CT Concrete&Steel Module 1 Lecture Material
CT Concrete&Steel Module 1 Lecture Material
Technology –
Concrete & Steel
BARC205E: MODULE 1
• Cement is a finely ground powder that acts as a ‘hydraulic binder’ which means
it hardens when water is added. This process is called ‘hydration’.
Standard cement mix ratio is 4 parts of aggregate, 2 parts of sand and 1 part of
cement
The Roman Secret: Unveiling the History of Cement
o The most famous buildings still stand today including the Roman
Pantheon (which remains the largest unreinforced concrete
dome in the world) and the Colosseum.
The Pantheon
From Lime Mortars to Portland Cement
Portland Cement is produced by heating (at about 1350–1400°C) a precise blend of limestone (a
source of calcium), clay, and other materials in a kiln at high temperatures to form clinker, which
is then finely ground with gypsum (a source of sulfate).
The inventor Joseph Aspdin, of England, patented the basic process in 1824. The name has
been derived based on a Portland stone, a limestone from the Isle of Portland.
Improvements in Manufacturing Portland Cement
Rotary Kiln (Mid-19th Century):
The introduction of the rotary kiln revolutionized cement production. This more efficient
method used a continuously rotating cylindrical furnace to heat the raw materials, leading to
increased production capacity and improved quality control.
Fine Grinding (Late 19th Century):
Developing methods for finer grinding of clinker enhanced the reactivity of cement with
water, resulting in faster setting times and potentially stronger concrete.
Portland Cement Blends (20th Century):
The addition of supplementary cementitious materials (SCMs) like fly ash or slag to Portland
cement became a common practice.
Cement Ingredients
Raw materials, composition and function
Raw Materials for Manufacture of Cement
Corrective Auxiliary
Lime Component Clay Component
Ingredients Components
Lime Component
Limestone:
• Calcium carbonate (CaCO3) of all geological formations qualifies for the production of Portland cement.
• Limestone is of a predominantly fine grained crystalline structure.
• The hardness of limestone depends on its geological age; usually, the older the geological formation, the Limestone
harder the limestone.
• Limestone usually contains admixtures of clay substance or of iron compounds, which influence its
color.
Chalk:
• Chalk is a sedimentary rock which is characterized by a soft earthy texture.
• It is used as a raw material especially for the wet process of cement manufacture.
• Since blasting is not required for quarrying of chalk, and the crushing process can also be omitted, this Chalk
raw material considerably lowers the cement production costs.
Marl:
• Limestone with admixtures of silica, clay substance, and iron oxide are called marls.
• The hardness of marls is lower than that of limestone; the higher the content of clay substances, the lower
their hardness.
• Marls are an excellent raw material for cement manufacture, because they contain the lime and the clay
component in an already homogenized condition. Marl
Raw Materials for Manufacture of Cement
Clay Component
• Clay is formed by the weathering of alkali and alkaline earth containing aluminum silicates and of their chemical
conversion products, mainly feldspar and mica.
• Texturally, clays are fine grained; clay particles are usually under 2 microns in diameter.
• However, the chemical composition of clay may vary from those close to the pure clay, to that containing a con-
siderable amount of chemical admixtures as iron hydroxide, iron sulfide, sand, calcium carbonate, etc.
Raw Materials for Manufacture of Cement
Corrective Ingredients
• Corrective ingredients, also known as additives, are materials introduced into the cement production process to
compensate for compositional deficiencies in the raw mix or to adjust specific properties of the final cement.
• For the completion of the silica content, sand, high silica clay, diatomite, etc., are used as additives or corrective
ingredients.
• To compensate for deficiency in iron oxide (Fe2O3), such corrective materials as pyrite cinders, iron ore, etc., are
applied.
Raw Materials for Manufacture of Cement
Auxiliary Components
• Auxiliary components are added to influence various aspects of production, from raw material preparation to the
final cement product.
• The incorporation of alternative fuels and mineral admixtures promotes a more sustainable cement industry.
Magnesium Oxide
Alkalis such as Na2O and K2O
Other Auxiliary Sulphur
Components Chloride
Fluoride
Phosphorus
Composition and Function of Raw Materials in Cement
Cement
Manufacturing
Process
Stages, Storage, Package & Dispatch
Stage 1: Stages of Cement Manufacture
Raw Material
Extraction/Quarry
Stage 2:
Crushing, Proportioning,
and Blending
Stage 3:
Pre-Heating Raw Material
Stage 4:
Kiln Phase
Stage 5:
Cooling and final grinding
Stage 6:
Packing and Shipping
The ore rocks are quarried and crushed into smaller pieces of about 6 inches.
Stage 1:
Raw Material Secondary crushers or hammer mills then reduce them to an even smaller size of 3
Extraction/Quarry inches. After that, the ingredients are prepared for pyro processing.
Stage 2: CRUSHING:
Crushing, Proportioning, The crushed raw ingredients are made ready for the cement-making process in the kiln
and Blending by combining them with additives and grinding them to ensure a fine homogenous
mixture.
Stage 3:
Pre-Heating Raw Material BLENDING:
1. Dry blending:
Stage 4: In the cement plant, the raw mix is dried (moisture content reduced to less
Kiln Phase than 1%); heavy wheel-type rollers and rotating tables blend the raw mix and then
the roller crushes it to a fine powder to be stored and fed to the kiln.
Stage 5:
Cooling and final grinding 2. Wet blending:
Raw materials are broken down by vigorous stirring with water in wash mills,
Stage 6: producing a fine slurry. The slurry tanks are stirred by mechanical means or compressed
Packing and Shipping air or both.
PRE-HEATING:
Stage 1: • A pre-heating chamber utilizes the hot gases produced from the kiln in order to
Raw Material reduce energy consumption and make the cement-making process more
Extraction/Quarry environment-friendly. The raw materials are passed through here and turned into
oxides to be burned in the kiln.
Stage 2:
Crushing, Proportioning, KILN PHASE:
and Blending • The clinker is produced from the raw mix through a series of chemical reactions
between calcium and silicon dioxide compounds. The kiln is angled by 3 degrees to
Stage 3: the horizontal. Cylindrical steel kilns, lined with refractory materials, range from 200
Pre-Heating Raw Material meters long and 7 meters in diameter in wet process plants to shorter lengths in dry
process plants.
Stage 4:
Kiln Phase Though the process is complex, the events of the clinker production can be written in
the following sequence:
Stage 5: 1. 100°C (212°F): Evaporation of free water
Cooling and final grinding 2. 100°C (212°F) - 430°C (800°F): Dehydration and formation of oxides of silicon,
aluminum, and iron
Stage 6: 3. 900°C (1650°F) - 982°C (1800°F): CO2 is evolved and CaO is produced through
Packing and Shipping calcination
4. 1510°C (2750°F): Cement clinker is formed
CLINKER COOLING:
Stage 1: • After exiting the kiln, the clinker is rapidly cooled down from 2000°C to 100°C-200°C
Raw Material by passing air over it.
Extraction/Quarry
• At this stage, different additives are combined with the clinker to be ground in order
Stage 2: to produce the final product, cement.
Crushing, Proportioning,
and Blending • Gypsum added to and ground with clinker regulates the setting time and gives the
most important property of cement, compressive strength.
Stage 3:
Pre-Heating Raw Material • Clinker heat is recycled to boost kiln efficiency.
Stage 4: • The final stage involves grinding cooled clinker into a fine powder using steel ball-
Kiln Phase lined rotating drums, producing 150 billion grains per pound of cement.
Stage 5:
Cooling and final grinding PACKING AND SHIPPING:
• Cement is conveyed from grinding mills to silos from where it is packed in 50 kg bags.
Stage 6:
Packing and Shipping • Most of the product is shipped in bulk quantities by trucks, trains, or ships.
Tests for Cement
Field Testing & Lab Testing
Field tests
1. Fineness Test a. Put a filter paper into the cell then weight 2.84g of cement sample into it.
a) Sieve test b. Put another filter paper on it and compress with the plunger.
c. Attach the cell on top of the U-tube manometer.
b) Air permeability d. Evacuate the air in the manometer through the side tube using the aspirator bulb
test until the oil reaches level 1.
e. Close the side valve and monitor the oil as it start to fall.
2. Consistency Test f. Using a stop watch, measure the time taken for the oil to fall from level 2 to level 3.
3. Setting Time g. The S value of OPC cement should not be less than 2250 cm2/gm.
1. Fineness Test
CONSISTENCY TEST:
a) Sieve test This test is conducted to find the setting
b) Air permeability times of cement using a Vicat’s apparatus.
7. Chemical Composition After the paste has attained hardness, the needle does not penetrate the paste more
Test than 0.5 mm. The time at which the needle does not penetrate more than 0.5 mm is
taken as the final setting time.
8. Tensile Strength Test
Lab tests
1. Fineness Test
SOUNDNESS TEST:
a) Sieve test
Importance of Soundness Test of Cement:
b) Air permeability
test • The soundness test of Cement measures
the expansion that occurs in hardened
2. Consistency Test Cement, known as soundness.
3. Setting Time
The Le Chatelier equipment is used to test the
4. Soundness Test durability of Cement.
5. Compressive Strength
The apparatus is used to detect the presence
Test of uncombined lime and magnesia in cement.
6. Heat of Hydration Test
For OPC, Low heat cement, High alumina
7. Chemical Composition cement and rapid hardening cement, the
Test soundness obtained must not exceed 10mm.
1. Fineness Test
a) Sieve test COMPRESSIVE STRENGTH TEST:
b) Air permeability
The compressive strength test can only be
test done once the standard consistency test has
2. Consistency Test been completed.
1. Fineness Test
a) Sieve test HEAT OF HYDRATION TEST:
b) Air permeability
During the hydration of cement, heat is produced due to
test chemical reactions.
2. Consistency Test
This heat may raise the temperature of concrete to a high
3. Setting Time temperature of 50°C. To avoid these, in large scale
4. Soundness Test constructions low-heat cement has to be used.
5. Compressive Strength This test is carried out using a calorimeter adopting the
Test principle of determining heat gain.
6. Heat of Hydration Test It is concluded that Low-heat cement should not
7. Chemical Composition generate 65 calories per gram of cement in 7 days and 75
calories per gram of cement in 28 days.
Test
8. Tensile Strength Test
Lab tests
a) Sieve test The briquette method is used to determine the tensile strength of
b) Air permeability Cement.
3. Setting Time A 1:3 cement-sand mortar with the water content of 8% is mixed
4. Soundness Test and moulded into a briquette in the mould.
5. Compressive Strength This mixture is cured for 24 hours at a temperature of 25°C - 29°C
Test and in an atmosphere at 90% relative humidity.
6. Heat of Hydration Test The average strength for six briquettes tested after 3 and 7 days is
7. Chemical Composition recorded.
Overall, OPC is a reliable choice for many construction needs due to its robust
and adaptable nature.
TYPES OF HYDRAULIC CEMENT
2. PORTLAND POZZOLANA CEMENT (PPC):
Portland Pozzolana cement (PPC) is a type of hydraulic cement that's made by blending Portland cement (OPC Clinker +
gypsum) with pozzolanic materials, such as fly ash or silica fume.
The pozzolanic materials improve the workability and durability of the cement, making it suitable for a variety of
construction applications.
PPC is commonly used in home building construction and mass concrete structures, such as dams and bridges, where
durability is a critical factor.
TYPES OF HYDRAULIC CEMENT
3. RAPID HARDENING CEMENT:
• The strength of this cement after three days is almost the same as the
Portland cement after a week, with the same water-cement ratio.
• The main benefit of using rapid hardening cement is that the formwork
can be removed earlier, lowering the cost of construction.
• Low heat cement is made by reducing the amount of tricalcium aluminate by 6%.
• This results in slower strength gain and lower heat of hydration, making it ideal for use in large concrete structures
that are prone to cracking due to heat buildup.
• Low-heat cement is commonly used in the construction of dams, nuclear power plants, and large-mass concrete
structures.
TYPES OF HYDRAULIC CEMENT
6. SULFATE RESISTANT CEMENT:
• Sulphate-resisting cement is a type of hydraulic cement that's designed to resist the damaging effects of sulphate
salts present in soil and groundwater.
• Sulphate-resistant cement is commonly used in construction projects where the soil or groundwater has a high
sulphate content, such as in coastal areas, mines, and canal linings, retaining walls.
7. WHITE CEMENT:
• It is used in areas where the temperature is very low and areas that require
frost resistance infrastructure, such as concrete pavements, bridges, and
buildings located in cold climates.
GRADES OF CEMENT
• A grade of cement indicates its strength that is measured in Mega Pascal (Mpa) or N/mm2.
• Strength of cement is usually measured after 28 days of curing for a standard cube.
33 Grade Cement
43 Grade Cement
53 Grade Cement