Target Test Contact Number: 9667591930 / 8527521718

Chemistry - Section
4. The structure of diphenylmethane is given
below:

A
1. An alkane can form Structural isomers if the
number of carbon atoms is-
1. ≥1 The number of structural isomers possible
2. ≥2 when one of the hydrogen atom is replaced by
3. ≥3 a chlorine atom are :
4. ≥4 1. 6 2. 4
3. 8 4. 7
2. Which one of the following pairs represents
stereoisomerism?
1. Chain isomerism and rotational isomerism
2. Structural isomerism and geometrical 5.
isomerism
3. Linkage isomerism and geometrical ​
isomerism . Where X and Y are
4. Optical isomerism and geometrical 1. Positional isomers
isomerism 2. Functional isomers
3. Metamers
3. Which of the following pairs of carbon 4. Tautomers
skeletons is an example of isomerism?
6. The shortest C-C bond distance is found
in
1. Diamond
2. Ethane
1. 3. Benzene
4. Acetylene

7. Among the following, the strongest acid is:

1. CH3COOH 2. CH2ClCH2COOH
2. 3. CH2ClCOOH 4. CH3CH2COOH

8. Which of the following represent the correct

decreasing order of acidic strength of
3.
following?
(i) Methanoic acid
(ii) Ethanoic acid
(iii) Propanoic acid
(iv) Butanoic acid
4. 1. (i)>(ii)>(iii)>(iv)
2. (ii)>(iii)>(iv)>(i)
3. (i)>(iv)>(iii)>(ii)
4. (iv)>(i)>(iii)>(ii)

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9. The strongest acid, among the compounds 13. The most stable carbocation among the
given below, is: following is:
1. HC≡CH
2. C6H6
3. C2H6 1. 2.
4. CH3OH

10. Which of the following happens to be the

carbanion with highest stability?
3. 4.

14. Which of the following statements about the

inductive effect is correct?
The inductive effect transfers electrons
1.
from one carbon atom to another.
The inductive effect operates in both σ-
2.
and π-bonds.
3. The inductive effect does not create any
charge in the molecule.
11. The IUPAC name of the following 4. The inductive effect creates partial charges
compounds is: and is distance-dependent.

15. In Kjeldahl's method, the nitrogen present is

estimated as-
1. N2
2. NH3
1. 1-Bromocyclohexane carboxylic acid
3. NO2
2. 3-Bromocyclohexanoic acid
3. 3-Bromoheptanoic acid 4 None of the above
4. 3-Bromocyclohexanecarboxylic acid
16. The Prussian blue colour obtained during
12. Which of the following σ-bonds participate the test of nitrogen by Lassaigne's test is due to
in hyperconjugation? the formation of-
1. Fe4[Fe(CN)6]3 2. Na3[Fe(CN)6]
3. Fe(CN)3 4. Na4[Fe(CN)5NOS]

1. I and II 2. I and V
3. II and IV 4. III and IV

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17. 22.
The IUPAC name iS'
1. Chloromethylbenzene
2. Chlorophenylmethane
The IUPAC name of 3. (1) and (2) both
i​ s- 4. None of the above
1. 3-(Methylethyl)pentan-2-one
2. 3-(Methylethyl)pentan-4-one 23. The compound which forms one
3. 3-Ethyl-4-Methylpentan-2-one monochloro product when treated with
4. 3-Ethyl-2-Methylethyl-4-one chlorine is:
(1) n-pentane
(2) isopentane
18. The IUPAC name of Glutaric acid is: (3) neo-pentane
1. Pentane-1, 5-dioic acid (4) None of these
2. Pentene-1, 5-dicarboxylic acid
3. Propane-1, 3-dioic acid 24. Nucleophiles are:
4. None of the above 1. electron loving
2. electron hating
19. The IUPAC name of 3. nucleus loving
4. nucleus hating
​ is:
25. In hyperconjugation, the atom involved is:
(1) propene-1, 3-dial 1. βΗ atom
(2) Propene-1, 3-dicarbaldehyde 2. α-H atom
(3) Pent-3-ene-1, 5-dial 3. γ-H atom
(4) Pent-2-ene-1, 5-dial 4. All of these

20. The IUPAC name of (CH3)3C CH2CH2Cl is: 26. Who pointed out the concept of
(1) 2, 2-Dimethyl-4-chloro butane hyperconjugation?
(2) 1-Chloro-3, 3-dimethylbutane (1) Nathan and Baker
(3) 4-Chloro-2, 2-dimethyl butane (2) Mulliken
(4) none of these (3) Kekule
(4) Kolbe
21.
IUPAC name of the following compound is:

CH3 − CH − CH2 − O − C2 H5

OH

1. 1-Ethoxypropan-2-ol
2. 3-Ethoxypropan-2-ol
3. 1-Ethoxy-2-hydroxypropane
4. None of these

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27. Which of the following is the most unlikely 32. The non-staggered form(s) of ethane among
resonance structure for the p-nitrophenoxide the following is-
ion?

1. 2.

1. 2.
3. 4. None of these

33. Which of the following acids shows

stereoisomerism?
1. Oxalic acid
2. Tartaric acid
3. 4. 3. Acetic acid
4. Formic acid

34. The structure of isobutyl group in an

organic compound is

28. Which of the following is an electrophilic

reagent?
1. RO-
2. BF3
3. NH3
4. ROH

29. Allyl isocyanide has:

1. 9 σ, and 4π-bonds.
2. 8 σ, and 5π-bonds
3. 9 σ, and 3π-bonds,
4. 8 σ, and 3 π bonds
35. The best method used for the separation of
naphthalene and benzoic acid from their
30. The total number of isomeric carbocations
mixture is -
possible for the formula C4H9+ is:
1. Sublimation
(1) 3 2. Chromatography
(2) 4 3. Crystallisation
(3) 2 4. Distillation
(4) 5

31. Only two isomeric monochloro derivatives

are possible for:
(1) n-butane
(2) 2,4-dimethylpentane
(3) benzene
(4) 2-methylbutane

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Chemistry - Section
38. The incorrect IUPAC name among the
following is:

B 1.
36. Number of σ -p conjugation in the given
compound is:

2.

1. 4
2. 6
3. 7
4. 8
3.
37. Which of the following is the most correct
electron displacement for a nucleophilic
reaction to take place?
1.

2. 4.

3.

4. 39. The general molecular formula, which

represents the homologous serious of alkanols
is:
1. Cn H2n O2
2. Cn H2n O
3. Cn H2n+1 O
4. Cn H2n+2 O

40. The number of sigma (σ) and pi (π) bonds in

pent-2-en-4-yne are:
1. 13 σ bonds and no π bond
2. 10 σ bonds and 3 π bonds
3. 8 σ bonds and 5 π bonds
4. 11 σ bonds and 2 π bonds

41. Rank the following in order of decreasing

nucleophilicity in an aprotic solvent:
− −
RO , RCOOH , ROH , OH

1. RCOOH > ROH > RO > H O− −

2. OH − > ROH > RO− RCOOH

3. RO− > H O− > ROH > RCOOH
4. RCOOH > RO− > H O− ROH

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42. The aromatic compound among the 47. The Cl — C — Cl angles in 1,1,2,2-
following is:- tetrachloroethene and tetrachloromethane will
be about :
1. 120° and 109. 5°
1. 2. 2. 90° and 109. 5°
3. 109. 5° and 90°
4. 109. 5° and 120°

3. 4. 48. The IUPAC name of

CH3 − CH − CHO is
|

CH2 −CH3

1. Butan-2-aldehyde
43. The number of products that can be 2. 2- methylbutanal
obtained theoretically from the 3. 3- Methylisobutyraldehyde
monochlorination of 2- methyl butane is 4. 3- methylbutanal
1. 2
2. 3 49. Which of the following organic compounds
3. 4 exhibit tautomerism?
4. 5

44. An organic molecule necessarily shows I. II.

optical activity if it:
1. Is non-superimposable on its mirror image.
2. Is superimposable on its mirror image.
3. Contains asymmetric carbon atoms.
4. Is non-polar. III. IV.

45. In which of the following sets, from left to

right, is the hybridization sequence sp²-sp²-sp-
sp applicable? 1. I and II
1. CH2 = CH − C ≡ CH 2. I, III and IV
2. CH ≡ C − C ≡ N 3. I, II and IV
3. CH2 = C = C = CH2 4. I, II, III and IV

4.
50. 0.24 g of an organic compound containing
phosphorous gave 0.66 g of Mg2P2O7 by the
usual analysis. The percentage of phosphorous
46. The number of optical isomers formed by in the compound is-
hydrogenation of the compound, (CH 1. 77%
3)2C=CHCH3 are
2. 72%
1. 0 3. 87%
2. 1 4. 60 %
3. 2
4. 3

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