CH 3 Metal and Non Metal
CH 3 Metal and Non Metal
3 Non-metals
Fastrack Revision
lons by galining
which form negative
Non-metals are those
groups namely or gas. They
are mainly divided into two elements
electrons.
form of solid, Uquld
Elements there are certain
but Non-metals oCcur In the non-sonorous in nature
metals and non-metals, of both metals as well as non -
are non-malleable,
non-ductile,
electricity except
which show propertles conductors of heat and
known as metallolds. electrons are and are poor
metals. These are ions bylosing
Elements which form positive graphite. form acidic oxides or
ºNon-metals react with oxygen to
called metals. substances, malleable, ductile,
hard solld electricity. neutral oxides. steam but
Metals are conductors of heat and react with water or
sonorous and are good form Non-metals do not usually with water to form acids.
combine with oxygen (or air) to non-metal oxides react
Almost all the metals in nature.
the
not react with
dilute acids to
release
metal oxides which are basic oxygen º Non-metals do
so vigorously with
Sodlum and potasslum react prevent hydrogen gas. electrons
in the open. Hence, to oil. due to the transfer of as lonlc
that they catch fire if keptkept immersed in kerosene The compounds formednon-metal are known
accidental Fires, they are layer on from a metal to a compounds.
of forming a thick oxide compounds or electrovalent
º Anodising is a process metal from corrosion. Chloride:
aluminium, which prevents the But Formatlon of Magneslum
are insoluble in water. Mg2" " 20
Most of the metal oxides dissolve in water to form M9
some of the metal oxides 2.&2 Aoynesiutn catkan
react with both acids as well
alkalls. Metal oxldes whlch amphoteric Cr
and water are called
as bases to produce salt oxide are examples of (ONoride anion)
oxides. Aluminium oxide and zinc
amphoteric oxides.
respective metal
Metals react with water to produce Mg :
hydroxides and hydrogen gas.
Metal + Water Metal oxide + Hydrogen
Metal oxide + Water Metal hydroxide
as Cu, Hg, Ag, Properties of lonic Compounds:
Except a few less reactlve metals (such because of the strong
Pt, etc.), all metals react with dil. sulphuric acid and º They are generally solid and hard negative
dil hydrochloric acid to produce salt and hydrogen gas. force of attraction between the positive and
a metal reacts with
ºHydrogen gas is not Pvolved wnlcing agent
nitrlc acid because it is a strong
ions.
º They have high melting and boiling point.
in solvents sUch as
less reactive They are soluble in water but insoluble
º Reactive metal can displace a comparatively or in
metal From its compounds in aqueous salt solution petrol etc
molten form, They do not conduct electricity in solid state but conduct
alAA + Salt solution of BSalt solution of A+ Metal E
Metal (Motal A is mora rooctive than B)
electricty In molten state.
Occurrence of Metals:
the
º The reactivity series is a list of metals arranged in º The naturally occurring compounds of the
metals in the
order of their decreasing reactivity. The order of reactivity earth's crust are called minerals.
of metals is K> Na >Ca > Mg > Al> Zn > Fe > Pb> H> Cu Those minerals from which mnetals can be extracted
>Ag> AU. conventionally and economically are called ores. The
MNEMONICS process of extraction of metals from their ores Is called
Concept: How to remember reactivity series? metallurgy.
Mnemonics: Please Send Cats Monkeys And Zebras In Extraction of Metals:
Lovely Happy Coges Mode of Silver and Gold. Positlon Metal Process and Example
Interpretation: Heated in air:
P- Potossium S- Sodium C- Calcium
M-Mognesium A - Aluminlum Z- Zinc Metals Hg 2HgS (5)+30, (9)
|- Iron L - Leod H- Hydrogen of low Heat, 2HgO (s) +25O, (9)
C- Copper M - MercUry S - Silver reactivity
G-Gold 2Hg0(s) Heat 2Hg(() +O, (9)
Heated in air: Al Electrolytic reduction of aluminium
Cu 2Cu,S(s) +30, (g) Joxide
Metals at AL Found in the free state.
Heat, 2Cu,O (s) +250, (9) bottom Pt
2Cu,0(s) +Cu,S (s) of activity Ag
Heat, 6Cu(s) +SO 9) series
The process of purification of the metal obtalned after
Roasting:
Zn2ZnS (s) 30 (g) reduction is called refining of metals.
Hoat
º Electrolytic Refining: In this process, impure metal is made
2a, 2ZnO(s)+250, (9) the anode, thin strip of pure metal ls made the cathode
Calcination: and a solution of metal salt is used as an electrolyte. On
Metals of
Znco, (s) Heot ,Zno(s) +co, (9) passing current through the electrolyte, pure metal gets
medium deposited on the cathode and insoluble impurltles settle
reactivity Roductlon using carbon: at the bottom of the anode (known as anode mud).
ZnO(s)+C(s)-’Zn(s)+CO(9) Corrosion: is the slow process of eating away of metals by
Roductlon using aluminium: the reaction of atmospherlc air and molsture.
Mn3MnO, (s) +4AI (s) Rusting of Iron: can be prevented by galvanising, by
+3Mn() +2Al,O, (s) +Heat making alloys, painting, greasing or oiling and tin-plating
or chromium-plating.
Fe Fe,O, (s)+ 2Al (s) The process of coating ion and steel objects with a thin
-2Fe () +Al,O, (s) +Heat layer of zinc is called galvanisation.
Metals Electrolysis of their molten chlorides: An alloy is a homogeneous mixture of two or more metals
or ametal and a non-metal e.g, stainless steel (Iron +Nickel
of high Na At cathode: Na" +e Na
reactivity Mg Chromium), Brass (Copper + Zinc) etc. An amalgam is an
Ca At anode: 2Cl -Clz +2e alloy in which one of the metals is mercury.
Practice Exercise
Element Acid Base
- Multiple Choice Questions A. X
Mg +dil Ha Cu + dil Ha
Q15. Which one of the following correctly represents
Zn + dil HCI Fe + dil HCI (C8SE SOP 2023-24)
sodium oxlde?
(A (B) (D)
L Because aluniniium has more affinity for oxygen As the surface area of B is more. so extent of rusting
than carbon is also more.
2 Because it is easier to obtain a metal from its oxide. 2. Galvanisation is the process of applying zinc coating
as compared to its sulphides and carbonates to iron to prevent rusting
. Clnnabar (HgS) is an ore of mercury Two other methods to prevent rusting are:
0) Greasing (ü) PaintingB (ui) Alloying (iv) Chromium Q10. In the arrangement shown below there are three
plating, (Any two) test tubes marked A, B andC. Few clean iron nalls
Or
C-iron hinges on a gate because Iron is in contact are placed in these tubes. Water is poured In test
vith both atmospheric oxygen and moisture tube A, boiled distilled water and 1 mL of oill are
poured in test tube B and anhydrous calcium
- Very Short Answer Type Questions chloride is added in test tube C.
Na'
Q8. Ametal that exists as a lquld at room temperature
HCL FeSOa -CuSOa AgNO is obtained by heating its sulphide in the presence
of air. ldentify the metal and its ore and give the
B8 reaction involved. (NCERT EXEMPLAR)
Ag Cu AI Au
Test tube I Test tube ll Test tube l Test tube IV
Ang. Mercury is the only metal that exists as Uquid at rOom
Based on the above experiments: temperature. Cinnabar (HgS) is an ore of mercury.
The reactions are as follows:
() In which test tube(s) no reaction occurred? Heat
Give reason. 2Hg5(s)+ 30, (9) 2Hg0(s) +250, (g)
(ü) Arrange the given metal samples in the 2Hg0 (s) Heat
2Hg (0) +0, (9)
increasing order of reactivity.
Ans. ) Reaction does not occur in test tube I. II and IV Q9. The following reaction takes place when aluminium
because a less reactive metal cannot displace
powder Is heated with Mn0,:
a more reactive metal from its compounds in
solution form 3Mn0,(s) +4Al(s)--Mn) +2Al,0,() +Heat
() Au <Ag_<Cu < Al is the increasing order of () Is aluminium getting reduced?
reactivity. (i) Is Mn0, getting oxidised?
Ans. () No. because oxygen is added to aluminium
Q6. Zinc granules were added to zinc sulphate, copper
therefore. it is getting oxidised
sulphate, aluminium sulphate and Iron sulphate (ü) No. since manganese has lost oxygen therefore.
solutions as shown in the given test tubes:
it is getting reduced.
Q10. Compound X and aluminlum are used to join (1) Magnesium Is a Metal:
railway tracks. (a) It is a good conductor of heat and electricity.
() ldentify the compound X. (b) It is malleable andductile.
() Name the reaction. (c) It forms basic oxides.
(i) Write down its reaction.
Ans. (0) The compound 'X is iron () oxide (Fe,0). ZMg +O ’ 2Mg0
Mg0 + Hy0 ’ Mg (OH),
(ii) The reaction is known as thermite reaction.
hlagnesium hydroxide
MgO is basic in nature.
(uw) Fe,0, (s)+ 2Al (s)2Fe()+ AL,0, (s) +Heat
Q3. Explain the following statements:
T0P (0) Most metal oxides are insoluble in water but
Practice all the reactions used for obtaining metals of some of these dissotve in water. What are these
oxldes and thelr solutions in water called?
low, medium and high reoctivity.
(1) At ordinary temperature, the surface of metals
Q11 During extraction of metals, electrolytic refining Is such as magnesium, aluminium, zinc, etc. is
used to obtain pure metals. covered with athin layer. What is the composition
of this layer? State its Importance.
() Which material will be used as anode and (üü) Some alkali metals can be cut with a knife.
cathode for refñning of silver metal by this (CBSE 2016)
process?
Ans. () These oxides are called basic oxides and solution
(i) Suggest a suitable electrolyte also. of these metal oxides in water is called alkali.
(ii) In this electrolytic cell, where do we get pure
e.g. NaOH (Sodium hydroxide).
silver after passing electric current? (0) This layer is called oxide layer. It makes the metal
Ans. () In electrolytic refining, impure silver is made the less reactive and prevents further oxidation. Due
anode and a thin strip of pure silver is made the to this layer. the metal cannot get corroded and
cathode. remains intact
(ii) Asolution of silver salt (üke AgNO,) is Used as (i) Some alkal metals can be cut with a knife be
an electrolyte. cause they are very soft and have low densities.
() Pure silver Is deposited on the cathode in this e.g. Sodium, potasslum. lithium etc.
electrolytic cell Q4. Of the three metals X, Yand Z. X reacts with cold
water. Y with hot water and Z with steam only.
- Short Answer Type-llQuestions ldentify X, Yand Z and also arange them in order
Q1 Write one example of each of the following:
of increasing reactivity.
Ans. Metals ike potassium and sodiun react with cold
() Most malleable metal and most ductile metal. water. So. X is Kor Na.
(i) The best conductor of heat and the poorest Magnesium reacts with cold water. so. Yis Mg, Metals
conductor of heat. Uke aluminium. Iron and zinc reacts with steam So.
(i) A metal with hlghest melting point and a Zis AL Fe or Zn
metal with lowest melting polnt. (caSE 2016) Increasing order of Reactivity:
Ans. () Gold is the most malleable and the most ductile K> Na>Mg > Al> Zn> Fe
metal
(0) Silver 0s the best conductor and lead Is the cOMMON ERROR
poorest conductor of heat. Most students commit errors in writing the corect order
(l) Tungsten has the highest melting point and of reoctivity of metals.
mercury has the lowest melting point.
05. State which of the following chemical reactions
q2. State three reasons for the following facts: will take place giving suitable reason for each.
(0) Sulphur is a non-metalL
() Zn(s) + CuS0, (ag) (i) Fe(s) + ZnsO.(oq)
(ii) Magnesium is a metal. (ii) Zn(s) + FeS0(aq)
One of these reasons must be supported with a Ans. ()) Reactian will take place because Zn is above Cu in
chemical equation. (CBSE 2015)
the activity series and is more reactive than Cu.
Ans. (i) Sulphur is a Non-metal:
(Y) Itisapoor conductorof heat and electricity.
Zn(s) +CuS0, (oq) Cu(s) +Zr50, (og)
Reaction wll not take place as Fe ls below Zn in
(b) It is neither malleable nor ductile.
the activity seriesand cannot displace Zn from
(c) It forms acidic oxides. its solution.
S+0, ’ S0, (ii) Reaction will take place because Zn is more reac
S0, +H,0 ’ H,S0, (Sulphurous acid) tive than Fe.
50, is an acidic oxide. Zn(s) +Fe50.(oq) Fe(s) +Zn50.(a)
Q6. An element 'M' with electronic configuratlon 2, 8, Ans.
3combines separately with CI so anions. Write
the chemical formulae of the compounds formed. Basis of
Predict with the suitable reason the nature of Difference Roasting Calcination
the bond formed by element 'M in general. How Use This is used for sulphide This is used for
will the electrical conductivity of the compounds ores. carbonate ores.
formed vary with respect to'M? (CaSE SQP 2023-24)
ProcesS The ore heated The ore is heated
Ans. SymboW M C Symbo/ M SO. strongly in the pres-strongly in imited
Formula Formula ence of excess air. air
(i) 'C can be reduced by using suitable reducing Ans. 2Cu +0, Heal 2Cu0
Rcddish Black
Compound
agents such as carbon, aluminium. etc. brown
mtal K)
09. With the help of suitable chemical equations,
list the two main differences between roasting Xis copper metal
and Yis copper oxdde
and calcination. How is metal reduced from the
product obtained after roasting/calcination of the TiP
ore? Write the chemical equation for the reaction Proctice drawing well-lobelled diogram of electrolytic
involved. (C8SE 2023) refining of copper.
Electrolytic Refining of Copper: exothermic The amount of heat evolved is
so large that the metals are produced in the
Key molten state and is thuS USed to oln cracked
machine parts.
Calhode Anode Q2. A metal 'M is stored under kerosene. It vigorously
catches fire, if a small piece of this metal is kept
Acidified copper open in air. Dissolution of this metal In water
sulphale soluion releases great amount of energy and the metal
catches fire. The solution so formed turns red
itmus blue.
- -Tank
() Name the metal 'M.
(iü) Write formula of the compound formed when
this metal is exposed to air.
Ct
() Why is metal 'M stored under kerosene?
(v) Ifoxide of this metal is treated with hydrochloric
Impurilies acid, what would be the products?
(anode mud)
(V) Write balanced equations for:
Reaction for Electrolytic Refining: (a) Reaction of 'M with air.
At cathode: Cu? (og) +2eCu (s) (b) Reaction of'M with water.
At anode: Cu (s) Cu' (oq) 2e (c) Reaction of metal oxide with hydrochlorlc
acid. (CBSE 2020)
-E Long Answer Type Questions Ans. () The metal 'M is sodium (Na).
(i) Formula of the compound formed is Na,0.
Q1 () List in tabular form three chemical properties on (üi) Sodium reacts with oxygen so fast that it catches
the basis of which we can differentiate between fireeif
kept O So. It ont
Is always kept Immersed
a metal and a non-metal.
(ü) Give reasons for the following:
in kerosene oil accidental
fire.
(iv) Sodium oxide reacts with hydrochloric acld to
(a) Most metals conduct electricity well. produce sodium chloride and water.
(b) The reaction of iron (lll) oxide (Fe,0,] with (v) (a) Reaction wlth air. 4Na +0, -2Na,0
heated aluminium is used to join cracked
machine parts. (C8SE 2019) (b) Reaction with water:
Ans. 2Na(s) +2H,0 (0) - 2NaOH(0q) +H, (9)
TiP (c) Reaction of sodium oxide with HC:
+Heat energy
Learn and understand the difference between metols
ond non-metals on the basis of their physicol ond Na,0 (s)+ 2ZHCI (oq) --2NaCl (oq) +H,o(0)
chemical propertles.
Q3. ) By the transfer of electrons, illustrate the
() Difference between metals and non-metals on formation of bond in magnesium chloride and
the basls of chermical properties are: identify the ions present in this compound.
Basis of (i) lonic compounds are solds. Give reasons.
Metal Non-metal
No Difference (i) With the help of a labelled dlagram show the
1. Nature Metals are Non-metals are experimental set up of action of steam on a
metal (CBSE 2020)
electropositive electronegative
and form cations and form anions Ans. 0) Mg + 2e
28.2
Mg?
28
2 Reaction with They react with They react with
oxides OxVgen to form oxygen to form (Magnasium caion)
basic oxides acidic or neutral
2 0.a
oxides (Chioride anion)
3. Reaction with They react with They do not
dilute acids dilute acids to react with dilute ci:
form a salt and acids as they are Mgi
evolve hydrogen incapable to
gas. displace hydrogen i:
(u) (a) Metals are good conductors of electricity (ü) lonic compounds are soids because of the
because they contain free electrons which strong force of attraction between the positive
can move easily through the metal and and negative ions.
conduct electricity. (u) Metals Uke aluminium, Iron and zinc react with
(b) It is a displacement reaction which is highly steam to form the metal oxide and hydrogen
Matal samplo
a strong oxidising agent The layer of aluminium
Hydrogen
GlantIool
wDalod in Baling oxide prevents further reaction ofaluminium due
lubo Glass to which the reactivity of aluminlum decreases.
tube
(ili) Because these metals are highly reactive and
-Cork Waler. readily react with atmospheric oxygen and other
Clamp
Burnar gases.
Sland Detrery (iv) Element Z EC
tubo
Ca 20 2 8 8 2
7 28 7
Chapter Test
Multiple Choice Questions Q3. What happens when calcium is treated with water?
Q1 Observe the given reactions and answer the () t does not react with water.
question that follows: (ü) It reacts violently with water.
Na Na+e (ii) It reacts less violently with water.
(1, 8, 7) (2. 8) (v) Bubbles of H, gas formed stick to the surface of
calcium.
(2,8,8) a. () and (iv) b. () and ()
c ) and (1) d (i) and (iv)
Mg Mg+2e Q4. The electrical conductivity and melting point of an
(2,8,2) (2,8)
alloy is:
Which of the following are correct representations a. less than that of pure metal
for the ionic compounds formed of these ions? b. more than that of pure metal
a
C. equal to that of pure metal
d. electrical conductivity is less and melting point is
more than that of pure metal
b. Assertion and Reason Type Questions
Directions (0. Nos. 5-6): Eoch of the following questions
consists of two statements, one is Assertion (A) and the other
is Reason (R). Give onswer:
a. Both Assertion (A) and Reason (R) are true
d
and Reason (R) is a correct explanation of
Assertion (A).
Q2. Clean small pleces of magnesium, zinc, aluminium, b. Both Assertion (A) and Reason (R) are true
Iron and copper by rubbing them with a plece of but Reason (R) is not a correct explanation of
sand paper. Take them in separate test tubes. Add Assertion (A).
about 10 m of dilute hydrochloric acid to each of c Assertion (A) is true but Reason (R) is false.
them. d. Assertion (A) Is false but Reason (R) is true.
Q5. Assertion (A): Mg0 exists in liquid state.
Reason (R): The electrostatic forces of atraction
between Mg2 andand 0 jons constitute ionic bond.
Q6. Assertion (A): Zinc is used in the galvanisation of
Mg Al Zn Cu Fe iron.
ldentify the correct statement(s). Reason (R): Its coating on iron articles increases
) The rate of evolution of hydrogen gas bubbles their life by protecting iron from rusting.
is not same in all the test tubes. Case Study Based Question
(i) The rate of formation of bubbles is the fastest
in the case of magnesium. Q7. The chemical properties of metals are mostly
(iii) The reactivity decreases in the order: linked with the clectron releasing tendency of
Mg > Zn > Al > Fe > Cu their atoms. Greater the tcndency, more will be the
(iv) In the case of copper, no bubbles are seen and reactivity of the metal. They react with oxygen,
the temperature also remains unchanged. This water, acids, etc. Since they can lose electrons,
shows that copper does not react with dilute
HCL they act as reducing agents. Some rcactions of
a (ü) and (iv) b. (in) and (iv) metals are given as:
c Only (ii) d. (0). (i) and (iv) Metal + Oxygen ’ Metal oxide
Metal + Water >Metal hydroxide + Hydrogen Short Answer Type-I Questions
Melal + Acid ’ Metal salt + Hydrogen Q13. State the conditions under which the following
(diluic) metals react with water. Write chemical equatlon
Metal X + Salt solution of metal Y ’ for its reaction with each: (a) Na (b) Mg (c) Fe
Salt solution of Metal X+ Metal Y Q14. (0) Write the electron dot structure of calcium (20)
(Displacement reaction) and sulphur (16).
Read the above passage carefully and give the (i) Show the formation of Cas by transfer of
answer of the following questions: electrons.
) Metals such as.......a.nd.....a.ct so vigorously () State two physical propertles of Cas.
that they catch fire if kept in the open. Hence, to Q15. Distinguish between the following:
protect them and to prevent accidental fires, they () Electrolytic reduction and electrolytic refining
are kept immersed in.... (i) Minerals and ores
a. phosphorus, magneslum, water (i) Alloys and amalgams.
b. sodium. potassium. kerosene oil Long Answer Type Questions
C. sodium. potassium. water
d. tin. lead. alcohol Q16. Sample pieces of five metals, A, B, C, D and E are
(ii) Which of the following pairs will give dlsplacement added to the tabulated solutlons separately. The
reaction? results observed are shown in the table glven
a. NaCl solution and copper metal below:
b. MgCl,solution and aluminiurm metal Solutlon
c. FeSO, solution and silver metal Metal FeSO CuSO, ZnSO, AgNO, Al(S0),
d. AgNO, solution and copper metal A No Acoating No
(ii) There are four metals K, L, Mand N. Identify them change on metal change
by using the hints given below. 8 Grey Brown No Acoating No
Kforms basic oxide. depositcoating change on metal change
Lforms amphoteric oxide. No No No No No
Oxlde of M dissolves in water to fom alkal. change change change changechange
N does not react with water at all. No No Acoating No
a. K’Zn. L ’ AL M’Na, N’Fe change change on metal change
b. K’ Fe. L ’ Na. M’K. N’Zn E Brown New New No
c. K’K. L’Cu. M’ Pb. N’ Na coating coating coatingchange
d. K’Cu, L ’ Zn, M ’K, N’ Pb Based on the observations recorded in the table
(iv) Food cans are coated with tin and not with zinc answer the following questions:
because: (0) Which is the most reactive metal?
a. zinc is costier than tin (i) Which is the least reactive metal?
b. zinc has a higher melting polnt than tin (i) What would be observed if metal D was added
C. zinc is more reactive than tin
d. zinc Is less reactive than tin to a solution of copper(l) sulphate?
(v) What would be observed if metal E was added
Very Short Answer Type Questions to a solution of iron(ll) sulphate?
(v) Arrange the metals A, B, GD and E in order of
Q8. Name two metals which react with dilute HNO, to decreasing reactivity.
evolve Hgas. Q17. Give reasons for the following:
Q9. Make a distinction between metals and non-metals () Sodium hydroxide solution cannot be kept In
with respect to the nature of their oxide. aluminium contalners.
Short Answer Type-IQuestions () Sitver metal does not combine easily with
Q10. Differentiate between roasting and calcination. oxygen but silver jewellery tarnishes after
Glve examples. some time.
Q1L (0) in electrolytic refining of impure copper metal, (ui) Sodlum is obtalned by the electrolysis of its
what are used as cathode and anode? molten chlorlde and not from its aqueous
solution.
(i) Show the formation of KCl from potassium and (iv) Aluminium reacts with dilute HCl slowy in the
chlorine atoms. beginning.
Q12. Name two metals that start floating after sometime () Hydrogen is not a metal but has been assigned
when immersed in water and explain why they do a place in the reactivity serles of metals.
So.