MOLE CONCEPT-MPS

1. Ans: (b) 5. Ans: (a)

Anything which occupies space and has mass can 1

3A + 2B → C + D
2
be defined as matter. Matter is composed of tiny
12
particles known as atoms. Limiting reagent for A = =4
3
2. Ans: (b)
12
B= =6
one of oxygen atoms in Na2SO4.10H20 = 14 2

Moles = given mass/molar mass = 32.2/322 So, A is the L.R.

= 0.1 moles 1
3A → D
2
So, no. of moles of oxygen atoms = 0.1×14
1
3→
= 1.4 2

Moles = mass/molar mass 1/ 2 1

12 → × 12 = × 12
3 6
1.4 = mass/16
= 2 moles of D
Mass = 1.4×16
mass
= 22.4 g moles =
molar mass
3. Ans: (d)
60
2=
16 g of oxygen and 1.0 g of H2 have same no. of M.M

moles so It also have same no. of molecules. M.M = 30

4. Ans: (c) 6. Ans: (b)

Cu2+ + H2S → CuS + 2H+ Atomic mass of C = 12

1 mole of Cu2+ reacts with 1 mole of H2S So, atomic weight of x = 2.96 × 12

Molar mass of Cu+2 = 63.5 g mol–1 Given, 1 mole of element x has mass 0.444

Molar mass of H2S = 34 g times the mass of 1 mole of element of y.

63.5 g of Cu+2 → 1 mol of H2S So atomic weight of x = 0.444 × A.wt. of y

→ 34 g of H2S Atomic weight of x

So atomic weight of y =
0.444
The min quantity of H2S needed to precipitate
2.96 12
63.5 g of Cu+2 will be 34 g = = 80 amu
0.444
7. Ans: (a) = 0.0066 moles (O2 is limiting reagent)

M .M C6 H12O6 = 180 g/mol ∴ Mass of Mg left in excess

C6H12O6 + 6O2 → 6CO2 + 6H2O = 0.0066 × 24 = 0.16 g

(44 × 6)g CO2 → 180g Glucose 10. Ans: (a)

180 11. Ans: (c)

44g CO2 → g Glucose
6
12. Ans: (d)
= 30g Glucose
13. Ans: (b)
8. Ans: (c)
14. Ans: (a)
AgNO3 + NaCl → AgCl + NaNO3
15. Ans: (a)
3.4
No. of moles of AgNO3 = = 0.02 16. Ans: (a)
170
10% solution of NaCl means 10 g NaCl in 100
5.85
No. of moles of NaCl = = 0.1
58.5 grams of solution.

Limiting ragent = AgNO3 17. Ans: (b)

1 mole of AgNO3 produces 1 mole of AgCl

∴ 0.02 mole of AgNO3 will produce 0.02 mole of 18. Ans: (a)

AgCl 19. Ans: (d)

Weight of AgCl produced 20. Ans: (b)

= 0.02 × 143.5 = 2.87 g 21. Ans: (c)

9. Ans: (a) 22. Ans: (b)

1 23. Ans: (c) After a chemical reaction, the total mass

n Mg = = 0.0416 moles
24
of reactants and products do not change as law of
0.56
n O2 = = 0.0175 moles conservation of mass.
32
24. Ans: (c) Law of multiple proportions states that
The balanced equation is
if two elements form more than one compound
1
Mg + O2 → MgO
2 between them, then the ratios of the masses of the

Initial 0.0416 moles 0.0175 moles O second element which combines with the fixed

Final (0.0416 – 2 × 0.0175) 0 2 × 0.0175

 mass of the first element will always be a ratio of volume
moles =
22.4
small whole numbers
Equal volume of N2 and H2.
On fixing the mass of oxygen, X reacts with
1
oxygen in different proportions thus explaining L.R. for N2 =
22.4  1
law of multiple proportions.
1
L.R. for H2 =
25. Ans: (a) 22.4  3

Modern atomic weight scale is based on C12. The So, H2 is L.R.

standard unit for expressing the mass of atom is

amu (atomic mass unit). It is equal to 1/12 of the 33. Ans: (b)

mass of an atom of carbon-12. 34. Ans: (d)

26. Ans: (a) 35. Ans: (a) Urea NH2CONH2

78.4 gm Se will be present in 100/0.5 × 78.4 = 1.568 × Molar Mass = 60 g/mol
104
2 14 100
N= = 46.6
60
5.0 10−5 106
27. Ans: (a) ppm =
100 So, the percentage of nitrogen in urea is 46.6

= 50/100

= 0.5 36. Ans: (a) Empirical formula of the compound is

28. Ans: (c) CH2O, its molecular formula,

29. Ans: (d) ⇨ (CH2O)n = CnH2nOn

30. Ans: (b) I give 0.0835 moles of the compound contain 1 g

31. Ans: (b) The limiting reactant (or limiting of H, it means (2n) × (0.0835) moles of H in the

reagent) is the reactant that gets consumed first in compound contains 1 g of H.

a chemical reaction. Therefore,

32. Ans: (a) 2n × (0.0835) = 1

N2 + 3H2 → 2NH3 2n = 12

given moles The molecular formula of CH2O is C6H12O6

Limiting Reagent =
stoichiometric co-efficient
37. Ans: (c) v volume of solute
%= 100
v volume of solution
Molar mass of Carbon = 12.
15 15
Molar mass of Hydrogen = 1. = 100 = 100 = 20%
(15 + 60) 75
Molar Mass of Oxygen = 16.
40. Ans: (d) No. of moles of NaCl = 3
Mass of CH2O = 12 + 2(1) + 16 = 30.
1000
No. of moles of H2O = = 55.55
Molecular weight of compound = 180. 18

So, the molecular weight is 180/30 = 6. 55.55

X H2O =
55.55 + 3
Molecular formula of compound is C6H12O6.
= 0.95

41. Ans: (c) Let the mass of NaOH added by x

.
x given mass
38. Ans: (a) Moles = =
40 molar mass

% CH3OH by mass = 60%

Moles of solute 1000
Molarity =
Mass of CH3OH ÷ mass of solution Volume (ml)

60 x 1000
= 2=
100 40  250

Let, the mass of the solution be 100 gm  x = 20 gm

Mass of CH3OH = 60 gm 42. Ans: (c) 98 (w/v) aq. H2SO4 means 98 g of H2SO4

Mass of H2O = 40 gm is present in 100 mL of water.

60 Wt. of H2SO4 = 98 g
Moles of CH3OH = =
32
Volume of solution = 100 mL
40
Moles of H2O = = Molecular wt. of H2SO4 = 98 g
18
98
% mole of CH3OH = (moles of CH3OH ÷ total ∴ No. of moles of H2SO4 = = 1 mol
98
moles) × 100
wt.
no. of moles =
 60  60 40   mol. wt.
=    +   100 = 45.8%
 32  32 18  
no. of moles of solute
Molarity = 1000
% mole of H2O = 100 – 45.8 = 54.2% Volume of solution (in mL)

39. Ans: (a) ∴ Molarity of the given solution = 11000 = 10 M

100
 46. Ans: (c) As B is a limiting reagent so, it should

43. Ans: (a) be present in limited amount and its amount

Mass % of X = should be less than the amount of A.

Mass of X
× 100
(Mass of X + Mass of Y)
47. Ans: (d)

5 48. Ans: (c)

∴ mass % of X = × 100 = 21.74%
5 + 18
49. Ans: (b)
−3
44. Ans: (d) V1 = 2.5 10 dm 3

50. Ans: (a)

N1 = 2  M1 = 2  0.2 = 0.4
51. Ans: (b)
N1V1 = N 2V2
moles = Given mass/molar mass

0.4  2.5 10−3 = N 2  0.5 = 56 g/ 28g

N2 = 0.002 N = 2 moles of N2 molecules

2 moles of nitrogen gas molecules contain 4 mol

45. Ans: (d)
of nitrogen atom.