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Mole Concept DPP 3 SOLUTION

This document is a chemistry assignment for XIth grade, covering various concepts such as mole ratios, atomic weights, and chemical reactions. It includes calculations related to the preparation of compounds, neutralization reactions, and the law of constant composition. An answer key is provided at the end for self-assessment.

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Ashish Kumar
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26 views4 pages

Mole Concept DPP 3 SOLUTION

This document is a chemistry assignment for XIth grade, covering various concepts such as mole ratios, atomic weights, and chemical reactions. It includes calculations related to the preparation of compounds, neutralization reactions, and the law of constant composition. An answer key is provided at the end for self-assessment.

Uploaded by

Ashish Kumar
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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CLASS : XIth SUBJECT : CHEMISTRY

DATE : Solutions DPP No. : 3

Topic :- SOME BASIC CONCEPTS OF CHEMISTRY


1 (b)
See mole ratio 𝐴 :𝐵 :𝐶::1 :2 :1
2 (d)
14𝑁
1 mg C4H10 = × 10―3 atoms,
58
2𝑁 × 10―3
1 mg N2 = atoms,
28
𝑁 × 10―3
1 mg Na = atoms,
23
3𝑁
1 mL = 1 g H2O = atoms,
18
( ∵ M g of a substance = 𝑁 molecules = 𝑎 × 𝑁 atoms;where 𝑎 is number of atoms in one
molecule).
3 (c)
An aromatic hydrocarbon (empirical formula C5H4)
+ H2SO4→ monosulphonic acid
∵ 0.104 g of monosulphonic acid required 10 mL
N
of 20 NaOH for complete neutralisation
0.104 1
∴ = × 10 × 10―3
𝑛(5 × 12 + 4 × 1) 20
104
𝑛= = 3.25 ≈ 3
32
The molecular formula of hydrocarbon will be C15H12.
4 (a)
2
In 12 g carbon, mass of C-14 isotope = 12 × 100 = 0.24𝑔
0.24
∴ Number of C-14 atoms in 12 g of 𝐶 = 14
× 6.02 × 1023
= 1.032 × 1022
5 (b)
To prepare 20 g zinc sulphate crystals, zinc required
22.65
= × 20
100
= 4.53𝑔
6 (b)
6.02 × 1025
Number of gram molecules = 6.02 × 1023 = 100

7 (a)
Ferrous is Fe2+
8 (b)
5
𝑀= = 1.47
34 × 100/1000
9 (b)
4.6 × 1022 atoms weight =13.8 g
Hence, 6.02 × 1023 atoms will weigh
13.8 × 6.02 × 1023
= 4.6 × 1022
= 108.6 g (molar mass)

10 (c)
Eq. of HCl = Eq. of CaCO3
𝑤 100
Thus, 36.5 = 50
;
∴ 𝑤 = 73 g HCl;
50 g HCl is present in 100 g HCl solution and thus, volume of solution required for,
73 × 100
73 g HCl = 50
= 146g.
12 (d)
The law of constant composition ― According to this law, “A chemical compound is always
found to be made up of the same elements combined together in the same proportions by
weights”.
This law is same as law of definite proportions.
13 (d)
Atomic weight of the element
𝑋 = 6.643 × 10―23 × 𝑁𝐴 = 40
20 × 1000
No. of moles of 𝑋 = 40
= 500
14 (a)
Limiting reagent is one which is completely consumed in reaction.
15 (d)
ppm = wt. of solute in 106 g H2O
103 g H2O contains 10 g CaCO3
10 × 106
∴ 106 g H2O contains = 103
= 10,000 ppm CaCO3
16 (d)
BaCl2 + H2SO4⟶BaSO4 +2HCl
mm 20 × 0.5 20 × 1
taken = 10 20 0 0
mm 0 10 10 20
formed
Milli mole of BaSO4 = 10
or Mole of BaSO4 = 10―2
17 (d)
Percentage of element 𝑀 in 𝑀2𝑂3 = 53
Let the atomic mass of 𝑀 = 𝑥
Mass of 𝑀in 𝑀2𝑂3 = 2𝑥
Total atomic mass of 𝑀2𝑂3 = 2𝑥 + 16 × 3
= 2𝑥 + 48
Percentage of an element
Mass of an element in a compound
= × 100
Total mass of compound
2𝑥
53 = × 100
2𝑥 + 48
53(2𝑥 + 48) = 200𝑥
𝑥 = 27
18 (a)
H3BO3 accepts OH― ions to act as weak monobasic Lewis acid.
H3BO3 + H2O⟶B(OH)― +
4 +H ; 𝐾𝑎 = 10―9
19 (a)
Meq. of KOH added = 25 × 0.4210 = 10.525
Meq. of KOH left = 8.46 × 0.2732 × 2 = 4.623
∴ Meq. of KOH used by oil = 10.525 – 4.623 =5.902
𝑤
or 56 × 1000 = 5.902
𝑤
or KOH = 0.3305 g
∴Saponification no.
= wt. of KOH used in mg per g of oil
0.3305
= 1.5763 × 1000
= 209.6
20 (c)
(NH4)2SO4⟶2NH3 + H2O + SO3
3NH3 + 2HCl⟶2NH4Cl
(NH4)2SO4 ≡ 2NH3 ≡ 2HCl
132 g 73g
73gHCl ≡ 132g(NH4)2SO4
132 × 292
292 g HCl ≡ 73
g(NH4)2SO4
= 528 g(NH4)2SO4
ANSWER-KEY
Q. 1 2 3 4 5 6 7 8 9 10
A. B D C A B B A B B C

Q. 11 12 13 14 15 16 17 18 19 20
A. A D D A D D D A A C

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