JEE

JEE Revision Express (2025)

Practice Sheet (Chemistry)
Chemical Bonding

Q1 Shape of a molecule having 4 bond pairs and two (C) 2s − 2s < 1s − 2p < 1s − 1s
lone pairs of electrons, will be: (D) Both (A) and (C)
(A) Square planar (B) Tetrahedral
Q7 Which of the following compounds have same
(C) Linear (D) Octahedral
hybridisation?
Q2 The number of π -bonds and σ -bonds in the (A) CIF3
Lewis structure of SO3 is (B) PF5
(A) 3σ, 3π (C) XeF4
(B) 3σ, 2π (D) SF4
(C) 3σ, 1π
Q8 Molecule obtained by sp3 d2 hybridisation has
(D) None of these
bond angle of
Q3 Which of the following phenomenon will occur (A) 90∘
∘ ′
when two atoms having unpaired electron of (B) 109 28
same spin approach each other? (C) 120∘
(A) Bonding will not occur (D) 72∘
(B) Orbital overlap will not occur
Q9 Only sp and sp2 hybrid orbitals are involved in
(C) Both (a) and (b)
the formation of
(D) None of the above
(A) CH3 − CH = CH2
Q4 Select the molecule which has only one π -bond. (B) CH3 − CH3
(A) CH ≡ CH (C) CH3 − C ≡ CH
(B) CH2 = CH − CHO (D) H2 C = C = CH2
(C) CH3 − CH = CH2 (E) CH3 − C ≡ C − CH3
(D) CH3 − CH = CH − COOH
Q10 Which of the following molecule has regular
Q5 pi bond is formed by the overlapping of geometry
(A) p − p orbital along their axis (A) H2 O
(B) s − p orbitals along the axis of p - orbital (B) PF3
(C) p − p orbitals perpendicular to their axis (C) SF6
(D) s − s orbitals (D) XeF6

Q6 Which is correct option for overlapping strength Q11 The molecular shape of SF2, NH+
4 and XeF2 are:
(A) 2s − 2s < 2s − 2p < 2p − 2p (A) The same, with 2, 0, and 1 lone pair of
(B) 1s − 1s < 1s − 2p < 1p − 2p electrons, respectively

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(B) The same, with 1, 1, and 1 lone pair of (A) NH3

electrons, respectively (B) CH4
(C) Different, with 0, 1, and 2 lone pair of (C) CO2
electrons, respectively (D) NO
(D) Different, with 2, 0, and 3 lone pair of
Q17 Which of the following species is/are superoctet
electrons, respectively
molecule?
Q12 Which of the following resonating structure (A) AlF3
is correct for CO2 ? (B) SiCl4
(C) XeF2
(D) ICl3
(A) I (B) II
Q18 The correct order of a dipole moment is:
(C) III (D) IV
(A) CH4 < NF3 < NH3 < H2O
Q13 What is not true about resonance? (B) NF3 < CH4 < NH3 < H2O
(A) The resonating structures are hypothetical (C) NH3 < NF3 < CH4 < H2O
(B) The unpaired electrons in various resonating (D) H2O < NH3 < NF3 < CH4
structures are same
Q19 Which of the following is not true about H2 O
(C) Hybrid structure is most energetic
molecule?
(D) Hybrid structure is least energetic
(A) The molecule has μ =0
Q14 The type of bonds present in CuSO4 ⋅ 5H2 O (B) The molecule can act as a base
are (C) Shows abnormally high boiling point in
(A) Electrovalent and covalent comparison to the hydrides of other elements
(B) Electrovalent and coordinate of oxygen group
(C) Electrovalent, covalent, coordinate, and H- (D) The molecule has a bent shape
bond
Q20 H2 O is polar, whereas BeF2 is not because
(D) Covalent and coordinate
(A) Electronegativity of F is greater than that of
Q15 The melting point of RbBr is 682
∘
C while that O
of NaF is 988
∘
C . The principal reason for higher (B) H2 O involves H-bonding, whereas BeF2 is a
melting point of NaF is: discrete molecule
(A) The two crystals are not isomorphous (C) H2 O is angular and BeF2 is linear
(B) The molar mass of NaF is less than the molar (D) H2 O is linear and BeF2 is angular
mass of RbBr .
Q21 Which of the following compounds may one
(C) The bond in RbBr is covalent
expect to be strongly ionic in character?
(D) The internal distance (rc + ra ) is higher for
(A) BaCl2
RbBr than for NaF
(B) CsCl
Q16 In which of the following molecules octet rule is (C) CaCl2
not followed? (D) SrCl2

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Q22 According to Fajans rule covalent character B. have the minimum overlap
is favoured by C. have same symmetry about the molecular axis
(A) Large cation and small anion D. have different symmetry about the molecular
(B) Small cation and large anion axis
(C) Large cation and large anion Choose the most appropriate from the options
(D) Small cation and small anion given below:
(A) A, B, C only (B) B and D only
Q23 Which of the following order incorrectly
(C) B, C, D only (D) A and C only
represents the property indicated?
(A) F −< Cl− < Br− < I− −polarisability Q27 Which of the following atomic orbital
(B) NaF < Na2 O < Na3 N− Covalent overlappings are not allowed?
character
(C) Na
+
> Mg2+ > Al3+ > Si4+ − Polarising
power
(D) All are correct.

Q24 Electronegativity values of atoms A and B are

1.20 and 4.0 respectively. The percentage of
covalent character of A − B bond is
(A) 50 (B) 27.76
(C) 55.3 (D) 72.24 (A) All of these
(B) (P)(Q)(R)
Q25 Which of the following leads to bonding?
(C) (P)(R)(T)
(A)
(D) (Q) only
−
Q28 The stability of the species Li2 , Li2 , Li+
2
(B) increases in the order of
(A) Li2 < Li+ −
2 < Li2
− +
(B) Li2 < Li2 < Li2
(C) (C) Li2 < Li− +
2 < Li2
(D) Li−
+
2 < Li2 < Li2

Q29 In the following which of the two are

(D) paramagnetic
(1) N2
(2) CO
(3) B2
Q26 The linear combination of atomic orbitals to form (4) NO2
molecular orbitals takes place only when the Correct answer is
combining atomic orbitals (A) (1) & (3) (B) (2) & (3)
A. have the same energy (C) (3) & (4) (D) (2) & (4)

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Q30 The pair of species with same bond order is:

(A) O2−
2 , B2
+
(B) O2 , NO+
(C) NO, CO
(D) N2 , O2

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Answer Key
Q1 (A) Q16 (D)

Q2 (A) Q17 (C, D)

Q3 (C) Q18 (A)

Q4 (C) Q19 (A)

Q5 (C) Q20 (C)

Q6 (D) Q21 (B)

Q7 (A, B, D) Q22 (B)

Q8 (A) Q23 (C)

Q9 (D) Q24 (B)

Q10 (C) Q25 (B)

Q11 (D) Q26 (D)

Q12 (D) Q27 (B)

Q13 (C) Q28 (B)

Q14 (C) Q29 (C)

Q15 (D) Q30 (A)

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