INDIAN SCHOOL AL WADI AL KABIR

Class: XI Department: SCIENCE 2023 – 24

Mole concept Date of submission:
SUBJECT: CHEMISTRY 30.04.2023

Worksheet No: 01 CHAPTER / UNIT: SOME BASIC CONCEPTS OF Note:

WITH ANSWERS CHEMISTRY A4 FILE FORMAT

NAME OF THE STUDENT CLASS & SEC: ROLL NO.

Multiple Choice Questions (1 M)

1. Which of the following reactions is not correct according to the law of conservation of mass?
a. 2Mg(s) + O2(g) → 2MgO(s)
b. C3H8(g) + O2(g) → CO2(g) + H2O(g)
c. P4(s) + 5O2(g) → P4O10(s)
d. CH4(g) + 2O2(g) → CO2(g) + 2H2O(g)

2. Which of the following statements indicates that the law of multiple proportions is being followed?
a. Sample of water taken from any source will always have hydrogen and oxygen in the ratio 2:1.
b. Carbon forms two oxides namely CO2 and CO, where masses of oxygen that combine with a fixed mass
of carbon are in the simple ratio 2:1.
c. A 10 g ribbon of Mg burns in oxygen and the entire magnesium converts to its oxide.
d. When two elements combine with a fixed mass of the third element, the ratio in which they do so is
a simple whole number ratio.

3. Match the items in Columns I and II.

Column I Column II
Physical quantity Unit

i. Molarity a. gml-1

ii. Mole fraction b. Mol

iii. Mole c. molkg-1

iv. Molality d. Unitless

e. molL-1

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 a. i – a , ii – e , iii – b , iv - c
b. i – b , ii – e , iii – d , iv – c
c. i – e , ii – d , iii – b , iv – c
d. i – e , ii – a , iii – b , iv – c

4. One atomic mass unit stands for

a. One C12 atom
b. One H-atom
c. 1/12th of the mass of H-atom
d. 1/12th of the mass of C12-atom
.
5. Under similar conditions, the ratio by volumes of gaseous reactants and gaseous products is __________

6. Which of the following compounds has the same empirical formula as that of glucose?
a. CH3CHO b. CH3COOH
c. CH3OH d. C2H6

7. One mole of NaCl contains 6.022 ×1023

a. Ions
b. Atoms
c. Molecules
d. Formula Unit

8. The modern atomic weight scale is based on

a. 12C b. 16O
c. 1H d. 13C

Assertion Reason type questions

a. If both Assertion and Reason are correct and Reason is the correct explanation of Assertion.
b. If both Assertion and Reason are correct but Reason is not the correct explanation of Assertion.
c. If Assertion is correct and Reason is wrong.
d. If Assertion is wrong and Reason is correct.

9. Assertion: 1 g atom of Sulphur contains Avogadro number of molecules.

Reason: Atomicity of S is eight.

10. Assertion: The formula of Calcium carbide is CaC2.

Reason: 1 mol of CaC2 contains two moles of C.

Very Short answer type (2 M)

11. State:
a. Law of definite proportion
b. Law of Multiple proportions

12. Prove that the sum of all mole fractions of a solution is unity?
13. Write the empirical formula of the following:

CO, Na2CO3, KCl, H3PO4, Fe2O3

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14. An organic compound contains 144g of carbon and 12 g of hydrogen. If molar mass of this compound is 78
gmol-1, calculate:
i. Empirical formula
ii. Molecular formula
15. How many moles of ethane are required to produce 66 g CO2 after combustion?
16. A solution is prepared by dissolving 150g of NaCl in 900 g of water. Calculate the mole fraction of each
component.

17. How many moles of N2 are required to produce 85g of NH3? Calculate its mass.
Short answer type (3 M)

18. What do you mean by limiting reagent?

400 g of N2 and 150 g of H2 are mixed together to form NH3. Identify the limiting reagent and calculate the
amount of NH3 produced.

19. Explain the following (Answer any three)

a. Mole fraction
b. Molarity
c. Molality
d. Atomic mass

20. The density of the 2M solution of NaCl is 1.25 g ml-1. Calculate molality of the solution.
21. Identify the limiting reagent if 0.6g of magnesium is added to a 100 ml solution of 0.4M hydrochloric acid.
Also, Calculate the mass of hydrogen gas produced.
(Mg = 24u)

22. Caffeine has the following percent composition: carbon 49.48%, hydrogen 5.19%, oxygen 16.48% and
nitrogen 28.85%. Its molecular weight is 194.19 g/mol. What is its molecular formula?

Passage based questions (4 M)

23.
Passage based question
One mole is the amount of a substance that contains as many particles or entities as there are atoms in exactly
12 g (or 0.012 kg) of the 12C isotope

This number of entities in 1 mol is so important that it is given a separate name and symbol. It is known as the
‘Avogadro constant’, or Avogadro number denoted by NA in honour of Amedeo Avogadro

Information regarding the number of particles as well as the percentage of a particular element present in a
compound is essential.

Mass percent of elements in a compound provides a check whether the given sample contains the same
percentage of elements as present in a pure sample. In other words, one can check the purity of a given sample
by analysing this data.

a. Calculate the number of moles present in 44 g of CO2.

b. Define the term molar mass.
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c. Calculate the no of Oxygen atoms in 100 g of CaCO3.

OR
c. Calculate the mass percentage of all the elements in Glucose.

Long answer type (5 M)

24. a. Commercially available con HCl is in an aqueous solution containing 40% HCl gas by mass. If its density
is 1.2 gcm-3, calculate the molarity of HCl solution.

b. Empirical formula of a gaseous compound is CH2Cl. 0.12 g of the compound occupies a volume of
37.20cc at 105 degree centigrade and 760 mm Hg. Find the molecular formula of the compound.

c. State Avogadro law.

Answers

1 b. C3H8(g) + O2(g) → CO2(g) + H2O(g)

2 b. Carbon forms two oxides namely CO2 and CO, where masses of oxygen that combine with a
fixed mass
of carbon are in the simple ratio 2:1.

3 c. i – e , ii – d , iii – b , iv – c

4 d. 1/12th of the mass of C12-atom

5 the simple whole number ratio
6 b. CH3COOH
7 d. Formula Unit

8 a
9 d Assertion is wrong and Reason is correct

10 b. Both Assertion and Reason are correct but Reason is not the correct explanation of Assertion.

11 a. A given compound always contains exactly the same proportion of elements by weight.
b. If two elements can combine to form more than one compound, the masses of one element
that
combine with a fixed mass of the other element, are in the ratio of small whole numbers.

12

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13 CO – CO
Na2CO3 - Na2CO3
KCl – KCl
H3PO4 - H3PO4
Fe2O3 - Fe2O3

14

Element Mass Moles Ratio Simplest ratio

C 144 12 1 1
H 12 12 1 1

Empirical formula = CH
Empirical formula mass = 13
n = 78/13 = 6
Molecular formula = C6H6
15 C2H6 + 7/2 O2 → 2CO2 + 3H2O

No: of moles of CO2 = 66/44 = 1.5 moles

C2H6 CO2
As per eqn 1 mol 2 mol
As per qsn ? 1.5 mol

Ans: 0.75 moles of ethane.

16 n NaCl = 150 / 58.5 = 2.56

n H2O = 900 / 18 = 50

χ NaCl = 2.56 / 2.56 + 50 = 0.0487

χ H2O = 50 / 52.56 = 0.951

17 N2 + 3H2 → 2NH3

No: of moles of NH3 = 85/17 = 5 moles

N2 NH3

As per eqn, 1 mol 2 mol

As per qsn, ? 5 moles

Therefore no: of moles of N2 = 2.5 moles

18 Limiting reagent: The reactant, which gets consumed first, limits the amount of product formed
and is,
therefore, called the limiting reagent.

N2 + 3H2 → 2NH3

No: of moles of N2 = 400/ 28 = 14.28 mol

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 No: of moles of H2 = 150 / 2 = 75 mol

N2 H2
As per eqn. 1 3
As per qsn, 14.28 ?

No: of moles of H2 required for 14.28 moles of N2 = 42.84 mol

Therefore, H2 is excess reagent i.e N2 is limiting reagent.

N2 NH3
As per eqn. 1 2
As per qsn, 14.28 ?

Therefore no: of moles of NH3 = 28.56 mol

Mass of NH3 = 28.56 × 17 = 485.52 g

19 a. Mole fraction : It is the ratio of number of moles of a particular component to the total number
of moles
of the solution.

b. Molarity : It is defined as the number of moles of the solute in 1 litre of the solution.

c. Molality: It is defined as the number of moles of solute present in 1 kg of solvent.

20 Molarity = 2M
Assume volume of solution = 1 L
Therefore, No of moles of NaCl = 2 mol

Mass of NaCl = 2 × 58.5 = 117 g

Mass of 1 L of solution = 1.25 gml-1× 1000g = 1250 g.

(Since density = 1.25 gml-1 and density = mass / volume)

Mass of water = 1250 g -117 g

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 = 1133 g
Molality = No: of moles of solute/ Mass of solvent(kg)
= 2/1.133
= 1.765 molkg-1

21 Moles of Mg = 0.6/24 = 0.025 mol

Moles of HCl = Molarity × Volume
= 0.4 M× 0.1
= 0.04 mol

Mg + 2HCl → MgCl2 + H2

Mg HCl
As per eqn, 1 2
As per qsn, 0.025 ?

No: of moles of HCl = 0.05 mol

HCl is the limiting reagent.

HCl H2
As per eqn, 2 1
As per qsn, 0.04 ?

Moles of H2 = 0.02 mol

Mass of H2 = 0.02 × 2
= 0.04 g

22 Moles of C = 49.48/12 = 4.12 mol

Moles of H = 5.19/1 = 5.19 mol
Moles of O = 16.48/16 = 1.03 mol
Moles of N = 28.85/14 = 2.06 mol

Empirical formula = C4H5N2O

Molecular formula = C8H10N4O2

23 a. 1 mole
b. The mass of one mole of a substance expressed in grams.
c. No of moles = 1mol
No of molecules = 6.022 × 1023
No of O atoms = 3 × 6.022 × 1023 = 18.066 × 1023 atoms
OR
c. Molar mass of Glucose = 180 g

Mass% of C = 12 × 6 / 180 ×100 = 40 %

Mass% of H = 1 × 12 / 180 ×100 = 6.66 %
Mass% of O = 16 × 6 / 180 ×100 = 53.3 %

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24 a. Total mass of solution = 100 g
Mass of HCl = 40g

Moles of HCl = 40/36.5 = 1.09 mol

Density of solution = m/v
1.2 = 100/ V
Vol of solution = 83.3 ml

Molarity = moles of HCl / Vol of solution in L

= 1.09/0.0833
= 13.08 M

b.
pV = nRT
p = 760 mm Hg = 1 atm
V = 37.2 cm3 = 0.0372 L
R = 0.082 atm LK-1mol-1
T = 378 K

n = 0.0012 mol
n = m / MM
0.0012 = 0.12 / MM
Molar mass = 100 g mol-1

Molar mass / Empirical formula mass = 100/ 49.5 = 2

Molecular formula = C2H4Cl2

c. Equal volumes of all gases at the same temperature and pressure should contain equal
number of molecules.

Prepared by: Checked by:

Ms. Jasmin Joseph HOD – SCIENCE & FRENCH