CODE-A

K-2
NEET-19 are
=N
toluene
HC in
and sp sp carbon
-CHy
(2) -CHO
(4) H,C=0 & &
sp²
ASSIGNMENT-29
CHEMISTRY sp is (2)
2 4
(2) (4) C,H, (4) hybridized
5(2) 1(4) is
compound
for in
carbon in
1-hydroxycyclohexene
(2)
alcohol
(3)
Cyclohexene
Cyclohex-3-en-1-ol
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Foundatlons
-OH
(1)
of
sp
respectively

carbon
Hybridizationsp of
& & Covalency

sp²
of CH,
Number
are
the
of
name Hexenol
(4)
Lnd.)New sp² sp² 6(1) (3)
4 IUPAC
OH
1(1) 3
(3) (1)
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6. 7 8, (1)
Educallonal
8, compound But-3-yne-1-ene
(4)
Tower,
Aakash Enhancement ?compound
Chemistry
But-3-Gn-1-yne
(2) is following ls
following
Aakash these
of
(Dlvlslons following isCH,CH-C#CH cOOH (2)
heterocyclic the (4)
CN
Ofice: of among the
Organic All 2 4(4)
(2)
in in
(2) (4) atoms group
Regd, group
Generalanswer:
is
following 2°-Carbon But-1-yn-3-gn9
(3)
ÇH,
functional
(1)
But1-on-3-yno
priority
of
Rank :
Covered
Toplcs correct
the of
name
Maximum (3) OH Principal
Number IUPAC
theofWhich
Chemlstry 1(1) 3
(3)
Choose (1)
IS 9.
3. 4
2.
 for NEET-19
Chemistry Assignment
Rank Enhancement Proramme
19. Out of acetone and propen-1-ol, which one is me
10. IUPAC name ofis stable
(1) Neo-pentane (1) Acetone
(2) lsobutane (2) Propen-1-ol
(3) 2, 2-Dimethyl pentane (3) Both are equally stable
(4) 2, 2-Dimethylpropane (4) Stability can't be compared
11. Correct IUPAC name of compound 20. Free radicals are formed by
(1) High temperature
(2) Presence of light
(1) 1-Ethyl -2, 2-dimethyl cyclohexane (3) Presence of peroxide
(2) 1, 1-Dimethyl-2--ethylcyclohexane (4) Allof these
(3) 2-Ethyl-1, 1-dimethylcyclohexane
21. Which of the following is/are electrophile?
(4) All are correct
(1) H+ (2) BF,
12. Which shows ester group? (4) Allof these
(1) -COOR (2) -so,H (3) AICI,
22. Electron rich species are known as
(3) NH, (4) NO,
(1) Electrophiles (2) Nucleophiles
13. Ethylalcohol and dimethyl ether are
(3) Free radicals (4) None of these
(1) Chain isomers (2) Position isomers
(4) Functional isomers 23. Inductive effect is
(3) Metamers
14. Propan-1-ol and propan-2-ol are (1) Distance dependent effect
(1) Functional isomers (2) Chain isomers (2) Temporary effect
(3) Position isomers (4) Tautomers (3) Stronger than mesomeric effect always
15. Which of the following is/are example(s) of (4) All of these
metamers?
24. Which of the following is the strongest acid?
(1) CH,--CH-CH,-CH, &CH,-CH,-O-CH (1) HCOOH
CH,
(2) CH,-CH,-NH, &CH,-NH-CH, (2) CH,-COOH
(3) Both (1)&(2) (3) CH,-CH, COOH
(4) C,H,OH &CH,OH (4) CH,-CH,-CH,-COOH
16. The number of structural isomers of CH,, is 25. Displacement of -electrons due to attack of a
(1) 2 (2) 3 nucleophile or an electrophile is called
(1) Inductive effect (2) Electromeric effect
(3) 4 (4) 5
17. Glucose and fructose are: (3) Mesomeric effect (4) Allof these
(1) Positional isomers 26. Cis and trans isomers are
(2) Metamers (1) Stereo isomners (2) Functional isomers
(3) Chain isomers (3) Metamers (4) Tautomers
(4) Functional isomers 27. Select the
18. The number of tautomerisable hydrogens in
aromatic compound in the following
acetaldehyde is (1)
(2)
(1) 3 (2) 2
(3) 4 (4) 0 (3)
(4) All of
(2)
these
Chemlstry Asslgnmnent-20
Rank Enhancement Programme for NEET-19
28 Which is least roactlve to nitration2 36. The enolic form of acetone contains
(1) Benzene (2) Nitrobenzene
(1) Nine o-bonds, one r-bonds and two lone pairs
(3) Chlorobenzene (4) Anlline
(2) Eight o-bonds, two -bond and two lone pairs
IUPACname of smallest
29. is saturated alcohol which (3) Nine G-bonds, one -bond and one lone pair
optically active
(1) Butan-1-ol (2) Butan-2-ol
(4) Nine G-bonds, two T-bonds and one lone pair
(3) Pentan-2-ol 37. Compound giving violet colouration in test of
(4) Propanol sulphur is
n How many primary (1") carbon atoms are present (1) Na,[Fe(CN),NO] (2) Na[FeCN),NOS]
In 4-ethyl, 2, 3dimethyl hexane?
(2) 3
(3) Fe,[FeCN)l (4) Na,[Fe(CN),]
() 2 38. Which of the following is not an aromatic
(3) 5 (4) 6 Compound?
34. Which of the following is functional isomer of
butan-2-ol? H

(1) Butan-1-ol (1) (2)

(2) Ethoxy ethane

H
(3) 2-Methyl propan-2-ol
(3) (4)
(4) All of these
32. Carbocations are involved all reactions except 39. What is maximum number of isomers for formula
(1) Dehydration of alcohols C,H,?
(2) Addition of HBr to propene (1) 2 (2) 3
(3) Aldol condensation (3) 4 (4) 5
(4) S,1 reaction 40. Toluene, when treated with Br,/Fe, gives
p-bromotoluene as the major product because -
33. Compound having sp, sp² and sp hybridised C CH, group
atom
(1) Is para directing due to hyperconjugation
OH (2) Is meta directing due to inductive effect
(1) (2 -CH (3) Activates the ring through inductive effect
(4) Deactivates the ring
(3) (4) 41. Cis but-2-ene has higher boiling point than
0-H trans but-2-ene. It is because of
34. Which of the following is the most stable? (1) Hydrogen bonding in cis-isomer
(1) (2) Higher molecular mass of cis-isomer
oCCI, (3) London dispersion in cis-isomer

(3) (4) (4) Polarity in cis-isomer

CBr, Cl, 42. Order of electronegativity of carbon is

35. Correct IUPAC name for given (1) Csp >CspGsp?

compound
(1) 3-cyclopropylbut-1-ene (2) Gsp =Csp=Csp?
(2) 2-cyclopropylbut-3-ene (3) Csp sp
(3) 1-butenyl cyclopropane
(9) 1-(methyl propenyl) (4) Csp <C2<so
cyclopropane
(3)
 Chemistry Assignment
for NEET-19
Rank Enhancement Programme
CH,
the purificatíon CH,
43. Which of the following is used for
b.p.?
a liquid that decomposes before (2)
(2) Sublimation (1) -CH,
(1) Distillation -CH,
(3) Vacuum distillation (4) All of these
44. Liebig method is used for the estimation of (4)
(3)
(1) Nitrogen
(2) Sulphur 51. Which is not found in
alkenes?
(3) Carbon and Hydrogen (1) Chain isomerism
(4) Halogens (2) Geometrical isomerism
colour in
45. The compound that does not gíve a blue (3) Metamerism
Lassaigne's test of nitrogen is (4) Position isomerism
(1) Aniline (2) Glycine tautomerism?
52. Which of the following cannot exhibit
(3) Hydrazine (4) Urea
46. The structures (CH,),CBr and CH,(CH,),Br
represent
(1) Chain Isomerism (1) (2) |
(2) Optical isomerism
(3) Geometrical isomerism
(4) Functional Isomerism (3) (4) All of these
47. Geometrical isomerism can be exhibited by
53. The correct oder of stability is
(1) (2) () (CH),C> (CH),CH >CH,> CH,CH
(3) -N=N (4) Allof these (2) CH,CH,* > CH, > (CH,,CH* > (CH),C*
48. Which of the following compounds will have (3) CH,CH,> CH,>(CHJ,CH >(CH,),C
highest dipole moment? (4) All of these
NO, NO, 54. How many isomeric alkenes can form isopentane
OH only on hydrogenation?
(1) (2)
OH (1) 2 (2) 4
(3) 1 (4) 3
NO,
55. Choose the correct pair.
(3) (4) Allare equal (1) Trans but-2-ene < cis but-2-ene (Dipole
OH moment)
49. In Carius estimation of iodine, 0.20 g of an organic (2) Trans but-2-ene cis but-2-ene
compound gave 0.33 g of silver iodide. The
percentage of iodine in the organic compound is
(aHhydrogendalion
(3) Cis but-2ene < trans but-2ene (Boiling point)
(1) 24.4% (2) 19.87% (4) Cis but-2-ene > trans but-2-ene (Melting point)
(3) 89.17% (4) 98.71% 56. Correct order regarding stability of Gonfommation of
50. Select the rearranged major product of following cyclo-hexane.
carbocation (1) Chair > twist boat > boat > half chair
CH, (2) Chair > boat > twist boat > half chair
(3) Chair > boat > half chair > twist boat
(4) Chair > half chair > boat > twist boat
(4)
 A e n tPA
heaty
RAnk Enhanoement Prourenme for NEET-19
the following free ladieala ln the lnoreaalNg
57 Anange 62.
alability
onte of thelr Tautomerlsm is exhlblted by
-
(1) O (2)
(0) (O) (D) (3) C-CH CHOH (3) Both (2) &(3)
()DCA R
03. Arange the following compOunds the decrsasing
order of thelr valuas of pk,
()AB D> I. CH, COOH
I, H-COOH
A8 Which one of the following compounde le most
basic in aqueous medlunn? . CH, COOH
() (C,), N 2) (CH,), NH (3) |> | >|
) CH,CH,NH, (4) CH,NIH, 04. Whlch one of the followlngg cerbocatlons ls most
elable ?
A9 The homolytie and heterolytle bond dlasoclatlon
enegy of a diatonic molecule (AB) la glven as
(1) CH, - ¢- CH, (2) C,H, -H,
A-B(g)> AtB, AH = xkJmol CH,
A-B(g)-A'+B, AH = ykJmol
(3) C,H, H- CH, (4) CH, =CH-CH,
Which one of the following statements about x and
y is comect? 86. Identify the type of leomerlsm shown by the
() N>y following compounde.
I. CH,CH, CH,NH,
I. CH,CH,NHCH,
(2) Depends on nature of A and B
o0 Which of the following compound ahow8 CH, -N- CH,
geometical isomerts? IlI,

() GH, GH= NOH (1) Chaln lsomerlsm

@) CH, -N=NCH, (2) Functlonal lsomerism
(3) Positlon lsomerlsm
(3) CH, -CH - Ç-CH,CH, (4) Metamorlsm
H, 66, IUPAC name of the following compound is
(4) All of these
ô1. ChoOsa the aromatic Compound from the following.
OH

(1)
(2)
(1) Proplophenone
(2) Ethyl phenyl ketone
(3) (3) Phenylpropanal
(4)
(4) Ethylbenzalcdahyce
(6)
 Chemistry Assignment-2%
Programme for NEET-19 estimation of halogen W
Rank Enhancement Carius method of
69. Inof an gram
geometrical isomers shown by molecular organic compound gave m, gram of AgBr.
67. Nunmber of Then % of bromine in the
compound is
fomula C,H(CH,)CIBr
80 m,
(1) 2 m, x 100 (2) X -100
(1) 188 W
W
(2) 4 80 W
188 W x 100 x 100
(3) 6
(3) 80 (4) 188 m,
(4) 8 does not gave
following statements about 70. Lassaigne's extract of a compound sulphate then
68. Which one of the blood red coloured ppt. with ferrous
carbenes is not true? correct?
singlet which of the following statement is
(1) Triplet carbene is more stable than (1) It contains N only, no sulphur is present
(2) Singlet carbene is paramagnetic (2) It contains S only, no nitrogen is present
carbenes are
(3) Both singlet and triplet (3) It does not contain N and S both
electropiles or S
(4) It may or may not contain N
(4) Triplet carbene is linear
ChemistryAssignment-29
Rank Enhancement Programme for NEET-19
K-2
CODE-A

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Rank Enhancement Programme for NEET-19

CHEMISTRY ASSIGNMENT-29
Answers
1 (4) 15. (3) 29. (2) 43. (3) 57. (3)

2. (1) 16. (2) 30. (3) 44. (3) 58. (2)

3 (1) 17. (4) 31. (2) 45. (3) 59. (2)

4. (2) 18. (1) 32. (3) 46. (1) 60. (4)

5 (4) 19. (1) 33. (3) 47. (4) 61. (2)

6 (1) 20. (4) 34. (1) 48. (2) 62. (3)

7 (4) 21. (4) 35. (1) 49. (3) 63. (1)

8 (1) 22. (2) 36. (1) 50. (3) 64. (3)

9 2) 23. (1) 37. (2) 51. (3) 65. (2

10. (4) 24. (1) 38. (3) 52. (4) 66. (1)

11. (3) 39. (1) 53. (3) 67. (3)

25. (2)

12. (1) 26. (1) 40. (1) 54. (4) 68. (2

13. (4) 27. (4) 41. (4) 55. (1) 69. (2)

14. (3) 28. (2) 42. (3) 56. (1) 70. (4)

(7)