26-05-2025

2331CJA101031250002 JA

PART-A-PHYSICS

SECTION-I(i)

1) Which of the following is dimensionally correct for "pressure" :

(A) Momentum per unit volume

(B) Momentum per unit volume and per unit energy
(C) Energy per unit volume
(D) Force per unit length

2) If the mass, time and work are taken as fundamental physical quantities then dimensional formula
of length will be

(A) M1/2 T1 W–1/2

(B) M–1/2 T1 W1/2
(C) M–1 T2 W1/2
(D) None of these

3) A projectile passes two points A and B at same height after 3 s and 6 s of its projection. Horizontal
separation between the points A and B is 150 m. The horizontal range is closest to:-

(A) 180 m
(B) 240 m
(C) 350 m
(D) 450 m

4) Displacement time graph is given it's corresponding velocity time graph will be :-
(A)

(B)

(C)

(D)

0
5) A stone is thrown vertically upward with an initial velocity v . The distance travelled in time is

(A)

(B)
(C)

(D)

SECTION-I(ii)

1) A particle is projected with a velocity of 20m/s in horizontal direction from top of a tower of height
20m. [Take g = 10 m/s2]

(A) particle will strike the ground at time = 2 sec

(B) horizontal displacement of particle will be 40m.
(C) average speed of particle is 20m/s during flight
(D) magnitude of average velocity of particle is 20m/s during flight

2) A particle is projected with speed 40 m/s such that at maximum height its speed 20 m/s, then :

(A) Angle of projection is 60°

(B) Time of flight is sec.
(C) Range is m.
(D) Maximum height is 60 m.

3) A particle leaves the origin with an initial velocity m/s and a constant acceleration

m/s2. Its velocity and position vector when it reaches its maximum
x–coordinate are

(A) m/s
(B) m/s

(C)
m

(D)
m

4) Two shells are fired from a cannon with a speed u each, at angles of α and β respectively to the
horizontal. The time interval between the shots is T. They collide in mid-air after time t from the first
shot. Which of the following conditions must be satisfied?

(A) α > β
(B) tcos α = (t – T) cos β
(C) (t – T) cos α = tcos β
(D) (usinα)t –1/2 gt2 = (usin β) (t – T) – 1/2 g (t – T)2

SECTION-I(iii)

Common Content for Question No. 1 to 2

According to Newton's law of gravitation, force between two particles of masses m1 & m2 separated

by distance r is given by , here G is universal gravitation constant. Now suppose we

take density (ρ), distance (L) and universal gravitation constant (G) as fundamental physical
quantities then:

1)

Dimensional formula of pressure is :

(A) ρ2L2G
(B) ρL2G
(C) ρLG
(D) Can not be determined

2)

Dimensional formula of velocity is :

(A)

(B)

(C)

(D)

Common Content for Question No. 3 to 4

A sprinkler has a shape of hemisphere, which has small holes drilled into the spherical part of its
surface. From these small holes, water flows out with velocity v. Near the sprinkler, the water flow is
distributed evenly over all the directions of the upper half-space. The sprinkler is installed at the
ground level so that its axis is vertical. In what follows, the air resistance can be neglected, and the

dimensions of the sprinkler can be assumed to be very small.

3)

A vessel of negligible dimension at a distance of from sprinkler is continuously receiving the

water. After closing the sprinkler, find out time interval for which vessel receives water with lesser
rate, before the water collection completely stops:

(A)
(B)

(C)

(D)

4)

Find the surface area of the ground watered by the sprinkler :

(A)

(B)

(C)

(D)

SECTION-III

1) At t=0 an object is released from rest at the top of a tall building. At the time t0 a second object is
dropped from the same point. After time t (t > t0) from starting the separation between objects
become ℓ. There is value of to such that the given separation ℓ is achieved in the earliest possible
value of t. Then find the value of t0 (in seconds) if ℓ = 45 m, g = 10 m/s2)

2) The graph illustrates motion of a bucket being lowered into a well from the top at the instant t=0,
down to the water level, filled with water and drawn up again. Here 'x' is the depth. Find the
average speed of the bucket in m/s during whole operation.

3) A particle ia moving from A to D as shown in figure, then average speed from A to D is (in m/sec):
4)

In a new system of unit, unit of mass is 4kg, unit of length is 2m and unit of time is sec. How
much Newton is equal to 1 unit of force in this new system.

SECTION-IV

1) Column-I contains two vectors whose length represents it's magnitude and arrow represents it's
direction. Column-II contains some properties of vector, match them correctly.

Column-I Column-II

(A) (P) Parallel vectors

(B) (Q) Antiparallel vectors

(C) (R) Equal in magnitude

Unequal in
(D) (S)
magnitude

Neither parallel
(T)
nor antiparallel

PART-B-CHEMISTRY

SECTION-I(i)

1) An alpha particle is projected towards a nucleus containing x number of protons inside it and
closest distance of approach is R. If α-particle is projected towards another nucleus, which contains
50% more number of protons, then what percentage increment in velocity of α-particle is required to
get same closest distance of approach?

(A) 20%
(B) 22.5%
(C) 18%
(D) 24.5%
2) A certain oxide of iron contains 2.5 gm oxygen for every 7 gm of iron. If it is regarded as a
mixture of FeO and Fe2O3 in the weight ratio of x : y ; find x : y.

(A) 9 : 20
(B) 9 : 40
(C) 9 : 10
(D) 2 : 1

3) How many moles of e– weigh one Kg

(A) 6.023 ×1023

(B)

(C)

(D)

4) The conversion of oxygen to ozone 3O2 → 2O3 occurs to the extent of 15% only. The mass of ozone
that can be prepared from 67.2 L of oxygen at S.T.P. will be -

(A) 14.4 gm
(B) 96 gm
(C) 640 gm
(D) 64 gm

5) The 1st, 2nd and the 3rd ionization enthalpies I1, I2 and I3, of four atoms with atomic numbers n, n +
1, n + 2 and n + 3, where n < 10, are tabulated below. What is the value of n?

(A) 6
(B) 7
(C) 8
(D) 9

SECTION-I(ii)

1)

Choose the correct relation on the basis of Bohr's theory -

(A)
velocity of electron ∝

(B)
frequency of revolution ∝
(C) radius of orbit ∝ n2Z

(D)
force on electron ∝

2)

Same mass of glucose (C6H12O6) and acetic acid (CH3COOH) contain :

(A) Same number of carbon atoms

(B) Same number of Hydrogen atoms
(C) Same number of oxygen atoms
(D) All of above

3) When a equimolar mixture of Cu2S and CuS is titrated with Ba(MnO4)2 in acidic medium, the find
products contain Cu2+, SO2 and Mn2+. If the Mol. mass of Cu2S, CuS and Ba(MnO4)2 are M1 M2 and M3
respectively then :

(A)
Eq. mass of Cu2S is

(B)
Eq. mass of CuS is

(C)
Eq. mass of Ba(MnO4)2 is
(D) Cu2S and CuS both have same equivalents in mixture.

4) Consider the following ionization steps :

M(g) → M+(g) + e– ; ΔH = 100 eV
M(g) → M2+(g) + 2e– ; ΔH = 250 eV
select correct statement(s) :

(A) I.E.1 of M(g) is 100 eV

+
(B) I.E.1 of M (g) is 150 eV
(C) I.E.2 of M(g) is 250 eV
(D) I.E.2 of M (g) is 150 eV

SECTION-I(iii)

Common Content for Question No. 1 to 2

Rutherford model : The approximate size of the nucleus can be
calculated by using energy conservation theorem in Rutherford’s α-scattering experiment. If an α-
particle is projected from infinity with speed v, towards the nucleus having z protons then the α-
particle which is reflected back or which is deflected by 180° must have approach closest to the
nucleus. It can be approximated that α-particle collides with the nucleus and gets back. Now if we
apply the energy conservation initial and collision point then :
(Total Energy)initial = (Total Energy)final
(K.E.)i + (P.E.)i = (K.E.)f + (P.E.)f
(P.E.)i = 0, since P.E. of two charge system separated by infinite distance is zero, finally the particle
stops and then starts coming back.

Thus the closest distance of approach can be calculated using above equation. The nucleus is so
small a particle that we can’t define a sharp boundary for it. Experiments show that the average
radius R of a nucleus may be written as
R = R0(A)1/3
where R0 = 1.2 × 10–15 m
A – atomic mass number
R – radius of nucleus

1) If the diameter of two different nuclei are in the ratio 1:2 then their mass number are in the ratio
:

(A) 1 : 2
(B) 1 : 2
(C) 1 : 8
(D) 1 : 4

2) Closest distance of approach of a particular nucleus is calculated by the projection of α-particle

from infinity at a particular speed let this distance is the true distance. If the radius calculation for
the same nucleus is made by, α-particle with half of the earlier speed then the percentage error
involved in the distance calculation is

(A) 75%
(B) 100%
(C) 300%
(D) 400%

Common Content for Question No. 3 to 4

Comprehension-3
NaBr, used to produce AgBr for use in photography can be self prepared as follows : Fe + Br2 →
FeBr2 .....(i) FeBr2 + Br2 → Fe3Br8 .....(ii) (not
balanced)
Fe3Br8 + Na2CO3 → NaBr + CO2 + Fe3O4 .....(iii) (not balanced)

3) Mass of iron required to produce 2.06 × 103 kg . of NaBr.

(A) 420 g
(B) 420 kg
(C) 4.2 × 105 kg
(D) 4.2 × 108 g

4) If yield of (iii) reaction is 90% then mole of CO2 formed when 2.06 × 103 g NaBr is formed.

(A) 20
(B) 10
(C) 40
(D) none

SECTION-III

1) Number of orbitals among the following which have two or more radial nodes are-
3s , 4p, 4d, 6f, 7g, 5s, 8i

2) 3.8 gm of a tribasic carboxylic acid derivative of a saturated hydrocarbon required 100 ml of 0.6M
NaOH solution to reach equivalence point. Calculate molar mass of tribasic carboxylic acid
derivative of saturated hydrocarbon.
Fill your answer as sum of digits (excluding decimal places) till you get the single digit
answer.

3) 148 gm of a sample of Ca(OH)2 dissolved in 250 ml, 0.6 M HCl solution. The excess of HCl was
titrated with 0.3 M NaOH solution of which 100 ml was used. If the percentage purity of sample is
x%, report x.

4) Find the number of transition element in the following

Zn, Cr, Fe, Pd, Cu

SECTION-IV

1)

Column-I (n–factor
Column-I (Reaction)
of underline)

(A) When converted into Bi5+ and S (P) 18

(B) When reduced into Cr

3+
in acidic medium (Q) 11

(C) When 2 3
converted into Fe O and SO
2
(R) 2
 (D) When converted into MnO42– (S) 10
and NO

PART-C-MATHEMATICS

SECTION-I(i)

1) Sum of n terms of 1+ (1+ x) + (1+ x + x2) + (1+ x + x2 + x3) + .... is-

(A)

(B)

(C)

(D) None of these

2) Let Vn+1 = 3Vn – 2Vn–1 ∀ n ∈ N and V0 = 2, V1 = 3, then value of V6 is :-

(A) 65
(B) 33
(C) 17
(D) 36

3) The sum is in the form

and
Then x is

(A) 25
(B) 19
(C) 20
(D) 24

4) Sum of Integral values of n for which is an integer is :

(A) – 8
(B) – 11
(C) 4
(D) 7

5) The number of real roots of the equation, e4x + e3x – 4e2x + ex + 1 = 0 is :

(A) 4
(B) 2
(C) 3
(D) 1

SECTION-I(ii)

1) Let a1, a2, a3, .....an are in A.P., and a3, a5, a8, b1, b2, b3,....bn are in G.P. and a9 = 40, then

(A)

(B)

(C)

(D)

2) For 0 < x < 1, then

(A)

(B)

(C)

(D) F(x) + f (1−x) 2

3) Let a, b and c are non zero real numbers such that 3(a2 + b2 + c2 + 1) = 2(a + b + c + ab + bc +
ca), then :

(A) a, b and c are in AP

(B) a, b and c are in GP
(C) a, b and c are in HP
(D) a2, b2 and c2 are in GP

4) Let Sn = . Identify which of the following statement(s) is(are) correct?

(A)
If S10 = , then (p + q) is equal to 12.
(B)
If S10 = , then (p + q) is equal to 21.

(C)
=

(D)
=

SECTION-I(iii)

Common Content for Question No. 1 to 2

From first 'n' natural numbers, 2 consecutive numbers are removed the arithmetic mean of the

remaining number is then answer the following

1) Geometric mean of removed numbers is p, then

(A) p ∈ (1, 7)
(B) p ∈ (10, 12)
(C) p ∈ (7, 8)
(D) p ∈ (8, 10)

2) n is divisible by

(A) 15
(B) 25
(C) 3
(D) 7

Common Content for Question No. 3 to 4

Let such that {x}, [x], x are in G.P.

3) The value of x is

(A)

(B)

(C)

(D) none of these

4) Common ratio of this G.P. is

(A)
(B)

(C)

(D)

SECTION-III

1)

If x,y,z are positive real numbers, then the minimum value of is equal to

2) Given the positive integers a,b,c are in increasing geometric progression in that order with
positive integral common ratio also log6a + log6b + log6c = 6 and 2(b – a) is the square of an integer.
If (a + b + c) takes its minimum value, then digit at the unit place of (a + b + c) is

3)

Let then the value of is

4) If , then the value of 2logab :-

SECTION-IV

1) Match the column :

List-I List-II

If Σn = 210, then Σn2 is divisible by the greatest

(A) (P) 16
prime number which is greater than

Between 4 and 2916 is inserted odd number (2n +

(B) 1) G.M.'s. Then the (n + 1)th G.M. is divisible by the (Q) 10
greatest odd integer which is less than

In a certain progression, four consecutive terms are 40,

(C) 30, 24, 20. Then the integral part of the next term of the (R) 34
progression is more than

(D) where H.C.F. (a, b) = (S) 46

1, then a – b is less than

(T) 30
 ANSWER KEYS

PART-A-PHYSICS

SECTION-I(i)

Q. 1 2 3 4 5
A. C B D A B

SECTION-I(ii)

Q. 6 7 8 9
A. A,B A,B,C,D B,C A,B,D

SECTION-I(iii)

Q. 10 11 12 13
A. A B C C

SECTION-III

Q. 14 15 16 17
A. 3 3 4 4

SECTION-IV

Q. 18
A. A->PR,B->QR,C->ST,D->PS

PART-B-CHEMISTRY

SECTION-I(i)

Q. 19 20 21 22 23
A. B C D A D

SECTION-I(ii)

Q. 24 25 26 27
A. A,B,D A,B,C,D A,B A,B,D

SECTION-I(iii)

Q. 28 29 30 31
A. C C B B

SECTION-III

Q. 32 33 34 35
A. 5 1 3 4
 SECTION-IV

Q. 36
A. A->S,B->P,C->Q,D->R

PART-C-MATHEMATICS

SECTION-I(i)

Q. 37 38 39 40 41
A. C A C A D

SECTION-I(ii)

Q. 42 43 44 45
A. A,B A,C,D A,B,C,D A,B,D

SECTION-I(iii)

Q. 46 47 48 49
A. C B C D

SECTION-III

Q. 50 51 52 53
A. 3 6 7 3

SECTION-IV

Q. 54
A. A->PQRT,B->RST,C->PQ,D->RST
 SOLUTIONS

PART-A-PHYSICS

1) Pressure = =

2)
a + c = 0, b – 2c = 0

2c = 1
b=1

3)

tf = 3 + 6 = 9s
Δt = 3s

ux = = 50 m/s
Range = 50 × 9 = 450 m

5) Distance travelled during time of ascent =

Time of descent =

Distance & travelled during time of descent =

Total distance =

7) u cos θ = 20
40 cos θ = 20

cos θ = = θ = 60°

Range = u cos θ T =

8)
At maximum x–coordinate vx = 0 ⇒ t = 3s. So ms–1 and

9) For two shells to collide in mid–air, they must reach the same point at the same time. Here,
the first shell is fired at an angle a and has a longer time of flight (t). The second shell is fired
at an angle β(<α) and has a shorter time of flight (t–T)

x1 = x2

y1 = y2

10)

ρ = ML–3, G = M–1L3T–2
∴ [P] = ML–1T–2 = ρ2L2G

11)

ρ = ML–3, G = M–1L3T–2

12)

Water is in smaller rate when water at 30° projection stops and get 60° projection only.
T' = T(60) – T(30)

13)

Maximum range of sprinkler is

So area = πr2 =

15) Average speed = = = 3 m/s

 16) AB ⇒

BC ⇒

CD ⇒

average speed =

17)

[F] = MLT–2 = nM1L1T1–2 = 1M2L2T2–2

n=1

PART-B-CHEMISTRY

19)

(i)

(ii) ⇒ R1 = R2 ⇒

20)
x x x

y 2y 3y
Given weight ratio
O : Fe
2.5 : 7

21)

JA13PCMC02SCE

22)

(A) 3O2 2O3

3 mol
= 67.2 lit = 14.4 gm
23)
By observing the values of I1, I2 & I3 for atomic number (n + 2), it is observed that I2 >> I1.
This indicates that number of valence shell electrons is 1 and atomic number (n+2) should be
an alkali metal.
Also for atomic number (n + 3), I3 >> I2.
This indicates that it will be an alkaline earth metal which suggests that atomic number (n +
1) should be a noble gas & atomic number (n) should belong to Halogen family. Since n < 10;
hence n = 9 (F atom)
Note: n = 1 (H atom) cannot be the answer because it does not have I2 & I3 values.

24)

(A) v = 2.18 × 106 × ⇒v∝ or v ∝

(B) f = or f = ∝ f∝

(C) r ∝ n2 / Z [T ∝ ] F=

F∝ F∝
So ans (A,B,D)

25)

Glucose molecular mass = 180

CH3COOH molecular mass = 60

∴ Same mass ⇒ a moles of CH3COOH & moles of glucose.

Hence each atom will be same.

26) Let ; nCuS = a

n–factor = 8 6 10

27)

28)
ratio of atomic mass number

29) Given R =

∴ R′ = = 4R

∴ % error = × 100 = 300 %

30)

8 mole NaBr obtain from

= 3 mole Fe

mole of Fe = mole NaBr =

mass of Fe = = 420 kg

31)

mole of CO2 = =

32) Number of spherical nodes = (n – ℓ –1)

Orbitals having two or more spherical nodes are
3s , 4p, 6f, 7g, 5s

33) (MF = C7H10O6 , M = 190)

34)

gm eq. of acid = Σ gm eq. of base

% Purity = × 100 = 3.

35) A transition element is one which has partially filled d–orbital generally d-block elements
are known as transition elements except elements has fully filled d-orbital. So except Zn all are
 transition elements. 4 Cr, Fe, Pd, Cu

36) n–factor = Total less or gain of e– per molecule.

PART-C-MATHEMATICS

38) V2 = 3V1 – 2V0 = 5

39)

and

40)

n + 2 = 1, –1, 5, –5
n = –1, –3, 3, –7
sum = –8

45) sn = =

s10 = = =
⇒ p + q = 21

]
46)

n = 50 ; I = 7
removed numbers are = 7, 8
GM =

47)

n = 50 ; I = 7
removed numbers are = 7, 8
GM =

50)

Using A.M. > G.M.

(xlogy – logz + ylogz – logx + zlogx – logy)/3
≥ (xlogy – logz . ylogz – logx . zlogx – logy) ...(1)
Let E =
logE = (logy –logz). logx+(logz – logx)
logy + (logx – logy) logz.
⇒ logE = 0 ⇒ E = 1

∴ (1) ⇒

51) Let a = x, b = xr, c = xr2

∴ log6a + log6b + log6c = 6
⇒ abc = 66 ⇒ x3r3 = 66
⇒ xr = 36

∴
and

∴
which is square of an integer only for r = 2,9
∴ a = 18, b = 36, c = 72 & a = 4, b = 36, c = 324
∴ (a + b + c)least = 126
52)

53)
a=2

54)

(A)

Hence, the greatest prime number by which Σn2 is divisible by 41.

(B) 4, G1, G2, G3 ..... G2n+1, 2916

(C)

(D)