PAGE

NOTE300K

QSmall koes mncambeks - unbleanant Smell, but

Ha'eennembes ae fsasant They ahe
Cinnameu- Ciwma maldehyde
AMaldelyde
3Snlubiiy
chs-CH-CHH pslau(hyabuatditic)
hydunpkabic
=0

Dibte dibe neactio

H ---O=C

Hydungoa hacndig
Aldebdes and Kedesses ahe Aoluble n
usak oue to natiem inesmttecula
Watet.
ighen membeshyckbbabic bat
wBata de ueasesJutM

Lindeimeecula ce o attactin. she

oH
Nu
RR
Nu R.
Ketses' aldahydes
Chemicoinpetes
Nu
NU
the
mle
uks heleasuis elecea n he Moe
les heleaàg e
ahe Kedneaymeho becauie elecHom
aldeydeA
beint boilg
th highen oare Kesam
ydnocasbom cthex
Adchyden keteoes Alcslola 1
aci>dCoabeylic
attatom
ae ydanbens tham pont
theyatdsbut Cawzouli
ie wrtassoated
th Jbendng Kedones
ane ydge
debyces, while
assoatd
ith Alcesa
biate ipole- banding dhogen Hy
NOTE800K
PAGE
 Mpc dicatiiui aldehydcs and edonea!
Aldekydes and kloe igkly ea thve

Cm) ate ie to atta Ckuig 1eagent

The aldehydes amd kedomes ie the

3 Oidao

S. eactioms due to atyabasgiat

1Nutleshlilic addit'o
C=0

Plecseweic chhekl Caubna has pesitie

has
megatie Chauge
tasands o atyma. The tehaheda ntehe diatk
wthica Comes
ms o-H bond Aucdenlilc additeu
takeslare JM the ie ak acic medium.
 PAGE
DATE / I
NOTEB00K

=0 es tonated andC aceuia

esitiue Change . thong addc madiuua
met table because eMCeS aud
þibtomate Mucleoblle as well

1
Feathiuisies
elechonic
aldeyges
Caxbemyl anbss
the eaLivity
Q1aunhs atached mee be the
Akwaindace and le
healtiity aMeMe eactie
than ketenes

u aneate Coombonads,benzeue
hane mee
shnld he the eatitty but aath
Cpnbeda ane eM heachie due th +Ê
Caateda
ect. dne to Caebeny!
HeAmance and
attack
Chasye
H
 PAGE
DATE / /
MOTEBOOK

H H

aialdelyte aalaldehyde beNZaldehyde

aietone acett þcnen henzeh htmeme
gMaable mucleai'c addit'o
Aldittn HCN
Additon sediw bibulbalte
floaation acetals and
5) Realhlla chlaintataa -elmadia 4chleehna
Reacte

=0 t CN -C-0 -C-H

ynahycia

+ HCN
H CN Cyn)
Cynehydlin
 |OATE
NOrEB00K

Cynalydin
-C-OH

a-hyducayaida

accl

- OH

C=0 tNaHSo

Aueme<ackaldebyde.
 PAGE
DATE | / 13
NOTEB0OK

Tha eactiom
aldehydes beCause bislbhic addition Cummband
s Ablble watee and Cam be Cemveted
back to he 0iginal canbenyl compamds

addi tiealpasduct
Cadduct
tmaldehyde t GiR
Aldelhyce 2alcoha
IKetne t G-R. 3°albhat

HU OR
H R
Hemiacetal
Calkasy alatat) Cagea dialkny
Compaund)
Hldelaydes gie acekals wih alcahta but
H otenaes the 04gem t cene

HO - A,
 AGE
DATE /

Ht
R-0-H
R

Ro
RH R
R
(Nuclobhiic adaitioSeaciOm uuite
Aldite aumMomia deivatues
C=N

dasiatie
The aea(tiam ia gaeeble and catalysed
by auda
HN-H
aamaia Dmime
H, N-A =NR
Amine Subithyed imine
H,N-OH =N-CH
0dme
H,N-NH, (=N-NH
ydazine taydazome
 TPAGE
|DATE / / 15
NOTEBOOK

HN- NH-O >=N-NH

phenl hydazine hemyl hydoazone
=N-NHKo N,

a-pin'toblcay
hydazine (0smge)
dazome.
(Q-DNP) Cued)
(24-DNP)
H,N-NH-c-NH, ’ = N-NHCO Nt
Snicaahazide ARmicabazome

bH ot audAhld be 3to s as AHAmgacidic

me dium (au

3loxidatio:» Aldebydes ae ceidlad easly

Cmaed to kedomes. keomes
smdenga
Aldalyde 0xilisin Casbaxylic acd

Caidiaing agesat
3 HNDa Cnc
STle
heachaateat)
 DATE / / PAGE
NOTEB0oK

CHa--cHg
o unaweltica aet Ke tones Keo

Smallex alkyl gpaubd

CH-(-ta >HCoDH +(H,otet

Feklug
asoy
deluston A
PehlinoSeutosnBis RoAcelle

Hoc00HAas4 HO-CoONA
HOCooH
Sodiue batas
1attastate

tt
RCHOt &CuT t SOH RCOD t Cu t34.

s.Talesi ueagentl TAlet Seageont

heating