W.S 5
W.S 5
chemistry Pa r t 1
From Lecture 1 to Lecture 6 (till the end of benzene )
2021
2 (Exp./ May 21) The correct arrangement for the steps of preparing
alkane from alkyne is:
a oxidation - dry distillation - neutralization by NaOH - catalytic hydration
3 (Exp./ May 21) One of the following compounds has only three
isomers, which is:
a propane
b pentane
1
c hexane
d butane
a pentene
b pentane
c butene
d butane
b 6-bromo-2-ethyl-2-hexene
c 2-bromo-5-methyl-4-heptene
d 2-bromo-5-ethyl-4-pentene
6 (Exp./ May 21) (X), (Y) and (Z) are three opened-chained
hydrocarbons, if:
(X): Reacts by addition at two stages.
(Y): All its bonds are strong sigma bonds.
(Z): Decolorizes the color of alkaline potassium permanganate
solution.
Which of the following choices expresses the compounds (X), (Y)
and (Z)?
a X: Alkyne, Y: Alkane, Z: Alkene 2
b X: Alkene, Y: Alkyne, Z: Alkane
b unsaturated
c alkene
d branched alkene
A B C D
C2HBrClF3 CF4 CBr2Cl2 C5H10
a propene
b 2-butene
c ethene
d 2-methyl propene
b Compound (A) is 2-methyl-2-pentene, the addition is done to carbon atoms number 1,2
c Compound (B) is propene, the addition is done to carbon atoms number 2,3
d Compound (B) is propene, the addition is done to carbon atoms number 1,2
b CnH2n-2Br2
c CnH2nBr4
d CnH2nBr2
c 2-chloro-2-methyl propane
d 2-methyl-2-chloropropane
nd
1 5 (2 session 21) The compounds which are similar in their physical
state and their chemical properties are:
a C8H18, C18H38
b C20H42, C18H38
c C3H4, C8H16
d C3H6, C16H32
nd
1 6 (2 session 21) The number of methylene groups in 2,2-dimethyl
butane is equal to the number of methyl groups in:
a propene
b propane
c pentane
d ethyne
nd
1 8 (2 session 21) Two organic compounds (A) and (B), they are open
chain hydrocarbon compounds. The compound (A) has 3 carbon
atoms, the compound (B) has 6 carbon atoms. The compound (B)
is chemically more active than (A). The two compounds (A) and (B)
are:
a (A) is a gaseous alkane, (B) is a liquid alkene.
c 2.5 mol
d 1.5 mol
b oxidation only, but not a detecting test for the double bond existence.
c oxidation and reduction, but not a detecting test for the double bond existence.
d oxidation only and it is a detecting test for the double bond existence.
st
2 2 (1 session 21) The number of methylene groups in ethyl butene
equals:
a 3
b 2
c 4
d 1
st
2 4 (1 session 21) The following reactions occurs in suitable
conditions to obtain the compounds (A), (B), and (C) as follow:
(X) (Y)
C2H2Br2 C4H6
a The color of bromine discharges with (X) and doesn’t change with (Y).
b The color of bromine doesn’t change with both of (X) and (Y).
d The color of bromine doesn’t change with (X) and discharges with (Y).
st
2 6 (1 session 21) Which of the following expresses saturated
hydrocarbon which doesn’t contain methyl group?
a C5H12
b C6H12
c C7H8
d C7H12
st
2 7 (1 session 21) hydrogenation of the compound produced from
reduction of phenol, in suitable conditions leads to form….
a Picric acid
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b Aliphatic compound
c Vinvyl chloride
d Aromatic compound
2022
A B C D
st
2 (1 session 22) The name of the opposite compound
d 2-methyl-3-phenyl-2-butene
st
3 (1 session 22) The total number of atoms in the molecule of an
olifene equals (18), the number of its unbranched isomers is………
a 13 11
b 6
c 4
d 3
b ethyl bromide.
c 1-bromo ethanol.
d vinyl bromide
HX HX
A B C
st
6 (1 session 22) The compounds upon which the Markownikoff’s rule
could be applied are....
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a CH3CHCHCH3 , CH3CCCH3
b CH2CHCH2CH3 , CH3CCCH3
c CH3(CH2)2CH3, (CH3)2CCH2
d CH3CCCH3 , (CH3)2CHCH3
st
7 (1 session 22) The product of catalytic hydration of propyne is...
a CH3CH2CHO
b CH3COCH3
c CH3CH2CH2OH
d CH3CHOHCH3
b 5 mol
c 6 mol
d 8 mol
nd
9 (2 session 22) The following reaction shows the thermal catalytic
cracking process for the compound (Y):
Y → B + 2C3H6
If you know that the compound (B) is produced by dry distillation of
C4H9COONa salt, then the compounds (Y) and (B) are ...
a (Y): Decane, (B): Butane.
d oxidation reaction only, but does not detect the double bond.
A B C D
The correct choice which represents the substances (A), (B), (C)
and (D) is
a (A): Aromatic, (B): Alkyne, (C): Alkene, (D): Alkane.
A B C D 14
a A
b B
c C
d D
nd
1 4 (2 session 22) all of the following about cyclic hexane are correct,
except ….
a Saturated cyclic compound
c Stable alkane
a ortho-nitrobenzaldehyde
b para-nitrobenzaldehyde
c meta-nitrobenzaldehyde
Benzaldhyde
d Mixture of ortho and para-nitrobenzaldehyde
15
2023
1 (Exp./ March 23) The number of isomerism of alkyne has three
carbon atoms, bromine atom and chlorine atom equals
a 5
b 2
c 4
d 3
2 (Exp./ March 23) From the following reactions that occur at suitable
conditions:
Excess HCl
C2H2 C
b A>C>B
c A>B>C
d B>C>A
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C6H5
a 4,5-dimethyl decane.
b 2-phenyl-3-methyl-2-hexene.
CH3_C=C_CH3
c 3-methyl 2-phenyl-2-hexene. C3H7
d 2-propyl-3-phenyI butane.
b 10 moles
c 4 moles
d 6 moles
Reduction (1)
CnHnO CnHn (A)CnH2n
d ethene with Cl
2
b C2H3Br , C2H5Br
c C H Br , C H Br
2 2 2 2 4 2
d C H Br , C H Br
2 3 2 4 2
18
10
D
8
C
6
A
4
B
2
Catalytic Hydrogenation
Heptane X Y
reforming
H H H H H H
_C_C_C_C_C_C_
a cyclo propane.
b cyclo butane.
c propane.
d Propene.
1 2 (1st session 23) The following steps take place to convert compound
its general formula CnH2n+2 to compound its general formula is CnH2n,
except
a strong heat then quick cooling —polymerization— hydrogenation.
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b A<B<C
c B<C<A
d C<A<B
HX AlCl3 anhydrous
C3H6 (A) (B)
+C6H6
21
2024
st
1 (1 session 24) From the following reaction:
CaO /
(CH3)2CHCOONa + NaOH X + Na2CO3
c ethane.
d butane.
st
2 (1 session 24) From the following organic compounds:
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b 3-ethyl-1-pentyne.
c 3-methyl pentane.
d 3-ethyl-1-pentene.
st
4 (1 session 24) Three openchain hydrocarbons (A), (B) and (C),
on burning 1 mol of each of them in excess amount of oxygen :
(A): Give number of moles of H2O(V) < number of moles of CO2(g)
(B): Give number of moles of H2O(V) = number of moles of CO2(g)
(C): Give number of moles of H2O(V) > number of moles of CO2(g)
Which of the following choices is correct ?
a (C): Cyclopropane, (B): Reacts by substitution.
st
5 (1 session 24) The opposite compound:
(CH3)2C(C6H5)CH2CH(CH3)2
Which of the following choices represent the IUPAC name for the
previous compound?
23
a 2,4-dimethyl-4-phenyl pentane.
b 1,1,3,3-tetramethyl-1-phenyl propane.
c 2,4-dimethyl-2-phenyl pentane.
d 2,4,4-trimethyl decane.
nd
7 (2 session 24) (A), (B) and (C) are three hydrocarbons, by adding
HBr to each of them separately:
(A): gives 1,1-dibromo ethane.
(B): gives bromo ethane.
(C): doesn’t react.
Which of the following choices represents these compounds?
a (B): ethene, (C): ethyne.
c Sodium hexanoate.
d Sodium butanoate.
nd
1 0 (2 session 24) The following table represents molecular formula of
three hydrocarbons (A), (B) and (C):
A B C D
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Hydrolysis
(X) Propyl hydrogen sulphate
Process W Thermal
decomposition
If you know that each of (X), (Y) and (Z) are organic compounds,
deduce each of the following?
1- IUPAC name of the produced compound from adding HBr to compound (Z)
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3-Name of process (W) if you know that, the compound (Y) makes effervescence with
sodium carbonate
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4- Molecular formula of compound (Y)
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