1

Education Poiint Career institute

Khargone

12th NEET PC 04 - 08 - 24
ENTRANCE EXAM - NEET-UG

Time Allowed : 120 mins Maximum Marks : 360

Section A a) Face near the charge becomes negatively charged

and the opposite face becomes positively charged
1) Which of the following is deflected by electric field? [4] b) Cube becomes positively charged
a) γ - rays b) Neutrons c) Cube becomes negatively charged
c) α - particles d) X - rays d) Face near the charge becomes positively charged and
2) Two identical charged spheres suspended from a common the opposite face becomes negatively charged
point by two massless strings of lengths l, are initially at 9) Electric force between two charged spheres is 18 units. If
a distance d(d « l) apart because of their mutual repul- the distance between the centres of the sphere is tripled,
sion. The charges begin to leak from both the spheres at the electric force will be [4]
a constant rate. As a result, the spheres approach each a) 2 units b) 54 units
other with a velocity v. Then v varies as a function of c) 3 units d) 6 units
the distance x between the spheres, as [4]
10) A charged oil drop is suspended in uniform field of 3×
a) V∝ x− 2
1
104 V m - 1 so that it neither falls nor rises. The charge
b) V∝ x - 1
on the drop will be : (take the mass of the charge 9.9
c) V∝ x × 10 - 15 kg and g =10 ms - 2 ) [4]
d) V∝ x 2
1

a) 3 · 3 × 10−18 C
3) The conservation of electric charge implies that [4] b) 4 · 8 × 10−18 C
a) Simultaneous creation of equal and opposite charge c) 1 · 6 × 10−18 C
is permissible d) 4 · 3 × 10−18 C
b) Charge cannot be created 11) Three capacitors connected in series have an effective
c) Total charge of the entire universe remains constant capacitance of 2µF . If one of the capacitors is removed,
d) Charge cannot be destroyed the effective capacitance becomes 3 µF . The capacitance
4) For the isolated charged conductor of given figure, the of the capacitor that is removed is [4]
electric fields at points A, B, C and D are EA , EB , EC a) 32 µF
and ED respectively. Then: b) 23 µF
c) 6µF
d) 1µF
12) A capacitor of capacitance C1 is charged upto potential V
and then connected in parallel to an uncharged capacitor
[4] of capacitance C2 . The final potential difference across
a) ED > EA = EB =EC = 0 b) EB = 0, EA = EC = ED each capacitor will be: [4]
c) EA = EB = EC > ED d) EA = EB > EC > ED ( )
a) 1 + C C1 V
2
5) A conducting sphere of radius 10 cm is charged with 10 ( )
μC. Another uncharged sphere of radius 20 cm is allowed b) 1 − C C1 V
2

to touch it for some time. After that if the spheres are

c) C1 V
separated, then surface density of charges on the spheres C1 +C2

will be in the ratio of [4] d) C2 V

C1 +C2
a) 1 : 1 b) 2 : 1 13) When a capacitor is connected to a battery, [4]
c) 1 : 3 d) 1 : 2
a) A current flows in the circuit for sometime and then
6) The minimum value of charge on any charged body may decreases to zero
be [4] b) The current keeps on decreasing
a) 1 coulomb c) The current keeps on increasing
b) 1.6× 10 - 19
coulomb d) No current flows in the circuit at all
c) 4.8× 10 - 12
coulomb 14) The work done to move a charge along an equipotential
d) 1µC surface from A to B [4]
7) If a charge q is placed at the centre of the line joining two a) Is a negative quantity.
equal charges Q such that the system is in equilibrium, b) Is a positive quantity.
then the value of q is : [4] c) Cannot be defined.
a) − Q2 b) Q 4 d) Is zero.
c) − Q d) Q
4 2 15) If P.D. across a capacitor is changed from 15 V to 30
8) When a negative charge ( - Q) is brought near one face V, work done is W. What will be the work done when
of a metal cube, the: [4] P.D. is changed from 30 V to 60 V? [4]
 2

a) 3W b) 2W 24) For a fixed potential difference applied across a conduc-

c) W d) 4 W tor, the drift speed of free electrons doesnot depend upon
[4]
16) Electric potential V at any point x, y, z in space is given
by V = 6z2 . The value of the electric field at the point
a) Length of the conductor
(2, - 1, 3) is [4]
b) Temperature of the conductor
a) - 36 b) 24
c) Mass of the electrons
c) - 12 d) 12
d) Free electron density in the conductor
17) A charge Q is uniformly distributed over the surface of
a spherical shell of radius R. The work done in bringing 25) The ratio of masses of three wires is 1 : 2 : 3 and that
a test charge Q0 from its centre to its surface is [4] of their lengths is 3 : 2 : 1. If the wires are made of
same material, the ratio of their resistance will be: [4]
1 QQ0
a) 4πε R a) 9 : 4 : 1 b) 27 : 6 : 1
b) Zero c) 1 : 2 : 3 d) 1 : 1 : 1
0

c) QQ 0
ε0 R 26) A proton and anα - particle moving with the same ve-
1 QQ0
d) 4πε0 2R locity enter into a uniform magnetic field, acting normal
to the plane of their motion. The ratio of the radii of the
18) The electrostatic force between the metal plates of an
circular paths described by the proton and α - particle
isolated parallel capacitor C having a charge Q and area
is: [4]
A is: [4]
a) 4 : 1 b) 1 : 16
a) Independent of the distance between the plates c) 1 : 2 d) 1 : 4
b) Inversely proportional to the distance between the 27) Assertion: If an electron and proton enter a perpendicular
plates magnetic field with equal momentum, then the radius of
c) Proportional to the square root of the distance be- the curve for the electron is more than that of proton.
tween the plates Reason: Electron has less mass than a proton. [4]
d) Linearly proportional to the distance between the
plates a) If both Assertion & Reason are true and the reason
is the correct explanation of the assertion,
19) An electric dipole of moment p is placed in an electric b) If Assertion is true statement but Reason is false
field of intensity E. The dipole acquires a position such c) If both Assertion & Reason are true but the reason
that the axis of the dipole makes an angleθ with the is not the correct explanation of the assertion,
direction of the field. Assuming that the potential energy d) If both Assertion and Reason are false statements
of the dipole to be zero when θ = 90◦ , the torque and
the potential energy of the dipole will respectively be [4] 28) A wire of length 2m carries a current of 1 ampere is
bend to form a circle. The magnetic moment of the coil
a) pE sin θ, −pE cos θ
is [4]
b) pE cos θ, −pE cos θ a) 2π b) π4
c) pE sin θ, 2pE cos θ c) π 1
d) π2
d) pE sin θ, −2pE cos θ
29) A beam of electrons passes undeflected through mutually
20) A charge Q is kept at the centre of a circle of radius r. perpendicular electric and magnetic fields. If the electric
A test charge q0 is carried from a point X to the point field is switched off, and the same magnetic field is
Y on this circle such that arc XY subtends an angle of maintained, the electrons move [4]
60o at the centre of the circle. The amount of work done
in this process will be [4] a) Along a straight line
Qq
b) Along a parabolic path
a) 4πε
1
0 2r
0
c) In an elliptical orbit
b) Zero √ d) In a circular orbit
c) 4πε
1 3Qq0
r
√
30) When an electron enters a magnetic field of 0.01 T with
0

d) 1 3Qq0
4πε0 2r a speed of107 ms−1 , it describes a circle of radius 6 mm
21) A wire of resistance 10Ω is elongated by 10%. The there. Then specific charge of the electron is given by
resistance of the elongated wire is: [4] [4]
a) 12.1Ω b) 13.1Ω
c) 10.1Ω d) 11.1Ω a) 1.87×1011 Ckg−1
b) 1.67×1011 Ckg−1
22) Ten identical cells each of emfε and internal resistance c) 1.57×1011 Ckg−1
r are connected in series to form a closed circuit. An d) 1.77×1011 Ckg−1
ideal voltmeter connected across three cells will read: [4]
a) 7ε b) 3ε 31) An electron having mass m, charge q and kinetic en-
c) 13ε d) 10ε ergy E enters a uniform magnetic field B perpendicularly.
Then its frequency of rotation will be: [4]
23) The specific resistance of a conductor increases with: [4]
a) qB
a) Decrease in cross - sectional area 2πE
b) Increase in temperature b) qB
2πm
c) Decrease in length c) qBE
2πm
d) Increase in cross - sectional area d) qB
πm
 3
( )
32) An electron with velocity⃗v = vx î + vy ĵ moves through 41) A long solenoid carrying a current produces a magnetic
( ) field B along its axis. If the current is doubled and the
a magnetic field B ⃗ = Bx î − By ĵ . The force ⃗F on
number of turns per cm is halved, then the new value of
the electron is : (e is the magnitude of its charge) [4] the magnetic field is: [4]
a) e (vx By − vy Bx ) k̂ a) B b) B2
c) 2B d) 4B
b) −e (vx By − vy Bx ) k̂
c) −e (vx By + vy Bx ) k̂ 42) If a conducting wire carries a direct current through it, the
d) e (vx By + vy Bx ) k̂ magnetic field associated with the current will be .
[4]
33) The force on a charge due to a magnetic field can act
[4] a) Only inside the conductor
b) Neither inside nor outside the conductor
a) On a charge which is at rest c) Only outside the conductor
b) Moving in the opposite direction of the magnetic d) Both inside and outside the conductor
field
43) Uniform electric and magnetic fields are produced pointing
c) Which is moving in the direction of the magnetic
in the same direction. An electron is projected pointing
field
in the same direction, then [4]
d) Moving in the perpendicular direction
a) The velocity of electron decreases
34) Magnetic field intensity at the centre of a coil of 50
b) The velocity of electron increases
turns, radius 0.05 m and carrying a current of 2 A is:
c) The electron turns to left
[4]
d) The electron turns to right
a) 4× 10 - 5 T b) 0.5× 10 - 5 T
c) 1.26× 10 - 4 T d) 3× 10 - 5 T 44) An electron beam is subjected to a magnetic field of
2×10−3 T and an electric field of 3.4 ×104 Vm−1 per-
35) Two long parallel wires are at a distance of 1m. If both
pendicular to the magnetic field. If the deviation of
of them carry 1A of current, then the force of attraction
electrons is zero, the velocity of the beam is [4]
per unit length between the two wires is: [4]
a) 5× 10 - 7 Nm - 1 b) 5× 10 - 8 Nm - 1 a) 2.4×107 ms−1
c) 2× 10 - 8
Nm - 1
d) 2× 10 - 7 Nm - 1 b) 1.7×107 ms−1
c) 2.7×107 ms−1
36) A circular loop of radius r, carrying a current I lies in y d) 7.1×107 ms−1
- z plane with its centre at the origin. The net magnetic
flux through the loop is: [4] 45) A proton (charge +e) enters a magnetic field of strength B
(Tesla) with speed v, parallel to the direction of magnetic
a) Directly proportional to r lines of force. The force on the proton is [4]
b) Directly proportional to I a) EvB/2 b) 2evB
c) Zero c) Zero d) EvB
d) Inversely proportional to r
37) An electron is moving in a circular path under the influ- Section B
ence of a transverse magnetic field of 3.57× 10 - 2 T. If 46) In the formation of sulphur trioxide 2SO2 (g) + O2 (g)
the value of e/m is 1.76 × 1011 C/kg, the frequency of 2SO3 (g). The rate of reaction is expressed as - d[O2]
dt =
revolution of the electron is [4]
2.5 × 10−4 mol L−1 s−1 . The rate of disappearance of
a) 1 GHz b) 62.8 MHz
SO2 will be [4]
c) 100 MHz d) 6.28 MHz
a) 50.0× 10 - 4 mol L - 1 s - 1
38) Mass of proton is 1.6× 10 - 27 kg. The proton enters the
b) 3.75× 10 - 4 mol L - 1 s - 1
magnetic field of 2 T at an angle 30◦ with the direction
c) - 2.25× 10 - 4 mol L - 1 s - 1
of the field. The velocity of the proton is 2 × 107 m/
d) 5× 10 - 4 mol L - 1 s - 1
s. The radius of the path described by the proton is [4]
a) 4 cm b) 6 cm 47) The unit of rate constant for a first order reaction is [4]
c) 5 cm d) 3 cm a) Mol/L b) Mol/L/s
c) Mol2 /L2 /s2 d) S–1
39) A circular loop of radius 15.7 cm carries a current of 15
A. At its centre is placed a second loop of radius 1.57 48) Consider the reaction
cm having 30 turns and a current of 1 ampere. What N2 (g) + 3H2 (g) → 2N H3 (g)
torque acts on the small loop if the planes of two loops The equality relation between d[N H3 ]
dt and −d[H2 ]
dt is: [4]
are at right angles and the induction due to large loop is
a) d[N H3 ]
= − 13 d[H 2]
quite uniform throughout the volume of small loop? [4] dt dt
a) 2.26× 106 N/m b) 1.14× 10 - 6 N - m b) d[N H3 ]
dt = − 23 dt2 ]
d[H

c) 1.39× 10 - 6
N - m d) 1.13× 106 N/m c) d[N H3 ]
dt = − 32 d[H
dt
2]

40) A charged particle moves with velocity⃗v in a uniform d) d[N H3 ]

dt = − d[Hdt
2]

magnetic field B ⃗ . The magnetic force experienced by 49) The unit of the rate of reaction is the same as that of
the particle is [4] the rate constant for a: [4]
a) Always zero a) It cannot be same
b) Zero, ifB
⃗ and ⃗v are perpendicular b) First order reaction
c) Zero, ifB
⃗ and ⃗v are parallel c) Zero order reaction
d) Never zero d) Second order reaction
 4

50) The reaction2 N O + Br2 → 2N OBr follows the mech- ∆[Br− ] 6 ∆[H ]
′
d) =
anism given below:
∆t 5 ∆t

N O + Br2 N OBr2 (f ast) 60) For the reaction 3A→ 2B, rate of reaction − d[A]
dt is equal
NOBr2 + NO → 2NOBr (slow) to [4]
If the concentration of both NO and Br2 is increased two a) +1 d[B]
dt
times, the rate of reaction would become: [4] 3
d[B]
a) 2 times b) 8 times b) +2
3 dt
d[B]
c) 4 times d) 6 times c) +1
2 dt
d[B]
51) A reaction is first order in A and second order in B. d) +3
2 dt
How is rate affected when concentration of both A and 61) For a chemical reaction 2X + Y→ Z, the rate of appear-
B are doubled? Choose the correct option: [4] ance of Z is 0.05 mol L–1 min–1 . The rate of disappearance
a) Two times b) Eight times of X will be: [4]
c) Four times d) Three times a) 0.05 mol L - 1 min - 1 b) 0.1 molL–1 min–1
c) 0.25 mol L - 1 min - 1 d) 0.05 mol L–1 hour–1
52) The order of the reaction
H2 (
hv
g) + Cl2 ( g) −→ 2HCl(g) is: [4] 62) For a reaction 2A→ 3B, rate of reaction − d[A]
dt is equal
a) 3 b) 1 to [4]
c) 0 d) 2 a) +3 d[B]
2 dt
2 d[ B]
53) The rate law for a particular reaction is given as rate = b) + dt
k[A][B]2 . c) +1 d[B]
3 dt
How is the rate of reaction affected if we double the d) +2 d[B]
3 dt
concentration of B? [4]
63) The following experimental rate data were obtained for a
a) Becomes half( 12 ) reaction carried out at 25o C:
b) Three times A(g) + B(g) → C(g) + D(g)
c) Two times
Initial Initial Initial
d) Four times
[A(g) ]/mol [B(g) ]/mol rate/mol
54) Which of the following rate laws is third order overall? dm - 3 dm - 3 dm - 3 s - 1
[4] 3.0× 10 - 2
2.0× 10 - 2
1.89× 10 - 4
a) Rate= K[A] [B]
5 2
3.0× 10 - 2
4.0× 10 - 2
1.89× 10 - 4
b) Rate= K [A] [B]
2

c) Rate= K[A] [B]

3 3
6.0× 10 - 2
4.0× 10 - 2
7.56× 10 - 4
d) Rate= K[A] [B]
3 1

55) For the reaction A + 2B→ C + D, the rate law is given

by r = k[A][B]2 , the concentration of A is kept constant What are the orders with respect to A(g) and B(g) ? [4]
while that of B is doubled. The rate of the reaction will: a) Order with respect to A(g) - Second
[4] Order with respect to B(g) - First
a) Not change b) Become half b) Order with respect to A(g) - Zero
c) Quadruple d) Double Order with respect to B(g) - Second
56) The unit of rate constant for the reaction 2A + 2B→ c) Order with respect to A(g) - First
A2 B2 which has rate = k [A]2 [B]is: [4] Order with respect to B(g) - Zero
a) S - 1 b) Mol L - 1 d) Order with respect to A(g) - Second
c) Mol L - 1
s - 1
d) Mol - 2 L2 s - 1 Order with respect to B(g) - Zero

57) The rate constant for a first order reaction is equal to 64) As temperature increases, the reaction rate: [4]
the initial rate of reaction when the initial concentration a) First decreases then increases
of the reactant is [4] b) Increases
a) 0.1 M b) 10 M c) Decreases
c) 1 M d) 1× 10 - 2 M d) Stays the same
58) In a chemical reaction X→ Y, it is found that the rate of 65) For the reaction, A + 2B→ AB2 , the order w.r.t. reactant
reaction doubles when the concentration of X is increased A is 2 and w.r.t. reactant B is zero. What will be change
four times. The order of the reaction with respect to X in rate of reaction if the concentration of A is doubled
is [4] and B is halved? [4]
a) 12 b) 2 a) Decreases four times b) No change
c) 1 d) 0 c) Increases two times d) Increases four times
59) Which of the following expressions is correct for the rate 66) If the reaction, aA + bB + cC−→ xX + yY + zZ,
of reaction given below? obeys the rate law expression
5Br– (aq) + BrO– 3 (aq) + 6H+ (aq) → 3Br2 (aq) + 3H2 O(l) Rate = k[A]p [B]q
[4] then the overall order of the reaction would be . [4]
∆[Br− ] 5 ∆[H ]
+
a) P + q b) (p)a + (q)b
a)
c) A + b + c d) A + b
∆t = 6 ∆t
∆[Br− ] ∆[H+ ]
b) = 6 ∆t
∆t 67) For the reaction 2A + 3B + 23 C → 3P, which statement
∆[Br− ] ∗
c) ∆t = 5 ∆[H
∆t
]
is correct? [4]
 5

a) dnA
dt = 3 dnB
2 dt = 4
3 dnC
dt
Experiment Initial Initial Initial
b) dnA
= 2 dnB 3 dnC concentration concentration concentration
dt 3 dt = 4 dt
c) dnA
= 2 dnB 4 dnC of [A]/mol of [B]/mol of
dt 3 dt = 3 dt
dnB dnC L- 1 L- 1 [A]/mol
d) dnA
= dt = dt
dt L - 1s - 1
1. 0.30 0.30 0.10
68) In a second - order reaction, first order in each reactant
2. 0.30 0.60 0.40
A and B, which one of the following reactant mixtures
will provide the highest initial rate? [4]
3. 0.60 0.30 0.20

a) 0.1 mole of A and 0.1 mole of B in 1 litre solvent [4]

b) 0.1 mole of A and 0.1 mole of B in 0.1 litre solvent a) Rate = k[A][B]2 b) Rate = k[A]2 [B]0
c) 0.1 mole of A and 0.1 mole of B in 0.2 litre solvent c) Rate = k[A][B] d) Rate = k[A]2 [B]
d) 0.2 mole of A and 0.2 mole of B in 0. 1 litre
solvent 76) The concentration of a reactant is decreased by 0.2 M in
20 minutes. The average rate of the reaction is .
[4]
69) A hypothetical reaction, A2 + B2 −→ 2AB follows the a) 0.01 M min - 1 b) 1 M min - 1
mechanism as given below; c) 0.2 M min - 1 d) 0.02 M min - 1

A2 A + A ...(Fast) 77) For the reaction, N2 (g) + 3H2 (g) −→ 2NH3 (g) under
A + B2 −→ AB + B ...(Slow) certain condition of temperature and partial pressure of
A + B−→ AB ...(Fast) the reactants, the rate of formation of NH3 is 10 - 3 kg
The order of the overal reaction is: [4] hr - 1 . The rate of conversion of H2 under same condition
a) 2 b) 1 is: [4]
c) Zero d) 1 12
a) 2× 10 - 3 kg hr - 1
70) For the reaction; 2N2 O5 −→ 4NO2 + O2 rate and rate b) 1.5× 10 - 3 kg hr - 1
constant are 1.02 × 10 - 4 M sec - 1 and 3.4 × 10 - 5 c) 3× 10 - 3 kg hr - 1
M sec - 1 respectively, then concentration of N2 O5 , at that d) 1.76× 10 - 4 kg hr - 1
time will be: [4]
a) 3 M b) 3.5× 105 M 78) The bromination of acetone that occurs in acid solution
c) 1.732 M d) 1.02× 10 - 4 M is represented by this equation. CH3 COCH3(aq) + Br2(aq)
71) For a reaction, −→ CH3 COCH2 Br(aq) + H+ (aq) + Br - (aq) These kinetic
3A + 2B −→ C, the rate law is given as, data were obtained for given reaction concentrations.
Rate = k[A][B]2 . Initial concentrations, M
[CH3 COCH3 ] [Br2 ] [H+ ]
The molar concentration of A is kept constant and molar
0.30 0.05 0.05
concentration of B is tripled, then the rate of reaction
will increase by . [4]
0.30 0.10 0.05
a) 2 times b) 4 times
c) 9 times d) 6 times
0.30 0.10 0.10
72) In reaction A→ B, if the concentration of reactant is
increased by 9 times, then the rate of reaction increases 0.40 0.05 0.20
3 times. What is the order of reaction? [4]
a) 3 b) 2
c) 12 d) 13 Initial rate, disappearance of Br2 , Ms - 1
5.7 × 10 - 5
73) In a first order reaction, the concentration of reactant
5.7 × 10 - 5
decreases from 800 mol/dm3 to 50 mol /dm3 in 2 × 104
1.2 × 10 - 4
sec. The rate constant of reaction in sec - 1 is: [4]
a) 1.386× 10 - 4 b) 3.45× 10 - 5 3.1 × 10 - 4
c) 2× 10 - 4
d) 2× 104 Based on these data, the rate equation is: [4]

74) The rate constant for a first - order reaction is 4.606× a) Rate = k[CH3 COCH3 ][Br2 ][H+ ]
10 - 3 s - 1 . The time required to reduce 2.0 g of the b) Rate = k[CH3 COCH3 ][Br2 ]
reactant to 0.2 g is . [4] c) Rate = k[CH3 COCH3 ][Br2 ][H+ ]2
a) 1000 s b) 100 s d) Rate = k[CH3 COCH3 ][H+ ]
c) 200 s d) 500 s
79) For a reversible reaction, A⇀
↽K1 K2 B, Ist order in both
75) CompoundsA and B react according to the following the directions, the rate of reaction is given by: [4]
chemical equation. a) K1 [A]+ K2 [B] b) K1 [A]- K2 [B]
A(g) + 2B(g) −→ 2C(g) c) K1 [A] d) - K2 [B]
The concentration of either A or B were changed keeping 80) For the reaction 2A + B−→ 3C + D which of the
the concentrations of one of the reactants constant and following does not express the reaction rate? [4]
rates were measured as a function of initial concentration.
a) − d[A] b) − d[C]
Following results were obtained. Choose the correct 2dt 3dt

option for the rate equations for this reaction. c) d[D]

dt d) − d[B]
dt
 6

81) The results given in the below table were obtained during the reactants and the products varies exponentially with
kinetic studies of the following reaction: time. Which of the following figures correctly describes
2A + B → C + D the change in concentration of reactants and products with
Experiment [A]/molL - 1 [B]/molL - 1 Initial time? [4]
rate/molL - 1

min - 1
I 0.1 0.1 6.00× 10 - 3

II 0.1 0.2 2.40× 10 - 2

III 0.2 0.1 1.20× 10 - 2

a)

IV X 0.2 7.20× 10 - 2

V 0.3 Y 2.88× 10 - 1

b)
X and Y in the given table are respectively: [4]
a) 0.3, 0.3 b) 0.4, 0.3
c) 0.4, 0.4 d) 0.3, 0.4
82) Following mechanism has been proposed for a reaction :
2A + B−→ D + E
A + B −→ C + D ...(slow) c)
A + C −→ E ....(fast)
The rate law expression for the reaction is: [4]
a) R = K [A][B] b) R = K [A][C]
c) R = K [A]2 [B] d) R = K [A]2
83) The rate law for a reaction between the substances A d)
and B is given by rate = K [A]n [B]m . On doubling
87) The magnitude of the rate constant of a zero - order
the concentration of A and halving the concentration of
reaction is 0.0015. The unit of rate constant for this
B, the ratio of the new rate to the earlier rate of the
reaction is . [4]
reaction will be as: [4]
a) Mol - 1 L s - 1 b) S - 1
a) 2(n - m) b) (m + n)
c) Mol L - 1
s d) Mol L - 1 s - 1
c) (n - m) d) 1/2m+n
88) For a hypothetical reaction, aA + bB→ product, the rate
84) For the non - stoichiometric reaction, 2 A + B→ C + D,
law is r = k[A]x [B]y then: [4]
the following kinetic data were obtained in three separate
experiments, all at 298 K. a) {a + b) < (x + y)
Initial Initial Initial rate of b) (a + b) = (x + y)
concentration concentration formation of c) (a + b) > (x + y)
[A] [B] C (mol d) (a + b) may or may not be equal to (x + y)
L - 1s - 1)
89) For the chemical reaction
(i) 0.1 M 0.1 M 1.2× 10 - 3
N2 (g) + 3H2 (g) ⇀ ↽ 2NH3 (g)
the correct option is: [4]
(ii) 0.1 M 0.2 M 1.2× 10 - 3
a) − d[N 2]
dt = 2
1 d[NH3 ]
dt
(iii) 0.2 M 0.1 M 2.4× 10 - 3
b) − d[N 2]
= 2 d[NH3 ]
dt dt
c) − 13 d[H 2]
dt = − 2
1 d[NH3 ]
dt
The rate law for the formation of C is [4] d) 3 d[H
dt
2]
= 2 d[NH3 ]
dt

a) d[C]
= k[A][B]2 90) For a reaction 2NO2 Cl(g) −→ 2NO2(g) + Cl2(g) the rate
can be expressed as
dt
b) d[C]
= k[A]2 [B]
i. − d[NOdt2 Cl] = k1 [NO2 Cl]
dt
c) d[C]
= k[A][B]
ii. d[NO = k2 [NO2 Cl]
dt 2]
d) d[C]
= k[A] dt
d[Cl2 ]
iii. dt = k3 [NO2 Cl]
dt

85) The rate of the reaction, A + B + C−→ P is given by; The reaction is first order. The relationship between k1 ,
r = − d[A] . The order of the reaction k2 and k3 is . [4]
1 1 1
dt = K[A] [B] [C]
2 2 4

is: [4] a) 2k1 = 2k2 = k3

a) 12 b) 2
b) K1 = k2 = 2k3
c) 1 d) 54
c) K1 = k2 = k3
86) Consider the reaction A⇀
↽ B. The concentration of both d) K1 = k2 = k23