15-12-2024

1001CJA101021240028 JA

PART-1 : PHYSICS

SECTION-I

1) Find the work and power required to move the conductor shown in figure, one full turn in the
positive direction at a rotational frequency of N revolutions per minute, if , where is

radially outward from the axis of the cylinder shown.

(A) Work = 4πrB0I L

(B) Work = 2πrB0I L

(C)

(D)

2) A solenoid with N1 = 1000, r1 = 1.0 cm, and is concentric within a second coil of N2 =
2000, r2 = 2.0 cm, and . Find the mutual inductance assuming free-space conditions.

(A) 1.58 mH
(B) 2.53 mH
(C) 3.20 mH
(D) 4.65 mH

3) Assertion (A) : KVL rule is applicable in AC circuit shown below.

 Reason (R) : VC (Voltage across capacitor) in the circuit = 2V
(Take all voltages shown as RMS)

(A) Both the assertion and reason are true and reason is a true explanation of the assertion.
Both the assertion and reason are true but the reason is not true the correct explanation of the
(B)
assertion.
(C) Assertion is true but Reason is false.
(D) Both the Assertion and Reason are false.

4) The below graph shows the average power Pav against the frequency of the driving force acting on

an oscillator. Consider the following statements:

(1) The sharpness of the peak at resonance is determined by the damping constant.

(2) The sharpness of resonance is defined by .

(3) The peak occurs at the frequency of velocity resonance when the power absorbed by the
oscillator from the driving force is maximum.
Which of these statements are correct?

(A) (1) and (2)

(B) (2) and (3)
(C) (1) and (3)
(D) (1), (2) and (3)

5) An object of mass 2 kg hangs from a spring of negligible mass and spring constant of 800 N/m.
The spring is extended by 2.5 cm when the object is attached. The top end of the spring is oscillated
up and down in SHM with an amplitude of 2 mm. The damping constant is γ = 0.5 sec–1. The
amplitude of forced oscillations (in cm) when forced frequency is equal to natural frequency, is :-

(A) 1
(B) 2
(C) 3
(D) 4

6) In a damped forced oscillation, if the damping coefficient b is increased, what is the effect on the
resonant frequency ωr compared to the natural frequency ω0?

(A) ωr = ω0
(B) ωr < ω0
(C) ωr > ω0
(D) ωr is independent of b

7) The magnitude of the field in a two dimensional x-y plane, is inversely proportional to distance

from the origin and field at point P has magnitude given by , where K is positive constant. A
wire carrying current I is laid in xy plane with its ends at point A(–1, +1) and point B(1, 3). Then

force on wire AB is :-

(A)

(B)

(C)

(D)

8) A uniform magnetic field B exists perpendicular to the plane of the Figure in a circular region
of radius b with its centre at O. A circular conductor of radius a (< b) and centre at O is made by
joining two semicircular wires ABC and ADC. The two segments have same cross section but
different resistances 10 Ω and 5 Ω respectively. The magnetic field is increased with time and there
is an induced current in the conductor.

(A) The ratio of electrostatic fields inside the conductors ABC and ADC is 3.
(B) The ratio of electrostatic fields inside the conductors ABC and ADC is 1 : 2.
(C) Charge accumulated at junction A is negative and that is at C is Positive.
(D) Potential difference between A and C is half of the total EMF induced in the ring.

9) Three A.C. voltmeters are connected in a circuit as shown in figure. Reading of voltmeters are, V1
= 260 V, V2 = 125 V and V3 = 240 V. All voltmeters are drawing negligible current from the circuit.
Find the ratio of inductive reactance to capacitive reactance. Assuming circuit is more inductive.

(A) 0.24
(B) 4.2
(C) 4.00
(D) 1.25

10) A regular tetrahedron is made of constant resistance per unit length 'λ'. The length of each side
is 'ℓ'. An ideal cell of emf 'V' is connected across AB. The magnitude of the magnetic field due to the
wire 'ABC' at the centroid of the triangle ABC is ______ tesla. (consider only the contribution of

triangle ABC) (Given : λ = 2 Ω/m, ℓ = 1 m, V = 10 volts)

(A) 0
(B) 2
(C) 4
(D) 8

11) Circuit shown consists of two resistance R1 and R2 of equal and fixed value, a variable R, a
capacitor C and an alternating voltage source. If the variable resistance is made to vary over a wide

range than :-

(A) Peak voltage between A and B is uniform when R changes from 0 to ∞.

(B) Peak voltage between A and B is first decrease then increase when R changes from 0 to ∞.
(C) Peak voltage between A and B is increasing continuously when R changes from 0 to ∞.
(D) Peak voltage between A and B is decreasing continuously when R changes from 0 to ∞.

12) For the given figure which options is not correct?

(A)
Induced emf along the metal wire is .
(B) induced electric field is non zero outside the cylinder.
(C) Deflection shown by the voltmeter is zero.
(D) Deflection shown by the voltmeter is non-zero.

13) For a series LCR circuit given graph drawn between current i and angular frequency of AC

source applied. Then which option is incorrect ?

(A) At resonance, angular frequency .

(B) When ω = ω then source voltage lead by from circuit current.

2

(C) When ω = ωr then power factor of circuit is 1.

(D)
When ω = ω1 then power factor of circuit is .

14) Two identical superconducting rings are co-axially placed vary close (infinitesimally small
separation) to each other. Each of the coils has inductance L and carries a current I0 in the same
direction. Mutual induction between two loops is L then choose incorrect alternative. (Take the

mutual inductance of the system to be equal to L initially)

(A) Current in each coil is 2I0 when separation between them is infinitely large.
(B) Flux linked with each coil remains same when they are at infinitely large.
Minimum work done by an external agent has to be done in making their separation infinitely
(C)
large is .
(D) Current in each coil remains same when they are at large separation.

15) Statement-I : In a region of time varying magnetic field two charges of same magnitude moves
A to B in clockwise and anticlockwise manner. Work done in clockwise path is not equal to work
done in anticlockwise path.
Statement-II : Work done in electrostatic field is independent of path.
(A) Both statement are true but statement-II is correct explanation of statement-I.
(B) Both statement are true but statement-II is not correct explanation of statement-I.
(C) Statement I is true but statement II is false.
(D) Both the statements I and II are false.

16) Friction coefficient between a ring of mass m & radius R and ground is μ. Find time when ring

will start rotating if charge density on ring is λ & magnetic field throughout the radius r > R.

(A)

(B)

(C)

(D)

17) Loop P of radius (r << R) moves towards loop Q with a constant velocity 'v' in such a way that
their planes are always parallel. At what separation between the two loops is the induced emf in loop

P maximum? [Given: v = 10 m/s, R = 4 m]

(A) 4m
(B) 2m
(C) 1m
(D) 0.5m

18) Find potential difference across inductor at time when P.D. across source becomes half of
maximum.

(A) 96.5 V
(B) 100 V
(C)
(D)

19) Correct phasor diagram for below AC circuit is (Given: IL > IC) [I0 → source current]

(A)

(B)

(C)

(D)
20) Find ammeter reading.

(A) 2A
(B)

(C)

(D) 1A

SECTION-II

1) An inductor, capacitor and resistance are connected in parallel with a conducting wire. At t = 0
capacitor is uncharged and there is no current in inductor. Conducting wire PQ is moving with
constant velocity 1 m/s. Find work done (in J) by the external force on the wire PQ in first 3 seconds.

2) As shown in figure, a hollow cone and a hemispherical shell are joined together. Mass of each is
2 kg and combined body is rotating about its axis with angular speed 200 rad/sec. 3 Coulomb charge
is uniformly distributed over the entire surface. Find magnetic dipole moment (in Am2) of the system
if R = 20 cm and h = 40 cm.

3) In the given circuit, we are interested in measurement of voltage across capacitor. Assuming very
low damping and steady state, the value of R for which voltage amplitude across capacitor is

maximum, is given by in ohm. Find x.

4) An industrial load is modeled as a series combination of an inductor and resistance as shown in

the figure. Calculate the value of capacitance C (in µF) across the series combination so that the net

impedance is resistive at an angular frequency ω = 2000 rad/s.

5) A uniform ring of mass M and radius R carries a current I (see figure). The ring is suspended
using two identical strings OA and OB. There exists a uniform horizontal magnetic field B0 parallel to

the diameter AB of the ring. Calculate the ratio of the tension in the two strings. [Given: θ =
 0

60°, M = 1 kg, g = 10 m/s2, r = m, B = 1 T, I = 1 A]

PART-2 : CHEMISTRY

SECTION-I

1) For He+ ion in 1st excited state, select the correct statement(s) :
(P) P.E. in 1st excited state is – 13.6 eV
(Q) K.E. in 1st excited state is 13.6 eV
(R) Total energy in 1st excited state is – 13.6 eV

(A) P, Q, R
(B) P, Q
(C) Q, R
(D) P

2) Ln,z = orbit angular momentum for nth orbit of hydrogen and hydrogen like species then calculate

ratio of

(A) 1 : 1
(B) 2 : 1
(C) 1 : 2
(D) 2 : 3

3) Assertion: The boiling points of aldehydes and ketones are higher than hydrocarbons and ethers
of comparable molecular masses.
Reason: Absence of inter molecular hydrogen bonding in aldehydes and ketones.

(A) Both assertion and reason are true and reason is a correct explanation of the assertion.
Both assertion and reason are true but the reason is not the correct explanation of the
(B)
assertion.
(C) Assertion is true but reason is false
(D) Assertion is false but reason is true

4) Total number of nodal surfaces in 5px orbital is

(A) 2
(B) 3
(C) 1
(D) 4

5) Proposed mechanism for decomposition of O3 is given as :

Net reaction :

O3 O2 + O (fast equilibrium)
O + O3 2O2 (slow)
Some informations are :
(P) Overall order of the reaction is 3/2
(Q) Overall order of the reaction is 1
(R) Increasing O2 concentration decreases overall rate of reaction.
(S) Decreasing O3 concentration increases overall rate of reaction.

(A) P and R
(B) Q and R
(C) Q and S
(D) P and S

6)

Column-I Column-II

(A) 4 (p) Number of nodes in 3s

(B) 5 (q) Number of sub-shells in third energy level

(C) 3 (r) Number of unpaired electron in Fe2+

(D) 2 (s) Number of electrons with n = 3 in an atom of phosphorus.

(A) A-r, B-s, C-q, D-p
(B) A-s, B-q, C-p, D-r
(C) A-p, B-q, C-s, D-r
(D) A-r, B-s, C-p, D-q

7) For a zero order reaction,

Variation of concentration of A with time is given as:
Then calculate time to reduce concentration of A from 2 M to 0.5 M

(A) 10 sec
(B) 20 sec
(C) 15 sec
(D) 25 sec

8) In the following reaction : xA yB

where –ve sign indicates rate of disappearance of the reactant. Thus, x : y is (use : log10 2 = 0.3)

(A) 1 : 2
(B) 2 : 1
(C) 3 : 1
(D) 3 : 10

9) Maximum number of electrons in a shell having will be:

(ms = Spin quantum number)

(A)
(B) 2n2
(C) n2
(D)

10) Select the correct statement(s) :

(P) Catalyst does not change the ΔH of the reaction
(Q) On increasing concentration of reactant, rate of reaction always increases
(R) On increasing temperature, rate of reaction increases mainly due to increase in collision
frequency between reactant molecules.

(A) Only P
(B) Only Q
(C) Only R
(D) None of these

11) The final major product "Q" obtained in the following reaction is
(A) CH3CH2OH
(B) CH3CHO
(C) CH3COOEt
(D) Both (A) and (B)

12) Which compound can show Hoffmann degradation?

(A)

(B)

(C)

(D) Both (A) and (C)

13) The major organic product obtained in the following reaction is:

(A)

(B)

(C)

(D)

14) Consider the following sequence of reactions, the final product (Q) is:
(A)

(B)

(C)

(D)

15) Statement-I: When is reacted with , the marked nitrogen will

react with acetone to form major product.
Statement-II: In the above reaction, pH range is maintained between 4.5 to 6.0

(A) Both statement-I & statement-II are true

(B) Statement-I is true & statement-II is false
(C) Statement-I is false but statement-II is true.
(D) Both statements-I and Statement-II are false.

16) Reaction incorrectly matched with product is

(A)

(B)
(C)

(D)

17)
Select the incorrect statement for above reaction sequence.

(A)

(B)
(C) (P) and (R) can be differentiated by NaHCO3 test
(D) (Q) and (S) are same compounds

18) The product obtained in the following reaction is:

(A)

(B)

(C) CH3OH
(D) CH3COOH

19) A container containing two acid amides

Following sequences of reaction are made on amides:

The final product obtained in the following reaction is

(A) Compound (X)

(B) Compound (Y)
(C) Compound (P)
(D) Compound (Q)

20) The unknown "T" is

PhCOOCH3 (P) + (Q)

(P) (R) (S)

(S) (T)

(A) Ph COOH
(B) CH3COOH
(C) CH3COOPh
(D) PhCOCH3

SECTION-II

1)

Total number of possible structures of amines of molecular formula , which on reaction

with benzene sulphonyl chloride to form a precipitate that is insoluble in alkali is

2) Total number of possible different acetals when acetaldehyde is treated with glycerol under mild
acidic condition is?

3) The t1/2 of a reaction becomes 4 times when initial reactant concentration is halved. The order of
reaction is

4) For a 1st order reaction value of is :

5) How many orbitals will have energies between those of 8s and 8p sub-shells according to Aufbau
principle ?

PART-3 : MATHEMATICS

SECTION-I

1) Number of words which can be formed using all the letters of word HIP HIP HURRAY in which all
H′s lie some where between R′s is

(A) (198)7!
(B) (99)7!
(C) (99)8!
(D) (198)8!

2) Values of a and b are obtained by throwing an unbiased die for two times. What is the probability
that roots of the equation ax2 – 2bx + 7 = 0 are real and distinct ?

(A)

(B)

(C)

(D)

3) A fair coin is tossed n times. Let pn denotes the probability that no two (or more) consecutive
heads occur in n tosses.
Assertion A : The probabilities p2, p3, p4 are in arithmetic progression.
Reason R : The probabilities p1, p2, p3, ..........., pn are in decreasing order.

(A) A is true, R is true and R is correct explanation for A.

(B) A is true, R is true and R is NOT the correct explanation for A.
(C) A is true, R is false.
(D) A is false, R is true.

4) , than smallest natural value of x will be :

(A) 2
(B) 3
(C) 4
(D) 1

5) Number of solution of the equation in is -

(A) 0
(B) 1
(C) 2
(D) 4

6) If three fair dice are tossed and the product of the three numbers that appear is even, the
probability that the sum of the numbers is also even, is

(A)

(B)

(C)

(D)

7) Four consecutive natural numbers are chosen from first 50 natural numbers. What is the
probability that their sum is divisible by 3 ?

(A)

(B)

(C)

(D)

8) If , then value of will be :

(A)

(B)

(C)

(D)

9) For the set of observations : 5, 5, 7, 10, 12, 12, 14, 15; Match entries of List-I with that of List-II ;
and mark correct option :

List-I List-II
 Sum of digits in [variance] is, ([.] is greatest integer
(A) (I) 13
function)

Twice of sum of mean deviation about median and mean

(B) (II) 3
deviation about mean is

The value of [Standard deviation] is (where [ . ] is greatest

(C) (III) 4
integer function)

(D) Absolute difference of median and mean is (IV) 1

(A) (A) – I, (B) – III, (C) – II, (D) – IV
(B) (A) – III, (B) – II, (C) – IV, (D) – I
(C) (A) – IV, (B) – II, (C) – IV, (D) – I
(D) (A) – III, (B) – I, (C) – II, (D) – IV

10) Ratio of coefficient of x51 to coefficient of x50 in the expansion of (1 + x + x2) (1 + x2)50

(A)

(B)

(C)

(D)

11) is equal to

(A) 1275
(B) 1625625
(C) 42925
(D) 125499

12) 95C90 + 5 . 95C91 + 10 .95C92 + 10 .95C93 + 5.95C94 +95C95 equals :

99
(A) 30 . C4
101
(B) C6 – 100C5
98
(C) 95. C3
98
(D) 495. C3

13) The equation = has

(A) Two irrational and one rational solutions

(B) One irrational and two rational solutions
(C) One irrational and two prime number solutions
(D) All rational solutions

14) In a random experiment, a fair coin is tossed. If Head is obtained, then an unbiased die is thrown
2 times and sum of number is recorded. If Tail is obtained, then 2 Tokens are drawn, from a box that
contains tokens numbered as 1, 2, 3,.........., 10, with replacement, and sum of the number is
recorded. If it is known that sum recorded is prime than the probability that the head was obtained,
is :

(A)

(B)

(C)

(D)

15) Statement I : Number of ways in which number 500 can be written as a product of two even
natural numbers are 2 (Order of number does not matter). Statement II : 500 identical balls can be
distributed among five students in 254C4 ways. If atleast 50 balls are given to each student.

(A) Statement I is true, but statement II is false.

(B) Statement I is false, but statement II is true.
(C) Both I and II are true.
(D) neither statement I, nor statement II is true.

16) Variance of first 11 terms of an Arithmatic Progression, with common difference –5 is :

(A) 150
(B) 350
(C) 250
(D) 450

17) Let x1, x2, x3,........x10 be ten observations of a random variable X.

If and
then variance of these observations is :

(A) 1.35
(B) 1.31
(C) 1.21
(D) 1.25

18) 3 squares of dimension 1 × 1 are selected at random from CHESS BOARD. The probability that
these selected squares lie on diagonal of chess board and exactly 2 squares are connected with one

another is , where a, b are relatively prime, then a + b is :

(A) 6944
(B) 3472
(C) 3477
(D) 6949

19) If number of words formed by rearranging all the letters of the YUVRAJSINGH such that, It must

contains the phrase "YUVI" but not the phrase "IRA" is n, then the value of is :

(A) 550
(B) 330
(C) 165
(D) 530

20) Coefficient of x99 in x100 + 2x99 (1 + x) + 3x98 (1 + x)2 + .......... + 101 (1 + x)100 will be

101
(A) C99 – 101C98
101 101
(B) 100 x C99 – C98
101 101
(C) 101 C99 – C98
101 101
(D) 101 C98 – C99

SECTION-II

1) How many 6 digit number can be formed using digit 1,2, 3, 4 so that no 2 consecutive digits are
same in the number and each digit (1, 2, 3, 4) should used at least once in the number.

2) How many natural numbers can be formed which lie in the interval (700, 2678) using digits 2, 6,
7, 8 ?

3) Let & then k1 + k2 is equal to

4) For k = 1, 2, 3 the box Bk contains k red balls and (k + 1) white balls.

Let & , where P(Bk) represents probability of selection of box Bk. A box is selected
randomly and a ball is drawn, if it is known that drawn ball is red. Then the probability that it has

come from Box B2 is , where p & q are coprime then p + q is equal to

5) Number of 6 digit number (Formed without using zero & without repetition) such that first 3
places of the number are in increasing order and last 3 places are in decreasing order will be
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. C A C C D B A C B A A D C D B A B A A D

SECTION-II

Q. 21 22 23 24 25
A. 68 7 2 25 3

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C A B D B A C B C A D D B B A C B A D C

SECTION-II

Q. 46 47 48 49 50
A. 03 06 3 4 21

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. A C B A B C B C D D C D B A C C C C B C

SECTION-II

Q. 71 72 73 74 75
A. 576 55 110 53 1680
 SOLUTIONS

PART-1 : PHYSICS

1) The force on the conductor is

F = IL×B = ILaz × B0ar = B0ILaϕ
so that the applied force is
Fa = B0IL(–aϕ)
The conductor is to be turned in the aϕ direction. Therefore, the work required for one full
revolution is

Since N revolutions per minute is N/60 per second, the power is

2) For long coils of small cross section, H may be assumed constant inside the coil and zero for
points just outside the coil. With the first coil carrying a current I1,

(A/m) (in the axial direction)

B = μ0 2000 I1 (Wb/m2)
Φ = BA = (μ0 2000 I1) (π × 10–4) (Wb)
Since H and B are zero outside the coils, this is the only flux linking the second coil.

M12 = N2 = (2000) 4(π × 10–7) (2000) (π × 10–4) = 1.58 mH

3)

= 6V

4) The quality factor Q measure sharpness and

Sharpness =
Hence statement (2) is wrong
5) The amplitude of forced oscillation is ,

0
At p = ω , we get . To evaluate A,
we need to know F0 , the amplitude of the driving force and which measures the damping of
system.
F0 = spring constant × displacement amplitude = (800 N/m) (2×10–3 m) = 1.6 N

where

A = 4 cm

6)

With increased damping the resonant frequency shifts lower than the natural frequency.

7)
Field at any point (x,y) can be written as
B = –Bsinθ + Bcosθ

A small segment of the wire at point (x,y) can be taken as

Force on segment is

∴ Force on wire AB is

If x2 + y2 = t , tA = 2, tB = 10
then 2xdx + 2ydy = dt;
xdx + ydy = 1/2 dt

8)

Current (and hence current density) in the entire loop must be same.
From microscopic form of Ohm's law we can write
σ1E1 = σ2E2

⇒ R2E1 = R1E2 ⇒
The induced electric field must be uniform ever)'where in the circular conductor. It is given by

2πaEin = πa2 ⇒ Ein =

There is accumulation of charge at the junctions which produce additional electric field in the
conductor. If R1 > R2 then E1 > E2. In this case the charge at the upper junction is negative and
charge at the lower junction will be positive. In figure En is electric field due to charge.
ES + Ein = E1
Ein – E0 = E2
__________________

9) , V3 = (VL–VC)

VR = 100 V, = 1252–1002 ⇒ VC = 75V

VL = 315 V

10) Drawing the equivalent circle

(This is balanced wheatstone Bridge)

At the centroid 0. The field produced will be zero.

11)

PQ = Phasor of source
PB = Phasor of voltage across R
BQ = Phasor of voltage across C
AB = Phasor voltage between A & B

here pointer B moves on a circle of radius when R is change

= maximum inst. voltage between A & B

which is constant.
12)

∴ induced emf across two ends of rod =

Here in loop PQTSP has zero current
∴ deflection in voltmeter must be zero.

13)

.......(1)

∴ At w = w1 or w = w2
On solving (1)

.....(2)

....... (3)

∴ At w = w1 i.e. circuit in capacitive

At w = w2 i.e. circuit is inductive power factor

∴ at w1 & w2
(2) & (3)

At wr ϕ = 0º cosϕ = 1

14) ϕeach loop = qself + fmutual

= LI0 + MI0 = 2LI0

(ϕeach)initial = ϕeach final

2LI0 = LI
I = 2I0

Ui = L + L + MI1I2
=L +L = 2L

or Ui =

Uf = LI2×L
= L × (2I0)2 =
Wex = Uf – Ui

15) Both statement are true but statement-II is not correct explanation of statement-I
there work done by induced field is path dependent.

16)

λR2dθ = μ mg R
17)
Magnetic field due to Q and x is given by

|E| = (B.πr2)

to Maximize |E|

⇒ x = R/2

∴x= = 2 m (from coil B)

18)

VL = I0 XL sin(ωt + π/4)
VL = 96.5 V.

19)

20)

Irms = 1A
21) = 4V = constant.
charge on the capacitor, Q = Cε = 2C
Work required to charge the capacitor,
W = Q. ε = 8 J

⇒ 2iL = 4t
iL = 2t, Fext = (2 + 2t) × 2 × 2 = 4(2 + 2t)

22) Moment of inertia of combined body,

L = I.ω = angular momentum.

× 3 × 200 × 0.04 = 7 A.m2

23) vR + vL + vC = v

vR = iR , vL = L , vC =

vR = RC , vL = LC

RC + LC + vC = v

We can compare this equation with equation of forced damped oscillation. For very low

damping and in steady state, amplitude of vc would be maximum when

where, ω = 60 rad/sec, = 104

and

3600 = 10000 –

24) If the imaginary part of impedance a admitance is zero, then the circuit will behave purely
resistive
 ⇒ ωC =

= 25 µF

25)
Magnetic dipole moment
Magnetic torque
= IπR2 B0 ( × (– )) = IπR2 B0 ( )
To counterbalance this torque we must have T1 > T2
Torque about centre C
–(T1cosθ–R – T2cosθR) + IπR2 B0 = 0

T1–T2 =
And (T1 + T2)cosθ = Mg

⇒ (T1 + T2) =
Solving (i) and (ii)

(Mg + πIRB ) = Mg + πIRB and T2 = Mg – πIRB

0 0 0
T1 =

PART-2 : CHEMISTRY
26)

For He+ ion En = –13.6 × = –KEn =

For h = 2, E2 = –13.6 eV
P.E. = – 27.6 eV
K.E = 13.6 eV

27)

29)

Number of Nodal surfaces = n - 1

30)

r = K2 [O3] [O] = K2 . [O3] .

= K . [O3]2 [O2]–1

31) no. of nodes = n -1

32)

For zero order: t3/4 = 1.5 t1/2

33)

34)

Total number of lector in a shell = 2n2

Number of electron in a shell having (ms = + 1/2) = n2

35)

theory based

36) (P) = CH3 - COOEt

(Q) CH3CH2OH + CH3CHO
37) CH3COO– + CH3 – NH2

CH3–NH2

38) Acetylation of salicylic acid gives aspirine

39)

40)
Both Statements are correct.

41) NaBH4 does not reduce - COOH group

42)
43)

44)

45) PhCOOCH3 PhCOOH + CH3OH

PhCOOCH (PhCOO)2Ca PhCOCH3

PhCOCH3 CH3-COOPh (T)

46) 2° - amines form white ppt that is insoluble in alkali

 47)

49)

50) Correct order is : 8s 5g 7f 7d 8p

PART-3 : MATHEMATICS

51)

52) Sample space = S = {(1, 1), (1, 2).........(6, 6)?

n(s) = 36
For distinct and real roots D > 0
4b2 - 28a > 0 ⇒7a < b2
Favourable cases E = {(1, 3), (1, 4), (1, 5), (1, 6), (2, 4), (2, 5), (2, 6), (3, 5), (3, 6), (4, 6), (5,
6)}
n(E) = 11

Required probability

53) pn = pn–1 p(T) + pn–2p(T)p(H) ; ; p1 = 1, ;

Alternatively : Clearly p1 = 1 and p2 = 1 – p(H H) =

Now for n ≥ 3,

Compute ;

Hence ; ; ⇒ p2, p3, p4 are in A.P.

54)

put

or
or

or
smallest natural value of x = 2

55) Maximum value at only

56) Product of the three numbers appearing is even ⇒ atleast one of the throw is even.
Possible cases: E1 ≡ Exactly one even and 2 odd.
E2 ≡ Exactly two even and 1 odd.
E3 ≡ All three even.

Now P(E1 ∪ E2 ∪ E3) = 1 – P(all three throws are odd) =

Hence P(E1 or E3 / E1 ∪ E2 ∪ E3) = =

57) Total selections of four consecutive

natural number from first 50 natural numbers
n(s) = 47
S={(1, 2, 3, 6), (2, 3, 4, 5)..........(47, 48, 49, 50)}
Selection of four consecutive natural numbers, if their sum is divisible by 3
n(E) = 15
E={(3n, 3n + 1, 3n + 2, 3n + 3) : n ∈ N}
E = {(3, 4, 5, 6), (6, 7, 8, 9), (9, 10, 11, 12), .....(45, 46, 47, 48)}

Required probability
 58)

Put

59) Obs. 5, 5, 7, 10, 12, 12, 14, 15

Variance = σ2

Median

xi

5 5 6
5 5 6
7 3 4
10 0 1
12 2 1
12 2 1
14 4 3
15 5 4

60) (1 + x + x2) (1 + x2)50 =

Coefficient of
Coefficient of

Required ratio =

61)

= n2 = (n - 1)2 + ........+ 12

= 42925

62) 5C0 95C90 + 5C1 95C91 + 5C2 95C92 + 5C3 95C93 + 5C4 95C94 + 95C95
= 5C5 95C90 + 5C4 95C91 + 5C2 95C92 + 5C3 95C92 + 5C1 95C94 + 5C0 95C95
= 5+95C95 = 150C95

63) Take , then equation will be :

(2 + t) + (t - 1) = (1 + 2t)3
3 3

Here (2 + t) + (t - 1) = 2t + 1
∴ a3 + b3 = (a + b)3 can be interpreted
∴ 3a2b + 3ab2 = 0
∴ a = 0 or b = 0 or a + b = 0

∴ t = -2, 1,

64) Prime as sum on throwing a die 2 times : 2, 3, 5, 7, 11

Such no. of cases = 15 lake (1, 1), (1, 2), (2, 1) and so on.
Prime as sum on drawing tokens 2 times : 2, 3, 5, 7, 11, 13, 17, 19
Such no. of cases = 37 lake (1, 1), (1, 2), (2, 1), (1, 4), (4, 0), (2, 3), (3, 2) etc.

∴ Req. probability

65) Statement I : N = 500 = 22 × 53

500 = 2d1 × 2d2 ⇒ d1d2 = 125 = 53
∴ 500 can be expressed as product

two even natural no. in = 2 ways

Statement II :
x1 + x2 + x3 + x4 + x5 = 250
Number of non negative integer solutions = 250 + 5 - 1 C5-1
= 254C4

66) AP : a, a + d, a + 2d, ....., a + 10d, d = -5

Variance

= 10d2 = 250 (as d = -5)

67) Variance of = Variance of xi - λ

68) No. of ways of selecting 3 squares of dim 1 × 1 both diagonals, where exactly & are
connected

69) Words with phrase "YUVZ" : R. A, J, S, N, G, H

Such no. of words = 8!
So no. of words with phrase YUVI but not IRA
n = 8! - 6! = 6! (8 × 7 - 1) = 95 × 6!

70) x100 + 2x99 (1 + x) + 3 x98 (1 + x)2 + ......... + 101(1 + x)100

...........(1)
 Coefficient of 99 =

71) Numbers which have no 2 consecutive digits are

Same :
But these numbers are also consist numbers in which all digit are not used.
Numbers formed with only 2 digit = 6 × 4C2 = 36
Number formed with only 3 digit = 4C3 × (3 × 25 - 6) = 360
Required numbers = 972 - 396 = 576

72) 3 digit ⇒

4 digit ⇒

= 55

73) k1 = 25 + 3 × 4 = 37
k2 = 26 + 9 = 73
k1 + k2 = 110

74)

75)