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Inorganic Notes (Hija) - 81

The document discusses the chemical properties and reactions of alkali metals and their compounds, including their behavior in water and reactions with acids. It highlights the differences in reactivity and solubility among various alkali metals and their oxides, hydroxides, and carbonates. Additionally, it addresses the challenges in extracting alkali metals and their unique characteristics compared to other groups of elements.

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JOHN JUMA
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0% found this document useful (0 votes)
6 views20 pages

Inorganic Notes (Hija) - 81

The document discusses the chemical properties and reactions of alkali metals and their compounds, including their behavior in water and reactions with acids. It highlights the differences in reactivity and solubility among various alkali metals and their oxides, hydroxides, and carbonates. Additionally, it addresses the challenges in extracting alkali metals and their unique characteristics compared to other groups of elements.

Uploaded by

JOHN JUMA
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© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Nog, t Cl p= Noda | Peodion with Wiregen ANitride arwahion ¥ H 7 Ovly bi ou “ndride_ hr» baled _with Ns Hau ton i t Ns = LinW > kin hyd ral yce Vn waley Ao ant Nay nog nid by iy | _thakivy imll | We Tye +¥s0 —> Hiot + Wy Sut M#Ny ——> Ne poodiow, when MW - cthay afloult onelals | Wty ouby > Idhiwa- hos: owls the ivallat caltonre wine ob al MA aloud uth ft wtrerls trong atleadion to barat af 4 “gator 2 yayulling fo abe guatict Laltece fuigy Whit b Jorg ennugln 4o_ttigpruotie the divou'gtiow ety 4 “Na ond loge paitive econ an involved_}n forming @® Onpes i __ Mayt vaclal_qrom onider dupendin aida : ; Abe witol alow “Ne Caen a gy © a =O) miss A Wonwoal onder 02° _( siwple oxide) _ _ (8).-Rsgride_, On?> — C toyapler ont)” . eas i) Suprvonide Og Cove ‘wnplte ode) Jy the cotton tras ‘alg power tho prroside avd tys_divtorted Yo doom yorwnud oxide. > That why tdlrivw (Li) tows fon» normal onde only ——, ft 0, > Lin 0 Bo. covmot folavite_piroride beonutt of et b polaviae Juptronids, thonyow Na forms norma) oride_a pavoride wy : _ | les 8 | Wo 4 0, —> Noo -- lower Aewuprad uve Not 0; —> NogQ, --- af bavgay Huy rradony - Je Ky Pb and © fit wok polarizing sowtr Calion . Jo they fares norwel oxide, peranide oud Luptroride wy e410, > ako KE 0g 22 BO M4 On orcayy ————> Ky CHEMICAL PROPERTIES OF Oxpes OF Goup Ta. (ll they dyiolve_t_waler to jor _hdrotide whith ow bavic_ Lig! WhO 4Me0 —> avon normal onide M0, t Nao ——»> MOH + Hn0, ~ -- peronidy enele MO, +Ro0 ——> MoH tly0,40, ~~. Luperorido (They aot wah dildt_ouds (HCL, ol Aly) Woda t Wel — > mcla fy0, | M09 4 Nel —> _yncla Hod 409 M0 4 HCl ——> Md 4 PO... We =O | WYDPox DEL _ Hydrondes of altel imebolt aw_hight. y_-batte hay vot witt AN ove te dorm volt cud _ualor _Mot_4 Hel ——s mich, ¢ Boo tg, Root + Hel => Hod! # HO eo WW)! Thee sod with aude onde ike ((0,) Comm with JO), 05 ) 1 Nao + (0, —» Nos(0, ¢ Hed . Ge Oy ty in ex(osd pitarbonale is jonwued ; , AMOR + (0, orcs ——> MH, NB: oth turbonades avd _bitochanafar op alkel’ _welalt_ae tw wat (Ha@o,) ti slightly lull due to high dupove of_peloviratiows heute hala “digit 04 covadeud chor” | Due to ‘ety ally folubldy: TK dhe waa why foOH canneh be wel to tut (OY the (alot), Uvwwndor « Becowe (all) a 41. > Col, + ho _ ae while gph fib Wook + W, ——> Nos, ato = _ : Joludy . Gam Qu: _ Mott {Malt dal toe _alwous raved ip vet tudrorovbor _Jolvaud [ke _Kerasivne oi) “bith woud tha ae 2 in ttirlod -ph_snail_a giv. Atv rpmdoins kyo (14:0) tity gen aed Ua hid a fh all _ Swits_of_notign + . Qe oe ee 4 —© (it) the hybrid 4 dhsli_melaly do not dvcomnone on _tuabtvy onc Hoh whith Aitoaayora $e bind due do _highey diye} ___Lpoloviaotion - " - ' = f 4o,__kioh —;—> 13,0 4. Ayo A _—_I Mow A> No wodinn __| = aliali itll 2xtvok li ~_albypennes i Alkali vwietaly ydiyo witli o dorm barre hydridai whidi_work wd water fo dor Injdronide« ~ bout hydrariby MH 4 Ayo >" M08 A CALBONAICS > Atkal’ metal carbonates do not deovapyse_¢ heafivy 4 Thyy bave |Lhigle Awennal dabliy) dv 4o low Avge 04 _polovioadion pF age AiO, whch dupyapat a on healing fo form bird dus to high deque oj polaridaliow - Au y a | hil0q ——>_Lij0 4 Bro" “co, Bub 00, > Mo wodton + 5 | BICAPBONATES _ (HO hay hare i_polartdabi Day than (0,7") _ I 1 > Bicorborat og “alkali metal decoinyese on beating fo etm carbo fo ylativdy highie deqae ation thon in darborake —— dat te labs hither tga of eelatilion_Hon-iv reora! CRO," ty Lovqey ~ anton’ Hray (0327) As . 2 treept_1ie05 haya b_dugitt_o, polarization at tht_nuuft —|siwallar cateonee and Farge anon hewte it dea even oud at Lot Anmperad av Sage i a rs L2H tan pattie Aequcoe Jolulion due to ablontion try, tas = ~~ Lhydratlon pro =O WWW g_ a> Ma (Oy + Oy + HO = Alkal’ uncle! 2rceot thu: LLRs, > Lip, + HOt Oy | dup bigs, > hy dstovaparh iow = | (sable) &) NMiRAies | The _ndeaha oy alkall _polurigation onwog Mie vs wito,’ 3 no, £Op | nitvale _Cathrites vtghle) whine tn _abeltyuatal vcopt_bi Excapt dor hing Livy > Litt, 40, aN, ‘the, Lil, a> 0 + Ovo +0] a Liable Oveyall_yrm brown fumed - | bino, x? biO tO, toy fe |_ ABYSS OF ALKALI MGIAL To FORM COMP) exs —__>Alkali metal do not awlen Remon 27 How aint org (wt = boxe Lingle posthiv chorgs) v forge alow dhe Ansregoxt they ctimet tld! Ligaydl thay 2 Yiojoq why alvalt wmelaly do yet pan wil di) Neo? whly tweak datvogauttve_wachl Uike AU) do. t AMOMALOW PéMayiOuD! GF TIRCT Memgee OF éAca trPoug_« deklt_bo} sanalays behoviowt from other qtoup_tnsualedre Gray wviey_ gov dewmiwt (ow top) 4 eush fiw in fined, DYewows : = vty y hued wall alee “fini law w tay fhoys aaa ete ve They have_h nigh to onizodiow ety vy No ausilab iby of b eld Viiv warts with -teygrn to norwat oxi rae ‘Lmebals av diyivul + : DFE RENCE bin Lifaiwah_AN_OTNED. ANwali” wolali — { Arowalos paste mM [dhru va wi, — > b40 vowly ! Not Oy > No,O ond Mat OQ, — > No.0," GW | (Wns combine with nicogen to give_Lithivia ia while eid: | Lit Ny —— "big while ; ‘| Ma Na —> No ren ° Gi) (ouponncl cn Lithivnn ust bow hina ill -cowapoved-40 thot of- fey qlkal’ waetals « a ty (i0h =e 0 eo Mob E> _No-wodiew. “Tl : i | ‘ : he QI Gownound oy Have wore covalent in characte than thise of oho || alkali _yaab - strowal y tow'c A LOH aw iy volube in wale LiCl 8 Jobuble ty argu solveug -ujlilé “thlarddly larity of oboe “|| ay tnuobulde F | Lio wy _weakew | tir - WV Vahiuya has hh wt and bP (fh aha alkole vichd | =e ow, dept Loin BP gard tsp e O . ! (Wau — dibontfe sore hylcded cnysols Atiel BUOY Mo | solu while_glver group duuburt fro auhydross : : ! _ | _ DIAGONAL _ ReLATionssriTP Te dno thualanby tw propartres bdween the grat elo sj he_group aud tus deand dewaev? 4 thy wort qroup towwidey _ Group ta Oe a Wa | Peeron 9 Wi be c 8 | eon 8 Ne My OAL Weull tone utr % dhog owl suladacwebva 18) Sdueyn Ltidwe oud Mod west ' @) Belueen Be ane M: . (it) B oud gt Coupes [Reasons of diogoud) vdlatiowglat Gt {tudo dachamugadihy Gi) Stuer oforure wads (i) findlow LE (we) Stoubow’ itachi sutlor charge . | De relations’ belwaon bi aud Mg | rile “pllour'g_aue_the puoptitied Hutlar grow beth 47 aud Mg (\ fath woth with Nagas te give arvitt . a keth, => ban ‘ My tWa » Mga . PR hay bell gor nevwol_ertle poy te, Lich. PAO Civoo. male CrrO May 4g ——> MgO =i (Wd They ont Tuhonidat ke Cott). ond wat, a wnaber baer Fae th ir od Ben I vot exe? ot row Aeurpuod ue “UiW, zr, +O by Mo Cato), Mls + (On 4.0 | the Corewate ay but kt aud Mg decvyapates ow bbb to jor onide Htn(0y a? bizo 4 (0, MeO, —RR> MgO + (0, “| DIFFICUVAes MUN eked IN EXTRACTION OF ALKALI MeqaLs (J the alalt metal colon cannot be dichorgd at cade Mad ! hdroyon ton will. Gi, iat ital” art Conger afuchopastive Tend ‘they, a: be easy 7 Lrphoted by cured frown thety ons. i 20 +c —— fet lo Ma +: —> No van. Coup TA GLemMeNnyEs - Eleunewd Aounte wawber J. be Be [- - i : e a cic sw 2 alafrowe iva || Ge we eo our bq $e a dw) pd = Bh = dub yp 8 coumete + [Mele aot sustae balean_ogton ie pale pv Mg a Bo soll: do’ not pe “pochive_qlame tact - eho: at the “lale cout wwutal av uhiny Slvey = gray aloud oy) tr alfaline earth's val tae ghee Me aud BP. fusstare! to there 1 8 tint” atl wattah! CHEMICAL: REACTIONS 1E ALEALIIOE -QNRTH eral othe vagcttudhye oe aout yelal Inewenger down” day group duo to t f (wwiact in ie : (o)| Reaction vara Wajeb. : » >The weartiuty of eof sical i gownued trail wang, oud the joder a slows adto satay owing ae 0 sat | ¥ bee doar not rend with old wakes | or ius Reavers’ : _ > Be has very Laree yet outa afien . eueryn ining bet > be tors harae of Be whedh "ats futlao E Be ull wotny : fo Be + hO > {20 Tau. ai ee oe dhawn DY ¥ Mg _voads Chuync) with geo Ao jor Hye bud soa Neat wot cold watev « We, £ B00 fy a? _MYPc + Reg) ith Abia’ CL foumed ogfev wow pou ix Ma 4 He aie No yews fan at vO) Se, avd bo wot with ld wat to ‘fon hyd Nonden Qu Hao Matt fad gy => M M(H) Cony + Bagg. oat whow Ms to, dy or do ‘Beacon _10 ah Dake acl a Dip Hse Peodtion wih dil Het >A gio fa dove ud _yeorks wal dl to Llber excep Ge wahitle doe not reac’ oth dil Hel due 46 dy ox'dafiory polodeal ats _wsult op Ay vty lit nf towinagr owirgy ey Bo to Be fo __-be_& Hl (oat — No “rey: Sub SM tiel => Mel + He who “wero allatine eaifhl metab ; xttoel be Qeadion wer dil HO “t v Set AlOy —> No vey v Ma Wtherafas dy gas more reactive than Ma i> Tas BS boeccus form idoluble tulphae_whith futlasrseadton_ey the is Mg gy t Belg —> ihe@®t Hao vta/fe and Bodo pol pod wil dite iy alah aw a 1 Selubod thy Of sulphate dyn cr kon alice unermy and | ee by aration energy. 4 hyalina? > laflies ony > Solulaildy be oteuy. - _ ~ oe 8 Boye SeI0g aud ( ay tug fat hud _ horge ches og Bat trtt gud (att (fects Vari, CONC _HNOg, AMD fonte Hide CU Bets vended passively bot atid fase: to “goneandio oe _pvetuctive hho oy $e)" _ ‘the ee. modal wads “eiduatng acyeute A pouee they aw oxcelloed’ Tt ME RNG gag), NGA 20 TAG HulOy ——> MM f Op + Hrs whi Si at Tnause they 0 Veie suudhing 2) ~ invcluble sulphates Sh yeaddow 4 _tont Gilde with Ine otal dye to Luly onal spouse uy thy, at» “low en oly pve ed Malo peo pouchaly @Deerction. with Diluie Maow: ve Re. hast ‘abil iby e_fowailag causfe due dots gual “tiae fhan all surf’ quieted ttt fl reorks_witte_dil- NaOH | OL Complex so F : ae ee -e 7 Bef Wood + fo ——> Hagl BeloH)a T+ Mat | Bud, ctluws donot of they haw large afer and an fom | cour ! | MDI Hoot ——> Moray (2h Reaction wis Aifeogen_ 4 Mifeibe foe ATONS 7A sodttly usta Con towbine wll “Ms gas fo all Peosevs ! . _ v they haw’ gualler_caften'é radius . - v te [ee fete chars Ga) —_ Athy a Lhe ir cl Me enough toc f deco yogi rie Ae and. Wi dio cate Joualo yuerqy 0 oll ie, Mt Ms _— Hus i aac Mg opel lost Os A) Rerciions wna warousrs —_ 2 bod wit hatogene Ae form tome hobiles _ercegh Bor which 1 —Leovalevd huttdes. — —— i1_te Bo 4%, —— Ger, = ovals — Mot X_ ——> Ma — Tome JELected — tompountdy oF eApTH mesALs- (@)) Oxipes. : : coer ee a re ERI —1M4 avd fo gov noiwiel ontlat uly what x baw _ | “ey Mgt 0; ——> Mp0 I~ fe and Bo toa form normal otile end plontdey = | ie oe tO. = dO roma! onthe> a ee a Li thay su ite waist te gia bare hydiondat 9 Mg0_ 4 Hv0 ——> Ma(ott)s =~ =~ onal onthe Gis_t Hoo —> Ir, 4 Bea === _poponid_ CW) thay read wits dufe avd Coq cel A) nie eq = Mg0 tHcy)” —> Moth, + uo -—= boul eb 4 A ey Fitts th, ° @ Aypeonipgs Belo), te ning, — | onl elot), tf IMaCH —> NogbeO, tH ose Belo)» + WA —=> bell dro sah iw Beall brand, awe bewie tt | mes thd —> mgt ho ys Wudronvelos 4 gueve Ua decernpars en eteg ed wilot)s a NOt Oo <= S 2 T) s:TGszpnwcltaapt id eeaeemmenncat than the “alin b— Oltanomes Lv Bela. _ts highly uudalls ape Be(oti)a huh | Getta PRD —> Before + He v thoy bydrorider ants volal! 9 vq Cally tO +> Ca ot)s + He (A) Ceopowntes : |e thay ola vue fo w (ao, + zen | > Thun devo hoahis MO —y> MO t On (2) NiaAtes |_> Derouaperes “on Lafing ‘te_fornn’ ones : M (N03), > "Mo NO, Oy (i [Bien CBonnte.s > Biro vowels oy. eat mefalr do —— due fo _unjhaf ywsudt op i din larisadjon. Ly, MUBOs),. SM, +O, t He ‘Qad iv acqueows solv | mt HCO) 3604) ence —H0 .cvtouspottnn + i to te : ' feges Wl APRDSES |The: wot tomo caroide. lowe G* GP brow dose toa polaripe LG tual carbicl? | Lie oy walielo. vhructutnd Of abl bet ces Boal | T_ tedhoy pouwtaiiny tow (east Ge to CE > Mow wat las poling ow | wat C2 5 My degC TiO —> CHee + Bod AlyC, * oo — > Che + AD,0 Aloae_wilh (yoo for Dhyne tq__ Colo 40 —— > CHEcH # Caton), | te 4 pie _svasiatiag (Sot, Mot, Sve ) hydralyte bo jor” wothane a [ealonipes Oey - covaleud ost aye four =Melculae utrurtwd oy Modes Jel — _polyuna 1b a iT oeeh], ne ath thevides hue the gjoud wate oud — pei te is wey. ee salad RO ——> Be (ot), a A alive yo hydichys egw divolva to jy_oW + |__-APPLLcaTont OF qeou'. OA Clements (o)_ be iuysd ob dayl_ so 10,2» (0,", $057" avd Ca0y* The ‘olufiow —rovtotwi da 2 wwvaly dull avd Bo (Ms), ov ote aniowtt ret gou_prurvee of 0g?” , 40, ?* (0,8 amd GOe* |» Soy? ajuda while gg of dol hal is -Tivolwbe tu Act on GS ig BolO4 "+ Hel —» No OXY vWF glvss twlaitt_ppk 4 Hots ulatle O Soluble jy Bel fend walvivng | v_ SOge- Sat glut wlute tt gy Sols whith quivolubly im LAW oud 1 id fox oloyclews —gou_snneling. Nhe buodt_wadehet__ ol je, BadOg + rz — atl tit Hel = lv y= oralade giv’ while hy Bots whith th whl with ro i ai_tvolved = : at Basta Oe EAC) = bal + Arle oy orale atid) Moly as a dah ial ted in with bi No, and J ‘Mall(Os, - wm M0 tt ts odd 4 1; Noy6Oy white _pgh oF My ls pe do —! iy My + NoalOs oq, Ma (xe) + Nosdgap— ———— | * Jrucluble white pe: op - a he Mg S04 y odded to NallCOs , ne jonwadion op phe te Nit ava rate + aay = == Wg tat and horcltt_op fi oy water | Hace water confor neg a mately (a St can be | 7 femporary bade 2 Fp al ; uid b [solute (aH), and My (HO v Pamonod thadyw + Type ; waker_hardvas dut to afd or ‘chlorides oy “Wy rl Mgt t EXYPASION OF MAGNE,IUM FROM Moda 1M eA Winfe2 » © > Ma erty in My whith wv goluble Mm dea wader fly to vecover Mg j QV Mach + Coot), or. Nudh——> Moat, Ca > frog © a (ni ava vist) (-tiqge unter) while got CH) Ahgfota F ACH ove > Mach tHeO » (Pave mtn Moth: ay alvthvolya) te Down’ coll to ebforh pure_Mg. “it M_tadhnds 2 My? ¢ Be —> Mg nl HF i th ately | ; — { oui rele - Mad L ABILITY OF C60)H METALS fo form comPLEnes 12 Ovoup fla donot gon cowflutes_extepk Be whic gonny wt roordtdation puimber af : vb hay smal awit sud / eon ste thal) why 1 neevences_ ai “Barium AND one. Rou wemgees hs (ANOMALOUS pPOPERIIES OF: Be). (D4 dar tot vent vith“ water hte othe tnuberdo (TE tap don _coonpleres wile _ottaee comet (ib Th cawide 4 Seah rear with water 10 yom radon : —— dy tabides af ner _onuonburs tera _athyne 4 | ie WW) (wi) xii) (ia) | I =—=© COT e rutile, he laid (Bulle) can_uvde o_aicorthon Yo —— Hoe _polywaer "in (Betts) while thlovider_o)_othew OUb weber — | Has chloride ( Lenewehir dg lo_nok eects! - alls) hydichyse_ tn water wolale —chlovede 4 tine ‘ong Hs ts, Beta + Jta0 = bilo)’ + ond Gut 4 |___Mila + Ho — > May + acl” axils gud hydiclyie oy thet ashen ave louie Mis havdoy ate Mgormas mainly covalut ipa (24 Seth) whle other ‘tnewsbery fort matty “fone ted (eq “fady) safe. At cannot _towbine eltvedly “tata Baggy fo dor hydride , dw wmembis do» : D/AGONAL DELATIONSHT® gefweeN papyzi runs AND ALUMiniuM . : ose ad hybone 480 and defo) are_auughdvitt_whle L_figher MHP “gud §-P that ones -qieup DA tows als (i) Tap beth gor) howe e _qnybelnte ori _grd pda Thy hth 4oun _fovaleut _chlovilay AAbtls ond Belle } wlth hyo lye | Ih_watoy - _ v Ald, 4 3.0 —o> Al(OH), + Bic} _ v beth, t 2410 —> ge (os 4 ane) ‘They ov —ballr_sondered_pautve by cone HNO,” > si fz, Ab Aone HNO, —> flQ tM tig ——Inuoluble_protecting foyer —— 80 t+ NO tO Be A cove HNO, G0) hy or covalutt: # chlorides whore rvolnwler con tin ru_po philo Hil orws dior tt Ctl ins 800 | aah, Danie, ai, - a f J (wil) iu hava turbidas Lilet; aud 9.) whit oot io ud Ao y-vntdlnane able qari op = Be (oth «Gat. + oto A> Bed t tHe os geile sgcve 04 PLlOH)s t Sel “Ta Th ‘kdl vod uit Alu Nol sell do four ‘plot ond th gal “ul vided Nod dy) —>- Noy [De (ot t 2 () 4 v AL + NaOH dd > Ma [ALCot)« | + Hag) EXAMPLES: 7 1 Arrange the yellow vig (oCls; dolls, Math, drth Gi, hell Ot initeasig font tharodoy » T Wink! Ma/ ahnoet all Lond aywlomie > ese drow op 7 {iat Aout gar dt fechoweaaties thie, Ia_< Mach cacl. _a Arrange pata ll ha) Fst aco clewtoses ally menage ua cbonagol . a oy ese gd Jn ie mare Ori highly bande ts She HO pI 00 4G a ee te Wecbopartve nt tues) ; / DIAGONAL “RELAFiOntN HIP Ss tu dusdliratly wundy jn _proptitins Mins qinat alwasud tn a ~Saiadd ane gisup oud Anes seco oA yo St 2 the aa he pepe oy leone) pra dh Dogan) velalisship-onur Gravee Alay ead han! =_ ) Giualloy gshou! ina pow (i) | Siwalon dectrones at tushy vol ag LO) _ hath touisotion energy (tv) wile epfedive wudear cha iv) Sivan Malomte-ties (re to 24g Yux_= 122 pra, Cwg.t dom, Yae 758 pm,“ Far_# 1443p») ‘Maree importous dugg owe a) toda aud Mogutaitu vw (a) (iw Ou ful |G) Bovon avd chron aby | Paved a ul Be g C Group $4 - Group Ha: top Die Coraup Wa \ ‘hey Pevi'od 4 Wa Mg AL ca DIAGONAL PELATIONUHIP Séiwi@eN Liftivng (Li) AR) MAGNESIUN + both tombtne with otygen_go 4o_orw nonuas_exife uly fo Alig 4 On =. DLO fa) Magra _t Ox, 31M 0c (ihe fe (therate iy” . _ fe Goth vead_with witeogen to dorm _nivider whith rad uit water bhigy + Sap ents ALN car : Nga: > Yay _—> Mate Go IL my tt, =x wot tWade (ii) he vilirale sn oy both Li and Mg ou Ih dianilor aags. on heetiy eh oride RO,_at avd 0 —————— ify LIN, — 150) + ‘Aig, 10)

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