Batteries 10 00141 v3
Batteries 10 00141 v3
Review
Energy Storage Systems: Technologies and
High-Power Applications
Ahmed Aghmadi and Osama A. Mohammed *
Energy Systems Research Laboratory, Department of Electrical and Computer Engineering, Florida International
University, Miami, FL 33174, USA; aaghm001@fiu.edu
* Correspondence: mohammed@fiu.edu
Abstract: Energy storage systems are essential in modern energy infrastructure, addressing effi-
ciency, power quality, and reliability challenges in DC/AC power systems. Recognized for their
indispensable role in ensuring grid stability and seamless integration with renewable energy sources.
These storage systems prove crucial for aircraft, shipboard systems, and electric vehicles, addressing
peak load demands economically while enhancing overall system reliability and efficiency. Recent
advancements and research have focused on high-power storage technologies, including superca-
pacitors, superconducting magnetic energy storage, and flywheels, characterized by high-power
density and rapid response, ideally suited for applications requiring rapid charging and discharging.
Hybrid energy storage systems and multiple energy storage devices represent enhanced flexibility
and resilience, making them increasingly attractive for diverse applications, including critical loads.
This paper provides a comprehensive overview of recent technological advancements in high-power
storage devices, including lithium-ion batteries, recognized for their high energy density. In addition,
a summary of hybrid energy storage system applications in microgrids and scenarios involving
critical and pulse loads is provided. The research further discusses power, energy, cost, life, and
performance technologies.
Keywords: hybrid energy storage system; pulse load; flywheel; supercapacitor; battery; superconducting
magnetic energy storage; grid service; transportation system
element and the lightest metal on the periodic table. Electrochemical cells are intercon-
nected in series or parallel in a typical battery configuration. Each cell comprises a negative
electrode (anode during discharge) and a positive electrode (cathode during discharge),
with an electrolyte layer as a separator. Additionally, a separator acts as a barrier between
the cathode and anode within each cell [23,24].
Battery performance and safety depend heavily on the electrolyte and separator
selection. Solid-state electrolytes, one of the emerging technologies, offer faster charging
and discharging times and increased safety [25]. Nevertheless, choosing materials that
can provide high ion conduction is constrained when the electrolyte is polymer-based
because of concerns about electrochemical stability. However, liquid electrolytes offer a
more comprehensive range of alternatives since various solvents have distinct viscosity
and dielectric constants that affect their performance in different ways [26,27].
As for the cathode, various lithiated metal oxides, including LiCoO2, Li-Mn-O,
LiFePO4, and lithium-layered metal oxide, can be utilized. Each cathode material possesses
unique electrochemical properties, affecting energy density, power density, and safety as
shown in Table 1. For instance, while lithium cobalt oxide offers high energy density, it
raises concerns about thermal stability and safety. On the other hand, lithium iron phos-
phate exhibits lower energy density but provides enhanced safety and thermal stability.
Therefore, carefully considering cathode materials is essential to balancing performance
metrics and ensuring safe battery operation.
During the charging process, the cathode transforms into lithium ions, traversing
the lithium salt electrolyte toward the anode, where they combine with external electrons.
The electrolyte, comprising organic carbonates of lithium (e.g., LiPF6), facilitates this elec-
trochemical process [24,28]. It is worth noting that electrolyte selection and formulation
significantly affect battery performance, particularly in ion conductivity, viscosity, flamma-
bility, and thermal stability. Therefore, optimizing electrolyte properties enhances battery
efficiency, safety, and lifespan.
Lithium-ion batteries are recognized for their high energy density, rapid response,
extended cyclic life, and high efficiency. The discharge voltage curves, particularly in Li-Mn
and Li–phosphate batteries, exhibit a notably flat profile, simplifying the application design
as nearly 80% of stored energy falls within this region. These advantages have positioned
lithium-ion batteries as prevalent choices in portable electronic devices and promising
components in electric and hybrid vehicles. However, challenges in implementation include
the substantial cost associated with large-scale utilization due to special packaging and
internal overcharge protection circuits. Additionally, deploying batteries in power systems
and managing grid-tied battery energy storage systems introduce complexities [26,30–33].
The amount
2.3. Compressed Airof stored
Energy energy
Storage depends on the stored water volume and the level
(CAES)
difference between both bodies. PHES serves as a valuable solution for grid stabilization
Compressed air energy storage (CAES) is an advanced technology for efficient en-
and enhancing overall grid reliability [34–36].
ergy storage. Its operational mechanism involves air compression into underground cav-
erns or storage tanks
2.3. Compressed during
Air Energy periods
Storage of low electricity demand. Subsequently, the stored
(CAES)
compressed air is released during peak demand periods, undergoing expansion, and driv-
Compressed air energy storage (CAES) is an advanced technology for efficient energy
ing turbines to generate electricity. The CAES process is structured around two essential
storage. Its operational mechanism involves air compression into underground caverns
stages: compression and expansion. Surplus electricity is judiciously employed in the
or storage tanks during periods of low electricity demand. Subsequently, the stored
compression
compressed air phase to compress
is released duringandpeak
storedemand
air. Conversely,
periods, the stored compressed
undergoing expansion,air and is
methodically released during the expansion stage to generate electricity. It is pertinent
driving turbines to generate electricity. The CAES process is structured around two essential to
acknowledge that CAES
stages: compression andexhibits a relatively
expansion. Surpluslower energyisefficiency,
electricity ranging
judiciously between
employed in the40
and 70%. Despite
compression phasethis
toefficiency
compresslimitation,
and store CAES plays an integral
air. Conversely, role compressed
the stored in addressing airen-
is
ergy demand fluctuations and contributes significantly to the overall stability
methodically released during the expansion stage to generate electricity. It is pertinent of the elec-
trical grid [37–39].
to acknowledge that CAES exhibits a relatively lower energy efficiency, ranging between
40 and 70%. Despite this efficiency limitation, CAES plays an integral role in addressing
2.4. Supercapacitor
energy Energy Storage
demand fluctuations and contributes significantly to the overall stability of the
Supercapacitors,
electrical grid [37–39].also known as ultracapacitors, play a pivotal role in energy storage
systems owing to their exceptional attributes, including high power density, swift charg-
2.4. capabilities,
ing Supercapacitor Energy Storage
extended cycle life, and broad operating temperature range. Their signif-
icance has surged notably,
Supercapacitors, particularly
also known within transportation
as ultracapacitors, and smart
play a pivotal role grid applications,
in energy storage
systemsthey
where owing to their exceptional
effectively smooth outattributes, including
energy spikes. high power
Nonetheless, density,
it is crucialswift charging
to recognize
capabilities,
that extendedof
the performance cycle life, and broad
supercapacitors operating
can temperature
be influenced range.
by diverse Their significance
parameters like tem-
has surgedcurrent,
perature, notably,and
particularly
voltage, within transportation
resulting andinsmart
in fluctuations theirgrid applications,
physical where
and chemical
they effectively smooth out energy spikes. Nonetheless, it is crucial to
properties. Moreover, real-world conditions may lead to disparities among individualrecognize that the
performance of supercapacitors can be influenced by diverse parameters like temperature,
current, and voltage, resulting in fluctuations in their physical and chemical properties.
Moreover, real-world conditions may lead to disparities among individual cells within
supercapacitor modules, leading to diminished service performance and posing risks to
system reliability and safety.
In contrast to rechargeable batteries, supercapacitors have a comparable chemical
composition and operational method, allowing energy storage and conversion via ion
diffusion and migration. However, supercapacitors have particular characteristics that
make them essential in storage systems. They can store hundreds of times more energy
cells within supercapacitor modules, leading to diminished service performance and pos-
ing risks to system reliability and safety.
In contrast to rechargeable batteries, supercapacitors have a comparable chemical
composition and operational method, allowing energy storage and conversion via ion dif-
Batteries 2024, 10, 141 fusion and migration. However, supercapacitors have particular characteristics that 6make of 21
them essential in storage systems. They can store hundreds of times more energy than
traditional capacitors because they operate as double-layer electrochemical capacitors as
depicted
than in Figure
traditional 2. Furthermore,
capacitors they
because they sufferas
operate fewer losses and
double-layer have a longercapacitors
electrochemical lifespan.
Notably, supercapacitors can withstand several charge and discharge cycles, significantly
as depicted in Figure 2. Furthermore, they suffer fewer losses and have a longer lifespan.
beyond the
Notably, lifespan of lead–acid
supercapacitors batteries,
can withstand which
several generally
charge last only cycles,
and discharge a few thousand cy-
significantly
cles. Supercapacitors also excel at supplying higher currents than regular batteries
beyond the lifespan of lead–acid batteries, which generally last only a few thousand cycles. [40–
44].
Supercapacitors also excel at supplying higher currents than regular batteries [40–44].
Figure 2. Structure
Figure 2. Structure of
of supercapacitor.
supercapacitor.
ever, organic electrolytes, which use solvents like propylene carbonate (PC) or acetonitrile
(CH3CN), offer better electrochemical stability, enabling higher voltages and higher energy
densities. Supercapacitors may operate at higher voltages and store more energy per unit
volume because of the stability that organic electrolytes provide up to 2.7 V. Despite their
benefits, organic electrolytes are more expensive, have flammability-related safety issues,
and need organic solvents, which poses environmental problems. The optimal operating
voltage, energy density specifications, cost considerations, safety issues, and environmental
impact all play a role in choosing between aqueous and organic electrolytes [42–47].
2.5. Flywheel
Flywheel energy storage systems (FESSs) are formidable solutions in energy storage,
boasting a range of advantages that position them as a competitive alternative. Among
these advantages are the notably high energy density, low maintenance requirements, and
rapid response capabilities inherent to FESS technology. One of the key strengths lies in
the environmental sustainability of FESSs, as they adeptly harness the kinematic energy
of rotational mass to absorb and release energy efficiently, contributing to an extended
operational lifespan.
The operational principle of an FESS involves storing kinetic energy as an electrome-
chanical system. This is achieved by rotating mass on magnetic bearings, effectively
minimizing friction even at elevated speeds. The magnetic bearings play a crucial role in
facilitating the smooth rotation of the flywheel, ensuring that energy is stored and released
with minimal losses. This design contributes to the high efficiency of FESS, reaching approx-
imately 90% at rated power. The combination of a prolonged cycling life and elevated power
and energy densities positions FESS as a compelling technology for various applications.
Despite these commendable characteristics, an FESS encounters challenges in the form
of standing losses. The self-discharge rates, reaching approximately 20% of the stored
capacity per hour, represent an area of concern that necessitates further attention. Efforts
to address standing losses are crucial for optimizing the FESS’s overall efficiency and
performance, particularly in scenarios where extended periods of energy storage without
discharge are prevalent.
Flywheel energy storage systems offer robust advantages, making them an attractive
option in the diverse landscape of energy storage technologies. The focus on environmental
sustainability, high efficiency, and energy density positions FESS as a promising solution
for applications ranging from grid stabilization to uninterruptible power supply. While
challenges such as standing losses persist, ongoing research and innovation can enhance
their performance further and address limitations, solidifying the role of FESSs in the future
of energy storage [48,49].
The quantity of kinetic energy (E) stored in a rotating object depends on both its mass
and velocity, as expressed by the following equation:
1
E= Rω 2 (4)
2
where R represents the moment of inertia, and ω is the rotational velocity.
To guarantee the reliability and stability of the flywheel energy storage system (FESS),
precise control of the flywheel speed within a specific range is imperative. Consequently,
the accessible energy of the flywheel is determined within the defined parameters of
maximum and minimum speeds.
1 2
Ep = R ωmax − ω2min (5)
2
While the flywheel has a significant power density, its energy density is very low.
As a result, it is best suited for grid applications that need frequency management and
short-term power quality services. Additionally, flywheel energy storage can be used in a
hybrid design with high-energy storage devices such as batteries or fuel cells [48–52].
𝐸 = 𝑅 ω −ω
2
While the flywheel has a significant power density, its energy density is very low. As
a result, it is best suited for grid applications that need frequency management and short-
term power quality services. Additionally, flywheel energy storage can be used in a hybrid
Batteries 2024, 10, 141 8 of 21
design with high-energy storage devices such as batteries or fuel cells [48–52].
11 2
E𝐸== LI𝐿𝐼 (6)
22
The schematic
The schematicrepresentation
representationbelow—Figure
below—Figure3—illustrates
3—illustrates thethe integral
integral components
components of
of a typical SMES system, encompassing a cryogenic system, superconducting
a typical SMES system, encompassing a cryogenic system, superconducting coil, protective coil, pro-
tective system,
system, and control
and control system. system. The superconducting
The superconducting coil serves
coil serves as theascentral
the central compo-
component,
nent, functioning
functioning as theas theofcore
core the of
SMESthe SMES
systemsystem by storing
by storing energy.energy. Maintaining
Maintaining its su-
its supercon-
perconducting
ducting state is state is facilitated
facilitated by the cryogenic
by the cryogenic refrigerator
refrigerator system,zero
system, ensuring ensuring
losses zero
and
losses and resistance in the coil. The coil is typically crafted from superconducting
resistance in the coil. The coil is typically crafted from superconducting materials like mate-
rials like mercury
mercury or niobium–titanium.
or niobium–titanium. The protective
The protective system system safeguards
safeguards againstagainst irregu-
irregularities
larities the
within within
SMEStheunit,
SMES unit,the
while while the control
control systemsystem establishes
establishes the connection
the connection betweenbetween
grid
grid power
power requirements
requirements and SMES
and SMES coil power
coil power flows.flows.
Figure 3.
Figure 3. Structure
Structure of
of SEMS.
SEMS.
Advancements in in superconducting
superconductingmaterials
materialsand
andcryogenic
cryogenicsystems have
systems opened
have openedup
up
newnew possibilities
possibilities for superconducting
for superconducting magnetic
magnetic energyenergy storage
storage (SMES)(SMES) in various
in various appli-
applications. The combination
cations. The combination of improved
of improved superconducting
superconducting coils
coils and and advanced
advanced power power
condi-
conditioning
tioning systems enables SMES to respond swiftly, typically within milliseconds, withwith
systems enables SMES to respond swiftly, typically within milliseconds, the
the capacity
capacity to handle
to handle power
power ratings
ratings extending
extending to several
to several megawatts
megawatts [53–57].
[53–57].
however, exhibit lower energy density, with values spanning from 2.5 to 15 Wh/kg and 0.2
to 2.5 Wh/kg, respectively.
Efficiency, denoting the ratio of useful energy output to the input, is relatively high
across all technologies. Supercapacitors and SEMS lead with efficiency levels between 95%
and 99%, while lithium-ion batteries and flywheels maintain efficiency within the range of
85% to 95% and 90%, respectively.
Lifetime, indicating the number of charge–discharge cycles a storage system can un-
dergo, is notably extended for flywheels and SEMS, ranging from 10,000 to 100,000 cycles
and exceeding 125,000 cycles, respectively. Lithium-ion batteries and supercapacitors,
however, have more limited lifetimes, ranging from 500 to 1000 cycles and over 125,000 cy-
cles, respectively.
Considering drawbacks, each technology has its challenges. Lithium-ion batteries face
limited cycle life and potential safety concerns. Flywheels encounter limitations in energy
density and higher upfront costs. Supercapacitors trade off energy density compared to
traditional batteries. SEMS poses challenges with high initial costs, complexity, and the
need for cryogenic cooling [58].
It is evident from examining the critical factors of different energy storage systems that
each choice has compromises and factors to consider. Supercapacitors have an excellent
power density that allows for rapid charging and discharging; moreover, their energy
density is lower than those of flywheels and lithium-ion batteries. On the other hand,
superconducting magnetic energy storage (SEMS) systems have higher power densities
and efficiency but are more complicated and have lower energy densities due to issues
such as high startup costs and cryogenic cooling requirements.
energy densities, creating a robust system capable of successfully mitigating short and
high-power fluctuations within systems (i.e., microgrids). The collaborative operation
of these storage components ensures a harmonious response to the dynamic energy de-
mands of the microgrid, contributing to its overall stability and efficiency. For instance,
research studies [7,8,59,60] have shown that an HESS can reduce the DC bus fluctuations
in a DC standalone microgrid by incorporating a Li-ion battery with supercapacitor in
case of pulse loads or variable pulse loads by allocating the high transient demand to the
supercapacitor and average demand to the battery. In another study [61], a hybrid energy
storage system (HESS) with an effective adaptive energy management technique (EMS)
was used to counteract power fluctuations. The authors concluded through a simulation
and experiment validation that the fluctuation in DC link voltage was reduced, and the
battery and supercapacitor’s coordinated function lessened the battery’s stress. In [62],
a dual model predictive control (D-MPC) technique for a hybrid energy storage system
(HESS) coupled with superconducting magnetic energy storage (SMES) and a battery in
naval DC microgrids was used to meet pulsed power demands.
The indispensability of a hybrid energy storage system becomes particularly apparent
in applications characterized by specific load profiles. Models where multiple loads exhibit
a standard profile, requiring relatively high pulse power but a lower average, highlight
the significance of an HESS. The high level of short-term current behavior inherent in
these scenarios necessitates components with higher power ratings, as failure to meet
these requirements could disrupt the entire grid. In such applications, the flexibility and
adaptability of an HESS prove instrumental in maintaining grid integrity and ensuring
reliable performance, making it an indispensable asset for the evolving landscape of DC
microgrids. Several research studies have been conducted to analyze the impact of HESSs
on power systems [61–71].
on lead–acid batteries for energy storage. However, the prevalence of very short power
failures and disturbances, often lasting less than 1 s, necessitates oversized battery banks,
incurring additional costs for unused energy reserves. Telecommunication centers and
critical facilities, mandated to have standby gensets, require short-duration energy storage
to mitigate brief power disturbances and facilitate a seamless transition to startup and syn-
chronize the standby gensets for an extended power supply. In addressing these challenges,
flywheel energy storage systems emerged as a viable alternative, offering immediate power
availability during outages, dips, or surges in voltage and/or current. Compared to batter-
ies, flywheel systems present a lower cost per power unit, reduced operating costs due to
lower maintenance and replacement expenses, and enhanced environmental friendliness.
The compact design of flywheel UPS technology, leveraging high power density, further
distinguishes it as a favorable option.
Flywheel energy storage systems operate on the principle of storing kinetic energy in
a rapidly spinning mass. During regular operation, the flywheel spins and stores energy.
In the event of a power disruption, the stored kinetic energy is rapidly converted back
into electricity, providing an instantaneous and reliable power source. This contrasts with
traditional lead-acid batteries, which require charging time before delivering power.
The economic advantages of flywheel systems become apparent when considering
their lower cost per power unit than batteries. Additionally, their reduced operating costs
stem from lower maintenance and replacement expenses, as flywheels do not suffer from
the degradation that batteries experience over time. The environmental benefits of flywheel
technology contribute to its appeal, aligning with the growing emphasis on sustainable
and eco-friendly energy solutions.
The compact design of flywheel UPS technology, leveraging high power density,
allows for more efficient use of space compared to traditional battery-based systems. This
makes flywheel systems particularly suitable for environments with premium space, such
as densely populated urban areas or critical facilities with limited physical footprint [79–81].
Similarly, supercapacitors are an effective solution for short-term failures with their
high power density and low cost per unit power. These systems, ranging from 20 kW to
several milliwatts in size, can function as bridging power supplies to more permanent
backup sources, such as gensets or fuel cells. Supercapacitor UPSs, known for their com-
pactness, entail minimal maintenance and standby power costs, making them a pragmatic
choice for applications requiring swift responses to short-term power disruptions [82–86].
N −1
PD (t) = Pmin + ∑ ( Pmax − Pmin )[δ(t − KT ) − δ(T − (K + D)T )] (7)
K =0
Figure 4.
Figure Pulse load
4. Pulse load structure.
structure.
As shown insupercapacitors
Integrating Figure 1, the computed instantaneous
or flywheels becomes avalue of theoption
strategic PPL demand may be
in response to
described using two components of the power profiles: average power P ave
the challenges posed by pulsed loads. This approach proves essential when a single en-and dynamic
power
ergy Pdyn ;struggles to handle a pulse load’s high instantaneous power demands, poten-
source Z T
tial power outages, and 1 concerns.
thermal
Pave = PD (t)dt When
= D ( Pcombined with appropriate power elec-
max − Pmin ) + Pmin (8)
T
tronic infrastructure and management methodologies, supercapacitors and flywheels
0
emerge as power-dense storageN −1 systems with a low cost per unit power, significantly en-
Pdyn = PD (t) − Phancing
ave = − Doverall
( Pmax system
− Pmin ) + ∑ max − Pmin ) ∗ (δ(t − KT ) − δ(T − (K + D)T ))
performance.
( P (9)
The configuration of Kincorporating
=0 supercapacitors or flywheels into the power sys-
tem is designed to manage dynamic power requirements effectively. In this approach,
Integrating supercapacitors or flywheels becomes a strategic option in response to the
while meeting typical pulse load demands, the long-term primary energy supply is com-
challenges posed by pulsed loads. This approach proves essential when a single energy
plemented by supercapacitors or flywheels’ rapid response and high-power capabilities.
source struggles to handle a pulse load’s high instantaneous power demands, potential
power outages, and thermal concerns. When combined with appropriate power electronic
infrastructure and management methodologies, supercapacitors and flywheels emerge
as power-dense storage systems with a low cost per unit power, significantly enhancing
overall system performance.
The configuration of incorporating supercapacitors or flywheels into the power system
is designed to manage dynamic power requirements effectively. In this approach, while
meeting typical pulse load demands, the long-term primary energy supply is comple-
mented by supercapacitors or flywheels’ rapid response and high-power capabilities. This
dynamic interplay offers notable benefits, including reducing system weight and volume.
Integrating these energy storage components minimizes voltage disturbances, frequency
variations, and heat-related issues, ensuring enhanced reliability and efficiency in power
system operations.
Supercapacitors, with their ability to deliver rapid bursts of energy and high-power
density, prove instrumental in handling the instantaneous power requirements of pulsed
loads. Their efficiency and longevity make them well suited for applications where frequent
and rapid charging and discharging cycles are essential. Similarly, flywheels leverage
kinetic energy storage, responding instantly to fluctuating power demands. Their rotational
inertia allows for seamless energy discharge during pulsed load scenarios, making them an
ideal complement to the primary energy source.
When implemented with careful consideration of power electronic infrastructure
and management methodologies, the integration of supercapacitors or flywheels into
power systems ensures a harmonious balance between instantaneous power demands and
sustained energy supply. This innovative configuration addresses the specific challenges
posed by pulsed loads and sets the stage for more efficient, reliable, and adaptable power
systems in communication, shipboard, and spacecraft applications [7,8,87].
Batteries 2024, 10, 141 13 of 21
becomes crucial to keeping a steady and uninterrupted power supply and avoiding power
outages [94].
Synchronous machines maintain consistent rotor angular positions in stable, disturbance-
free grids. On the other hand, power oscillations might result from changes in power in
renewable resources or from the loss of a primary transmission line. These oscillations can
potentially cause undamped electromechanical oscillations and rotor angular instability.
If not adequately mitigated, such disturbances, particularly those occurring across poor
transmission connections, may cause partial or complete power outages. Counteracting
these disturbances can be achieved by injecting or absorbing actual oscillatory power at
frequencies between 0.5 and 1 Hz. For this application, high-power energy storage devices
with sophisticated power electronics interfaces—such as SMES, supercapacitors, flywheels,
and high-power batteries—have become competitive options. These storage devices can
sense disturbances, react at full power in 20 ms, and inject or absorb oscillatory power for
a maximum of 20 cycles. As a result, they offer practical solutions for mitigating power
oscillations and ensuring grid stability [12,95].
4. Conclusions
This comprehensive study presents the critical roles of high-power storage technolo-
gies in promoting sustainable energy solutions, focusing on microgrid resilience, grid
stability, and frequency control. This paper discussed the profound impact of Li-ion bat-
teries, supercapacitors, superconducting magnetic energy storage (SMES), and flywheels
on these critical domains by distinguishing between high-energy and high-power storage
categories and providing valuable insights into their respective capabilities and diverse
applications. In addition, the beneficial integration of several storage technologies into
hybrid systems has emerged as a practical approach to maximizing performance met-
rics across distinct applications, providing detailed insights into critical decision-making
criteria for choosing specific storage solutions. In an energy environment characterized
by fast transitions and more renewable integration, the research emphasizes the crucial
role of high-power storage technologies in improving grid dependability and promoting
sustainability. Furthermore, this work enhances our understanding of the minor differences
between high-energy and high-power storage. It emphasizes their combined influence on
advancing sustainable energy solutions as the energy storage sector evolves with ongoing
technical advancements and strategic implementations. Research and development efforts
continue to investigate new substances and composites that will improve the energy den-
sity, power density, and cycle life of storage systems. This will encourage more innovation
in the continually developing field of energy storage technologies.
Abbreviations
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