L. R. & 8. M.

VI88ANJI ACADEMY
8econdary Beotion 2024-26
First Bummative Assesment VISSANI
ACADIMY
Subject: Chemiatry
8td: 10 Marka: 80
Date: 26/8/2024 Time: 2 hours
INSTRUCTIONS:
Answers to this paper must be written on the anawer sheet provided
separately.
You will not be allowed to write during the first flfteen minutes.
This time is to be spent in reading the quostlon paper.
The time given at the head of thls paper is the time allowed for
writing the answors.
The intended marks for the quostions or parts of quostiona aro glvon
alongside the questions.
This paper has 8 printed sides.
Section A is compulsory. Attempt any four questlons from Section B.
Draw a labeled diagram and for numericals show rough work in the column.

SECTION A (40 Marks)

(Attempt allquestions from this Section.)
Question 1
Choose one correct answer to the questions from the given options: [15]
(Do not copy the qucstions, write the corrcct answcrs only.)
(i) The metal hydroxide which reacts with both aoids and alkalis to fornm
salt andwater is:
(a) Calcium hydroxide (b) Maguesium hydroxide
(c) Aluminium hydroxide (d) erric hydroxide

(1i) In the molecule of Ammonia , nitrogen atom has:

(a)One shared pair of clectrons (b) Twoshared pairs of clectrons.
(c) One lone pair of clectrons (d) Two lone pairs of clectrons.

(ii) Ionisation Potential increases over a period from left to right becausc:
(a) Atomic radius increases nd nuclear charge increases.
(b) Atomic radius decreasesand nuclearcharge iercases.
(c) Atomic radius incrcases and nuclear chargedecereascs.
(d) Atomic radius and nuclcar charge decrcase.
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(iv) The vapour density of carbon dioxide [C = 12, O- 16] is :
(a) 12 (b) 16 (c) 44 (d) 22

(v) Assertion (A): The atomic mass of oxygen is 16 a.m.u; therefore, its
gram atomic mass is 16g.
Reason (R): The relative atomic mass of an element expressed in
grams is called gram atomic mass of that element.
(a) Ais true, and R is the correct explanation of A.
(b) Both Aand Rare true, but R isnot atrue explanation of A.
(c) Both A and Rare false.
(d) R is false, but A is a true explanation.

(vi) The salt which in solution gives a pale green precipitate with sodium
hydroxidesolution and a white precipitate with barium chloride
solution is:
(a) Iron (1) sulphate (b) Iron (II) sulphate
(c) Iron (II) chloride (d) Iron (III) chloride

(vii)The most metallic element in its respective group is placed :

(a) At the top (b) In the middle
(c) At the bottom (d) Sometimes in the middle and sometimes at the top

(viii) Which of the following is a non electrolyte ?

(a) Sodium chloride (b) Methyl alcohol
(c) Ammonium hydroxide (d) Nitric acid

(ix) If empirical formula of an organic compound is CH,0, then its

molecular formula can be :

(a) C,H,O, (b) CzH,0 (c) C,H,O (d) C,H,0,

(x) Which gas evolved when HCl reacts with calcium carbonate?
(a) Cl, (b) H, (c) CO, (d) H,S

(xi) Twice of vapour density gives us :

(a) Actual vapour density (b) Relative vapour density
(c) Molar volumc (d) Molecular mass
2
(xi) Given ahead are 4 covalent compounds. (A)H,O (B) CCL, (C) Cl, (D) NH,
Which of the following represents the correct order when they are
arranged in their increasing number of covalent bonds?
(a) B < D <A< C (b) C< D<A< B (c) A<C< D <B (d) C<A < D < B

(xiii) The particles present in strong electrolytes are:

(a) only molecules (b) mainly ions
(C) ions and molecules (d) only atoms

(xiv) Anhydrous Iron (II) chloride is prepared by:

(a) direct combination (b) simple displacement
(c) decomposition (d) neutralisation reaction

(xv) Out of given aqueous solution of the compounds the one which
contains both ions and molecules is:
(a) Sulphuric acid (b) Acetic acid (c) Nitric acid (d) Hydrochloric acid

Question 2
i)State the terms for the following: [5]
(a) The amountof substancewhich contains the same number of units as
the number of atoms in 12 gms. of Carbon-12.
(b) The chemical bond formed due to mutual sharing of electrons between
the given pairs of atoms of non-metallic elements.
(c) The energy required to remove an electron from a neutral gaseous atom.
(d) The formula which represents the simplest ratio between the atomns of
elements present in a compound.
(e) Two metal plates or wires through which the current enters and leaves
the electrolytic cell.
ii) Write one relevant observation for the following reactions [5]
(a) At anode, during electrolysis of fused lead (II) bromide.
(b) Dilute Hydrochloric acid is added to Copper (1I) carbonate.
(c) Addition of methylorange in the beaker containing hydrochloric acid.
(d) Action of heat on zinc nitrate.
le) When hot concentrated caustic soda solution is added to Aluminium Metal.

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ii) Study the given diagram which is related to electroplating of Nickel
on a nail and answer the following questions. [5]

(a) During electroplating the iron nail is placed at the cathode. Why?
(b) Name the ion that must be present in the electrolyte.
(c) State one condition that is necessary to ensure that the deposit is
smooth and even.
(d) Which is the oxidizing clectrode? The electrode that is connected to the
block of nickel or the one that is connected tothe nail to be plated?
(e) What change would you observe at the anode?

iv) Match the column Iwith column II: [5]

Column-I Column-II

Ferrous sulphide (a) Precipitation

(iü) Sodium sulphate (b) Simple displacement
(ii) Magnesium chloride (c) Metal oxide and dilute acid

(iv) Lead (II) chloride / (d) Synthesis

(v) Copper (I) sulphate (e) Neutralisation

v) Complete the following by choosing the correct answers from the

bracket: [5]
a) During the electrolysis of copper sulphate solution, if
[Copper / Platinum] is used as electrodes, the colour of the electrolyte
does not fade.
b) The indicator which does not change colour on addition of NaOH
Solution is [Methyl orange / Alkaline Phenolphthalein]

4
 c) If an element has one electron in the outermost shell, then it is likely
to have the [smallest/ largest] atomic size amongst all the
elements in the same period.
d) [Hydroxyl/ Sulphate] ions will readily discharge at the anode
during the electrolysis of Aq. solution of Copper sulphate.
e) Cations are [oxidised/ reduced] ions due to the loss of
electrons by the neutral atom.

SECTION B

(Attempt any four questions.)

Question 3
i) x -HCI H + CI (in solution state)
Y -PbBr, Pb? + 2Br (in molten state)
From the above reactions X or Y, identify the reaction which exhibits:[2]
(a) electrolytic dissociation (b) lonization
ii) The following rows shows the electronic configuration of the atoms
A, B, C and D. [2)
Element A D

Electronic configuration 2, 8, 8, 2 2,6 2, 8, 7 2, 4

Write the formula of the compound formed between:
1. A and B 2. D andC

iil) Write a balanced chemical equation for the following reactions : [3]
(a) Action of dilute sulphuric acid on sodium hydroxide.
(b) Action of dilute sulphuric acid on zincsulphide.
(c)Ammonium chloride is heated with sodium hydroxide solution.
iv) Distinguish between the following as directed: (3]
(a) An ionic compound and a covalent compound [Particles present]
(b) Acid and Alkali (characteristic ion yield when dissolved in waterl
(c) Cations and Anions Charge on it]

Question 4
i) By drawing an electron dot diagram, show the formation of Hydronium
ion. (Atomic No: O = 8and H = 1| [2]
ii) Give examples for the following : [2]
(a) Two bases which are alkalis.
(b) Anormal salt and an acid salt of the same acid.

5
 and pressure you collect
temperature
same conditions of litres of hydrogen,
ii)Under the litres of chlorine, 5
carbon dioxide, 3 sample
2 litres of sulphur dioxide.In which gas
litres of nitrogen and 1 litre of [3]
4
will there be ?
number of molecules.
(a) the greatest
of molecules.
(b) the least number
(c) Justify your answers. [3]
of the following:
iv) Name the gas in each potassium dichromate paper
clear green.
turns acidified
(a) A gas which black.
lead acetate solution
(b) A gas which turns
paper brown.
(c) A gas which turns KI

Question 5
following:
i) Give reasons for the
(a) NaCi has a high melting point. 1elements are
strong non-metals while group
(b) Group 17 elements are
strong metals.
compound obtained by Hazel. (2)
ii) Find the empirical formula of the
(atomic weight 56) with
When she heated 11.2 grams of element'M
16) to form a compound.
4.8 grams of element 'N' (atomic weight
instructions given in the brackets: [3]
iii)Arrange the following as per the
at the cathode).
(a) Zn2*, Na, Cu? (order of preference of discharge
acid (increasing order of
(b) Sulphuric acid, Phosphoric acid, Acetic
number of replaceable H atoms per molecule)
electron affinity)
(c) Potassium, Lithium, Sodium (increasing order of
given in the table.
iv) The pH values of three solutions A, B and C are
Andanswer the following questions: (3]

Solution pH value

A 12

B 2
7

(a) Which solution will have no effect on the litmus solution ?

(b) Which solution will liberate SO, when reacted with sodium sulphate?
(c) Which solution will turn the red litmus solution blue ?

6
Question 6
1) Define molar volume of a gas. What is the molar volume of 2 moles
nitrogen gas at S.T.P. ? [2]
iü) Read' the paragraph and Give a reason for each of the observations. (2]
Two different electrolytic cells A and B are connected in separate circuits.
Electrolytic cell A contains sodium chloride solution. When the circuit is
completed the bulb in the circuit glows brightly. Electrolytic cell B contains
sugar solution and the bulb does not glow. Give a reason for each of these
observations.

iii) Answer the following questions : [3]

a) Which feature of the Ammonia molecules leads to the formation of
Ammonium ions when Ammonia dissolves in Water ?
b) Name the other ion formed when Ammonia dissolves in Water.
c) Give one test that can be used to detect the presence of the NH*.
iv) Complete and balance the following equations: [31
(a) Na, SO, + H,SO4 >....... + ......
(b) CaCl, + Na,CO,
(c) ZnCO, + HNO, ->......... +

Question 7
i)Define the following [2]
a) Basic salt b) Electrorefining
ii) Identify the anion present in each of the following compounds. (2]
a) When a freshly prepared solution of ferrous sulphate is added to the
given solution and conc.H,SO, is gently poured from the side of the
test-tube,a brown ring is formed.
b) Addition of dilute hydrochloric acid to the given salt produces
effervescence. The gas produced turns lime water milky but does not
affect acidified potassium permnanganate solution.
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 ii) The preparation of lead sulphate from lead carbonate is a twO-steps
process. (Lead sulphate cannot be prepared by adding dilute sulphuric
acid to lead carbonate) [3]
(a) What is the first step that is required to prepare leadsulphate from
lead carbonate ?
(b) Write the equation for the reaction that will take place when the
second step is carried out.
(c) Why is the direct addition of dilute sulphuric acid to lead carbonate
an impractical method of preparing lead sulphate ?
iv) Choose the correct word which refers to the process of
electrolysis
from P to R, to match the description 1 to 3. [3]
P: Oxidation Q:Cathode R: An electrolyte
(1) Conducts electricity in aqueous or in molten state.
(2) Loss of electrons takes place at anode. (3) A reducing electrode.

Question 8
i) 8.2 grams of calcium nitrate is decomposed by heating according to
the given equation: 2Ca (NO3) ’2CaO +4NO, +0,
Calculate the following: [Atomic weights: Ca-40, N-14, 0-16] [3]
(a) Volume of nitrogen dioxide obtained at STP
(b) Mass of Ca formed
ii) With reference to electroplating, answer the following :
[3]
(a) Why are articles electroplated ?
(b) During silver electroplating, :
(1) Explain why AgNO, Solution is not used.
(2) Write reaction at Cathode.
iii) State giving reasons if: [2]
(a) Zinc and aluminium can be distinguished by heating the metal
powder with concentrated sodium hydroxide solution.
(b) Calcium nitrate and lead nitrate can be distinguished by adding
ammonium hydroxide solution to the salt solution.
iv) Draw the electron dot structure for the following.
[2]
(a) Oxygen gas (b) Methane gas