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If a trivalent impurity like indium is added in pure semi-
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conductor, the impurity atom can provide only three valence
electrons for covalent bond Start yourformation.
30 day free trial Thus a gap is left in
one of the covalent bonds.
The gap acts as a hole that tends to accept electrons. As the
trivalent impurity atoms accept electrons from the silicon
crystal, it is called acceptor impurity. The holes so created
are extrinsic carriers and the p-type Si-crystal so obtained is
called p-type extrinsic semiconductor. Again, as the pure Si-
crystal also possesses a few electrons and holes, therefore, the
p-type si-crystal will have a large number of holes (majority
carriers) and a small number of electrons (minority carriers).
It terms of valence and conduction band one can think that all
such holes create an accepter energy level just above the top
of the valance band as shown in figure. The electrons from
valence band can raise themselves to the accepter energy
level by absorbing thermal energy at room temperature and in
turn create holes in the valence band.
Number density of valence band holes (nh) in p-type
semiconductor is approximately equal to that of the acceptor
atoms (Na) and is very large as compared to the number
density of conduction band electrons (ne). Thus,
nh Na > > ne

electrical resistivity of semiconductors

Consider a block of semiconductor of length l1 area of cross-


section A and having number density of electrons and holes as

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ne and nh respectively. Suppose that on applying a potential
difference, say V, aUpload your documents
current I flows to download.
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(i)
It ne is the number density of conduction band electrons in the
semiconductor and ve, the driftStart your 30of
velocity dayelectrons
free trial then
Ie = eneAve
Similarly, the hole current, Ih = enhAvh
From (i) I = eneAve + enhAvh
I = eA(neve + nhvh) (ii)
If  is the resistivity of the material of the semiconductor, then
the resistance offered by the semiconductor to the flow of current is given by :
R =  l/A (iii)
Since V = RI, from equation (ii) and (iii) we have
V = RI =  l/A eA (neve + nh vh)
V =  le(neve + nhvh) (iv)
If E is the electric field set up across the semiconductor, then:
E = V/l (v)
from equation (iv) and (v), we have
E = e (neve + nhvh)
1/ = e (ne ve/E + nh vh/E)
On applying electric field, the drift velocity acquired by the electrons (or
holes) per unit strength of electric field is called mobility of electrons (or
holes). Therefore,
mobility of electrons and holes is given by :
e = ve/E and h = vh/E
1/ = e(ne e + nh h) (vi)
Also, = 1/ is called conductivity of the material of semiconductor
 = e (ne e + nh h) (vii)

The relation (vi) and (vii) show that the conductivity and
resistivity of a semiconductor depend upon the electron and hole number
densities and their mobilities. As ne and nh increases with rise in temperature,
therefore, conductivity of semiconductor increases with rise in temperature
and resistivity decreases with rise in temperature.

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