Product name

Safety Data Sheet

According to 29 CFR 1910.1200

Date of issue: 01-05-2019 Supersedes: - Version No: 1.0

1. Identification ☐

Product name X
Other means of identification:
X
X
X
X

Recommended use of the chemical and restrictions on use

For industrial use, for manufacturing of polymers.

The product should only be used in accordance with the use specified above. If the product is used outside the specified
usage, contact should be made with the supplier.

Manufacturer/supplier
X

Contact person X

Emergency Telephone Number

24hrs CHEMTREC +1 703-741-5970 / 1-800-424-9300.

2. Hazard(s) identification ☐

GHS Classification
This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Physical hazards Flammable Solids Category 1
Substances and mixtures which, in contact Category 3
with water, emit flammable gases
Health hazards Skin corrosion/irritation Category 1B
Specific target organ toxicity (Single Category 1
Exposure)
Specific target organ toxicity (Single Category 3
Exposure) (Respiratory Tract Irritation)
Specific target organ toxicity (Repeated Category 1
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Safety Data Sheet
According to 29 CFR 1910.1200

Date of issue: 10-25-2018 Revision date: 10-25-2018 Supersedes: - Version No: 1.0

Exposure)
Environmental hazards Aquatic chronic Category 2
OSHA defined hazards None known.

GHS Label elements

Signal word Danger

Hazard statements
Flammable solid.
In contact with water releases flammable gas.
Causes severe skin burns and eye damage.
Causes damage to lungs via inhalation.
May cause respiratory irritation.
Causes damage to lungs through prolonged or repeated exposure via
inhalation.
Toxic to aquatic life with long lasting effects.
Precautionary statements
Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Ground/Bond container and receiving equipment. Use explosion-proof
electrical/ventilating/ lighting equipment. Wear protective gloves/protective
clothing/eye protection/face protection. Handle under inert gas. Protect from
moisture. Wash hands thoroughly after handling. Do not breathe
dust/fume/gas/mist/ vapors/spray. Do not eat, drink or smoke when using this
product. Use only outdoors or in a well ventilated area. Avoid release to the
environment.
Response In case of fire: Use powder to extinguish. If swallowed: Rinse mouth. Do NOT
induce vomiting. If on skin (or hair): Take off immediately all contaminated
clothing. Rinse skin with water/shower. Wash contaminated clothing before
reuse. If inhaled: Remove person to fresh air and keep comfortable for
breathing. Immediately call a POISON CENTER or doctor/physician. Specific
treatment (see section 4 of this SDS). If in eyes: Rinse cautiously with water for
several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing. If exposed: Call a poison center/doctor/physician. Call a poison
center/doctor/physician/if you feel unwell. Collect spillage.
Storage Store in a dry place. Store in a closed container. Store locked up. Store in a well
ventilated place. Keep container tightly closed.
Disposal Dispose of contents/container in accordance with local/regional/national/
international regulations.

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Safety Data Sheet
According to 29 CFR 1910.1200

Date of issue: 10-25-2018 Revision date: 10-25-2018 Supersedes: - Version No: 1.0

Hazard(s) not otherwise classified If product comes in contact with water, toxic and irritating vapor may be
(HNOC) formed.
3. Composition/information on ingredients ☐

Mixtures

Chemical name CAS number Percentage (wt/wt)

2-Ethyl-1-hexanol 104-76-7 15-20
Titanium tetrachloride 7550-45-0 5-10
n-Heptane 142-82-5 3-10
Synthetic, amorphous silica 7631-86-9/112926-00-8 50-60
Aluminum hydroxide 21645-51-2 3-10
Magnesium Chloride 7786-30-3 7-9

4. First-aid measures ☐

Description of first aid measures

Inhalation Supply fresh air and call for a doctor.
Skin contact Wash skin thoroughly with soap and water. Remove contaminated clothing
and shoes. Wash contaminated clothing before use.
Eye contact Rinse immediately with soft water for at least 15 minutes. Hold eyelids open
and remove possible contacts. Seek medical help and continue rinsing during
transport.
Ingestion Rinse mouth with water. Drink a few glasses of water or milk. Never give
anything by mouth to an unconscious person. Do not induce vomiting.
Consult a physician.

Most important symptoms/effects, both acute and delayed

Burning and irritation of the eyes, skin and respiratory tract.

Indication of immediate medical attention and special treatment needed

Treat symptoms and injuries systematically.

5. Fire-fighting measures ☐

Extinguishing media
Suitable Dry sand. Extinguishing powder.
Unsuitable Water or foam if there is risk of contact with product.

Specific hazards arising from the chemical

Heated product or contact with water may cause strong reaction and emit toxic and corrosive fumes. Titanium

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According to 29 CFR 1910.1200

Date of issue: 10-25-2018 Revision date: 10-25-2018 Supersedes: - Version No: 1.0

tetrachloride decomposes in water to titanium dioxide and hydrochloric acid.

Special protective equipment and precautions for fire-fighters

Cool exposed containers with water spray if there is no risk of contact with the product. Move containers if this can be
done safely. Prevent extinguishing media to reach drains or water ways since water could be contaminated. Use self-
sustained breathing mask. Protective suite.

6. Accidental release measures ☐

Personal precautions, protective equipment and emergency procedures

Alarm and evacuate. Avoid direct contact with product. Provide sufficient ventilation. Use personal protective
equipment. Remove all ignition sources.

Methods and materials for containment and cleaning up

Use explosion-proof equipment and spark-free tools. Sweep or vacuum spilled material. Avoid dust formation. Cover any
drains. Place in a suitable container that is tightly closed and marked and dispose as waste. Avoid release into the
environment, sewers or water ways.

7. Handling and storage ☐

Precautions for safe handling

Apply occupational hygiene principles and avoid direct contact with product. Do not eat, drink or smoke when handling
chemicals. Provide sufficient ventilation. Avoid formation of dust. Use explosion-proof equipment and spark-free tools.

Conditions for safe storage, including any incompatibilities

Store as flammable product. Store in original containers, tightly closed in a cool and dry place. Protect from heat and
direct sunlight. Ground/bond container and receiving equipment. Avoid contact with air/oxygen. Take precautions
against electrostatic build-up. Keep separated from incompatible material and substances. See SECTION 10.

8. Exposure controls/personal protection ☐

Occupational exposure limits

US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)

None of the ingredients of this product are listed.
\

US. OSHA Table Z-1 (29 CFR 1910.1000)

Component Type Value

n-Heptane (CAS# 142-82-5) PEL- TWA 500 ppm (2000 mg/m³)

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Safety Data Sheet
According to 29 CFR 1910.1200

Date of issue: 10-25-2018 Revision date: 10-25-2018 Supersedes: - Version No: 1.0

US. OSHA Table Z-2 (29 CFR 1910.1000)

None of the ingredients of this product are listed.

US. OSHA Table Z-3 (29 CFR 1910.1000)

Component Type Value
Synthetic, amorphous silica TWA 20 mppcf or (80 mg/m³)/(%SiO2)
(CAS#7631-86-9/112926-00-8)

US. ACGIH Threshold Limit Values

Component Type Value

n-Heptane (CAS# 142-82-5) TLV- TWA 400 ppm

TLV-STEL 500 ppm

US. NIOSH: Pocket Guide to Chemical Hazards

Component Type Value

REL-TWA 85 ppm (350 mg/m3)

n-Heptane (CAS# 142-82-5) REL -C 440 ppm (1800 mg/m3) [15-minute]
Synthetic, amorphous silica REL-TWA 6 mg/m3
(CAS#7631-86-9/112926-00-8)

Appropriate engineering controls

Used in closed processes, no likelihood of exposure. Ventilation shall be effective. Make sure that eye-flashing
equipment is installed in proximity to the workplace. Apply occupational hygiene principles.

Individual protection measures, such as personal protective equipment

Eye/face protection Tightly fitted safety goggles.

Skin protection
Hand protection Protective gloves shall be used. Suitable material may be Nitrile- or Viton
rubber based on components in the substance. Penetration 480 min (EN 374).
For more information of suitable material, contact supplier of protective
equipment
Other Protective clothing if necessary.

Respiratory protection Respiratory protection shall be used at insufficient ventilation. Filter for dust
(particles), (type P3, EN143) and organic vapor with a boiling point >65 ⁰C, (type
A2, EN14389).

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Safety Data Sheet
According to 29 CFR 1910.1200

Date of issue: 10-25-2018 Revision date: 10-25-2018 Supersedes: - Version No: 1.0

General hygiene considerations Keep away from foodstuff, beverages, and feed. Wash hands before breaks and
at the end of work.

9. Physical and chemical properties ☐

Appearance Powder.
Color Pale pinkish brown.
Odor Faint smell of heptane.
Odor threshold Not applicable.
pH Not applicable.
Melting point/freezing point Not applicable.
Initial boiling point/Boiling range Not applicable.
Flash point Not applicable.
Evaporation rate Not applicable.
Flammability (solid, gas) Flammable solid.
Lower flammability/explosive limit Not applicable.
Upper flammability/explosive limit Not applicable.
Vapor pressure Not applicable.
Vapor density Not applicable.
Relative Density 0.3 g/cm3
Solubility Not soluble in water.
Partition coefficient -n-octanol/water Not applicable.
Auto-ignition temperature Not applicable.
Decomposition temperature Not applicable.
Viscosity Not applicable.
Explosive properties Not explosive.
Oxidizing properties Reacts rather slowly with air and moisture.

10. Stability and reactivity ☐

Reactivity
Titanium tetrachloride: May react violently with water.

Chemical stability
Stable if used and stored as recommended.

Possibility of hazardous reactions

Titanium tetrachloride: May attack metals in the presence of water or moisture and emit flammable hydrogen gas
causing risk of fire and explosion.

Conditions to avoid
Heat, sunlight, ignition sources, moisture.

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According to 29 CFR 1910.1200

Date of issue: 10-25-2018 Revision date: 10-25-2018 Supersedes: - Version No: 1.0

Incompatible materials
Water, strong oxidizers, alcohols.

Hazardous decomposition products

Carbon dioxides. Titanium tetrachloride: Corrosive hydrochloric acid is formed upon contact with water, water vapor or
alcohols.

11. Toxicological information ☐

Information on likely routes of exposure

Inhalation Inhalation of dust may irritate and cause corrosive burns on mucous membranes.
Ingestion May cause serious injuries to the respiratory tract. Corrode and irritates. May
cause nausea, coughing, headache and dizziness.
Skin contact Redness, burning. Causes severe skin burns.
Eye contact Redness, burning, pain. Causes serious eye damage.

Symptoms related to the physical, Burning and irritation of the eyes, skin and respiratory tract.
chemical and toxicological
characteristics

Delayed and immediate effects and No information available.

chronic effects from short- and
long-term exposure

Numerical measures of toxicity

No data for the mixture as whole.

Toxicity data for the components:

Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
n-Heptane (CAS# 142-82-5) >2 000 mg/kg (rat) 3 000 mg/kg (rabbit) 60 mg/l, 4hr, (rat)
Titanium tetrachloride( CAS # 7550- 464 mg/kg (rat) 3 160 mg/kg (rabbit) 0.46 mg/l, 4 hr, (rat)
45-0)

Skin corrosion/irritation Causes severe skin burns.

Serious eye damage/eye irritation Causes serious eye damage.
Respiratory or skin sensitization
Respiratory sensitization Contains no substance known to be sensitizer.
Skin sensitization Contains no substance known to be sensitizer.
Germ cell mutagenicity Not classified.
Carcinogenicity Not classified.
IARC Monographs. Overall Evaluation of Carcinogenicity

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Date of issue: 10-25-2018 Revision date: 10-25-2018 Supersedes: - Version No: 1.0

Synthetic, amorphous silica (CAS#7631-86-9/ 3 Not classifiable as to carcinogenicity to humans.

112926-00-8)
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Not listed.

US. National Toxicology Program (NTP) Report on Carcinogens

Not listed.
Reproductive toxicity Not classified.
Specific target organ toxicity – Causes damage to lungs via inhalation.
single exposure May cause respiratory irritation.
Specific target organ toxicity – Causes damage to lungs through prolonged or repeated exposure via
repeated exposure inhalation.
Aspiration hazard Not classified.

12. Ecological information ☐

Ecotoxicity
The product is classified as toxic to aquatic life with long-lasting effects.

No data for the mixture as whole.

Ecotoxicity for components:

Chemical Name Test Species Test Results
n-Heptane (CAS# 142-82-5) Fish LC50 Coho Salmon > 100 mg/l ,96h
(Onchorhyrnchus kisutch)
Crustacea EC50 Water fleas 1.5 mg/l, 48h
(Daphnia magna)
Algae IC50 Scenedesmus > 200 mg/l, 72h
quadricauda

Persistence and degradability

Titanium tetrachloride – Decomposes, in the presence of water, to titanium dioxide and hydrochloric acid.

Bioaccumulative potential
Titanium tetrachloride – The substance is highly reactive and does not last long in the environment n-Heptane - BCF =
776, 25, log POW = 4,66. Potentially bioaccumulative.

Mobility in soil
No information available.

Other adverse effects

No other effects known.

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Safety Data Sheet
According to 29 CFR 1910.1200

Date of issue: 10-25-2018 Revision date: 10-25-2018 Supersedes: - Version No: 1.0

13. Disposal considerations ☐

Disposal instructions
Waste characterizations and compliance with applicable laws are the responsibility solely of the waste generator.
Dispose of content and/or container in accordance with local, regional, national, and/or international regulations.

14. Transport information ☐

DOT IATA IMDG

UN Number 3396 3396 3396
UN Proper ORGANOMETALLIC ORGANOMETALLIC ORGANOMETALLIC
shipping name SUBSTANCE, SOLID, SUBSTANCE, SOLID, SUBSTANCE, SOLID,
WATERREACTIVE, FLAMMABLE WATERREACTIVE, FLAMMABLE WATERREACTIVE, FLAMMABLE
(metal alcoholate, n-heptane) (metal alcoholate, n-heptane) (metal alcoholate, n-heptane)

Transport hazard 4.3 (4.1) 4.3 (4.1) 4.3 (4.1)

class (es)
Packaging group II II II
Environmental Yes Yes Marine Pollutant-Yes
hazard
Additional - Packing Instruction P489 Max. EmS: F-G, S-N
information 50kg net Cargo aircraft only
Packing Instruction P483 Max.
15kg net Passenger and Cargo
aircraft
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not available.

15. Regulatory information ☐

US federal regulations
This product is a “Hazardous Chemical” as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.
All the ingredients are listed on the U.S. EPA TSCA Inventory List.

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)

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Not listed.

US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)

Not listed.

CERCLA Hazardous Substance List (40 CFR 302.4)

Titanium tetrachloride (CAS# 7550-45-0)-Listed

SARA Section 311/312 (40 CFR 370 Subparts B and C) reporting categories
Flammable solid, In contact with water emits flammable gas, Skin corrosion, Specific target organ toxicity (Single and
Repeated exposure)

SARA 313 (TRI reporting)

Titanium tetrachloride (CAS# 7550-45-0)-Listed

Other federal regulations

Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Titanium tetrachloride (CAS# 7550-45-0)-Listed

Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Titanium tetrachloride (CAS# 7550-45-0)-Listed

Safe Drinking Water Act (SDWA)

Not listed.

US state regulations
US. New Jersey Worker and Community Right-to-Know Act
n-Heptane (CAS# 142-82-5)-Listed
Titanium tetrachloride (CAS# 7550-45-0)-Listed

US. Pennsylvania Worker and Community Right-to-Know Law

2-Ethyl-1-hexanol (CAS# 104-76-7) –Listed
Titanium tetrachloride (CAS# 7550-45-0)-Listed
n-Heptane (CAS# 142-82-5)-Listed
Synthetic, amorphous silica (CAS# 7631-86-9)- Listed

US. California Proposition 65

US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance
Not listed.

Carcinogenic categories

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Date of issue: 10-25-2018 Revision date: 10-25-2018 Supersedes: - Version No: 1.0

EPA (Environmental Protection Agency)

142-82-5 n-Heptane
TLV (Threshold Limit Value established by ACGIH
142-82-5 n-Heptane
NIOSH-Ca (National Institute for Occupational Safety and health)
None of the ingredients is listed

International Inventories
Australia - AICS
All the ingredients are listed.
Canada -DSL/NDSL
All the ingredients are listed in DSL.

China - IECSC
All the ingredients are listed.
Europe- EINECS/ELINCS/NLP
All the ingredients are listed in EINECS.
Japan- ENCS
All the ingredients are listed.
Korea-ECL
All the ingredients are listed.
New Zealand- NZIoC
All the ingredients are listed.
Philippines – PICCS
All the ingredients are listed.
US - TSCA
All the ingredients are listed.

16.Other Information ☐

Once the information in the safety data sheet changes, this is shown in the checkbox located to the right of each chapter
heading. This means that certain hazard or safety information has changed in the current section. The detailed changes
are not showed. A supplier of a substance or preparation is required to provide an explanation of the changes on
request.

Information sources According to 29 CFR 1910.1200

Revision date 01-05-2019
Revision 1

Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the

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According to 29 CFR 1910.1200

Date of issue: 10-25-2018 Revision date: 10-25-2018 Supersedes: - Version No: 1.0

date of its publication. The information given is designed only as guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any
other materials or in any process, unless specified in the text.

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