is:
4.606 × 10–3 s–1. The time required to reduce 4 4
2.0 g of the reactant to 0.2 g is: 1)  288 pm 2)  288 pm
3 2
1) 500s 2) 1000s
3 2
3) 100s 4) 200s 3)  288 pm 4)  288 pm
4 4
69] Reaction between benzaldehyde and
acetophenone in presence of dilute NaOH is p-block Elements
known as: 74] Which of the following oxoacid of sulphur
1) Cross Cannizzaro’s reaction has – O – O – linkage?
2) Cross Aldol condensation 1) H2S2O8, peroxodisulphuric acid
3) Aldol condensation 2) H2S2O7, pyrosulphuric acid
4) Cannizzaro’s reaction 3) H2SO3, sulphurous acid
4) H2SO4, sulphuric acid

Ace Chemistry Private Tuitions Prof. Santosh Yadav 25


Ace Chemistry Private Tuitions
75] Identify the INCORRECT statement. 80] Which of the following is a basic amino acid?
1) Interstitial compounds are those that are 1) Tyrosine
formed when small atoms like H, C or N 2) lysine
are trapped inside the crystal lattices of 3) Serine
metals 4) Alanine
2) The oxidation states of chromium in CrO 24 −
81] Identify the INCORRECT match
And Cr2O72− are not the same
Name IUPAC official
3) Cr2+ (d4) is a stronger reducing agent than Name
Fe2+ (d6) in water a) Unnilunium i) Mendelevium
4) The transition metals and their compounds
b) Unniltrium ii) Lawrencium
are known for their catalytic activity due to
c) Unnilhexium iii) Seaborgium
their ability to adopt multiple oxidation
d) Unununnium iv) Darmstadtium
states and to form complexes
1) (c), (iii) 2) (d), (iv)
3) (a), (i) 4) (b), (ii)
Chemistry in Everyday Life
76] Which of the following is a cationic 82] Which of the following alkane CANNOT be
detergent? made in good yield by Wurtz reaction?
1) Cetyltrimethyl ammonium bromide 1) n - Heptane 2) n-Butane
2) Sodium dodecylbenzene sulphonate 3) n-Hexane 4) 2,3-Dimethylbutane
3) Sodium lauryl sulphate
4) Sodium stearate 83] Elimination reaction of 2-Bromopentane to
form pent-2-ene is:
77] The CORRECT option for free expansion
of an ideal gas under adiabatic condition is: a) -Elimination reaction
1) q < 0, T = 0 and w = 0 b) Follows Zaitsev rule
2) q > 0, T > 0 and w > 0 c) Dehydrohalogenation reaction
3) q = 0, T = 0 and w = 0 d) Dehydration reaction
4) q = 0, T < 0 and w > 0 1) (b), (c), (d)
2) (a), (b), (d)
78] On electrolysis of dil. Sulphuric acid using 3) (a), (b), (c)
Platinum (Pt) electrode, the product obtained 4) (a), (c), (d)
at anode will be:
1) H2S gas 2) SO2 gas 84] The number of faradays(F) required to
3) Hydrogen gas 4) Oxygen gas produce 20 g of calcium from molten CaCl2
(Atomic mass of Ca = 40g mol–1) is:
Metallurgy 1) 3 2) 4
79] Identify the CORRECT statement form the 3) 1 4) 2
following:
1) Vapour phase refining is carried out for 85] Which one of the followings has maximum
Nickel by Van Arkel method number of atoms?
2) Pig iron can be moulded into a variety of 1) 1g of O2(g) [Atomic mass of O = 16]
shapes 2) 1g of Li(s) [Atomic mass of Li = 7]
3) Wrought iron is impure iron with 4% 3) 1 g of Ag(s) [Atomic mass of Ag = 108]
carbon 4) 1g of Mg(s) [Atomic mass of Mg = 24]
4) Blister copper has blistered appearance
due to evolution of CO2

Ace Chemistry Private Tuitions Prof. Santosh Yadav 26


Ace Chemistry Private Tuitions
86] For the reaction 2Cl(g) ⎯⎯
→ Cl2(g), the s-block Elements
CORRECT option is: 90] The following metal ion activates many
1) rH < 0 and rS > 0 enzymes, participates in the oxidation of
2) rH < 0 and rS < 0 glucose to produce ATP and with Na,
responsible for the transmission of nerve
3) rH > 0 and rS > 0
singles.
4) rH > 0 and rS < 0
1) Calcium
2) Potassium
p-block Elements
3) Iron
87] Identify the CORRECT statement from the
4) Copper
following?
(a) CO2(g) is used as refrigerant for ice
cream and frozen food.
(b) The structure of C60 contains twelve six-
carbon rings and twenty-five carbon
rings.
(c) ZSM−5, a type of zeolite, is used to
convert alcohol into gasoline.
(d) CO is a colorless and odourless gas
1) (b) and (c) only
2) (c) and (d) only
3) (a), (d) and (c) only
4) (a) and (c) and

Surface Chemistry
88] Measuring Zeta potential is useful in
determining which property of colloidal
solution?
1) Stability of the colloidal particles
2) Size of the colloidal particles
3) Viscosity
4) Solubility

89] What is the change in oxidation number of


carbon in the following reaction?
CH4(g) + 4Cl2(g) ⎯⎯ → CCl4( l ) + 4HCl(g)
1) –4 to +4
2) 0 to –4
3) +4 to +4
4) 0 to +4

Ace Chemistry Private Tuitions Prof. Santosh Yadav 27

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