SOLUTIONS

Concentration terms

1. sol(1)
2.
100
Sol. Volume of 100 gram of the solution =
d
100 100
= mL = litre
1.09 1.09  1000
1
= litre
1.09  10
13
Number of moles of H2SO4 in 100 gram of the solution =
98
No. of moles of H2SO 4
Molarity =
Volume of solution in litre

13 1.09  10
= × = 1.445 M
98 1

3. sol(3)

4. sol(2)

5.
Sol. Total mass of solution = (15 + 35) gram = 50 gram
mass percentage of methyl alcohol
Mass of methyl alcohol
= × 100
Mass of solution
15
= × 100 = 30%
50
6.
8
Sol. 40 = 0.2 M
1

7.
xB  1000
Sol. We know, m=
(1– xB ) mA
Given : m = 5.2 and mA = 18

xB  1000
5.2 =
(1– xB )18
xB = 0.086
8.
0.02
Sol.  106 = 40
500

9.
Sol. (2) Atmospheric pressure is low.

10.
Sol. (2) V.P. does not depends on surface area of liquid. (it depends on temperature).

11.
Sol. (1) V.P. depends on temperature
12.
Sol. Vapour pr. depends on temperature not volume.

13. sol(2)
14. sol(1)

15.
C
C (1 −  ) +
Sol. i= n i=1–+ 
C n
16. sol(3)

17. sol(2)

18. sol(4)

19.
Sol. AxBy xAm+ + yBn+
Initial moles n o o
At eq b. n(1–) nx ny
Total mol at equilirium n[(1 −  ) + x + y]
i= =
lnitial mol n
i = ( 1– )+ x + y
It can also seen that all other expressions imply the same thing.
 (4).
20. sol(3)

21. sol(3)

22.
P n w  mA
Sol. = XB  B = B
P0 nA mB  w A

 w B  mA   w  mA 
  =  B 
m
 B  w A  glucos e  mB  w A urea

wB  18 1 18
=
180  100 60  50
wB= 6g

23. sol(4)
24.
in
Sol. RLVP =
in + N
2n
so 0.167 =
180
2n +
18
so n=1

25. sol(3)

26. sol(2)

27.
Pº − P
Sol. = 0.05 = XB
Pº
Where XB = mole fraction of solute.
1000  XB
Molality = = 1000 × 0.05 / 0.95 × 18
(X A  MA )

28.
Sol. According to question Ps = 0.95 P0
according raoult’s law Ps = P0 XA given MA = 0.3 MB
 WA 
 MA 
0.95 P0 = P0   MA = molecular wt. of solvent
 A WB
W 
M +M 
 A B 
MB= molecular wt. of solute
WA
0.3 MB
0.95 = W A= gram wt. of solvent
WA W
+ B
0.3 MB MB
 W B= gram wt. of solute
WA
on solving = 5.7.
WB
29. sol(4)

30. sol(1)

31.
wB
Sol. V = RT
mB

4
6 × 10–4 × 1 = ×0.082 × 300
mB

mg = 1.6 × 105
32. sol(1)

33. sol(3)

34. sol(4)

35. sol(3)

36. sol(2)

37. sol(2)

38.
Sol. For isotonic solution 1 = 2 ; C1 = C2 ; n1 = n2
W1 W 10.5 30 10.5  180
= 2  =  M= = 63 Ans.
M1 M2 M 180 30

39. sol(2)

40.
2.08
Sol. Tb = ikb m so i= =4
0.52  1
so the compex is K3 [Fe(CN6)]
K3 [Fe(CN)6] 3 K+ + [Fe(CN)6]3–
41.
Sol. AIPO4 Al3+ + PO43–
i=1+x=2
Tb = molality Kbi
Tb
 = 0.02.
Kb

42. sol(2)

43.
Sol. x3y2 3x2+ + 2y3– for complete ionization.
1– n m
i = 1 + (m + n – 1) 
i = 1 + (2 + 3 – 1) × 0.25 = 1 + 1 = 2
Tb = i × kb × m = 2 × 0.52 × 1 = 1.04
B.P. of solution (Tb) = Tb + Tbº = 1.04 + 373 = 374.04 K Ans.

44.
Sol. Highest boiling point will be of that solutions for which Tb is high.
Here in this case Tb i (van’t hoff factor)
i = 4 for Al(NO3)3
Al (NO3)3 Al3+ + 3 NO3–

45. sol(4)

46.
Sol. Higher freezing point  lesser Tf lesser molality  lesser number of particles

47. sol(2)

48.
w B  1000
Sol. T = Kf ×
mB  w A

50  1000
9.3 = 1.86×
62  w A

wA = 161.29 gm (water)
Amount of ice = 200 – 161.29 = 38.71 g

49. sol(1)

50. sol(3)
51. sol(1)

52.
Sol. Given is vapour pressure of pure component ‘A’, PºA = 120 torr
Partial vapour pressure of ‘A’, PA = 72 torr
Suppose, its mole fraction in solution is xA, then according to Raoult’s law
PA= PºA . xA
72 = 120 × xA
72
or xA = = 0.6
120

53. sol(1)

54. sol(3)

55.
Sol. A : Benzene B : Toluene

P = PA + PB

P = PA0 XA + PB0 XB

 
= 75 × +22× = 37.5 + 11= 48.5
2 2
PA 37.5
Mole fraction of benzene in vapour , YA = = = 0.78
P 48

Similarly, mole fraction of toluene in vapour , YB = 0.22

The vapour will contain higher percentage of benzene

56.
Sol. Given is vapour pressure of pure component ‘A’, PºA = 120 torr
Partial vapour pressure of ‘A’, PA = 72 torr
Suppose, its mole fraction in solution is xA, then according to Raoult’s law
PA= PºA . xA
72 = 120 × xA
72
or xA =
120 = 0.6
57. sol(3)

58. sol(3)

59. sol(2)

60. sol(3)

61. sol(4)

62.
Sol. Some solids dissolves exothermically as LiCl (H = –ve) and other dissolved endothermically
as KCl
(H = +ve). solvent-solvent interaction and solute-solute interaction are endothermic while
solvent-solute interaction is exothermic. The sum of the three interaction determines whether
Hsol is endothermic or exothermic.

63.
Sol. PTotal = 0.4 × 80 + 0.6 × 120 = 104 > 100 mm of Hg.

64.
Sol. (1) C6H6 + C6H6CH3

65.
Sol. (2) CHCl6 + CHCOCH3

66.
Sol. Due to H-bonding

67. sol(3)

68.
Sol. It shows negative deviation from Raoult’s law
ps (actual) = 580 torr
ps (Raoult) = 0.4 × 300 + 0.6 × 800 = 600 torr.

69.
Sol. solvent-solvent interaction and solute-solute interaction are endothermic while solvent-solute
interaction is exothermic. The sum of the three interaction determines whether Hsol is
endothermic as exothermic.

70. sol(4)

71.sol(2)
72
Sol. Henry’s law is m = K · P ; where m = mass of gas absorbed by given volume of the solvent.
P = pressure of gas ;
 log m = log K + log P

73.
Sol. CO2 + H2O ⎯⎯
→ H2CO3 ⎯⎯
→ 2 H+ + CO32–
NH3 + H2O ⎯⎯
→ NH4OH ⎯⎯
→ NH4+ + OH–
HCl + H2O ⎯⎯
→ H3O+ + Cl–
But CH4 and H2 are insoluble gases in water.

74.
Sol. Solubility  pressure
S2 P
= 2
S1 P1
P2
S2 = 5.3 × 10–4× = 6.8 × 10–4 M
P1