Bioenergy Lecture Part-3 To Part 7
Bioenergy Lecture Part-3 To Part 7
Efficiency = 87%
Efficiency = 55%
What is Pyrolysis?
“Pyrolysis is thermal cracking in the absence of oxygen.”
Cedric Briens
HEAT
Vapour
Condensation
Biomass
7
Fast Pyrolysis
Process
(Electrostatic
Precipitator)
The Organic Chemistry
Pyrolytic reaction using
cellulose:
Combustible Gas
Liquid Bio-Oil
Biochar
HEAT
3C6H10O5 C6H8O +8H2O +CH4+2CO+2CO2+ 7C
(Cellulose is a complex carbohydrate consisting
of oxygen, carbon, and hydrogen)
Water of Pyrolysis 10
Pyrolysis – Products
1) Intermediate products: Syngas, Charcoal
2) Main products (final products): Bio-oil and Bio-char
3) By products: Electricity and Thermal energy
Pyrolysis – By product
Some Advantages of Pyrolysis of Biomass
• Carbon neutrality
• Utilises otherwise waste biomass
• Potential to be self-sustaining energy-wise
• Increases bulk and energy density of
biomass
• Source of valuable chemicals
• Biomass source can be decoupled from the
energy utilisation
14
Mode of Biomass Pyrolysis
Product yields (dry feed basis) for pyrolysis of wood
16
Carbonisation/ Slow Pyrolysis
Fast Pyrolysis
Essential features of a fast pyrolysis process:
Applications of Bio-Oil
The Challenges
For upgrading of bio-oil to transport fuels
• Low volatility
• Low heating value.
• High viscosity
• Corrosiveness
Every biomass is different!
• Coking
Alternatives to upgrading
• Gasification of bio-oil to syngas
• Combination of bio-oil with diesel
23
Bio-char
27
Organisation of Development Action and Maintainance (ODAM, Tamil Nadu),
with support from the Siemenpuu Foundation in Finland, conducted a series of
biochar field trials in Southern India using common feedstocks to produce the
biochar. And used it for farming purposes.
Part - 4
Gasification
Why biomass gasification?
Biomass that can be used…
Very wide variety of feedstock can be used with simple processing in terms of
sizing and moisture reduction to less than 20%, bulk density of above 100 kgs/m3
& free flowing nature.
Sugarcane bagasse & Wild bushes and weeds Greening of waste lands
Sugarcane trash like Prosopis Juliflora, though production of
(briquetted) Lantana, Invader Bush etc. sturdy Energy species.
Basic Process Chemistry
• Conversion of solid fuels into
combustible gas mixture
called producer gas (CO + H2
+ CH4)
• Involves partial combustion of
biomass
Drying
Drying is what removes the moisture in the biomass before it enters Pyrolysis.
All the moisture needs to be (or will be) removed from the fuel before any
above 100°C processes happen. All of the water in the biomass will get
vaporized out of the fuel at some point in the higher temp processes. Where
and how this happens is one of the major issues that has to be solved for
successful gasification. High moisture content fuel, and/or poor handling of the
moisture internally, is one of the most common reasons for failure to produce
clean gas.
Combustion
Combustion is the only net exothermic process of the Five Processes of Gasification; ultimately, all of
the heat that drives drying, pyrolysis, and reduction comes either directly from combustion, or is
recovered indirectly from combustion by heat exchange processes in a gasifier. Combustion can be
fueled by either the tar gasses or char from Pyrolysis.
Cracking
Cracking is the process of breaking down large complex molecules such as tar into lighter gases by
exposure to heat. This process is crucial for the production of clean gas that is compatible with an internal
combustion engine because tar gases condense into sticky tar that will rapidly foul the valves of an engine.
Cracking is also necessary to ensure proper combustion because complete combustion only occurs when
combustible gases thoroughly mix with oxygen. In the course of combustion, the high temperatures
produced decompose the large tar molecules that pass through the combustion zone.
Reduction
Reduction is the process of stripping oxygen atoms off
combustion products of hydrocarbon (HC) molecules, so
as to return the molecules to forms that can burn again.
Reduction is the direct reverse process of combustion.
Combustion is the combination of combustible gases with
oxygen to release heat, producing water vapor and
carbon dioxide as waste products. Reduction is the
removal of oxygen from these waste products at high
temperature to produce combustible gases. Combustion
and Reduction are equal and opposite reactions. In fact,
in most burning environments, they are both operating
simultaneously, in some form of dynamic equilibrium, with
repeated movement back and forth between the two
processes.
Producer Gas Properties
Benefits…
• Green electricity.
• Use the systems to also generate steam, chilling, hot
water, hot air.
• High plant load factors (PLFs) about 80%.
• Quick and modular solutions with no pollution.
• Generate high energy, high value charcoal & biochar as
by-product.
Applications
1.2 MWe, Grid connected Power Plant using Agri-Residues as Biomass
Two major gasification process
Types of Gasification Processes
Types of Commercial Gasifiers
Although there are various types of gasifers (gasification reactors), different in design
and operational characteristics, there are three main gasifier classifications into which
most of the commercially available gasifiers fall. These categories are as follows:
• Less complex feedstock preparation with the use of coarse coal particles
• Product gas at relatively low temperatures, thus no need for expensive high-temperature heat
recovery equipment
• Feedstock flexibility: suitable to handle coals with high reactivity and moisture
• High "cold-gas" thermal efficiency, when the heating value of the produced hydrocarbon liquids
is accounted for
• Long feedstock residence time in gasifier and slag flow characteristics require carefully
controlled feed size distribution for proper operation
• Hydrocarbon liquids such as tars and oils are produced; increased effort to clean produced gas
if it is used for applications other than direct heating
• Can either be oxygen or air blown, but most commercial plants are oxygen blown
• Slagging operation
• High level of sensible heat in product gas, heat recovery is required to improve efficiency
• Environmentally most benign; produced syngas consists of mainly H2, CO and carbon dioxide
(CO2) with trace amount of other contaminants which can be removed downstream of the
reactor; glassy slag is inert and easily disposed
Fluidized bed gasification
Schematic of a fluidized bed gasifier and variation of the temperatures of coal and gas along the gasifier
is shown in the figure. Fluidized bed gasification offers good mixing of coal and air/oxygen and steam
mixture, which promotes both heat and mass transfer. This ensures an even distribution of material in
the bed and hence, a certain amount of partially reacted fuel is inevitably removed with the ash. This
places limitation on overall carbon conversion in fluidized bed processes. Fluidized bed gasifiers
generally operate below the ash softening temperature, because ash slagging can disturb the
fluidization of the bed. Size of the particles is critical; material that is too fine will tend to entrained in
the syn gas and leaves the bed over head. This is partially captured in cyclones and returned to bed.
This type of gasifier is suitable for reactive feed stocks such as low rank coals and biomass.
Characteristics
Fluidized-bed gasifiers may differ in ash conditions (dry or agglomerated/slagging) and in design
configurations for improving char use. Also, depending on the degree of fluidization and bed height,
these types of reactors sometimes are also named as circulating fluidized bed reactors, and/or
transport reactors.
• Higher cold gas efficiency than entrained-bed gasifiers, but lower carbon conversion
The load following ability of cross draft gasifier is quite good due to
concentrated zones which operate at temperatures up to 12000C.
Start up time (5-10 minutes) is much faster than that of downdraft
and updraft units. The relatively higher temperature in cross draft
gas producer has an obvious effect on exit gas composition such as
high carbon monoxide and low hydrogen and methane content
when dry fuel such as charcoal is used. Cross draft gasifier operates
well on dry air blast and dry fuel.
Part - 5
Gasification: Syngas
Gasification efficiency
Gasification opportunities and
challenges
Gasification: Syngas upgrading to fuels
• The carbon monoxide (CO) and hydrogen Fischer-Tropsch (FT) Synthesis
(H2) in the syngas are reacted over a catalyst
to form a wide range of hydrocarbon chains
of various lengths it is called Fischer-
Tropsch (FT) synthesis.
• The catalysts used are generally cobalt or
iron based. The reaction is performed at a
pressure of 20–40 bar and range of a
temperature either 200-250°C or 300-
350°C.
• Iron catalysts are generally used at the
higher temperature range to produce a in
this olefins lighter gasoline product.
• Cobalt catalysts are used at the lower
temperature range to produce waxy, long-
chained products that can be cracked for
diesel.
• Iron and cobalt catalysts can be used in a
range of different reactor types (fixed bed,
slurry reactor etc) to produce FT diesel.
CO
C–O Distribution
Mix H-H Tower
• The main sources of sugar required to produce ethanol come from fuel or energy crops. These crops are
grown specifically for energy use and include corn, maize and wheat crops, waste straw, willow and popular
trees, sawdust, reed canary grass, cord grasses, jerusalem artichoke, myscanthus and sorghum plants. There
is also ongoing research and development into the use of municipal solid wastes to produce ethanol fuel.
• Ethanol or ethyl alcohol (C2H5OH) is a clear colourless liquid, it is biodegradable, low in toxicity and causes
little environmental pollution if spilt. Ethanol burns to produce carbon dioxide and water. Ethanol is a high
octane fuel and has replaced lead as an octane enhancer in petrol. By blending ethanol with gasoline we can
also oxygenate the fuel mixture so it burns more completely and reduces polluting emissions. Ethanol fuel
blends are widely sold in the United States. The most common blend is 10% ethanol and 90% petrol (E10).
Vehicle engines require no modifications to run on E10 and vehicle warranties are unaffected also. Only
flexible fuel vehicles can run on up to 85% ethanol and 15% petrol blends (E85).
• Wheat/ grains/ corn/ sugar-cane can be used to produce ethanol
(Basically, any plants/ crops that composed largely of sugars)
Biomass
feedstock
Second Generation
for
bioethanol
production
• Biomass wastes consist of a complex mixture of carbohydrate polymers such as cellulose, hemi cellulose and lignin. Biomass is pre-
treated with acids or allowed to react with enzymes to reduce the size of the feedstock and produce sugars.
• The carbohydrate polymers are broken down with the help of enzymes or dilute acids into sucrose sugar and then fermented into
bioethanol. However, the lignin present in the biomass is used as a fuel for boilers in which bioethanol is produced. Enzymatic
hydrolysis, concentrated acid hydrolysis and dilute acid hydrolysis are the three basic methods for extracting sugar from biomass.
• On the other hand, corn can be processed into ethanol by either dry milling or wet milling. In the dry milling process, the corn
kernel is cleaned and broken down into fine particles through hammer milling. This process creates a powder with a course flour-
type consistency. The wet milling process involves soaking corn kernel in warm water to break down its proteins and release
starch.
• Once the biomass or corn is broken down into sugar via the hydrolysis process, the sugar solution is
ready to be fermented into ethanol. The addition of yeast to the solution followed by rapid heating
converts the sucrose sugars into fructose and glucose with the help of invertase present in the
yeast.
• These sugars further react with another enzyme, zymase, contained in the yeast to yield ethanol
and carbon dioxide. The fermentation process is carried out at temperatures between 250 and
300°C. The ethanol thus produced undergoes the fractional distillation process to remove excess
❖ Water-saving ethanol plant designs are very common. In addition, the water
discharged from these plants is regulated such that the water is environmentally
neutral when it leaves the plant.
❖ Certain plants manage and reuse the wastewater generated during the ethanol
process. Therefore, it is evident that using bioethanol has a positive effect on
ecology, minimizes exhaust gas emissions and improves energy safety and operation
of transport facilities.
Bioethanol from Algae
• Researchers have recently launched a proposal to cultivate massive amounts of seaweed or
algae. They claims that the project could occupy about ten thousand kilometers of seaweed
farm and they estimated that the farm would be able to produce bioethanol from algae, as
much as 20 million kiloliters or 5.3 billion gallons of bioethanol per year. This amount equal to
a third of Japanese fuel consumption a per year.
• Seaweed / algae has already been proven to be capable of becoming an alternative option
for producing biofuel. Most of the biofuel today is produced from food stock which has
its own disadvantage and the ratio of the crops and the amount of ethanol that it produces is
not balanced. Some suggest that the using of food stock for bioethanol production has
caused food prices to rise.
• This would be then processed by floating bio reactors. Facilities that would use enzyme to
breakdown the seaweed into sugar which would then be processed and be converted to
ethanol. This process will take place on the sea and would be then transported to land by
tankers.
What are the advantages of using algae / seaweed for
bioethanol production?
• We would be able to avoid the food price hike, if we would utilize this
new technology for we will no longer be taking away lands to farm
crops.
Some designs for nuclear power plants have toyed with the idea of using a Brayton cycle, such as the
South African Pebble-bed modular reactor and certain molten salt reactors. This would require using
heated gas from the reactor core to power the turbines. However, the large amount of research and
development needed to implement this has so far been a barrier preventing success. The majority of
nuclear reactors instead use a Rankine cycle steam engine, so current gas-cooled models must use
this heated gas to heat water in turn for the steam engine turbines.
Efficiency
Efficiency is a comparison of the energy output to the energy input in a given system.
It is defined as the percentage ratio of the output energy to the input energy, given
by the equation:
Efficiency = (Eout / Ein) × 100%
This equation is commonly used in order to represent energy in the form
of heat or power.