Chemistry, Revision sheet for First semester

Chemistry.

G11

Name :- …………………………………………. Class :-……………… Date :- ……………………………………………

I) Multiple Choice:-

1. The quantum number that indicates the position of an orbital about the three axes in
space is the
a. angular momentum quantum number.
b. spin quantum number.
c. magnetic quantum number.
d. principal quantum number.

2. The spin quantum number indicates that the number of possible spin states for an
electron in an orbital is
a. 5. c. 3.
b. 1. d. 2.

3. The electron configuration for the carbon atom (C) is 1s2 2s2 2p2. The atomic number
of carbon is
a. 12. c. 11.
b. 6. d. 3.

4. Louis de Broglie's research suggested that

a. frequencies of electron waves do not correspond to specific energies.
b. electrons usually behave like particles and rarely like waves.
c. electron waves exist at random frequencies.
d. electrons should be considered as waves confined to the space around
an atomic nucleus.

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5. An orbital that can never exist according to the quantum description of the atom is
a. 3d. c. 8s.
b. 6d. d. 3f.

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6. The number of atoms in 1 mol of carbon is
a. 5.022 x1022. c. 5.022 x 1023.
b. 6.022 x 1023. d. 6.022 x 1022.

7. Chlorine has atomic number 17 and mass number 35. It has

a. 35 protons, 35 electrons, and 17 neutrons.
b. 17 protons, 17 electrons, and 52 neutrons.
c. 17 protons, 17 electrons, and 18 neutrons.
d. 18 protons, 18 electrons, and 17 neutrons.

8. If n is the principal quantum number of a main energy level, the number of electrons
in that energy level is
a. 2n. c. n2.
b. n. d. 2n2.

9. All of the following describe the Heisenberg uncertainly principle except

a. it is one of the fundamental principles of our present understanding of
light and matter.
b. it states that it is impossible to determine simultaneously both the
position and velocity of an electron or any other particle.
c. it helped lay the foundation for the modern quantum theory.
d. it helps to locate an electron in an atom.

10. When an electrical current passed through a glass tube, it caused the surface of the
tube directly across from the cathode to glow. Scientists concluded that
a. a magnetic field was produced.
b. the particles of the beam were negatively charged.
c. there was gas in the tube.
d. atoms were indivisible.

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11. The number of orbitals for the d sublevel is
a. 1. c. 3.
b. 7. d. 5.

12. The main energy level that can hold only two electrons is the
a. third. c. first.
b. fourth. d. second.

13. In Rutherford's experiments, alpha particles

a. collided with electrons. c. were used to bombard thin metal
foil.
b. passed through a tube containing d. were used to bombard a cathode
gas. plate.

14. As the atomic number increases within a group of elements, the atomic radius
a. generally increases.
b. remains generally constant.
c. varies unpredictably.
d. decreases regularly.

15. The statement that an electron occupies the lowest available energy orbital is
a. Hund's rule. c. the Aufbau principle.
b. Bohr's law. d. the Pauli exclusion principle.

16. According to Bohr, electrons cannot reside at in the figure below.

a. point C c. point A
b. point B d. point D

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17. Both the Heisenberg uncertainty principle and the Schrödinger wave equation
a. led to the concept of atomic orbitals.
b. are based on Bohr's theory.
c. treat electrons as particles.
d. led to locating an electron in an atom.

18. A positively charged particle with mass 1.673 10–24 g is a(n)

a. positron. c. proton.
b. electron. d. neutron.

19. What is the mass of 3.56 mol of glucose, C6H12O6? (The molar mass of`C6H12O6 is
180.18 g/mol.)
a. 0.0198 g
b. 50.6 g
c. 2.14 1024 g
d. 641 g

20. The mass of 1 mol of chromium (atomic mass 51.996 amu) is

a. 51.996 g. c. 6.02 1023 g.
b. 198 g. d. 12 g.

21. Whose series of experiments identified the nucleus of the atom?

a. Chadwick c. Dalton
b. Bohr d. Rutherford

22. If 8 electrons completely fill a main energy level, what is n?

a. 8 c. 32
b. 2 d. 4

23. An atom is electrically neutral because

a. the numbers of protons and electrons are equal.
b. nuclear forces stabilize the charges.
c. the numbers of protons and neutrons are equal.
d. neutrons balance the protons and electrons.
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24. In a glass tube attached to a voltage source, electrical current passes from the negative
electrode, called the , to the other electrode.
a. anode c. Millikan
b. electron d. cathode

25. A spherical electron cloud surrounding an atomic nucleus would best represent
a. a px orbital.
b. a combination of px and py orbitals.
c. a combination of an s and a px orbital.
d. an s orbital.

26. The region outside the nucleus where an electron can most probably be found is the
a. electron cloud. c. s sublevel.
b. electron configuration. d. quantum.

27. In Rutherford's experiments, most of the alpha particles

a. passed through the foil. c. were absorbed by the foil.
b. combined with the foil. d. bounced back.

28. For each successive electron removed from an atom, the ionization energy
a. decreases.
b. increases.
c. remains the same.
d. equals the nuclear charge.

29. The units of molar mass are

a. mol/g.
b. amu/g.
c. g/mol.
d. amu/mol.

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30. Avogadro's number is
a. the number of protons and neutrons that can fit in the shells of the
nucleus.
b. the number of particles in exactly 1 gram of a pure substance.
c. the maximum number of electrons that all the energy levels can
accommodate.
d. the number of particles in 1 mole of a pure substance.

31. Which of the following lists atomic orbitals in the correct order they are filled
according to the Aufbau principle?
a. 1s 2s 2p 3s 3p 4s 4p 3d 4d
b. 1s 2s 2p 3s 3p 3d 4s 4p 5s
c. 1s 2s 2p 3s 3p 4s 3d 4p 5s
d. 1s 2s 2p 3s 4s 3p 3d 4p 5s

32. How many quantum numbers are needed to describe the energy state of an electron in
an atom?
a. 1 c. 3
b. 4 d. 2

33. Isotopes are atoms of the same element that have different
a. principal chemical properties. c. masses.
b. numbers of electrons. d. numbers of protons.

34. Because any element used in the cathode produced electrons, scientists concluded that
a. atoms carried a negative charge. c. atoms were indivisible.
b. all atoms contained electrons. d. only metals contained electrons.

35. Two electrons in the 1s orbital must have different spin quantum numbers to satisfy
a. quantum rule. c. the magnetic rule.
b. the Aufbau principle. d. the Pauli exclusion principle.

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36. According to the quantum theory of an atom, in an orbital
a. electrons cannot be found.
b. electrons travel around the nucleus on paths of specific radii.
c. an electron has no energy.
d. an electron's position cannot be known precisely.

37. Which model of the atom explains the orbitals of electrons as waves?
a. the quantum model c. the Bohr model
b. Planck's theory d. Rutherford's model

Use the periodic table below to answer the question

Choose the best answer from the options that follow each question.

38. All the alkali metal elements are found on the periodic table in
a. Period 2.
b. Group 2.
c. Period 1.
d. Group 1.

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39. What values can the angular momentum quantum number have when n = 2?
a. 0, 1 c.
b. d. 0, 1, 2

40. In early experiments on electricity and matter, an electrical current was passed
through a glass tube containing
a. liquid oxygen. c. gas under low pressure.
b. water. d. gas under high pressure.

41. If a mixture is uniform in composition, it is considered to be

a. elemental.
b. homogeneous.
c. molecular.
d. heterogeneous.

42. Which concept in Dalton's atomic theory has been modified?

a. Atoms can combine in chemical reactions.
b. Atoms of different elements have different properties and masses.
c. All matter is composed of atoms.
d. Atoms cannot be divided.

II) Completion:-

Use a periodic table above to answer the following questions.

1. Find the name for the element whose symbol is Bi.

2. In which period can you find the element iron?

3. Find the name for the element whose symbol is P.

4. In which period can you find the actinide series?

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 5. The oxygen in air causes iron to rust. Iron and oxygen are in
this process, and rust is the product.

6. The melting of butter is a change because it does not

produce any new substances.

7. An alloy such as a gold ring is an example of a(n) mixture.

8. Gravel is an example of a(n) mixture.

9. The short-range attractive forces that hold the nuclear particles together are called
.

10. are elements that are good conductors of electricity.

11. The particles of a substance in the are able to slide past each
other.

12. The name for the element whose symbol is Mg.

13. Any substance with a definite composition is a .

III) Short Answer :-

1. The electron configuration for nitrogen is 1s2 2s2 2p6. What does the 6 in 2p6 mean?

2. Distinguish between mass and weight.

3. What is an isotope?

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 4. State the law of conservation of energy.

5.Name three ways that mixtures might be separated.

6. Contrast heterogeneous and homogeneous mixtures.

7. Differentiate between the reactants and the products in the reaction represented by the
equation—copper + water copper(II) oxide + hydrogen.

8. Describe the nucleus of an atom.

9. What do quantum numbers describe?

10. What can you predict about the properties of xenon and helium, both in Group 18 in
the periodic table? Why?

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 11. Explain the meaning of Avogadro’s number.

IV) Problem:-

1. Determine the number of moles of helium in 10.0 g of helium. The molar mass of
helium is 4.00 g/mol.

2. How many moles of platinum are equivalent to 1.20 x 1024 atoms?

Use the periodic table below to answer the following questions.

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3. Draw the orbital diagram for argon.

4. Which element has the following electron configuration: [Ar] 4s2 3d10 4p5?

5. How many atoms are present in 80.0 mol of zirconium?

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