Vision: To establish the Department as a Centre of excellence for producing professionally competent and socially ‘committed Chemical Enginees E OF ENGINEERING, NAVI MUMBAI DEPART MICAL ENGI EERING MODELING SIMU ‘ATION AND OPTM! TION ASSIGNMENT: 6 (Module -04) CO: 4 B.E. CHEMICAL / SEM VIII /CBCGS / 2023-2024 BHARATI VIDYAPEETH COL ENT O! Q.1) Determine loop array matrix ri {ne Lo=—_—— Q.2) Explain types of simulations with examples Q3) Explain partitioning, precedence ordering and teari Q.4) Write linear mass balance with neat diagram for a. Mixer b. Splitter c. Reactor (fixed conversion model) Q.5) Solve William Otto flow sheet in the sequential oriented mode, only the step: calculation required? ing in flow sheet simulation sno A+B>C C+BOP+E P+C>G Mission MI To prepare student forthe calls challenges of chemical engineering by provi 1 To prpre set the cerca Nes fhe cemicl indus. eaten re edacie and ain student fo come responsible and ethical chemical engin th crs to serve the societyST Vision: To establish the Department as a Centre of excellence for producing professionally competent and socially committed Chemical Engineers. _— FutAy 3 rane) Drm [ome [eal BE ‘ae 3 a Exchanger 7 road) = a 5.975510" exp(-!2000/,) 2.596210" exp(-15000/} 9.628310" exp(- 20000/) Mission: MI: To prepare students for the challenges of chemical engineering by providing a high-quality education. ‘M2: To prepare students to meet the ever-changing needs of the chemical industry. M3: To educate and train students to become responsible and ethical chemical engineers to serve the society) Genders | FOR EDUCATIONAL USE |The ne army iS Used —te_initiqlize boop meth, A wrt aQe, Typeset simulathons | | A. Dtsewtt Simylathon medd t _ Lis Disewede Sienulahin wmoola) hep “to system ocuy at spcctRe_ times - 1 Division ot property mensyemtnt bruble calls. eee ee Ae quisition business prvcess: i 4 senator) system le sant centeding teeing — sd specitic times. So 2. Contos simulation medel + - 7 i The stete of system changes continu ously eves t. We A wesesvoiy as wates How i and out W- illed by steam — dist buhon. Be Mixed cavth NuoUs rnodel s i. Dt contains both discacte & continuous ehenenits. Vie A wefinery with _onhoyous ly changing pzcssa¥t inside vessel and discretely ectusing g hytbebons. Guar | FOR EDUCATIONAL USE3 A) Fax ti Honing = 1) The process of dividing a cornplon __ . = system into _smalles nore runugag bla sup - systems oF componente re 1A) PastiBoniay lecade groups of unite that must be solveeh to : - _ - = - 7 ui) The = “process Can be based) on physical u unig 7 such as factors, Sepasatoy , hoack | exchanges ete. 08 ib can te based on mettematal R | consideration, te Isolate sek, of equations -Hrok can is be solved indlependenty - B) Prece dena _ adoring wo : i) Precedence ovdesing involves Aestemmi ning He sequance. Lia which 1 eq uations oe presenting ditteserda units oy Subsystems shad be oluedl: i) A gastion is_anigue bret He peraen clence. ordering I 1A nobe _ — ___¥8)_This Aypiaally involvea solving eq uatHons for upsirea en ___ | nity before preceding to These Oloonshean, | Failut 40 esta biish 9 ppropriat® precenclona ovtles may | lead to con vesson co issues oF inacusaR resully in te simulation _ a — | o) Tearing t= OO tl 1) Tearing alse Keren «5 _aelexaon or idemnbin, ig 4 — | dechnique iseel _de__solre coupled equations iteratively « La) Teasng nvelves temporally breaking soma of te clapndanies — | bethoean dqyations 67 ntlaning cortata vartab as oy poramnetes — ~~ FOR EDUCATIONAL USE SanEnSSsEEEnESEES Sura{L iV) Teasin: Lin atte pendercias behvenn varia bles ox when solvi is. employ cal lohan frese a xe Strong 6 i re - _ ey ZL ng ; | aative. system of Sayan —simultonsously ie com putationally im practiced. os — 1] sg | {| | | j ; e 4 | - + _ 7 I i] || = iT I || Sundaram FOR EDUCATIONAL USE x —__y _upsttams unite + : Mig ig, we thak Rad tr He yninet. with tHe outlet, rom unit i, the jth outlet From anit ine 1 | The plidtes anit divid ead “shew into Speaitied fraon & fos eady cukpuk shea }. cs rae 2 Sly ff et NSH | - = a 2) a =) Reactor (fixeal concerion mode)’ gk | Foe Fos eah eatin 2A i _ S conversion —"e ue detinan Limits comp. Reaates | — Ri) 4 Nenad shedwraby OCP. hin = Eo Ketel, eed. yee pod: k SEER ce Kk ptacdank — a HE th Son oy £0, Kina FOR EDUCATIONAL USE| Qs I William Otte How sheat! = (2800) I A+B —c Mis 5.9188 x10 i c fee” — || +G@ — > Pre IK, = 2: 5962 no*_ _ - | P4o —+Gq Kas 4.6283 xid5 c=) Ly Jo Medulas meda ue Grup the process equations _ wtthin each unit “and mec de thse units in se - (a) The fost task in solving this een As te identify the beams -thad breaks all of He recycle any ef te streams itu v ther loop can be used eS a ar Sheam. 3) We sehe te unite accords’ de tee Flow shat tepole stable (reactor heat Crchansen dlecarter / dlistillackion column splitters) whose tha output Sheams of each unite axe caleulated From the inputs. _ 4) We Spedty te fed) Pow rates Kand - do the proces, +he volume of the fraction “te the oplittey. S\Here ue nittaltze tre problem by gues sing the | Pourfates, fos Fe and evaltarhing a calculated value dos thie | 7 Stream, — Executing the “equa. of with, stasdiny fine te veachey we also obtain tue input stream te each unt. Whe Auwsheat convergunca pblem ee ae Rondo _ ll —_equatten : Fe = g(Fa). whee glfe) & rund imply ates enecsting —seqsena A units and veetor value of Fe ae ee I Aetemm ined 2) iFererhively by making sewed Plowshet passes, |) Sohehin ct thie Pacshaet abtte top level ¢ ait finect | - FOR EDUCATIONAL USEit ws assume that an ot He sy tput streams could be _ determined readily within eady unite. oR EDUCATIONAL USEVision: To establish the Department asa Centre of excellence for producing professionally competent and socially ‘commited Chemical Engineers. BHARATI VIDYAPEETH COLLEGE OF ENGINEERING, NAVI MUMBAI DEPARTMENT OF CHEMICAL ENG! EERING MODELING SIMULATION AND OPTMIZATIO! ASSIGNMENT: 7 (Module -05) CO: 5 B.E. CHEMICAL / SEM VIII / CBCGS 12023-2024 Q.1)_ Explain Runge-Kutta fourth order method for solving ODE k ider a reaction A > B, carried out in a constant volume batch reactor. The initial Q2) Consit condition is; at 1-0, Ca=1 mol’m’. The rate constant of the reaction is 0.18". Determine the ‘concentration of A at 6 sec. (Take step size in time as 3 sec) low, At t=0, CAo=1.8 kmol/m’, 3) The model equation fora three estr in series is given bel CAy (0)=04 Kmolim’, CA ( concentration in all the reactor at 0.1 using Runge intime as 0.1? dy) 1 dn Ve, )-|44K, aoa) G ‘ea 0.2 kmolim'CA\(0)=0.1 kmol’m’, 1-2, ki=ki-ks=0.5, find Kutta-4" order method take the step size Co Nic ,)-{LeK, en 4) Find solution ofthe following equation using fixed point iteration (direct, Substitution method) take initial guess as x/=0.8 and x2-0.8 x, =1-05exp(0.7(1-x,)-1) x, =2-0.3exp(0.5(x, +x,)) ‘Also determine the highest eigen value and number of iterations required (use 5 iterations for reference) Q.5) Using newtons method with Armijo line search, solve the following system of equations with an initial guess x° =[2,1]" f= 2x) +x; -6=0 fy= x, 42x, -3.5=0 Meson MIT prepare students othe challenges of the challenges of chemical engineering providing a high-quality education Mo: Topepar onda mie chang ee be cemeinay NM Toccata ra stents oom esponile and etiea chem engineers 0 serve the sce1S TWNOLLVONGA Hod Cae oneydo ab Fi es wap Uap P MEA mE Re dps MyM RIWD OMp Hap ve oF dope sroteen Persh poumcrspae st agheen a Pea Me fale Sp © Bahan prop vedepnl Per | apped b peels dpe wre Ab OFA OLR Tomqid apm wien ay aS SapS Canunpda sty aa des y(n a Bet r ae > R= oR Yr ee 2 °X ipphitie HE CK Guaq : yx pow “h ssaranag 'k fo WNleR He PP ap Pp PES ——Baieraip op aap Coxe] MpED pM EMF Paes mpeg FRG A Tyee 48 8 ge PR SP PP FO RUE FE WIPRMPES wage aa WERE AH ye eRe ae HE ~ pwmpp omy am (hax) voP!Pe? oA Mb Moy (HT (ae seaaeaty te f= 1 , i IRM My gees oT an . rhe vteriey ea = ate) pq ety (Reg ey = 7 saad Fes Ay PM Pe GpEMy BEEN iene v e__ eee ee eerie >ee ~ ee NSte th = 043 = 8 seg — — 42 = bthe=ses = 6 soe =: 4 iteeation s t520 seo, 4 —> Kit h.t(p Mo) = 3x(40.1Kx1) = ~o, 2% | _ I Ky = he F(4oth 5 Coo ky ns Sxferg . (evocn 23) | kK, = &x 70.1 (i-vsd) = -o.2ce : Kae het poh, + Crot Ke) = Sx O+3 0 L-o2s5 Ki = 3xfos X (t= 958))] _ ° = 7O20I71S f | Ky = ha Ff teth casks) | = 3x fro. ' x C1-0.26178)) K,= - o.2eryns | ep Coat LCs Pek. + 2h th) mel = 4 + Lf= as] : 1. 0.342%(0.255) + 2(~0.26I15) - orm __| Cay = © -140834 24 jdyea tion, $9 2% see, Ca, = 01408 —| _ i = eh #(ti ta) = sxf-or x 6-taescD) . ps 70-2222 Ek leap ah) pnt sess aaeaed) 70.2222, = FOR EDUCATIONAL USEek se hf (bah tyre) 20-3x[01 70-1939 By “nt (thy, Gy tks )e sfoites Cornered 01034)) . i it Ky = ~o-164) Tt i. ey 2 Can (it eka asta) Co + M = omer 4 | (oan) + 2(- ‘oweet) ¢2(~0: 11934) +0 iu) f L ‘ 4 ¥ i - — tp | _—_insesate small St Qivens +20, Go = bBkmel/m* | lp, (@) = 0-44 molfn® , Ca, (0) = 0-2 mel /mn? Sp (@} = 0-1 mel (m5 § Te2,k, 2 Ke =Ky 20'S heo.t j ~ “To Find! concent? at t= 0-1 see. e Fos tank 14: t22 , Croale Ca) =o Ky = hn F (te, Gyo), Cao) i E : 1 [13 - "—— K, = on ea =(4 sevens] = 0.05 t — Kr 2 hrf (toh , Crotki, Gtk mL ! K,= ox} Uw. (Lyos)o-4es} = 0.048715 _ 22 0 sf Bs (4 es)o ues] bee art stg) fizeat =(4 4.s)xo.4e4e | = 004878 z 2 m— | Kye fo i K, Ll if | | soohventoprthuerkenetreteen — i Ky = het (to th eno tks, Gy tks) | Ky = ot 18498 — (yses)o-anoe] = 0-04156 —______|__ Ca,= Co) - + k, 42k, + 2k, + ky) Sf Gerais FOR EDUCATIONAL USESay Cay0ot) = 6,44977 kmel /m3. a | Fes we Zi to, ty GS, Gators o-4 Suis on chy F (to Cy Case) \ me bux 2H ( 440.5) 6.2 = 0. J: 00244 a Kee heheh, Soyo +18, Gite) Ol xlouuee _ “5)(s210,00244)[= 0.00282 a kK, #6 taf eaane =(410:8) Guero on]: 0.002318 ' - Ks = on [io uave = (hr05) (0.24 2-200) |. 0: boi294 CTS ~ _ Kye Oot To Gus 0+ 20;29/] zo oo22ig = - ! Gf = Ores (= 0°244 © 2xK0-0023)9 +2KO'00128 1 ¢o-002819) | é _ 1 G&, = 6.20199 Kime | [m3 | ee tenk 3! +20. k, 2S i Bly =Or20499 C3204 kK, = ou xf e209. on = 4.48 a> Kp = Oh f asters = (2:1 # 9:55 367 Mi = 4525 105° seisni 4.4773 XT — Ky tony [esses = (04 +05) | = gq. 0022 xl0> a I, A, = = G+ (R45 RSs (RK GSEs + 2x9.4713-+4.0029 x/0>) Ol + U46R nF F Cg = 0+ 100094 beat mS. | Ky> o.1ffontemms -(o1ea sy \| z FOR EDUCATIONAL USEv 2 tn os exp (O11 X2)-!) = 9. Cn%) | _ hy = 2-08 ep(os(%+%2)) = %g,%) a ini Rel —Guueas® 4 =0-B 7% = PB ———— : _ 3 O.T9S 44g © ee \ 1.332038 | 0-9542 33 — = T T 7 _ 2 o- osnese | i3me0q | o- 854775 | 1. toratF 1 kd —— 3 Lo-8S4ns Loz} | 6.929195 | 1, 2018S [0.829735 eos | 0.940240 LATLAss b-Pho29b winiass | 6-9 36920 | Lind SOF 6 -BBeI2n Letraset o-931180 LAUT TEV o.RBTIV6 GetT94 |g 937585 | Leta o-331s9 4 Ss e t & _ Neo vakue of |X) = o-g3te : Mya = O11 ras I (LxS-sc5 TP [log scam—o- ascend! — _ | ox™| “T xs =x] ~ [pe e4e2a0 — 9329795 || = | jw" =o 2aza, - | [vision en value = 0.292q9 ; Le > tal fcr] 7 iteeeaT —+ - Injapem tn [o.2a29] FOR EDUCATIONAL USE a“Sem nenfensonally competent and socially 1 = | poem Ts 2 -2n —_§ we 7 oe ee - zoe aie af alt J [o- <}- - afk = - — ey v[ense] Lowa 6.011428 ea FO BST 428 =-0-OTN42 ie - ie A iene} = [ tesesss | -o- Sl [ 0-92ss72 _ l| = 1.642958 x = 6.929542 _ I — macs 1) Ftxy Ged Pa} = C125) __3) I SSS | hoe = 44-6250. a ; an =F ee ek ek _ 1 462s es OO NAAR A S96T4 1 54686 FOR EDUCATIONAL USEsmpetent and socially Vision: To establish the Department as a Centre of excellence for producing professionally competent committed Chemical Engineers / I BHARATI VIDYAPEETH COLLEGE OF ENGINEERING, NAVI MUMBA! DEPARTMENT OF CHEMICAL ENGINEERING } MODELING SIMULATION AND OPTMIZATION ASSIGNMENT: 8 (Module -06) CO: 6 B.E. CHEMICAL / SEM VIII / CBCGS / 2023-2024 Q.1) Write necessary and sufficient condition for a single variable NLP Q.2) Discuss one dimensional search method Q.3) Maximize 12x-3x'-2x° start with range (0, 2) using one dimensional search method. Also find optimal solution Q.4) Maximize 8x-3x?+x"-2x'-x® start with range (0, 1.2) using one dimensional search method, Also find optimal solution Q.5) Write necessary and sufficient condition for a multivariable NLP Q.6) What are the conditions for a multivariable NLP function has a minima or maxima Q.7) Solve the multivariable function f(Y)=yi"+yi(I-y2)+y2"-yoys, Comment whether the solution fives maxima or minima of the function Q.8) Explain gradient search procedure Q.9) Solve fx, x2) = 2xixr+2xe-x1?-2x7 using gradient search method. Start with a trial solution (0, 0). Q.10) Solve the following problems numerically by Newtons method, a. Maximize, f(x}=12x-3x*-2x° start with solution b. Minimize f(x)=1/4 x'+x?-4x start with solution Q.11) Solve f (x)= x°-2x-5=0 using Regula Falsi method with bound values (2,3) Mission ML: To prepare students for the challenges of chemical engineering by providing a high-quality education, ‘M2: To prepare students to meet the ever-changing needs ofthe chemical industry. M3: To educate and train students to become responsible and ethical chemical engineers to serve the societyat) Bre a ayen gingle “RA Suthciont ond Newssery candition os Sole stable WAP = Wi Heatntia) —— vaviqble 7 the fo anchor” df) So at Fox" js a solution —_ a poof ix esse w UNE SEEONTNS unTEEINEEES —__.—— — — Necssrry Grditions _dfct 0 ye | wher ais celuhon, FX — |i) sufReienk amdition : _ —_ | dt Fea) pO, minima 5 convex 10 | axe - | A*fox) SO | maxima con cave I ax [ Qt | One Dimensional Sea%ch Metheal $- i) Dnj Haliza Pon with | |#i) Select Initial son | “x 4A sapectvely Li) Bnd He bral soludion Select §, (dolerence) lowes and Mpper_rwanges as ae? = KH | a co 7 & Liv) Now, j tery fe te Pollooing steps unbl He Stopping ule ts sah'shied: : aa 1) Baluate dt at x=x* - | sas dE zo $0 wesak x x | s) SF dt co | so weak Sax) dx FOR EDUCATIONAL USE— QsB | Moxm! ze 12x’ 334. 2x6 with rye (0,2) Hx) = 12-12% 3 — Ig oF = —_ dfex) = 736x" - cox - _. Br omaying, dle) «co ae, “ Xse AA Fa — anu PUOS = -1e Mx) <0, FOR EDUCATIONAL USEMaximum value ot Rinction : i - a kcx*) = 12X6837 -YLo- ite 2(e: my "Qt | Maximize — Bx’ 2 yd max4 x6 mange (0,2 Lon fx) = 8 - 6 +37 - 9x2 -6 98 _ _ _ i mao Re ab _ NL ee z = FG) = _9- Ex (oe) #306) — 8008 )*~6(0-6)® | Pext)s stss4 7° New x= x’ a. xs O6the 5 OF ; = 2. PO) > ~ 4,945 Neo % 2x0 6-6 (32854 64 re 1 - || ¢: oS o-3887 I 6.15 4 0.325 nea [eas 0.32 0.1318 ~0. 688 T I 01s o-7815 0. 1681 ~0. 0831 I 0.18 o.768T 01693 |e 1873 6.1893 6: 7681 0.7164 0. 03717 | 07640 0-7687 0.1663 -0,0N4 61640 0: 7663 © 161 0.00rF | b: 165) 0: 7663, [ o-1657 = 000595 [est 01651 0.1654 00177 FOR EDUCATIONAL USE_ | ts oe 2 oes4] Manin value of funchon, Foye 9x -3xt4 x3. a4. ae 2 9X0. 7654 = 200-7654)" + C0. es4)* ~2(0.700y1 es = Tse »9266 FOR EDUCATIONAL USE- Tt dunchion is te minimize, Ss Necessary, and suthuent codihing fos Multiwrrigble NIP A). Necessary conditions + ayo. f =o em BX? oe a a a yy Gradiot at Lagoa agian § Vines = AN 3.) + Z ABS hj OP) =o i +s Wi) gO) $0 Cis 4 --m) hy") 20 (j2u2,---p) iv) Xp 20 Gizta, mm) v)__AT ge(x™)20 (ists, - md Q.6 8) The Matix at 2nd ‘Pashil denvatve ts Hessians mabix. %y a 4. Fe is a relative minimyn when a Hessian matrix is posite Aedmik of exheme point 2: Fe tea velahive mimimnyn hen HeM is nage hee Aekwide at xteme point Ls TAM & neidtey tue ne -ve ter it fs Orstlercd as saddle point: Li)Positve deBnife means ail efaen values ove 20. DV) -ve debnite means al el gen -Naluss ae

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