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MP Board Chemistry Chapter Wise Important Questions 2023

Chapter 1 Solutions
(2023 Blueprint: 1 + 1 + 2 + 3 = 7 Marks)
2 Marks Questions
1. Definitions:
a. Molarity j. Hypertonic solution
b. Molality k. Parts Per Million (PPM)
c. Normality l. Azeotropic mixture / Constant
d. Mole fraction boiling mixture
e. Henry’s law m. Raoult’s law
f. Osmosis / Osmotic pressure n. Vant Hoff’s factor
g. Semipermeable membrane o. Molal elevation constant
h. Isotonic solution p. Molal depression constant
i. Hypotonic solution

3 Marks Questions
1. Write any three differences between ideal and non-ideal solutions
2. Write any three differences between solutions having positive deviation and
solutions having negative deviations.
3. Derive Raoult’s law for solution which contain non-volatile solute. (How can
molar mass of non-volatile solute be determined with the help of Raoult’s
law?)
4. Differentiate between molarity and molality.
5. Find the molarity / molality of pure water.
6. Define the depression of freezing point. Calculate the solute's molecular
weight by the help of depression of freezing point.
7. Define the elevation in boiling point. Calculate the solute's molecular weight
by the help of elevation in boiling.

Chapter 2 Electrochemistry
(2023 Blueprint 1 + 1 + 2 + 5 = 9 Marks)

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2 Marks Questions
1. Definitions:
a. Electrolysis i. Faraday’s (I and II) laws of
b. Strong electrolytes electrolysis
c. Weak electrolytes j. Nernst equation
d. Specific conductivity k. Corrosion
e. Molar conductivity l. Ohm’s law
f. Equivalent conductivity m. Cell constant
g. Specific resistance / n. Standard electrode potential
Resistivity o. Electrochemical series
h. Kohlrausch’s law

2. Write the cell representation of Galvanic / Daniel cell.

3. Write the measures to prevent corrosion.
4. Write factors affecting the corrosion.
5 Marks Questions
1. Write the applications of Kohlrausch’s law.
2. Explain standard hydrogen electrode (SHE) / Normal hydrogen electrode
(NHE)
3. Derive the relation between specific conductance and cell constant.
4. Draw the labelled diagram of Galvanic cell / Daniel cell and explain the cell
reaction.
5. Write the differences between electrochemical and electrolytic cell.
6. Differentiate between metallic and electrolytic conductors.
7. Differentiate between EMF and potential difference.

Chapter 3 Chemical Kinetics

(2023 Blueprint 1 + 1 + 2 + 3 = 7 Marks)
2 Marks Questions
1. Definitions:
a. Molecularity c. Rate of reaction
b. Order of reaction d. Half – life period
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e. Activation energy g. Threshold energy

f. Arrhenius equation h. Pseudo – Order reaction
3 Marks Questions
1. Explain zero order reaction with example.
2. Differentiate between rate of reaction and rate constant.
3. Derive the expression for rate constant of first order reaction.
4. Prove that the half life period of first order reaction does not depend on the
initial concentration of the reactant. (Derive the formula to calculate the half –
life period of first order reaction)
5. Differentiate between molecularity and order of reaction.
6. Describe the factors affecting the rate of reaction.
7. Write the unit of rate constant k for zero order, first order and second order
reaction.

Chapter 4: d and f Block Elements

(2023 Blueprint 1 + 1 + 1 + 1 + 3 = 7 Marks)
3 Marks Questions
1. Give reasons:
a. Coloured ion and coloured compound formation.
b. Formation of alloy.
c. Transition elements show variable oxidation state / variable valency.
d. Cu+ is colourless and Cu2+is coloured.
e. Zn shows only + 2 Oxidation State.
f. Transition elements mostly form complex compound.
g. Transition elements are good catalyst.
h. Transition elements become paramagnetic
i. Ionic radii of Fe2+ less than ionic radii of Mn2+.
2. Write the general electronic configurations of d and f block elements.
3. Write any three uses of lanthanides.
4. Write any three uses of actinides.
5. Write any three differences between d (transition) and f (inner transition)
block elements.
6. Write any three differences between lanthanides and Actinides.
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7. Write any three characteristics properties of transition (d block) elements.

8. Write any three characteristics properties of inner transition (f block)
elements.
9. What do you understand by Lanthanide contraction?
10. Write the electronic configuration of Fe2+ and Fe3+ (Atomic number of Fe =
26). Which one is more paramagnetic?
11. Discuss the change in any three of the following properties of the first
transition series:
i. Atomic / ionic radii
ii. Ionization energy
iii. Metallic character
iv. Oxidation States

Chapter 5: Coordination Compounds

(2023 Blueprint 1 + 1 + 1 + 2 + 2 = 7 Marks)
2 Marks Questions
1. IUPAC nomenclature:
a. [Cu(NH3)4]SO4 j. K 4 [Ni(CN)4 ]
b. [Cr(H2O)6]Cl k. Na2[SiF6]
c. [Cr(H2O)4Cl2]Cl l. K 4 [BF4 ]
d. [Co(NH3 )3 (NO2 )3 ] m. [Cr(NH3 )6 ]Cl3
e. [Ni(CO)4] n. K 3 [Fe(CN)6 ]
f. K2[HgI4] o. [Co(NH3 )6 ]Cl3
g. K[Ag(CN)2 ] p. K 2 [PtCl6 ]
h. K 4 [Fe(CN)6 ] q. K 2 [Zn(OH)4 ]
i. [Ag(NH3 )2 ]Cl r. [Ag(NH3 )2 ][Ag(CN)2 ]
2. Explain Werner's theory of coordination compounds.
3. Explain chalets? Give an example.
4. What is Zeise’s salt and ferrocene?
5. What are organometallic compounds? Explain.
6. What is ionization isomerism? Give one example of ionization isomerism in
coordination compounds.
7. Give any two differences between double salt and complex salt.
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8. What is effective atomic number? Explain with examples.

9. Explain the following: Ligand, Coordination compounds.

Chapter 10: Haloalkanes and Haloarenes

(2023 Blueprint 1 + 1 + 4 = 6 Marks)
4 Marks Questions
1. Name reactions:
a. Fittig reaction f. Wurtz reaction
b. Hunsdiecker reaction g. Reimer – Tiemann Reaction
c. Sandmeyer’s reaction h. Iodoform reaction
d. Friedel Crafts reaction i. Frankland reaction
e. Carbylamine reaction
2. What happens when: (Give only chemical equation)
a. 𝑛 – Butyl chloride react with alcoholic KOH
b. Methyl bromide react with sodium in the presence of dry ether.
c. Bromo benzene react with Mg in the presence of dry ether.
d. Methyl chloride react with alcoholic KCN
e. Acetone is heated with alkaline solution of Iodine
f. Chlorobenzene is heated with chloral in the presence of concentrated
H2SO4
g. Chlorobenzene is heated with sodium in the presence of ether.
h. Ethyl bromide is heated with Alcoholic – KOH.
i. Ethyl bromide reacts with silver nitrite solution
j. Methyl bromide reacts with sodium metal in the presence of dry ether.
k. Ethyl bromide reacts with sodium ethoxide.
l. Ethyl bromide reacts with magnesium metal.
3. Write the differences between SN1 reaction and SN2 reaction.
4. Write short notes on following: (i) Freon (ii) D.D.T.
5. What is elimination reaction? Mention Saytzeff’s rule associated with it.
6. How does nucleophilic substitution reaction occur in alkyl halide? Give its
reaction mechanism.
7. Explain the reaction with chlorine in the presence of FeCl3 in dark.
8. Explain the following reactions of chloroform: Effect of air and sunlight.
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9. How will you make (obtain) from chloroform:

a. Chloretone
b. Phenyl Isocyanide
c. Acetylene
d. Salicaldehyde
10. Write the equation of the following reactions of chlorobenzene:
a. Halogenation
b. Nitration
c. Sulphonation
d. Alkylation
11. Why are haloarenes less reactive than haloalkane?
12. Write the chemical reaction of chloroform with the following:
a. Silver powder
b. Concentrated HNO3
c. Acetone
d. Alkaline solution of phenol
13. Draw the labelled diagram of laboratory preparation of iodoform from
alcohol. Write related chemical equations.

Chapter 11: Alcohols, Phenols and Ethers

(2023 Blueprint 1 + 1 + 1 + 3 = 6 Marks)
3 Marks Questions
1. Differentiate in primary alcohol, secondary alcohol and tertiary alcohol
2. Write Victor Meyer method to distinguish primary, secondary and tertiary
alcohol.
3. Distinguish primary, secondary and tertiary alcohol using Lucas reagent.
4. Write any three differences between phenol and alcohol.
5. Write only chemical equations for following conversions:
a. Ethanol to diethyl ether
b. Diethyl ether to ethanol
c. Ethanol to ethyl acetate
6. What is Lucas reagent? By using Lucas reagent differentiate primary,
secondary and tertiary alcohol.
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7. Explain Kolbe reaction.

8. How to distinguish between alcohol and di – ethyl ether?
9. What do you understand by dehydration of alcohol? Explain its mechanism.
10. Give the reasons:
a. Boiling points of alcohols are higher than ethers.
b. Boiling point of alcohol is higher than its corresponding alkane.
c. Phenols are more acidic than alcohols.
d. Pure phenol is a colourless solid but it converted into pink after some time
by placing open in the air. Give chemical reaction.
11. What is the reaction of Diethyl ether with HI – Acid.
12. How will you obtain from phenol:
a. 2, 4, 6 Tribromo Phenol
b. 2, 4, 6 – Trinitrophenol
c. Picric acid
d. Benzene
e. Ortho and Para – Cresol
13. Give chemical equation of the following conversions:
a. Diethyl ether from ethanol
b. Ethanol from diethyl ether
c. Ethyl acetate from ethanol
d. Ethanol from glucose
e. Phenol from benzene diazonium chloride
14. What change in the colour is observed in phenol in the presence of oxygen?
Explain with reaction.

Chapter 12: Aldehydes, Ketones and Carboxylic Acids

(2023 Blueprint 1 + 2 + 5 = 8 Marks)
2 Marks Questions
1. What is tollens reagent?
2. Write method of preparation of urotropine and its uses.
3. Explain the chemical reactions of the following:
a. Rosenmund reaction c. Gattermann aldehyde synthesis
b. Cannizzaro reaction d. Perkin reaction
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e. Sandmeyer reaction i. Haloform reaction

f. Stephen’s reaction j. Etard’s reactions
g. Urotropine k. Gattermann – Koch reaction
h. Hoffmann Bromamide reaction l. Aldol condensation.
4. Write only chemical equation for the following conversion:
a. Calcium acetate to acetone
b. Formaldehyde to urotropine.
5. What happen when acetic acid reacts with following compounds?
a. Ammonia
b. Ethyl alcohol
6. Write silver mirror test for identification of Aldehyde.
7. How will you obtain the following compounds from benzaldehyde? (Give
equation only)
a. Cinnamaldehyde
b. Benzoin
c. Cinnamic acid
d. Benzoyl chloride
8. How will you obtain the following from acetic acid?
a. Acetic anhydride
b. Ethyl acetate
c. Trichloroacetic acid
d. Acetyl chloride
5 Marks Questions
1. How will you obtain the following:
a. Acetaldehyde from acetyl chloride
b. Acetone from calcium acetate
c. Acetic acid from ethyl acetate
d. Ethane from acetic acid.
2. Explain the quick vinegar process of the manufacture of acetic acid
3. How will you obtain:
a. Formic acid from acetic acid.
b. Acetaldehyde from acetylene.
4. Write short notes on the following:
a. Claisen condensation
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b. Benzoin condensation
5. Describe the method for the preparation of acetone in laboratory and give the
chemical equation with labelled diagram.
6. How will you bring out the following conversion:
a. Acetyl chloride to acetaldehyde
b. Methanal to ethanal
7. What happens when:
a. Acetyl chloride is reduced with hydrogen in the presence of barium
sulphate associated with palladium.
b. Benzaldehyde boils with 45% NaOH
c. Ammonia reacts with formaldehyde.
d. Acetic – acid reacts with PCl5
e. Acetone reacts with conc. H2SO4
f. Benzoic acid reacts with SOCl2
g. Acetic acid reacts with ammonia
h. Acetic acid reacts with caustic soda.
8. What happens when reduction of ethanal takes place:
a. Clemmensen
b. Wulf – Kishner
c. By LiAlH4
d. By Na – Hg/H2O
9. Write the differences between aldehyde and ketone.

Chapter 13: Amines (Organic Compounds Containing Nitrogen)

(2023 Blueprint 1 + 1 + 1 + 1 + 2 = 6 Marks)
2 Marks Questions
1. Explain the reasons:
a. Aniline is a weaker base than cyclohexyl amine.
b. Silver chloride dissolve in methyl amine solution.
c. It is difficult to prepare pure amine by ammonolysis of alkyl halide.
d. Aniline insoluble in water but soluble in HCl
e. Ethyl amine is more basic than aniline
f. Amines are soluble in water
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g. Tertiary amines not give acylation reaction

h. Ethyl amine is soluble in water while aniline is not.
2. What happens when: (Write equations only)
a. Ethyl amine react with Nitrous acid.
b. Aniline reacts with bromine water in aqueous medium.
c. Aniline reacts with sodium Nitrite and Hydrochloric acid at 278K.
3. Write examples of primary and secondary amines.
4. Write two differences between ethyl amine and aniline.
5. What is nitrating mixture?
6. What is Hinsberg’s reagent?

Chapter 14: Biomolecules

(2023 Blueprint 1 + 1 + 1 + 1 + 1 + 2 = 7 Marks)
2 Marks Questions
1. Write functions and sources of the following biomolecule elements:
a. Protein c. Fat
b. Carbohydrates d. Calcium
2. Write the definition of Zwitter ion and protein denaturation?
3. Write two differences between DNA and RNA.
4. What are Nucleic acids? Write two important works of them.
5. Write sources and deficiency diseases from:
a. Vitamin A e. Vitamin E
b. Vitamin B f. Vitamin K
c. Vitamin C g. Vitamin B1
d. Vitamin D
6. What is DNA fingerprinting? Why it is important?
7. What is peptide bond?
8. What are carbohydrates? Give types of carbohydrates.
9. What are enzymes? Give two examples with applications / uses.
10. Name of two water soluble vitamins and deficiency diseases.
11. Write two differences between α – Amino acid and protein.

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