THORNTON

Leading Pure Water Analytics

Smart TOC Sensor
5000TOCe Sensor Enhanced
Fast, continuous measurements
No reagents or chemicals needed
No moving parts
Meets USP 〈643〉, 〈645〉,
EP 2.2.44, and JP requirements
Compact wall-mount sensor design/
NEMA 4X enclosure for skid
mounting
770MAX Multiparameter Smart
Sensor compatible

Continuous On-Line Measurements

Total Organic Carbon Monitoring
 Features
• Advanced UV lamp design extends stability and wavelength emission over lamp life
• Sample Conditioning Coil (included) can prevent C02 permeation into the water sample and will stabilize inlet
flow, pressure and temperature irregularities
Smart TOC Sensor

• On-line continuous measurements, no batch measurement cycle

• 770MAX Smart Sensor interface
• Two TOC Sensors connect to one 770MAX, with four channels remaining for other available sensors
• Local LED Sensor status indication
• Integrates standard 770MAX Multiparameter Instrument features with specific TOC sensor functions
- UV Lamp run time status and UV Lamp ON/OFF control
- Fault and Error messages for TOC measurement
- TOC Sensor key lock function for safe operation
- Auto start function allows TOC Sensor to start automatically after power interruption

Benefits
• Continuous flow design provides rapid TOC response with complete oxidation
• No gases or reagents to handle, store or replace and no moving parts minimize routine maintenance and
service intervals
• Smart sensor design reduces installation and setup time
• Real-time continuous monitoring for precise data trending and better process control
• Wide dynamic operating range meets the needs of pure and ultrapure water applications
• Meets USP 〈643〉, 〈645〉, EP 2.2.44 and JP requirements for the Pharmaceutical Industry
• Sensor platform allows easy integration into water purification make-up and distribution system designs
• Ultra low TOC detection for ultrapure water applications to continuously monitor critical organic levels in
Semiconductor make-up, distribution and process systems
• Two TOC measurement points with one 770MAX instrument to manage performance of various unit processes
within water purification systems
• Compact NEMA 4X rated enclosure for demanding industrial environments
• Meets ASTM D5173 standard test method for on-line TOC monitoring
• Conductivity/temperature sensor and measurements traceable to NIST and ASTM D1125 and D5391

Applications
Pure and Ultrapure water production requires monitoring of organic contamination throughout the treatment
process. The 5000TOCe Sensor provides continuous, fast, and reliable monitoring of TOC levels from post RO
waters to point-of-use. With continuous on-line measurements, the 5000TOCe Sensor ensures TOC excursions
will not be missed.

Pharmaceutical-grade waters must meet strict water quality requirements. This highly regulated industry man-
dates the monitoring of Total Organic Carbon levels for PW (Purified Water), WFI (Water for Injection) and HPW
(Highly Purified Water). The instruments used in this application must also undergo periodic testing to verify the
ability to completely oxidize and accurately measure TOC. Testing requirements are described in the USP Chapter
〈643〉 and EP 2.2.44. The 5000TOCe Sensor provides the performance needed to meet these requirements, and
USP 〈645〉 for conductivity, while offering added benefits such as continuous on-line measurement in a low-
maintenance, industrial package. The 5000TOCe Sensor can operate at elevated temperatures to 100°C, where
steam and periodic hot water sanitizing is required.

Semiconductor manufacturing processes have some of the most stringent specifications for organic contamina-
tion in pure and ultrapure water systems. Use the 5000TOCe Sensor throughout the plant to monitor the integrity
of reverse osmosis membranes, the effectiveness of TOC destruct UV lamps, resin bed performance, organics
shedding, and the quality of the final rinse water.

Recycle and reclaim applications take advantage of the fast analysis time. The 5000TOCe Sensor provides con-
tinuous monitoring, not lengthy batch cycles. This provides the system operator with time to respond to TOC
excursions due to process variability.

Power generation makeup water treatment – from reverse osmosis to demineralizers, the 5000TOCe Sensor
provides fast reliable monitoring of TOC contamination in the water system. Organic contamination, can be
detected before it enters the steam cycle where its breakdown to organic acids can accelerate corrosion.

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Dimensional Data

Allow Minimum Clearance

of 18 in. [457] for UV
Lamp Replacement

Regulator
Not Shown

5000TOCe Sensor Dimension Diagram

Dimensions in Inches [mm]

5000TOCe Sensor Installation

The Thornton 5000TOCe Sensor minimizes installation and setup time. Two tubing connections are required, one for the sample
inlet, and one for the oxidized sample outlet. An isolation valve is recommended at the sample point for shutoff, as needed (valve
not supplied by Thornton).

Process Pipe Process

Pipe
Cross-Section

Isolation Valve

Regulator
(Optional)

Recommended

Sample
Safety Drain Drain

Atmospheric
Drain

Dimensions in inches and [mm]

3
 5000TOCe Performance Specifications

TOC Sensor
Measurement Range 0.05 - 1000 ppbC (µgC/L)
Accuracy ± 0.1 ppb C for TOC < 2.0 ppb (for water quality > 15 MΩ-cm [.067 µS/cm])
± 0.2 ppb C for TOC > 2.0 ppb and < 10.0 ppb (for water quality > 15 MΩ-cm)
± 5% of measurement for TOC > 10.0 ppb (for water quality 0.5 to 18.2 MΩ-cm)
Repeatability ± 0.05 ppb C < 5 ppb, ± 1.0% > 5 ppb
Resolution 0.001 ppbC (µgC/L)
Analysis Time Continuous
Initial response time < 60 seconds
Limit of Detection 0.025 ppbC
Conductivity Sensor
Cell Constant Accuracy ± 2%
Temperature Sensor Pt1000 RTD, Class A
Temperature Accuracy ± 0.25°C
Sample Water Requirements
Temperature 0 to 100 °C *
Particle Size <100 micron
Minimum Water Quality > 0.5 MΩ–cm (< 2 µS/cm), pH < 7.5 **
Flow Rate > 20 mL/min
Pressure 4 to 200 psig (0.3 bar to 13.6 bar) at sample inlet connection ***
General Specifications
Case Dimensions 11" [280mm] W x 7.4" [188mm] H x 5.25" [133mm] D
Weight 5.0 lb. (2.3 kg)
Enclosure material Polycarbonate plastic, flame retardant, UV and chemical resistant
UL # E75645, Vol.1, Set 2, CSA #LR 49336
Enclosure rating NEMA 4X, IP65 Industrial environment
Ambient Temperature/ 5 to 50°C / 5 to 80% Humidity, non-condensing
Humidity rating
Power requirements 100 - 130VAC or 200 - 240VAC, 50/60 Hz, 25W Maximum
Local Indicators Four LED lights for Fault, Error, Sensor Status and UV Lamp ON
Ratings/Approvals CE Compliant, UL and cUL (CSA Standards) listed, NEMA 4X, IP65
Conductivity and temperature sensors traceable to NIST, ASTM D1125 and
D5391. Meets ASTM D5173 Standard Test Method for On-Line Monitoring of
Carbon Compounds in Water by UV Light Oxidation
Sample Connections
Inlet connection 0.125" [3mm] O.D. (6' [2m] FDA compliant PTFE tubing supplied)
Outlet connection 0.125" [6mm] O.D. Barb connection (5' [1.5m] flexible tubing provided)
Inlet Filter 316SS, inline 60 micron
Wetted parts 316SS/Quartz/PEEK/Titanium/PTFE/Polyurethane (outlet tubing only)/EPDM
Wall Mount Standard, mounting tabs provided
Pipe Mount Optional, with pipe-mount bracket accessory
(for nominal pipe sizes 1" [2.4 cm] to 4" [10 cm])
Maximum Sensor Distance 300ft [91m]
* Temperature above 70°C requires Sample Conditioning Coil (included)
** For power plant cycle chemistry samples, pH may be adjusted by measurement after cation exchange.
*** Process pressure above 85 psig (5.9 bar) requires optional High Pressure Regulator p/n 58 091 552.
Specifications subject to change without notice.

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770MAX Capability
The 5000TOCe Sensor uses Smart Sensor technology interfacing with the 770MAX Multiparameter Analyzer/Transmitter. The
770MAX instrument will allow up to two 5000TOCe Sensors to be connected to any of the four Smart input channels, leaving the
two remaining channels for use with all other 770MAX Smart Sensors. The 770MAX also provides two pulse input channels for
additional flow measurements. The Sensor connects directly to the 770MAX instrument using standard patch cables.

The 5000TOCe Sensor is designed to meet the requirements of today's industrial facilities with its UL rating and NEMA 4X enclo-
sure. Combined with the 770MAX instrument it provides the most versatile and flexible TOC measurement platform available.

2 Pulse Input channels

770MAX
(Six-Channel inputs)

Smart Channel
Smart Channel

Smart Channel
Smart Channel

Other Smart Sensors available for:

5000TOCe 5000TOCe
• Conductivity/Resistivity
• pH/ORP
• Flow
• Dissolved Oxygen
• Temperature
• Pressure
• Level
• Dissolved Ozone

Measurement technology - UV Oxidation / Differential Conductivity

The 5000TOCe Sensor uses proven ultraviolet oxidation with differential conductivity (see schematic below) as the method to effec-
tively determine TOC concentrations. High performance Thornton conductivity sensors provide continuous conductivity measurement
before and after sample oxidation. This is accomplished using a continuous flow-through spiral quartz tube design that allows the
sample to flow continuously through the sensor. This design maximizes exposure to the 185 nanometer UV light, while minimizing
measurement response time and providing complete oxidation. This simple and effective design requires no reagents or chemicals
and includes no moving mechanical components.

Quartz Coil

UV oxidation
Conductivity Conductivity
Sensor (1) Sensor (2)

UV Lamp

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5000TOCe Sensor Ordering information
Description Part No.
5000TOCe Sensor, 110 VAC, 50/60 Hz 58 036 001
5000TOCe Sensor, 220 VAC, 50/60 Hz 58 036 002
5000TOCe Sensor for low TOC 110 VAC, 50/60 Hz 58 036 003
5000TOCe Sensor for low TOC 220 VAC, 50/60 Hz 58 036 004
Accessories
Printer, Serial Thermal, 110V * 58 079 010
Printer, Serial Thermal, 220V * 58 079 011
Kit, Tool, 5000TOCe Sensor 58 091 520
Kit, Pipe mounting, for 1-1/2” nominal pipe size 58 091 521
Kit, Pipe mounting, for 2” nominal pipe size 58 091 522
Kit, Pipe mounting, for 3” nominal pipe size 58 091 523
Kit, Pipe mounting, for 4” nominal pipe size 58 091 524
Adapter, 0.25” tube to 0.125” tube, compression type 58 091 540
Adapter, 0.125” tube to 0.25” NPT-male connection 58 091 541
Adapter, 0.125” tube to 0.25” NPT-female connection 58 091 542
Adapter, 0.125” tube to 0.5” 316 Stainless Steel pipe (0.75” Tri-Clamp Connection) 58 091 543
High Pressure Inlet Regulator, 1/4” NPT-female 58 091 552
Outlet Drain Tube 58 091 553
System Suitability and Calibration
Kit, Calibration & System Suitability Test (SST & Calibration Standards Sold Seperately) 58 091 559
Validation Support Package 58 091 558
Combined System Suitability Standards and Calibration Solutions Set 58 091 537
(Use with SST/Cal Kit 58 091 559. Includes solutions from 58 091 526 & 58 091 529)

System Suitability Standards (for use with SST/Cal Kit 58 091 559, includes 58 091 526
500 ppb as Sucrose, 500 ppb as p-Benzoquinone and reagent water for one test)

Calibration Solutions (for use with SST/Cal Kit 58 091 559, includes 58 091 529
500 ppb as Sucrose, 250 ppb as Sucrose verification, and reagent water)

Replacement Parts
Replacement Inlet Filter Element, 60 micron (Pkg.2) (Recommended w/ lamp change) 58 091 551
Replacement UV lamp (recommended every 4500 hours of operation) 58 079 513
Kit, Fuse, Sensor PCB (for use on both 110 and 220 VAC models) 58 091 519
Replacement thermal paper (for printer) 58 079 012
* Printer connects to 770MAX RS-232 Serial output.

Product Support
The following 5000TOCe products and services are also available:
• Factory Instrument Calibration • Customized Hands-On-Training
• Service and Calibration Contracts • System Suitability Testing
• On-Site Calibration
Please contact your local Mettler-Toledo Thornton office for more information.

www.mt.com/thornton
Visit for more information

Mettler-Toledo Thornton, Inc. Quality certificate.

36 Middlesex Turnpike Development, production and
Bedford, MA 01730 USA testing to ISO 9001.
Tel. +1-781-301-8600
Fax +1-781-301-8701
A certified ServiceXXL provider.
Toll Free +1-800-510-PURE (US and Canada only)
thornton.info@mt.com

CE Compliant
Subject to technical changes
© Mettler-Toledo Thornton, Inc.
ML0138 Rev.C 06/10 UL listed
Meets Canadian Standards