Q) Potassium permanganate and potassium dichromate are two

transition metal compounds.

a) Write any four characteristics of transition metals.
b) Write any two uses of potassium permanganate.
c) Draw the structure of dichromate ion. Cr0-

a) Transition elements are all metals, they show variable oxidation states,
they form coloured compounds and most of them are paramagnetic.

b) It is used as an oxidising agent in acidic, basic and neutral medium.

It is used as a primary standard in volumetric analysis.
2-

[ ·
O
S
es
-0 -
=J
Q) Write the structural formula of aldol formed from ethanal.
OH

2CHCHONH CH3-CH-CHL-CHO >

-

CH3-CH = CH-CHO
C
-Ho
CH-CHO
CH3CH =

-
 ①
CH3CHO + CHaHz-CHONgH
0 - 0
CHO
CH3-CH = CH -

② ②
-CHO
CHCHe-Ch =

citz
① +
CHO
CH-CH = c -

②
- Q
ciz
CHCH2CH CH-CHO
=
Q) Write the reactions of carboxylic acid with the following reagents.
(Write the chemical equations)

(i) Thionyl chloride (SOCl₂)

(ii) Chlorine in presence of small amount of red phosphorous.
(iii) Lithium Aluminium hydride (LiAlH₄)/ether.

&) CHOOH + sock > CH5c0 2

- -
+ sa + Hc)

Redy
CHS-COOH CHe-cook
2)
I
③ CHz-cool
as CH5CH2-of
Q) Complete
It
the following reactions:
alpha
a)
NO CH5OH + HCOOK
b) CH3CH CH-CHO
=

c) CH3CH = N-NH2
d)
Clts-CH-CH3
-
Q) Write the product in the following reaction

COOH
L
Q) Write the major product in the following
CHO
X
Nt No
N-OH

i
CH3-
=

-
Q) Carboxylic acids do not undergo Friedel-Craft’s reaction. Why?

This is because the carboxyl group is deactivating and the

catalyst aluminium chloride forms salt with the carboxyl group.

· I

# c Al +
Q) Identify A and B in the following reaction:

2
# CHO
+ Conc.NaOH A + B
CH2-OH
t Econ
Q) Identify the product:
CH₃MgX / H₂O
HCHO …………….

i) CH₃OH -
-
ii) CH₃CH₂OH

iii) CH₃-CH-CH₃
OH
iv) CH₃-CH-CH₂-CH₃
He
CHg-CH2-gx
OH
not CH5-CH2-OH
-
Mg(OH) X
Q) Draw optical isomers of [Cr(C₂O₄)₃]³- word
N
.

c
I O
ad
COn
 How are the following conversions carried out?
Q) Represent the chemical reactions. [0]
CrO3
a) Ethanol to ethanal a) CH3-CH-OH-CH3CHO
b) Phenol to picric acid OH off
c) Phenol to benzene
YANO NO
No
d) Phenol to tribromophenol
off
Na
>
of OH
By-xBr
d) M
S

ine water
> -
No
I
Bu
Q) Describe the method of preparation of potassium dichromate
(K₂Cr₂O₇) from chromite ore.

Step 1 : Conversion of chromite ore to sodium chromate.

4 FeCryOu + 8NacCOs + 702 >

-

8NagerOu + Geog + 8 CO2

Step 2 : Acidification of sodium chromate to sodium dichromate

2 Nay Cr On >
#
NacCra0y + ZNa + HO

Step 3 : Conversion of sodium dichromate to potassium dichromate

NacC0, + 2kd > Nad

Ker + 2
-
Q) In a coordination entity, the electronic configuration of the central
=> octahedral
metal ion is t2g³ eg¹.
Draw the crystal field splitting diagram for the above complex.

obstet
eg

↑
-

#-------
/state t - OhDo

1
#
state I
tag
Q) Mixture of Conc. HCl and anhydrous ZnCl₂ is an important
reagent which helps to distinguish between 1⁰, 2⁰ and 3⁰
alcohols. Give the name of the reagent.

come . HCl + Anky Zach2

.
CC-OH
*

Lucas Reagent B
C
- c -
o

c 20

BC

B)-
Q) Write the IUPAC name of the following :
·

o -Tetracarbonylnickel (o)
(i) [Ni(CO)₄]
+4 -
6
(1)
hexacyanoferrate
4 +2 - 1
(ii) K₄[Fe(CN)₆] -

Potassium
.

-
All the best..!!
Macas