NSE 236 P7 Solid State Detectors
NSE 236 P7 Solid State Detectors
(NSE 236)
SOLID-STATE DETECTORS
Solid-State Detectors 1
Semiconductor Radiation Detectors
• Early versions were called “crystal carriers” , but modern detectors are referred
as “semiconductor detectors” or “solid-state detectors”.
Solid-State Detectors 2
Semiconductor Properties
Solid-State Detectors 3
Semiconductor Properties
• When an electron gets “excited”, it is then free to move out of its specific bonding
site – this also creates a “hole”, thus the electron-hole pair
• Electrons move toward the positive potential and holes “move” toward the
negative potential – this is observed conductance
• Thermal energy can cause electrons to move into the conduction band
• In the absent of electric field, thermal electrons and holes are recombined and we
have an equilibrium concentration which is proportional to their formation rate
• The drift velocity of electrons and holes can be calculated as:
𝑣ℎ = 𝜇ℎ 𝜀 𝑎𝑛𝑑 𝑣𝑒 = 𝜇𝑒 𝜀 where:
𝜇ℎ 𝑎𝑛𝑑 𝜇𝑒 𝑎𝑟𝑒 ℎ𝑜𝑙𝑒 ′ 𝑠 𝑎𝑛𝑑 𝑒𝑙𝑒𝑐𝑡𝑟𝑜𝑛′ 𝑠 𝑚𝑜𝑏𝑖𝑙𝑖𝑡𝑖𝑒𝑠, 𝜀 𝑖𝑠 𝑒𝑙𝑒𝑐𝑡𝑟𝑖𝑐 𝑓𝑖𝑒𝑙𝑑 𝑚𝑎𝑔𝑛𝑖𝑡𝑢𝑑𝑒
• At some point the saturation velocity is reached where further increase in electric
field doesn’t increase drift velocity
• The saturation velocity in these detectors is approximately 107 cm/sec
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Solid-State Detectors
Semiconductor Properties
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Solid-State Detectors
Effect of Impurities (Dopants): intrinsic semiconductors
1- Intrinsic Semiconductors
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Solid-State Detectors
Effect of Impurities (Dopants): n-type semiconductors
2- n-type semiconductors
• In nearly all cases, the concentration of impurity, ND, is large compared with the
concentration of electrons expected in the intrinsic material, thus:
3- p-type semiconductors
• With p-type semiconductors, it’s the same idea
except now we add an impurity that is trivalent
(from group III of Periodic Table), so that there is the Band structure of a p-type
absence of an electron (or the addition of a hole). semiconductor. Dark circles in
the conduction band are
• These “acceptor impurities” (boron for example) also electrons and light circles in the
valence band are holes. The
create a site in the forbidden gap, but at a level very image shows that the holes are
close to the valence band. the majority charge carrier
• Thermal excitation ensures that some
electrons will always be available to fill the
acceptor sites (because of low energy
required), but this leaves holes behind
4- Compensated Material
• The heavily doped semiconductors are usually made in thin layers on the crystal
and essentially act to make electrical contact with high conductivity.
Solid-State Detectors 10
Ionizing Radiation in Semiconductors
• The doping levels typical in p- or n-type semiconductors are so low that these
atoms play no significant role in determining the interaction probabilities for
gamma rays.
• The quantity of interest is the average energy lost by the primary radiation to
create one electron-hole pair (ionization energy)
• Ionization energy (77 K): 3.76 eV in silicon and 2.96 eV in germanium, (~10
times less than a gas-filled detector ; and about 6 times less than NaI(Tl))
Solid-State Detectors 11
Leakage Current
• Even in the absence of ionizing radiation, Si and Ge detectors show some finite
conductivity and therefore a leakage current is observed.
• Random fluctuations in the leakage current will tend to obscure the small signals
following an ionizing event and represent a significant source of noise.
• Resistivity 𝜌 of highest purity silicon is about 5x104 Ω-cm (CZT, 𝜌~5x109 Ω-cm).
• For a 1-mm-thick slab of this silicon with 1-cm2 surface area and fitted with ohmic
𝑙
contacts, the electrical resistance between faces would be 5,000 Ω (𝑅 = 𝜌 𝐴) .
𝑉 500
• By applying 500 V: 𝐼𝑙𝑒𝑎𝑘𝑎𝑔𝑒 ≅ 𝑅 = 5000 = 0.1 𝐴 Leakage
Current
Si or Ge
• A typical peak pulse current generated from
ionizing radiation (with 105 charge carriers,
~300keV in Ge) is about 10-6 A.
Solid-State Detectors 12
Semiconductors Junction
Depletion Region 𝜀
• A net negative space charge on the p
side and a positive space charge on h
e
the n side of the junction region is p n
created.
• The accumulated space charge creates Fixed negative charge Fixed positive charge
an electric field (𝜀) that diminishes
the tendency for further diffusion.
• In the forward bias arrangement, all electrons and holes are caused to flow, thus
resulting in large currents (even with no radiation!)
Solid-State Detectors 13
Reverse Biasing
Reverse Biasing, no ionizing radiation
• With reverse biasing, the depletion region 𝜀
is enhanced.
𝑒𝑚𝑖𝑛
p ℎ𝑚𝑖𝑛 n
• Under reverse biasing, it is the minority
carriers (holes on the n side and electrons
on the p side) that are attracted across the
junction, establishing very small current.
Very Low Leakage Current
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Solid-State Detectors
Reverse Biasing
• The maximum operating voltage for any diode detector must be kept below the
breakdown voltage to avoid catastrophic deterioration of detector properties.
• With an electric field applied, both charges feel electrostatic forces that cause
them to drift in opposite directions.
• The motion of either the electrons or holes constitutes a current that will persist
until those carriers are collected at the boundaries (Shockley-Ramo Theorem).
• Because of differences in drift distance and carrier mobility's, one of the two
currents will persist for a longer time than the other.
Electron and hole mobility in Si
• In silicon or germanium, the hole mobility is
with in a factor of about 2 or 3 of the electron
mobility, so detectors made from these
crystals rely on complete integration of the
current due to both the electrons and holes.
• Dead layer includes the electrode and an unknown thickness of crystal beneath
the electrode in which charge collection is insufficient.
• In charged particle spectroscopy, this dead layer (~ 1-2 µm) can be a real
disadvantage because a portion of the particle energy will be lost before it can
reach the active region of the detector.
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Solid-State Detectors
Creating a junction
Surface barrier n 1
• Typical resolution is about 3-4% for alpha particles in a surface barrier and the
spectra look something like this:
18 𝜇𝑚
Count
α (5 MeV) Range
Si
E
• The sharp drop at the “rated” energy of the alpha – tail to the left indicating self
absorption, loss in air, or some from the dead layer though very thin.
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Solid-State Detectors
Silicone p-i-n Diodes
Silicon PIN Detector
• Even though silicon has a relatively low atomic Pure silicon
p (intrinsic) n
number (Z=14), photoelectric absorption is still
predominant in the soft X-ray region below 20
keV (to measure florescence X-rays).
• Unlike the thin depletion depths necessary for alpha (or X-ray) spectroscopy, a
detector with a very large thickness is needed for high-energy gamma
spectroscopy
• Large depletion depths (>1 cm) can be achieved with high purity germanium by
reducing impurity concentration to 1010 atoms/cm3
• Zone refining (HPGe): locally heating and slowly passing a melted zone, since
impurities tend to be more soluble in the molten germanium than in the solid.
𝑊𝑇 2 = 𝑊𝐷 2 + 𝑊𝑋 2 + 𝑊𝐸 2
𝑊𝐷 2 = (2.35)2 𝐹𝜖𝐸
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Solid-State Detectors
Solid-State Detectors
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Properties of some Semiconductor Materials
Ge (77) 32 5.33 0.72 2.98 36,000 42,000 >10-4 >10-4 0.4 @ 122 keV
0.9 @ 662 keV
CdTe (300 K) 48/52 6.06 1.52 4.43 1000 80 10-6 10-6 3.5 @ 122 keV
HgI2 (300 K) 80/53 6.4 2.13 4.3 100 4 7x10-6 3x10-6 3.2 @ 122 keV
5.96 @ 662 keV
CdZnTe (300 K) 48/30/52 6 1.64 5.0 1350 120 10-6 2x10-6 11.6 @ 662 keV
~5 @ 662 keV
with pixelated
Solid-State Detectors 26
Solid-State Detectors
C A C A
• The induced charge, ∆𝑸, on any electrode produced by q depends only on the
location of the moving charge and the configuration of the device
For a planar detector: 𝜑0 𝑧 = 𝑧 0≤𝑧≤1
𝑨𝒔𝒔𝒖𝒎𝒊𝒏𝒈 𝒔𝒂𝒎𝒆 𝒄𝒉𝒂𝒓𝒈𝒆 𝒕𝒓𝒂𝒏𝒔𝒑𝒐𝒓𝒕 𝒑𝒓𝒐𝒑𝒆𝒓𝒕𝒊𝒆𝒔 𝒇𝒐𝒓 𝒆𝒍𝒆𝒄𝒕𝒓𝒐𝒏𝒔 𝒂𝒏𝒅 𝒉𝒐𝒍𝒆𝒔:
∆𝑄 = 𝑛𝑒0 1 − 𝑍 − 𝑛𝑒0 0 − 𝑍 = 𝒏𝒆𝟎
Electron Hole
contribution contribution
If charge cloud is formed at location Z
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Image taken from: Zhon He, Nucl. Ins. Meth. Phy. A, 463 , 2001 Farsoni, NSE 536: Solid-State Detectors
Shockley-Ramo Theorem
• But in room-temperature detectors when holes can only move very short
distance compared to the detector thickness (or can not be collected
completely) , the induced charge on the anode is:
Recall pulse formation in semiconductors
∆𝑄~ 𝑛𝑒0 1 − 𝑍
Which is depth dependent!
Solid-State Detectors 30
Solid-State Detectors
Frisch-Grid Detectors
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Images taken from: Yonggang Cui et al., IEEE TRANSACTIONS ON NUCLEAR SCIENCE, VOL. 55, NO. 5, OCTOBER 2008
Frisch-Grid Detector Array
Images taken from: Yonggang Cui et al., IEEE TRANSACTIONS ON NUCLEAR SCIENCE, VOL. 55, NO. 5, OCTOBER 2008
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Solid-State Detectors
Coplanar-Grid Detectors
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Solid-State Detectors
Pixelated Detectors, a Position Sensitive Device
• The depth (Z) is obtained from the ratio of the signals coming from the
cathode and the anode.
Solid-State Detectors 34
Pixelated Detectors, Gamma-Ray Imaging
• Incoming gamma rays interact with the detector through Compton
scattering.
511 511 E: energy of incident photon (keV)
cos 𝜃 = 1 − + E’: energy of scattered photon (keV)
𝐸′ 𝐸
(a)The energies and positions of the first two interactions define a cone
of incident angles.
(b)The cones can be projected onto a plane (one circle per gamma-ray
event) to produce a two-dimensional image of the source.
E
(c) After repeating the
back-projections of many
events, the overlap of 𝜃
the cones indicates the
source position.
E’
Solid-State Detectors 36
Pixelated Detectors, Gamma-Ray Imaging
Polaris-H, a 3D-position-sensitive
CdZnTe detector
(from H3D company)
Solid-State Detectors 37