Chemistry Sample Paper
Chemistry Sample Paper
Chemistry
Time Allowed: 2 hours Maximum Marks: 80
General Instructions:
The time given at the head of this Paper is the time allowed for writing the answers.
The intended marks for questions or parts of questions are given in brackets [ ].
Section A
1. Question 1 Choose one correct answer to the questions from the given options: [15]
(a) Which of the following properties do not match with elements of the halogen family? [1]
a) They are highly chemically reactive b) They are diatomic in their molecular
form
a) Vinegar b) Antacid
16]
a) 53 g b) 106 gs
c) 212 g d) 165 g
(h) How many moles of oxygen are produced by the decomposition of six moles of potassium chlorate? [1]
2KClO3 → 2KCl + 3O2 ↑
a) 12 moles b) 9 moles
c) 3 moles d) 6 moles
(i) Which of the following does not differentiate between electrochemical cell and electrolytic cell? [1]
i. Spontaneous or non-spontaneous nature of chemical process
ii. Chemical reactions occurring at the electrodes
iii. Positive or negative nature of anode
iv. None of these
a) 1 : 3 b) 1 : 10
c) 10 : 1 d) 3 : 1
(m) Absolute alcohol can be obtained from rectified spirit by [1]
a) C2H5COOC2H5 b) C2H5COOCH3
c) CH3COOCH3 d) CH3COOC2H5
2. Question 2 [25]
(a) i. Nitrogen can be obtained in pure state by heating a mixture of ammonium chloride and a [5]
substance A. Name the substance A.
ii. A gas X reacts with another gas Y in the presence of catalyst Z to give a colourless gas C. The gas
C on reacting with air produces a brown gas A. The solution of X in water turns red litmus to blue.
Explain the observation.
iii. Why nitrogen dioxide is called mixed anhydride?
(b) Name the method used for preparation of the following salts from the list given below - [5]
Column I Column II
(c) Complete the following by choosing the correct answers from the bracket:
i. ________ are the longest periods, containing 32 elements each. [1]
ii. Soluble salts are prepared by ________ whereas insoluble salts are generally prepared by [1]
________.
iii. ________ is defined as the amount of substance which contains same number of units as the [1]
number of atoms in 12 g of carbon-12.
iv. Pure water consists almost entirely of ________ (ions/molecules). [1]
v. Hydrogen chloride and water are examples of ________ (polar covalent compounds/non-polar [1]
covalent compounds) and a solution of hydrogen chloride in water ________ (contains/does
not contain) free ions.
(d) Identify the following:
i. The covalent compounds of carbon and hydrogen. [1]
ii. A yellow non-metal formed when hydrogen sulphide gas is passed through concentrated nitric [1]
acid.
iii. The process of coating of iron with zinc. [1]
iv. Ice like crystals formed on cooling an organic acid sufficiently. [1]
v. Group 2 elements are called ________ metals. (alkali/alkaline) [1]
(e) i. The volumes of gases A, B, C and D are in the ratio, 1 : 2 : 2 : 4 under the same conditions of [2]
temperature and pressure.
i. Which sample of gas contains the maximum number of molecules?
ii. If the temperature and the pressure of gas A are kept constant, then what will happen to the
volume of A when the number of molecules is doubled?
iii. If this ratio of gas volumes refers to the reactants and products of a reaction, which gas law
is being observed?
ii. An element A is placed on the left side of the periodic table with valency 2 and element B is [3]
placed on the right side of the periodic table with valency 3.
i. Write the equation to show how A and B form ions.
ii. Which of the two elements will show reduction?
iii. If B is a diatomic gas, write the equation for the direct combination of A and B to form a
compound.
Section B
Attempt any 4 questions
3. Question 3 [10]
(a) Give the equations involved in brown ring test. [2]
(b) Write the products and balance the equation.
i. Zinc carbonate from Zinc sulphate. [1]
ii. Sodium sulphate using dilute sulphuric acid. [1]
(c) Arrange the following as per the instruction given in the brackets:
i. Na, K, Li (increasing chemical reactivity) [1]
ii. He, Ar, Ne (Increasing order of the number of shells) [1]
iii. Br, F, Cl [decreasing order of atomic radius] [1]
(d) Fill in the blanks by selecting the appropriate word from the given choice:
i. The carbon compounds containing ________ group are known as carbonylic acids. [1]
ii. A carbon atom linked with two carbon atoms is known as ________ carbon. [1]
iii. Complete the following, n = Molecular mass
________
[1]
4. Question 4 [10]
(a) The non-polar and polar covalent compounds are generally formed between what kind of atoms? [2]
(b) Calculate the mass of calcium that will contain the same number of atoms as are present in 3.2 gm of [2]
sulphur.
[Atomic masses: S = 32, Ca = 40]
(c) Answer the following questions with respect to the electrolytic process in the extraction of [3]
aluminium:
i. Identify the components of the electrolyte other than pure alumina and the role played by each.
ii. Explain why powdered coke is sprinkled over the electrolytic mixture.
(d) Explain the following:
i. Zinc oxide can be reduced to zinc by using carbon monoxide, but aluminium oxide cannot be [1]
reduced by a reducing agent.
ii. Anhydrous hydrogen chloride gas and anhydrous liquified hydrogen chloride are not acids. [1]
iii. Sodium chloride will conduct electricity only in fused or aqueous solution state. [1]
5. Question 5 [10]
(a) i. Write the IUPAC name of the given compounds: [1]
H
H− C − C ≡ C − H
|
H
iii.
v. ZnSO4 + NaOH →
vi. Pb(NO3) + 2NaOH →
7. Question 7 [10]
(a) i. What do you understand by a lone pair of electrons? [2]
ii. Draw the electron dot diagram of Hydronium ion. (H = 1, O = 8)
(b) A gas cylinder contains 24 × 1024 molecules of nitrogen gas. If Avogadro's number is 6 × 1023 and [2]
Section A
1. Question 1 Choose one correct answer to the questions from the given options:
(i) (c) They are metallic in nature
Explanation: {
They are metallic in nature
(ii) (c) Law of octaves
Explanation: {
Law of octaves
(iii) (b) It loses electrons and is oxidised
Explanation: {
It loses electrons and is oxidised
(iv) (b) Antacid
Explanation: {
Antacid
(v) (c) increase
Explanation: {
Given, pH = 4
On dilution, the concentration of H+ ions decreases, that results in increase in the pH value, as pH - loh[H+]
(vi) (a) Calcium nitrate
Explanation: {
Calcium nitrate
(vii) (a) 53 g
Explanation: {
Each Na2CO3 contain 2 × NA Na+ ion (NA = 6.02 × 1023)
2
=
106
2
= 53 g
2. Question 2
(i) i. The substance A = Sodium nitrate
catalyst
ii. A + B −−−−→ C
The gas C when comes in contact with air (O2) a brown gas D is produced which is due to nitrogen dioxide (NO2),
hence, C is NO.
2NO(g) + O2(g) ⟶ 2NO2(g)
The solution of A in water turns red litmus blue, hence it is a base i.e., NH4OH.
NH3 + H2O ⟶ NH4OH and A is NH3
catalyst
A + B −−−−→ C
Pt
iii. Nitrogen dioxide called mixed anhydrous because it dissolves in water forming two acids i.e., nitrous acid (HNO2)
and nitric acid (HNO3).
(ii) (a) - (ii), (b) - (iv), (c) - (iii), (d) - (i)
(iii)Complete the following by choosing the correct answers from the bracket:
i. 1. Sixth and seventh
2. 6 and 7
3. 6, 7
4. 7, 6
ii. 1. neutralisation, precipitation reactions
iii. 1. Mole
iv. 1. molecules
v. 1. Polar covalent compounds, contains
(iv)Identify the following:
i. 1. Hydrocarbons
ii. 1. Sulphur
iii. 1. Galvanization
iv. 1. Glacial acetic acid
v. 1. alkaline
(v) i. i. Sample of gas D contains the maximum number of molecules.
ii. When the number of molecules is doubled then the volume of the gas A will get doubled.
iii. Gay Lussac's law of combining volumes.
ii. i. Elements placed on the left side of the periodic table are electropositive (metals) and hence, will lose electrons
for stability. Elements present on the right side are electronegative and will gain an electron for stability.
A ⟶ A2+ + 2e-
B + 3e- ⟶ B3-
ii. Element B will show reduction.
iii. 3A + B2 ⟶ A3B2
Section B
3. Question 3
(i) 6FeSO4 + 3H2SO4 + 2HNO3 ⟶ 3Fe2(SO4)3 + 4H2O + 2NO
FeSO4 + NO ⟶ FeSO4 ⋅ NO
Nitroso ferrous
sulphate
32⋅10
⋅3.2
23
6.023× 10 ×10
= 4 gm.
(iii) i. Cryolite - lowers the fusion temperature of the electrolyte.
Fluorspar - increases the conductivity of the electrolyte or acts as a solvent.
ii. to prevent the heat loss from the electrolyte.
(iv)Explain the following:
i. This is because of the fact that aluminium has great affinity towards oxygen and so, it cannot be reduced by reducing
agents such as carbon monoxide, carbon or hydrogen.
ii. This is because neither of them forms hydrogen ions or hydronium ions (H3O+) due to the absence of water
molecules.
iii. Na+ and Cl- ions become mobile only on melting or dissolving it in water and only then can NaCl conduct
electricity.
5. Question 5
(i) i. Propyne
ii. Vinegar (CH3COOH acetic acid)
H O
| ||
H − C − C − O − H
|
(ii) Cl
|
Cl - C - Cl → CCl4
|
Cl
4 - single covalent bonds
Zn 47.8 65
47.8
65
= 0.73 0.73
0.73
=1
Cl 52.2 35.5
52.2
35.5
= 1.46 1.46
0.73
=2
Thus, the ratio of Zn : Cl atoms = 1 : 2. The empirical formula of the compound is ZnCl2.
(iii)The name and structure of at least one isomer in each of the following:
i. C2H5OH : Ethyl alcohol
ii. C2H5CHO : Propanal
iii. H3C-CH = CH2 : Propene
7. Question 7
(i) i. The pair of electrons which is not yet shared with other atoms in a covalent molecule is known as lone pair of
electrons.
ii.
= 1120 g
ii. Volume of nitrogen gas at STP
6 × 1023 molecules of N2 occupy 22.4 L at STP
23
6×10
= 896 L
(iii) i. Sodium hydroxide solution is a strong electrolyte. So the kind of particle present in sodium hydroxide solution are
ions only.
i.e., Na and OH ion.
+ −
+ −
NaOH ⇌ Na + OH
ii. Carbonic acid is weak electrolyte, so the kind of particles present in weak electrolyte are ions and unionised
molecules.
iii. Sugar particles present in sugar solution are molecules only.
(iv) i. Laboratory preparation of ethyl alcohol: By hydrolysis of C2H5Cl (ethyl chloride) with hot aqueous potassium
hydroxide solution.
Δ
C2 H5 Cl + KOH ⟶ C2 H5 OH + KCl
(aq)
ii. Laboratory preparation of methyl alcohol: By hydrolysis of methyl bromide with hot aqueous potassium
hydroxide solution.
Δ
8. Question 8
(i) i. Ba will form ions most readily. Because it's ionisation potential is lowest in the group.
ii. Ability of the element to attract the shared pair of electron in a covalent bond towards itself.
(ii) i. 6 × 1023 atoms of sulphur = 32 g
23
× 1022 = 0.533 g
6×10
2NaNO3 −
→ 2NaNO2 + O2 ↑
iii. The products formed when ammonium nitrate is heated are nitrous oxide and water (steam).
Δ
NH4NO3 −
→ N2O ↑ + 2H2O ↑